CN113598412B - Composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke and cigarette - Google Patents
Composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke and cigarette Download PDFInfo
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- CN113598412B CN113598412B CN202111016276.5A CN202111016276A CN113598412B CN 113598412 B CN113598412 B CN 113598412B CN 202111016276 A CN202111016276 A CN 202111016276A CN 113598412 B CN113598412 B CN 113598412B
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- activated carbon
- specific adsorption
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/045—Cigars; Cigarettes with mouthpieces or filter-tips with smoke filter means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention relates to the technical field of removal of harmful components in smoke, in particular to a composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke and a cigarette. The filter tip comprises a general adsorption section and a specific adsorption section; the specific adsorption section is loaded with a mixture of fine pore A type silica gel, graphene modified activated carbon and linoleic acid modified nano silicon-based oxide; the common adsorption section and the specific adsorption section are coaxially arranged in a serial manner. The composite filter tip has very ideal removal effect on the 2-acetylpyridine in the smoke of the cigarettes, can effectively reduce the spicy taste of the cigarettes, can not cause loss on aroma substances in the smoke, and improves the overall taste of the cigarettes.
Description
Technical Field
The invention relates to the technical field of removal of harmful components in smoke, in particular to a composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke and a cigarette.
Background
The sensory quality evaluation of the cigarettes by the smokers is performed by evaluating the comprehensive reflecting effect of the aroma components in the smoke generated after the cigarettes are burnt on the smokers after the smoke generated after the cigarettes are used by the smokers, namely the aroma components in the smoke generated after the cigarettes are burnt on the feelings of the smokers. The function of the oral cavity in the smoking evaluation is to judge the irritation (pungency), the roughness or the fineness of the smoke, the hardness or the softness of the smoke, the concentration or the weakness of the smoke, the fullness and the aftertaste of the smoke. Cigarette smoking is also dependent on the throat, and the effect of the throat in smoking is to judge the irritation of smoke (when the smoke flows to the front edge of the throat) and the size of the smoke stiffness (when the smoke passes through the throat).
The sensory quality of the cigarette is closely related to the types and the concentrations of chemical components of the smoke, the taste is also related to the threshold value of the chemical components, the number of the compound types distributed in the gas phase and the grain phase matters of the smoke aerosol of the cigarette is as high as thousands, and the composition and the content of the compound have important influence on the sensory quality of the cigarette. Some cigarettes often generate unpleasant sour taste, bitter taste, spicy taste, astringency and the like, and researches show that substances such as volatile carbonyl compounds, phenolic compounds, ammonia and the like with low molecular weight in smoke have a stimulating effect, and non-volatile organic acids have strong spicy, burnt and rancid smell when the concentration is high, and the substances stimulate taste receiving and sensory nerves of the oral cavity, stimulate sensory nerve endings and have a negative effect on the sensory quality of the cigarettes. The 2-acetylpyridine has special pungent smell, and can reflect the strong pungency and obvious miscellaneous gas on the sensory quality of the main stream smoke of cigarettes.
Along with the variation of smokers' habits, the cigarette products with lower irritation, mellow taste and clean aftertaste and pursuing comfort are more and more popular with consumers, so how to reduce the content of 2-acetylpyridine in cigarette smoke becomes a hot spot of current research.
Disclosure of Invention
The invention provides a composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke, which comprises a general adsorption section and a specific adsorption section;
the specific adsorption section is loaded with a mixture of A-type pore silica gel, graphene modified activated carbon and linoleic acid modified nano silicon-based oxide;
the common adsorption section and the specific adsorption section are coaxially arranged in a serial manner.
The invention discovers that the mixture of the A-type pore silica gel, the graphene modified activated carbon and the linoleic acid modified nano silicon-based oxide is adopted as a specific adsorption material, and meanwhile, the structure of the composite filter tip is matched, so that the 2-acetylpyridine in cigarette smoke can be effectively adsorbed, the loss of other aroma components is avoided, and the taste of the cigarette is improved.
