CN113605144A - Preparation method of opened paper based on wild goose bark fibers - Google Patents

Preparation method of opened paper based on wild goose bark fibers Download PDF

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Publication number
CN113605144A
CN113605144A CN202110861977.2A CN202110861977A CN113605144A CN 113605144 A CN113605144 A CN 113605144A CN 202110861977 A CN202110861977 A CN 202110861977A CN 113605144 A CN113605144 A CN 113605144A
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paper
goose
pulp
goose bark
drying
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CN202110861977.2A
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CN113605144B (en
Inventor
刘鹏
杨光辉
闫玥儿
陈刚
黄艳燕
黄宏健
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Fudan University
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Fudan University
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/06Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
    • D21B1/061Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods using cutting devices
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C7/00Digesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F13/00Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
    • D21F13/02Making hand-made paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

Abstract

The invention relates to a preparation method of a cut paper based on wild goose bark fiber, which takes wild goose bark as a raw material and is prepared by the procedures of sun drying, soaking fermentation, retting, coarse pounding, alkali cooking, fine grinding, size mixing, paper fishing and paper drying. The method has the characteristics of high efficiency and short time, shortens the production period and has the potential of being suitable for large-scale production.

Description

Preparation method of opened paper based on wild goose bark fibers
Technical Field
The invention relates to the technical field of papermaking, in particular to a method for making a paper made of opened paper based on wild goose bark fibers.
Background
The paper making technology is one of four inventions in China. The use and value of paper has taken an important position from ancient times to present in the history of human development. The requirements for the nature of the manual paper are different in different fields of ancient book restoration, book improvement and reconstruction, painting and calligraphy art, and gold stone propagation and development. Therefore, the hand-made paper with various varieties appears in China historically.
However, there are historically several kinds of handicraft paper making techniques which are evergreen in name (such as Kai paper, Xuezao paper, porcelain green paper, etc.), and the printed ancient book is scattered around the world, and the ancient book version identification and the cultural relic information record lack specific description and uniform name designation of the used paper, so the finishing and identification of the ancient book printed by the ancient paper which is lost are a big problem.
Among the lost handmade papers, the developed paper is considered to be one of the best Ming and Qing ancient book printing imperial papers, the paper quality of the developed paper is white, soft, smooth, fine, free from curtain lines, thin and tough, and has very high historical status and cultural value. Therefore, the manufacture of the high-quality handmade paper is an important problem to be solved urgently at present, has a promoting effect on the technical reconstruction of ancient paper, and also has an important significance on the development of related subjects such as the arrangement, protection, utilization and the like of ancient books.
Patent CN105544282B discloses a paper making process using paper mulberry bark as raw material, which comprises, first screening paper mulberry bark, soaking, boiling in a paper steamer, rolling, adding quicklime for a period of time, then boiling the obtained paper mulberry bark in a paper steamer at high temperature, washing the obtained paper mulberry bark to remove lime and impurities, rubbing and peeling, cutting the peeled raw material into thin pieces with a steel knife, mashing in a stone groove to obtain paper pulp, finally pouring the mashed paper pulp into a paper groove filled with water, stirring sufficiently to make the paper pulp form uniform suspended floccule in water, then making paper and squeezing, sweeping, drying and uncovering wet paper with water, however, it is not directed to the making of paper, does not have the advantages of traditional manual paper making, and more importantly, in the bark fiber as the paper making raw material, the width of the wild goose skin fiber is smaller, the length-diameter ratio is larger, and the wild goose skin fiber is more flexible; in the cooking step, the time is shorter, the temperature is lower, the bleaching step which is originally required to be independently operated is completed in one step through the combined action of lime and hydrogen peroxide, and the production period is greatly shortened.
