CN113592163A - Method and equipment for predicting concentration of nitrogen oxide at inlet of SCR (Selective catalytic reduction) denitration reactor - Google Patents

Method and equipment for predicting concentration of nitrogen oxide at inlet of SCR (Selective catalytic reduction) denitration reactor Download PDF

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CN113592163A
CN113592163A CN202110829703.5A CN202110829703A CN113592163A CN 113592163 A CN113592163 A CN 113592163A CN 202110829703 A CN202110829703 A CN 202110829703A CN 113592163 A CN113592163 A CN 113592163A
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陈超
黄章勇
薛菲
鄢烈祥
周力
刘军
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Abstract

The invention provides a method and equipment for predicting concentration of nitrogen oxides at an inlet of an SCR (selective catalytic reduction) denitration reactor. The method comprises the following steps: acquiring and preprocessing operation data of a plurality of boilers and SCR denitration reactors; determining input and output variables of a prediction model, constructing the prediction model by adopting a classification algorithm, adding a time-varying function in the prediction model to obtain the prediction results of the concentration of the nitric oxide under different lag time lengths, and updating the prediction model by adopting a sliding window by taking the time length corresponding to the minimum root-mean-square error in the prediction results as the lag time length; and training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model. The method can accurately predict the concentration of the nitrogen oxides at the inlet of the SCR denitration reactor, avoids dependence on manual experience, and can update the prediction model in real time.

Description

Method and equipment for predicting concentration of nitrogen oxide at inlet of SCR (Selective catalytic reduction) denitration reactor
Technical Field
The embodiment of the invention relates to the technical field of nitrogen oxide testing, in particular to a method and equipment for predicting the concentration of nitrogen oxide at an inlet of an SCR (selective catalytic reduction) denitration reactor.
Background
With the increasing upgrading of environmental requirements, the power industry has fully implemented ultra-low emission standards. In order to control the emission of pollutant nitrogen oxides, most of the existing coal-fired units generally adopt a solution scheme of increasing ammonia injection amount and increasing the number of catalyst layers, but the fluctuation of nitrogen oxides at the inlet of an SCR denitration reactor is severe, the representativeness of the measurement data of a continuous emission flue gas detection system (CEMS) is insufficient, and the measurement-control process of the SCR denitration system is delayed, so that the escape concentration of local ammonia is easily caused to exceed the design value, the aim of accurately injecting ammonia is difficult to achieve, and the safety, economy and stable operation of the denitration system are influenced, and even the equipment of a downstream system is damaged. At present, the artificial intelligence algorithm is used for predicting and optimizing the nitrogen oxide at the outlet of the boiler, in the denitration process of a large unit, because the section of a flue at a denitration inlet is large, a single boiler is matched with two SCR denitration reactors (namely, a selective catalytic reduction denitration reactor), the flow field of flue gas is not uniform, bias current possibly exists, the concentration of the nitrogen oxide at the inlet of each denitration reactor can also have difference, and the artificial intelligence algorithm is used for predicting the concentration of the nitrogen oxide at the outlet of the boiler and cannot be used for guiding the accurate ammonia spraying in the denitration process. Therefore, it is an urgent technical problem to be solved in the art to develop a method and an apparatus for predicting the concentration of nitrogen oxides at the inlet of an SCR denitration reactor, which can effectively overcome the above-mentioned drawbacks in the related art.
Disclosure of Invention
In order to solve the above problems in the prior art, embodiments of the present invention provide a method and an apparatus for predicting a concentration of nitrogen oxides at an inlet of an SCR denitration reactor.
In a first aspect, embodiments of the present invention provideA method for predicting the concentration of nitrogen oxides at an inlet of an SCR denitration reactor comprises the following steps: acquiring operation data of a plurality of boilers and SCR denitration reactors, removing abnormal values in the operation data, and combining parameters of the same type with consistent variation trend; determining input and output variables of a prediction model, constructing the prediction model by adopting a classification algorithm based on data driving, and adopting a regularization parameter which has a large influence on the performance of the model by adopting a queue competition algorithm
Figure 100002_DEST_PATH_IMAGE001
And kernel function width
Figure 725537DEST_PATH_IMAGE002
Optimizing, determining the optimal values of the two parameters, minimizing the error of the model, and improving the prediction accuracy of the model; adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, and updating the prediction model by adopting a sliding window with the time length corresponding to the minimum root mean square error in the prediction results as the lag time length; and training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model.