Preferably, the mass ratio of the A-type fine pore silica gel to the graphene modified activated carbon to the linoleic acid modified nano silicon-based oxide is 2:0.8 to 1.2:0.2 to 0.5. Under the relative dosage, the adsorption material can play a better synergistic effect, has better adsorption effect on the 2-acetylpyridine and can not adsorb and remove other aroma substances
Preferably, the pore size of the A-type fine pore silica gel is 2.5-4 nm.
Preferably, the graphene modified activated carbon is prepared by the following method:
the graphene modified activated carbon is prepared by the following method:
adding coconut shell activated carbon into graphene suspension with the concentration of 0.8-1.2 mg/mL under the stirring condition, fully soaking, and freeze-drying to obtain a graphene modified activated carbon material;
the addition amount of the coconut shell activated carbon is 50-100 mg/ml. The adsorption capacity of the activated carbon to the 2-acetylpyridine is weak, and the conjugated structure in the graphene molecules can generate intermolecular pi-pi action with the pyridine ring in the 2-acetylpyridine, so that the selective adsorption of the 2-acetylpyridine can be improved after the activated carbon is modified by the graphene.
Preferably, the linoleic acid modified nano silicon-based oxide is prepared by the following method: adding linoleic acid and nano SiO into n-hexane solvent 2 The powder is obtained by ultrasonic oscillation and stirring reaction. The hydroxyl number on the surface of the nano silicon-based oxide modified by linoleic acid is reduced, so that the nano silicon-based oxide is beneficial to dispersing in the filter rod plasticizer glyceryl triacetate and is convenient to uniformly add into acetate fibers.
Further preferably, the linoleic acid and the nano SiO 2 The mass ratio of the powder is 8-10:100.
Preferably, the ratio of the lengths of the universal adsorption section and the specific adsorption section is 1:1 to 1.5. Under the condition of the relative length, the adsorption effect of the specific adsorption section on the 2-acetylpyridine can be ensured, and the whole aroma of the flue gas can not be influenced.
Preferably, the addition amount of the mixture is 32-38 mg/branch. The better adsorption effect can be ensured under the addition amount.
Preferably, the addition amount of the mixture is 2-3 mg/mm.
Preferably, the materials of the general adsorption section and the specific adsorption section are acetate fibers.
In another aspect, the invention provides a cigarette comprising a composite filter according to the invention.
Preferably, the specific adsorption section of the composite filter tip is close to the cut tobacco part of the cigarette.
The invention has the following beneficial effects:
1) The composite filter tip has very ideal removal effect on the 2-acetylpyridine in the smoke of the cigarettes, and can effectively improve the taste of the cigarettes and reduce the pungency of the cigarettes.
2) The composite filter tip has obvious adsorption effect on 2-acetylpyridine, has no obvious adsorption on other components in the cigarette, can keep the original style of the cigarette unchanged, has certain improvement and improvement on the taste quality, meets the physiological needs of consumers, and improves the competitiveness of the product.
Drawings
FIG. 1 is a schematic view of the structure of a cigarette according to the present invention;
in the figure, 1 is a composite filter tip, 2 is a cigarette body, 3 is a general adsorption section, and 4 is a specific adsorption section.
Detailed Description
The following examples are illustrative of the invention and are not intended to limit the scope of the invention.
The graphene modified activated carbon related to the embodiment is prepared by the following method:
adding coconut shell activated carbon into graphene suspension with the concentration of 1mg/mL under the stirring condition, fully soaking, and freeze-drying to obtain a graphene modified activated carbon material;
the addition amount of the coconut shell activated carbon is 50mg/ml.
The linoleic acid modified nano silicon-based oxide in the example is prepared by the following method:
adding linoleic acid and nano SiO into n-hexane solvent 2 The powder is obtained by ultrasonic oscillation and stirring reaction.
The linoleic acid and nano SiO 2 The mass ratio of the powder is 9:100.