Disclosure of Invention
The invention aims to solve the problems and provide a method for making the opened paper based on wild goose bark fibers, the method takes the wild goose bark fibers as raw materials, the opened paper is made by the processes of solarization, fermentation, alkali cooking, beating, medicine adding and the like of the wild goose bark fibers, the method has the characteristics of high efficiency and short time, the fibers can be simultaneously cooked and bleached within 3 hours at the temperature of not higher than 100 ℃, the production period is shortened, and the method has the potential of being suitable for large-scale production.
The purpose of the invention is realized by the following technical scheme:
a preparation method of opened paper based on wild goose bark fiber is characterized in that wild goose bark is used as a raw material and is prepared by the procedures of sun drying, soaking fermentation, retting, coarse smashing, alkali boiling, fine grinding, size mixing, paper fishing and paper drying.
A preparation method of a starting paper based on wild goose bark fiber comprises the following steps:
(1) preparing materials: drying wild goose barks in the open air;
(2) soaking materials: soaking the obtained sun-dried goose bark in water;
(3) cutting: cutting the soaked goose barks;
(4) retting the pulp: putting the wild goose barks into a retting pool, and pouring plant ash;
(5) coarse tamping: pounding the goose barks subjected to the retting treatment directly until the fibers are loose and separated;
(6) cleaning: washing the mashed pulp;
(7) and (3) cooking: putting the smashed loose fibers on a steamer for steaming, then adding lime and hydrogen peroxide, and steaming again to obtain paper material;
(8) fine grinding: finely mashing the paper material in batches to form fine pulp;
(9) size mixing: pouring the prepared pulp fiber into a paper tank filled with clear water, adding the cactus juice, and uniformly stirring by using a wood stick. The cactus juice is a natural high-quality adhesive, has high-efficiency adhesion effect among fibers, and improves the strength of paper.
(10) Fishing out paper: firstly, flatly placing a bamboo curtain on a paper fishing frame, extending into a paper groove, and tucking up from the water from the outside to the inside to obtain wet paper sheets;
(11) drying the paper: drying the wet paper sheets together with the paper frame in the sun;
(12) uncovering paper: the dried paper sheet is fed and finished for use.
Preferably, the wild goose barks are sun-dried in the open air for 1-2 months in the step (1).
Preferably, the sun-dried goose bark is soaked in water for 1 month in the step (2).
Preferably, the step (3) cuts the above-mentioned impregnated goose barks into sheets having a length of 20 cm.
Preferably, the loose fibers smashed in the step (7) are put on a steamer to be steamed for 2-4 hours at the temperature of 80-100 ℃ for the first time, and are steamed for 1-3 hours again at the temperature of 60-80 ℃. The first cooking is to remove air in the capillary pores of the fiber raw material through the steam permeation, the cooking effect is poor at a low temperature when the temperature is lower than 80 ℃, the effect on the pores of the inner layer of the fiber is not good, and when the temperature is higher than 100 ℃, the effect can be further improved by continuously increasing the temperature, but the energy consumption is wasted. The exhaust function of the first cooking also lays a foundation for the second cooking. Meanwhile, the temperature of the use environment and the action efficiency of the hydrogen peroxide are both considered, and the control at 100 ℃ is more suitable. When the temperature is lower than 60 ℃, the pulp cooking effect is poor, the pulp is still stiff and is not easy to form pulp, and when the temperature is higher than 80 ℃, the decomposition of hydrogen peroxide is intensified, so that the effect of bleaching while cooking can not be achieved.
Preferably, the lime and the hydrogen peroxide in the step (7) are added in an amount of 10 wt% of the mass of the slurry. Lime has the functions of steaming and boiling the medicament and adjusting the hydrogen peroxide environment, and compared with the dosage of 20-50 wt% in the traditional hand-made paper production, the dosage of the medicament is relatively less.
Preferably, when the paper is fished in the step (10), the bamboo curtain is firstly flatly placed on the paper fishing frame, extends into the paper groove, is bellied from the outside to the inside, transversely and violently shakes for 3-5 times, and stays for 5 seconds. The operation makes the fiber have orientation distribution in both longitudinal and transverse directions, and eliminates the anisotropy of the fiber.