On the basis of the content of the embodiment of the method, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor, which is provided by the embodiment of the invention, adopts a classification algorithm to construct a prediction model, and comprises the following steps:
Figure 100002_DEST_PATH_IMAGE003
Figure 41112DEST_PATH_IMAGE004
Figure 641858DEST_PATH_IMAGE005
Figure 839621DEST_PATH_IMAGE006
wherein the content of the first and second substances,
Figure 387277DEST_PATH_IMAGE007
is the minimum value of the objective function;
Figure 88517DEST_PATH_IMAGE008
the vector coefficients of (a);
Figure 63426DEST_PATH_IMAGE009
is a non-linear transformation;
Figure 748485DEST_PATH_IMAGE010
is the nth element of the vector coefficient;
Figure 896570DEST_PATH_IMAGE011
is the norm of the vector coefficient;
Figure 452316DEST_PATH_IMAGE012
is a regularization parameter;
Figure 863706DEST_PATH_IMAGE013
predicting an error vector for the ith training set; n is the number of prediction error vectors of the training set; b is a prediction model parameter;
Figure 567220DEST_PATH_IMAGE014
is the ith Lagrangian multiplier; k is a kernel function; x is an input vector;
Figure 456678DEST_PATH_IMAGE015
is the ith input vector;
Figure 132510DEST_PATH_IMAGE016
is a prediction model;
Figure 446292DEST_PATH_IMAGE017
is the ith output vector;
Figure 840365DEST_PATH_IMAGE018
are constraints.
Based on the content of the foregoing method embodiment, in the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, the time-varying function includes:
Figure 330252DEST_PATH_IMAGE019
Figure 860590DEST_PATH_IMAGE020
Figure 613783DEST_PATH_IMAGE021
wherein z is a time-varying function;
Figure 291889DEST_PATH_IMAGE022
is the parameter value at the time t;
Figure 523150DEST_PATH_IMAGE023
the input vector at the K-th moment is taken as the input vector;
Figure 907995DEST_PATH_IMAGE024
the time-varying function output quantity at the K time is obtained; f is a time-varying function expression.
On the basis of the content of the above method embodiment, in the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, the minimum root mean square error includes:
Figure 832088DEST_PATH_IMAGE025
wherein RMSE is the root mean square error; m is the number of samples;
Figure 997490DEST_PATH_IMAGE026
is the ith predicted value;
Figure 32443DEST_PATH_IMAGE027
is the ith true value.
On the basis of the content of the embodiment of the method, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor, which is provided by the embodiment of the invention, adopts the sliding window to update the prediction model, and comprises the following steps: the method comprises the steps that a sliding window technology is used for updating a nitrogen oxide concentration prediction model at an SCR denitration inlet in real time, the prediction model is initialized at the starting stage, the prediction model adopts a self-contained historical database to establish an initial model for initial prediction, the self-contained historical database for initialization modeling of the prediction model is gradually replaced by latest actual operation data along with the operation of the prediction model, and the prediction model is updated after a time interval corresponding to a sliding window.
On the basis of the content of the foregoing method embodiment, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes, after the prediction model is updated: the size of the sliding window is adjusted according to the frequency of data acquired by the data acquisition system and the precision of the prediction model, and meanwhile, the operation duration of the prediction model is controlled to be millisecond level, so that the concentration of nitrogen oxides at the inlet of the SCR denitration reactor is predicted in real time.
On the basis of the content of the foregoing method embodiment, the method for predicting the concentration of nitrogen oxide at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes, after predicting the concentration of nitrogen oxide at the inlet of the SCR denitration reactor in real time by using the final prediction model: updating a prediction model by taking real-time acquired data and an actual value of the concentration of nitrogen oxides at an inlet of the SCR denitration reactor calculated by adopting a time-varying function as latest historical data; the real-time data acquisition and the actual value of the concentration of nitrogen oxides at the inlet of the SCR denitration reactor calculated by adopting a time-varying function are stored in a database.
In a second aspect, an embodiment of the present invention provides an apparatus for predicting an inlet nox concentration of an SCR denitration reactor, including: the first main module is used for acquiring the operation data of a plurality of boilers and the SCR denitration reactor, eliminating abnormal values in the operation data and combining the change trendsConsistent parameters of the same type; the second main module is used for determining input and output variables of the prediction model, constructing the prediction model by adopting a classification algorithm based on data driving, and adopting a regularization parameter with a large influence on the performance of the model by adopting a queue competition algorithm
Figure 271794DEST_PATH_IMAGE001
And kernel function width
Figure 163527DEST_PATH_IMAGE002
Optimizing, determining the optimal values of the two parameters, minimizing the error of the model, and improving the prediction accuracy of the model; adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, and updating the prediction model by adopting a sliding window with the time length corresponding to the minimum root mean square error in the prediction results as the lag time length; and the third main module is used for training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model.