Example 1
The embodiment relates to a composite cigarette filter, which has the following structure:
the composite filter tip comprises a general adsorption section and a specific adsorption section;
the specific adsorption section is loaded with a mixture of A-type pore silica gel, graphene modified activated carbon and linoleic acid modified nano silicon-based oxide;
the common adsorption section and the specific adsorption section are coaxially arranged in a serial manner.
The mass ratio of the A-type pore silica gel to the graphene modified activated carbon to the linoleic acid modified nano silicon-based oxide is 2:1:0.3.
the preparation method of the composite filter tip comprises the following steps:
mixing A-type pore silica gel, graphene modified activated carbon and plasticizer glyceryl triacetate in which linoleic acid modified nano silicon-based oxide is dispersed, adding the plasticizer according to 8% of the weight of the filter stick, adding the plasticizer into a tobacco bundle to prepare a specific adsorption section, and then compounding the specific adsorption section with acetate fibers to prepare the functional composite cigarette filter.
The length of the specific adsorption section in the composite filter tip is 15mm, and the length of the general adsorption section is 10mm;
the addition amount of the A-type pore silica gel, the graphene modified activated carbon and the linoleic acid modified nano silicon-based oxide in the acetate fiber is 3mg/mm.
The embodiment also relates to a cigarette provided with the composite cigarette filter, and the structural schematic diagram is shown in fig. 1, wherein 1 is the composite filter, 2 is the cigarette body, 3 is the general adsorption section, and 4 is the specific adsorption section. Wherein the length of the cigarette is 84mm plus or minus 0.5mm, the circumference is 24.35 plus or minus 0.2mm, and the specific adsorption section of the filter tip is close to the cut tobacco of the cigarette.
Example 2
The embodiment relates to a composite cigarette filter, which has the following structure:
the composite filter tip comprises a general adsorption section and a specific adsorption section;
the specific adsorption section is loaded with a mixture of A-type pore silica gel, graphene modified activated carbon and linoleic acid modified nano silicon-based oxide;
the common adsorption section and the specific adsorption section are coaxially arranged in a serial manner.
The mass ratio of the A-type pore silica gel to the graphene modified activated carbon to the linoleic acid modified nano silicon-based oxide is 2:1:0.5.
the preparation method of the composite filter tip comprises the following steps:
mixing silica gel, graphene modified activated carbon and plasticizer glyceryl triacetate in which linoleic acid modified nano silicon-based oxide is dispersed, wherein the plasticizer is added according to 8% of the weight of the filter stick to prepare the functional composite cigarette filter tip.
The length of the specific adsorption section in the composite filter tip is 20mm, the specific adsorption section is added into the tobacco bundle to be made into the specific adsorption section, and the length of the specific adsorption section and the acetate fiber composite attachment section is 10mm.
The addition amount of the A-type pore silica gel, the graphene modified activated carbon and the linoleic acid modified nano silicon-based oxide in the acetate fiber is 2mg/mm.
The embodiment also relates to a cigarette provided with the composite cigarette filter, the length of the cigarette is 94mm plus or minus 0.5mm, the circumference of the cigarette is 21.80 plus or minus 0.2mm, and the specific adsorption section of the filter is close to cut tobacco of the cigarette.
Comparative example 1
The difference compared to example 1 is that the mixture added to the composite filter is replaced by a mixture of coarse pore silica gel, activated carbon and linoleic acid modified nano silicon-based oxide.
Comparative example 2
The difference compared with example 1 is that the cigarette does not use a composite filter, a common filter prepared by acetate fibers is adopted, and the specification of the cigarette is the same as that of example 1.
Comparative example 3
The difference compared with example 2 is that the cigarette does not use a composite filter, a common filter prepared by acetate fibers is adopted, and the specification of the cigarette is the same as that of example 2.