Preferably, in the step (4), the plant ash accounts for 20% of the mass of the pulp.
Preferably, in step (9), the cactus juice is used in an amount of 5% by mass of the slurry.
Compared with the prior art, the invention has the following beneficial effects:
the opening paper manufactured by the method has the advantages of the traditional hand-made paper, is suitable for large-scale production, and has good artistic value and social and economic benefits. In the aspect of process, the wild goose bark selected by the invention is a good papermaking raw material with developed bast fiber and larger long diameter. The effect of the subsequent steps is improved by adopting a mode of cutting firstly, the unevenness of the cooking effect is increased by overlong raw materials, and the fiber length is reduced violently by overlong raw materials after cooking, which can cause poor paper-making performance; the optimized fiber length is adopted, a slight retting treatment is adopted, and a rough pulping step is adopted after retting, so that enough alkali can be ensured to act on the fiber through infiltration; lime and hydrogen peroxide are adopted for treatment in the cooking step, the aims of cooking and bleaching are achieved in one step, in the conventional manufacturing process, unbleached pulp is obtained after cooking, a bleaching section is required to be equipped if the whiteness is improved, more treatment processes cause more damage to fibers, so that the alkaline conditions and agents for cooking and bleaching are considered, the lime and the hydrogen peroxide are selected for treatment together, and further, the cooking temperature is controlled below 100 ℃ in cooperation with the use temperature of the hydrogen peroxide, so that the aim of one-step pulp-forming bleaching is achieved; the whole process is controllable, the severe cooking process is replaced by a plurality of relieving steps, the advantages of the traditional manual papermaking are well utilized, the production period is favorably shortened, and the potential of being suitable for large-scale production is realized.
Detailed Description
The present invention is described in detail below with reference to specific examples, but the present invention is not limited thereto in any way.
Example 1
A preparation method of a chopped paper based on wild goose bark fibers comprises the following steps:
(1) preparing materials: peeling off goose barks, scattering in summer, and drying in the open air for 30 days;
(2) soaking materials: soaking 5 kg of the obtained sun-dried wild goose bark fiber in water for 1 month; the water surface needs to submerge all goose skin fibers, and the water is replaced for 1 time in 1 month;
(3) cutting: cutting the soaked goose bark fiber to 20cm in length; the short pulp is not suitable, and although the short pulp is easy to be mashed, the short pulp is more easily subjected to medicine during retting and cooking, and fiber damage is easily caused;
(4) retting the pulp: putting the wild goose bark fiber into a retting pool, pouring 1 kg of plant ash, and retting at normal temperature for 15 days;
(5) coarse tamping: directly pounding the goose bark fibers subjected to the retting treatment until the fibers are loose and separated;
(6) cleaning: washing the mashed pulp;
(7) and (3) cooking: loosely putting the smashed fibers on a steamer for steaming for 3 hours for the first time; controlling the temperature at 95 ℃, and then cooking the mixture for 2.5 hours in lime which is 10 wt% of the mass of the slurry and hydrogen peroxide which is 10 wt%, wherein the temperature is controlled at 70 ℃;
(8) fine grinding: finely mashing the paper material in batches to obtain fine pulp which is very soft;
(9) size mixing: pouring the prepared pulp fibers into a paper tank filled with clear water, adding the cactus juice, and uniformly stirring by using a wood stick; the using amount of the cactus juice is 5 percent of the mass of the pulp;
(10) fishing out paper: firstly, flatly placing a bamboo curtain on a paper fishing frame, extending into a paper groove, and tucking up from the outside to the inside, then transversely and violently shaking for 3 times, and staying for 5 seconds to obtain wet paper sheets;
(11) drying the paper: drying the wet paper sheets together with the paper frame in the sun;
(12) uncovering paper: after days of drying, the opening paper based on the goose bark fiber is obtained.
Example 2
A preparation method of a chopped paper based on wild goose bark fibers comprises the following steps:
(1) preparing materials: peeling off goose barks, scattering in summer, and drying in the open air for 45 days;
(2) soaking materials: soaking 5 kg of the obtained sun-dried wild goose bark fiber in water for 1 month; the water surface needs to be submerged by all goose skin fibers, and the water can be replaced for 2 times in 1 month;