In a third aspect, an embodiment of the present invention provides an electronic device, including:
at least one processor; and
at least one memory communicatively coupled to the processor, wherein:
the memory stores program instructions executable by the processor, and the processor calls the program instructions to execute the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided by any one of the various implementation manners of the first aspect.
In a fourth aspect, embodiments of the present invention provide a non-transitory computer readable storage medium storing computer instructions for causing a computer to perform the method for predicting SCR denitration reactor inlet nox concentration provided in any one of the various implementations of the first aspect.
According to the method and the device for predicting the concentration of the nitrogen oxide at the inlet of the SCR denitration reactor, provided by the embodiment of the invention, the operation data of a plurality of boilers and the SCR denitration reactor are obtained and preprocessed, the input and output variables of the prediction model are determined, the prediction model is constructed, the time-varying function is added into the prediction model, the prediction results of the concentration of the nitrogen oxide under different delay time lengths are obtained, the time length corresponding to the minimum root-mean-square error in the prediction results is taken as the delay time length, the prediction model is updated by adopting the sliding window, the final prediction model is obtained, the concentration of the nitrogen oxide at the inlet of the SCR denitration reactor can be accurately predicted, the dependence on the manual experience is avoided, and the prediction model can be updated in real time.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, a brief description will be given below to the drawings required for the description of the embodiments or the prior art, and it is obvious that the drawings in the following description are some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
Fig. 1 is a flowchart of a method for predicting the concentration of nitrogen oxides at an inlet of an SCR denitration reactor according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of a device for predicting concentration of nitrogen oxides at an inlet of an SCR denitration reactor according to an embodiment of the present invention;
fig. 3 is a schematic physical structure diagram of an electronic device according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. In addition, technical features of various embodiments or individual embodiments provided by the present invention may be arbitrarily combined with each other to form a feasible technical solution, and such combination is not limited by the sequence of steps and/or the structural composition mode, but must be realized by a person skilled in the art, and when the technical solution combination is contradictory or cannot be realized, such a technical solution combination should not be considered to exist and is not within the protection scope of the present invention.
The embodiment of the invention provides a method for predicting concentration of nitrogen oxides at an inlet of an SCR (selective catalytic reduction) denitration reactor, and referring to FIG. 1, the method comprises the following steps: acquiring operation data of a plurality of boilers and SCR denitration reactors, removing abnormal values in the operation data, and combining parameters of the same type with consistent variation trend; determining input and output variables of the prediction model, constructing the prediction model by adopting a classification algorithm, (adopting a regularization parameter which has great influence on the performance of the model by a queue competition algorithm)
Figure 19487DEST_PATH_IMAGE001
And kernel function width
Figure 326972DEST_PATH_IMAGE002
Optimizing, determining the optimal values of the two parameters, minimizing the model error, and improving the prediction accuracy of the model); adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, and updating the prediction model by adopting a sliding window with the time length corresponding to the minimum root mean square error in the prediction results as the lag time length; and training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model. Wherein, obtaining the operating data of a plurality of boilers and SCR denitration reactors includes: the denitration system comprises a primary air quantity, a secondary air quantity, a coal feeding quantity, a main steam temperature, a main steam pressure, a flue gas quantity, a denitration reactor inlet temperature and the like. Analyzing and preprocessing the acquired data, analyzing the acquired historical operating data of the boiler and the SCR denitration reactor through a mechanism of generating nitrogen oxides, eliminating abnormal values in the data, and combining the parameters with the same type and consistent variation trend.
Based on the content of the above method embodiment, as an optional embodiment, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, which uses a classification algorithm to construct a prediction model, includes:
Figure 951988DEST_PATH_IMAGE028
(1)
Figure 217884DEST_PATH_IMAGE004
(2)
Figure 92300DEST_PATH_IMAGE029
(3)
Figure 469054DEST_PATH_IMAGE030
(4)
wherein the content of the first and second substances,
Figure 948577DEST_PATH_IMAGE031
is the minimum value of the objective function;
Figure 182112DEST_PATH_IMAGE032
the vector coefficients of (a);
Figure 747086DEST_PATH_IMAGE009
is a non-linear transformation;
Figure 393443DEST_PATH_IMAGE033
is the nth element of the vector coefficient;
Figure 993052DEST_PATH_IMAGE011
is the norm of the vector coefficient;
Figure 397488DEST_PATH_IMAGE034
is a regularization parameter;
Figure 449758DEST_PATH_IMAGE013
predicting an error vector for the ith training set; n is the number of prediction error vectors of the training set; b is a prediction model parameter;
Figure 902736DEST_PATH_IMAGE035
is the ith Lagrangian multiplier; k is a kernel function; x is an input vector;
Figure 356851DEST_PATH_IMAGE015
is the ith input vector;
Figure 932189DEST_PATH_IMAGE036
is a prediction model;
Figure 206176DEST_PATH_IMAGE017
is the ith output vector;
Figure 728424DEST_PATH_IMAGE018
are constraints.