Experimental example 1
The experimental example relates to detection of effective components in cigarette smoke in the experimental example:
the content of 2-acetylpyridine in cigarette smoke is detected by a GC-MS/MS method, and the method comprises the following specific steps: the total particulate matters of 5 cigarettes collected by a Cambridge filter disc are put into a 50mL conical flask, 20mL of methanol solution containing an internal standard is added, ultrasonic extraction is carried out for 30min, standing is carried out for 30min, and the upper layer extract is filtered by a microporous filter membrane with the size of 0.45 mu m for GC-MS/MS analysis. Chromatographic conditions: DB-WAX capillary column (30 m x 0.25mm x 0.25 μm); sample inlet temperature: 250 ℃; sample injection amount: 1 mu L, sample introduction without split flow; constant flow mode, column flow 1mL/min; heating program: the initial temperature was 45℃for 5min, and the temperature was raised to 180℃at a rate of 1.5℃per min, and then to 250℃at a rate of 5℃per min, and the temperature was maintained for 8min. Mass spectrometry conditions: EI ionization mode, ionization energy 70ev; ion source temperature: 230 ℃; transmission line temperature: 250 ℃; q1 andq3 temperature: 150 ℃; collision gas: n (N) 2 Purity 99.999%, flow rate 1.5mL/min; quenching gas: he, flow rate 2.25mL/min; the method comprises the steps of carrying out a first treatment on the surface of the Scanning mode: MRM mode.
The test results are shown in tables 1 and 2:
TABLE 1
TABLE 2
From the above data, it is clear that the composite filter according to the present invention can effectively adsorb 2-acetylpyridine.
Experimental example 2
The sensory evaluation of the cigarettes in examples and comparative examples was conducted with reference to the tobacco industry standard YC/T138-1998, sensory evaluation methods for tobacco and tobacco products, and the results are shown in Table 3.
TABLE 3 Table 3
Note that: taste vitality value (Taste Activity Value, TAV) =c Measuring the amount of released /TPM/C Threshold value Reflecting the contribution degree of the compound component to the sensory quality of the cigarette, when the value is more than 1, the compound is indicated to be contributed to the sensory system, and the higher the value is, the greater the contribution is.
The 2-acetylpyridine has obvious stimulation when the concentration is higher, and reflects stronger stimulation and obvious miscellaneous gas on the sensory quality of the main stream smoke of the cigarette, which is consistent with the evaluation result of the sensory quality of the cigarette, and the cigarette adopting the functional composite filter stick has reduced stimulation, miscellaneous gas and aftertaste which are superior to those of the control cigarette. The use of the functional composite filter stick can obviously reduce the irritation and miscellaneous gas of smoke and improve the comfort of the oral cavity by combining the sensory evaluation result of the cigarettes, and the overall aroma and style characteristics of the mixed cigarettes are not influenced.
While the invention has been described in detail in the foregoing general description, embodiments and experiments, it will be apparent to those skilled in the art that modifications and improvements can be made thereto. Accordingly, such modifications or improvements may be made without departing from the spirit of the invention and are intended to be within the scope of the invention as claimed.
Claims (11)
1. The composite filter tip for adsorbing 2-acetylpyridine in cigarette smoke is characterized by comprising a general adsorption section and a specific adsorption section;
the specific adsorption section is loaded with a mixture of fine pore A type silica gel, graphene modified activated carbon and linoleic acid modified nano silicon-based oxide;
the common adsorption section and the specific adsorption section are coaxially arranged in a serial manner.
2. The composite filter according to claim 1, wherein the mass ratio of the fine pore a-type silica gel, the graphene-modified activated carbon, and the linoleic acid-modified nano silicon-based oxide is 2: 0.8-1.2: 0.2 to 0.5.
3. The composite filter according to claim 1 or 2, wherein the pore size of the a-type pore silica gel is 2.5 to 4nm.
4. The composite filter according to claim 1, wherein the graphene-modified activated carbon is prepared by the following method:
adding coconut shell activated carbon into graphene suspension with the concentration of 0.8-1.2 mg/mL under the stirring condition, fully soaking, and freeze-drying to obtain a graphene modified activated carbon material;
the addition amount of the coconut shell activated carbon is 50-100 mg/ml.