(3) cutting: cutting the soaked goose bark fiber to 20cm in length; the short pulp is not suitable, and although the short pulp is easy to be mashed, the short pulp is more easily subjected to medicine during retting and cooking, and fiber damage is easily caused;
(4) retting the pulp: putting the wild goose bark fiber into a retting pool, pouring 1 kg of plant ash, and retting at normal temperature for 15 days;
(5) coarse tamping: directly pounding the goose bark fibers subjected to the retting treatment until the fibers are loose and separated;
(6) cleaning: washing the mashed pulp;
(7) and (3) cooking: loosely putting the smashed fibers on a steamer for steaming for 2 hours for the first time; controlling the temperature at 100 ℃; then stewing the mixture for 1 hour in lime which is 10 percent of the mass of the slurry and hydrogen peroxide which is 10 percent of the mass of the slurry again, and controlling the temperature to be 80 ℃;
(8) fine grinding: finely mashing the paper material in batches to obtain fine pulp which is very soft;
(9) size mixing: pouring the prepared pulp fibers into a paper tank filled with clear water, adding the cactus juice, and uniformly stirring by using a wood stick; the using amount of the cactus juice is 5 percent of the mass of the pulp;
(10) fishing out paper: firstly, flatly placing a bamboo curtain on a paper fishing frame, extending into a paper groove, and tucking up from the outside to the inside, then transversely and violently shaking for 3 times, and staying for 5 seconds to obtain wet paper sheets;
(11) drying the paper: drying the wet paper sheets together with the paper frame in the sun;
(12) uncovering paper: after days of drying, the opening paper based on the goose bark fiber is obtained.
Example 3
A preparation method of a chopped paper based on wild goose bark fibers comprises the following steps:
(1) preparing materials: peeling off goose barks, scattering in summer, and drying in the open air for 2 months;
(2) soaking materials: soaking 5 kg of the obtained sun-dried wild goose bark fiber in water for 1 month; the water surface needs to be submerged by all goose skin fibers, and the water can be replaced for 2 times in 1 month;
(3) cutting: cutting the soaked goose bark fiber to 20cm in length; the short pulp is not suitable, and although the short pulp is easy to be mashed, the short pulp is more easily subjected to medicine during retting and cooking, and fiber damage is easily caused;
(4) retting the pulp: putting the wild goose bark fiber into a retting pool, pouring 1 kg of plant ash, and retting at normal temperature for 15 days;
(5) coarse tamping: directly pounding the goose bark fibers subjected to the retting treatment until the fibers are loose and separated;
(6) cleaning: washing the mashed pulp;
(7) and (3) cooking: loosely putting the smashed fibers on a steamer for steaming, wherein the first steaming is carried out for 4 hours, and the temperature is controlled at 80 ℃; then stewing the mixture for 3 hours in lime which is 10 percent of the mass of the slurry and hydrogen peroxide which is 10 percent of the mass of the slurry again, and controlling the temperature at 60 ℃;
(8) fine grinding: finely mashing the paper material in batches to obtain fine pulp which is very soft;
(9) size mixing: pouring the prepared pulp fibers into a paper tank filled with clear water, adding the cactus juice, and uniformly stirring by using a wood stick; the using amount of the cactus juice is 5 percent of the mass of the pulp;
(10) fishing out paper: firstly, flatly placing a bamboo curtain on a paper fishing frame, extending into a paper groove, and tucking up from the outside to the inside, then transversely and violently shaking for 3 times, and staying for 5 seconds to obtain wet paper sheets;
(11) drying the paper: drying the wet paper sheets together with the paper frame in the sun;
(12) uncovering paper: after days of drying, the opening paper based on the goose bark fiber is obtained.
Comparative example 1
Compared with example 1, no cactus juice is added in step (9), and the rest steps are the same.
Comparative example 2
In comparison with example 1, no hydrogen peroxide was added in step (7), and the rest of the steps were the same.
The results of the physical properties of the paper portions obtained in examples 1 to 3 and comparative examples 1 and 2 are shown in Table 1.
TABLE 1 Performance results
Example 1 Example 2 Example 3 Comparative example 1 Comparative example 2
Whiteness (% ISO) 90 88 85 89 56
Tensile index (N.m/g) 99.8 91.4 87.5 74.3 95.3
Comparing the properties of the papers prepared in comparative examples 1 and 2 with those of the paper prepared in example 1, it was found that the tensile index of comparative example 1 was greatly reduced without the addition of the cactus juice, since the cactus juice acted as an interfiber binder; in comparative example 2, when no hydrogen peroxide was added, there was no bleaching effect, so that a drastic decrease in whiteness was exhibited.
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.