Specifically, the input vector x and the output vector y in the prediction model are in a nonlinear relation, and nonlinear transformation exists
Figure 37045DEST_PATH_IMAGE037
So that y is equal to
Figure 783285DEST_PATH_IMAGE038
The classification objective function is expressed by the formulas (1) to (3) in a linear relationship. The optimization problem in the high-dimensional feature space generally converts the above formula into its dual problem, and introduces Lagrange multiplier to solve:
Figure 544567DEST_PATH_IMAGE039
(5)
wherein L is a Lagrangian function;
Figure 604927DEST_PATH_IMAGE040
is an objective function.
The partial derivative of equation (5) can be obtained:
Figure 564793DEST_PATH_IMAGE041
(6)
(6) the formula is equivalent to the matrix form shown in formula (7):
Figure 685196DEST_PATH_IMAGE042
(7)
Figure 933774DEST_PATH_IMAGE043
(8)
eliminating in formula (7)
Figure 797825DEST_PATH_IMAGE044
And e, obtaining a linear equation system as shown in the formula (9):
Figure 612197DEST_PATH_IMAGE045
(9)
(8) in formulae (1) and (9)
Figure 169081DEST_PATH_IMAGE046
Is a unit vector, I is a unit matrix,
Figure 639376DEST_PATH_IMAGE047
is a kernel function matrix. And b and
Figure 838276DEST_PATH_IMAGE048
to predict the model parameters, it is also known from Mercer's theorem:
Figure 975997DEST_PATH_IMAGE049
(10)
wherein the content of the first and second substances,
Figure 435272DEST_PATH_IMAGE050
is the jth input vector; k is a symmetric positive-definite kernel function, commonly of the form gaussian Radial Basis (RBF) kernel function:
Figure 392864DEST_PATH_IMAGE051
(11)
wherein the content of the first and second substances,
Figure 661034DEST_PATH_IMAGE052
is the kernel function width; the prediction expression from which the function estimate for the new sample x can be derived is shown in equation (4).
Based on the content of the foregoing method embodiment, as an optional embodiment, in the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, the time-varying function includes:
Figure 653261DEST_PATH_IMAGE053
(12)
Figure 20789DEST_PATH_IMAGE054
(13)
Figure 731256DEST_PATH_IMAGE055
(14)
wherein z is a time-varying function;
Figure 537538DEST_PATH_IMAGE022
is the parameter value at the time t;
Figure 321954DEST_PATH_IMAGE023
the input vector at the K-th moment is taken as the input vector;
Figure 125962DEST_PATH_IMAGE024
the time-varying function output quantity at the K time is obtained; f is a time-varying function expression.
In particular, the amount of the solvent to be used,adding a time-varying function, wherein the nitrogen oxide concentration parameter in the prediction model is obtained from a CEMS (continuous emission monitoring system) which has hysteresis, adding the time-varying function into the nitrogen oxide concentration prediction model at the inlet of the SCR denitration reactor as shown in the formulas (12) to (13),
Figure 58146DEST_PATH_IMAGE056
the sample numbers in (1) are in one-to-one correspondence, and for t =1, 2, …, N, are based on
Figure 668119DEST_PATH_IMAGE056
Training algorithm f to obtain
Figure 369358DEST_PATH_IMAGE057
. Time-varying, i.e., when data fitting is performed, often encounters output variables
Figure 344268DEST_PATH_IMAGE058
The mapping relation with the output variable is changed continuously along with the time, and the time is called
Figure 826065DEST_PATH_IMAGE058
And
Figure 177412DEST_PATH_IMAGE059
is time-varying. At this time, the mapping relationship of the sum needs to be continuously updated based on the incremental data of the output variable x and the output variable y according to the time sequence. And establishing a denitration system time lag model by relying on historical operation data of the power plant DCS platform, testing the prediction effect under different lag time length conditions, and taking the time length corresponding to the minimum RMSE in the prediction result as the lag time length.