5. The composite filter of claim 1, wherein the linoleic acid modified nano silicon-based oxide is prepared by the following method: adding linoleic acid and nano SiO into n-hexane solvent 2 The powder is obtained by ultrasonic oscillation and stirring reaction.
6. The composite filter of claim 5, wherein the linoleic acid is in combination with the nano-SiO 2 The mass ratio of the powder is 8-10:100.
7. The composite filter according to claim 1, wherein the ratio of the lengths of the universal adsorption section and the specific adsorption section is 1:1 to 1.5.
8. The composite filter according to claim 1 or 7, wherein the amount of the mixture added is 32 to 38 mg/piece;
and/or the addition amount of the mixture is 2-3 mg/mm.
9. The composite filter of claim 1, wherein the materials of the universal adsorption section and the specific adsorption section are acetate fibers.
10. A cigarette comprising the composite filter of any one of claims 1 to 9.
11. The cigarette of claim 10, wherein the specific adsorption section of the composite filter is proximate to a cut tobacco portion of the cigarette.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101077223A (en) * | 2006-05-25 | 2007-11-28 | 红塔烟草(集团)有限责任公司 | Surface modification mesopore molecular screen for cigarette filter tip rod and preparation method thereof |
WO2012047346A1 (en) * | 2010-10-06 | 2012-04-12 | Celanese Acetate Llc | Smoke filters for smoking devices with porous masses having active nanoparticles and binder particles |
CN102793270A (en) * | 2012-08-07 | 2012-11-28 | 广西中烟工业有限责任公司 | Cigarette filter rod capable of reducing content of volatile carbonyl compounds in cigarette smoke and preparation method of cigarette filter rod |
CN104432505A (en) * | 2014-12-15 | 2015-03-25 | 湖南中烟工业有限责任公司 | Cigarette filter tip reducing carbonyl compounds in cigarette mainstream smoke and manufacture method thereof |
CN104489922A (en) * | 2014-12-11 | 2015-04-08 | 上海烟草集团有限责任公司 | Preparation and application of graphene oxide-bonded silica gel composite |
CN105533802A (en) * | 2016-01-18 | 2016-05-04 | 张麟德 | Smoke filtering device and tobacco product |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7370657B2 (en) * | 2003-04-02 | 2008-05-13 | Philip Morris Usa Inc. | Activated carbon-containing sorbent |
-
2021
- 2021-08-31 CN CN202111016276.5A patent/CN113598412B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101077223A (en) * | 2006-05-25 | 2007-11-28 | 红塔烟草(集团)有限责任公司 | Surface modification mesopore molecular screen for cigarette filter tip rod and preparation method thereof |
WO2012047346A1 (en) * | 2010-10-06 | 2012-04-12 | Celanese Acetate Llc | Smoke filters for smoking devices with porous masses having active nanoparticles and binder particles |
CN102793270A (en) * | 2012-08-07 | 2012-11-28 | 广西中烟工业有限责任公司 | Cigarette filter rod capable of reducing content of volatile carbonyl compounds in cigarette smoke and preparation method of cigarette filter rod |
CN104489922A (en) * | 2014-12-11 | 2015-04-08 | 上海烟草集团有限责任公司 | Preparation and application of graphene oxide-bonded silica gel composite |
CN104432505A (en) * | 2014-12-15 | 2015-03-25 | 湖南中烟工业有限责任公司 | Cigarette filter tip reducing carbonyl compounds in cigarette mainstream smoke and manufacture method thereof |
CN105533802A (en) * | 2016-01-18 | 2016-05-04 | 张麟德 | Smoke filtering device and tobacco product |
Non-Patent Citations (2)
Title |
---|
SCL@SiO_2纳米颗粒的制备及其稳定的Pickering乳液;樊晔;牛田;方云;夏咏梅;刘深鑫;;精细化工;35(12);1987-1992 * |
Surface-modification of SiO2 nanoparticles with oleic acid;Zongwei Li, Yongfa Zhu;Applied Surface Science;第211卷;315-320 * |
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