Claims (10)

1. The method is characterized in that wild goose bark is used as a raw material and is prepared by the procedures of sun drying, soaking fermentation, retting, coarse smashing, alkali boiling, fine grinding, size mixing, paper fishing and paper drying.
2. The goose bark fiber-based opening paper manufacturing method according to claim 1, which is characterized by comprising the following steps:
(1) preparing materials: drying wild goose barks in the open air;
(2) soaking materials: soaking the obtained sun-dried goose bark in water;
(3) cutting: cutting the soaked goose barks;
(4) retting the pulp: putting wild goose barks into a retting pool, and pouring plant ash;
(5) coarse tamping: pounding directly the goose barks treated by retting pulp until the fibers are loose and separated;
(6) cleaning: washing the mashed pulp;
(7) and (3) cooking: putting the smashed loose fibers on a steamer for steaming, then adding lime and hydrogen peroxide, and steaming again to obtain paper material;
(8) fine grinding: finely mashing the paper material in batches to form fine pulp;
(9) size mixing: pouring the prepared pulp fibers into a paper tank filled with clear water, adding the cactus juice, and uniformly stirring by using a wood stick;
(10) fishing out paper: firstly, flatly placing a bamboo curtain on a paper fishing frame, extending into a paper groove, and tucking up from the water from the outside to the inside to obtain wet paper sheets;
(11) drying the paper: drying the wet paper sheets together with the paper frame in the sun;
(12) uncovering paper: the dried paper sheet is fed and finished for use.
3. The goose bark fiber-based opening paper making method according to claim 2, wherein the goose bark is sun-dried in the open air for 1-2 months in the step (1).
4. The goose bark fiber-based dissolving paper making method according to claim 2, wherein the step (2) of immersing the sun-dried goose bark in water for 1 month.
5. The method for manufacturing the opened paper based on the goose bark fiber according to claim 2, wherein the step (3) cuts the impregnated goose bark into a sheet having a length of 20 cm.
6. The goose bark fiber-based opening paper making method according to claim 2, wherein the smashed loose fibers are placed on a steamer to be steamed for 2-4 hours at a temperature of 80-100 ℃ for 1-3 hours again at a temperature of 60-80 ℃.
7. The method for making the opening paper based on the wild goose bark fiber according to the claim 2, wherein the lime and the hydrogen peroxide are added in the step (7) in an amount of 10 wt% of the mass of the pulp.
8. The goose bark fiber-based boiled paper making method according to claim 2, wherein in the step (10), when the paper is fished, the bamboo curtain is flatly placed on the paper fishing frame, extends into the paper groove, is tucked from the water from the outside to the inside, is transversely and violently shaken for 3-5 times, and stays for 5 seconds.
9. The goose bark fiber-based splitting paper making method according to claim 2, wherein the plant ash is 20% of the mass of the pulp in the step (4).
10. The goose bark fiber-based dissolving paper making method according to claim 2, wherein the cactus juice is used in an amount of 5% by mass of the pulp in the step (9).
CN202110861977.2A 2021-07-29 2021-07-29 Preparation method of opened paper based on wild goose bark fibers Active CN113605144B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114645485A (en) * 2022-04-08 2022-06-21 四川农业大学 Natural mildew-proof insect-proof scented paper made of silkwood and preparation method of natural mildew-proof insect-proof scented paper

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CN1540092A (en) * 2003-11-01 2004-10-27 军 李 'Dongba' paper used by 'Naxi' mationality and preparation method
JP2008088612A (en) * 2006-10-04 2008-04-17 Oji Paper Co Ltd Household tissue paper and method for producing the same
CN105544282A (en) * 2016-02-01 2016-05-04 陕西科技大学 Papermaking process method utilizing paper mulberry bark as raw material
CN107034712A (en) * 2017-04-28 2017-08-11 贞丰县民族民间工艺厂 A kind of novel papermaking method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114645485A (en) * 2022-04-08 2022-06-21 四川农业大学 Natural mildew-proof insect-proof scented paper made of silkwood and preparation method of natural mildew-proof insect-proof scented paper

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