Based on the content of the foregoing method embodiment, as an optional embodiment, in the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, the minimum root mean square error includes:
Figure 733158DEST_PATH_IMAGE025
(15)
wherein RMSE is the root mean square error; m is the number of samples;
Figure 675706DEST_PATH_IMAGE026
is the ith predicted value;
Figure 582482DEST_PATH_IMAGE060
is the ith true value.
Specifically, the first 240 pieces of data of a sample are used as prediction model initialization data, and every 800 pieces of subsequent data are grouped into a group to be used as a test set for prediction model verification. And evaluating the prediction model, substituting the data of the test set into the prediction model, predicting the target value of the test set, namely the concentration of nitrogen oxides at the inlet of the SCR denitration reactor, and calculating the root mean square error as shown in the formula (15).
Based on the content of the foregoing method embodiment, as an optional embodiment, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention, which updates the prediction model by using the sliding window, includes: the method comprises the steps that a sliding window technology is used for updating a nitrogen oxide concentration prediction model at an SCR denitration inlet in real time, the prediction model is initialized at the starting stage, the prediction model adopts a self-contained historical database to establish an initial model for initial prediction, the self-contained historical database for initialization modeling of the prediction model is gradually replaced by latest actual operation data along with the operation of the prediction model, and the prediction model is updated after a time interval corresponding to a sliding window.
Specifically, a sliding window technology is used for updating a nitrogen oxide concentration prediction model at the inlet of the SCR denitration reactor in real time, the prediction model undergoes an initialization process in a starting stage, the prediction model uses a self-contained historical database to establish an initial model for initial prediction in the process, the self-contained historical database for initialization modeling of the model is gradually replaced by latest actual operation data along with the operation of the prediction model, and the prediction model is completely updated after a time interval duration corresponding to a sliding window is elapsed; the size of the sliding window can be reasonably adjusted according to the frequency of data acquisition of a data acquisition system and the precision of the prediction model, and meanwhile, the running time of the prediction model is controlled to be at millisecond level, so that the purpose of real-time prediction is achieved.
Based on the content of the foregoing method embodiment, as an optional embodiment, the method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes, after the prediction model is updated: the size of the sliding window is adjusted according to the frequency of data acquired by the data acquisition system and the precision of the prediction model, and meanwhile, the operation duration of the prediction model is controlled to be millisecond level, so that the concentration of nitrogen oxides at the inlet of the SCR denitration reactor is predicted in real time.
Based on the content of the foregoing method embodiment, as an optional embodiment, the method for predicting nitrogen oxide concentration at an inlet of an SCR denitration reactor provided in the embodiment of the present invention further includes, after predicting the nitrogen oxide concentration at the inlet of the SCR denitration reactor in real time by using a final prediction model: updating a prediction model by taking real-time acquired data and an actual value of the concentration of nitrogen oxides at an inlet of the SCR denitration reactor calculated by adopting a time-varying function as latest historical data; the real-time data acquisition and the actual value of the concentration of nitrogen oxides at the inlet of the SCR denitration reactor calculated by adopting a time-varying function are stored in a database.
The method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided by the embodiment of the invention comprises the steps of obtaining and preprocessing the operation data of a plurality of boilers and the SCR denitration reactor, determining the input and output variables of a prediction model, constructing the prediction model by adopting a classification algorithm based on data driving, and adopting a regularization parameter with a large influence on the performance of the model by adopting a queue competition algorithm
Figure 471941DEST_PATH_IMAGE001
And kernel function width
Figure 144843DEST_PATH_IMAGE002
Optimizing, determining the optimal values of the two parameters, minimizing the error of the model, and improving the prediction accuracy of the model; adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths so as to predictThe time length corresponding to the minimum root mean square error in the result is the lag time length, the prediction model is updated by adopting the sliding window to obtain the final prediction model, the concentration of nitrogen oxides at the inlet of the SCR denitration reactor can be accurately predicted, the dependence on manual experience is avoided, and the prediction model can be updated in real time.
The method for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor, provided by the embodiment of the invention, collects the operating data of a coal fired power plant boiler and the SCR denitration reactor in a preset area, the total number of sample data is 9400, the size of a sliding window is set to 240, the first 240 data are taken as model initialization historical data according to the time sequence, each 800 data are taken as a group for prediction, the model is evaluated, the RMSE (root mean square error) value of the predicted value and the actual value of the sample data in a test set is within 20, and the method is verified to have higher precision.
The implementation basis of the various embodiments of the present invention is realized by programmed processing performed by a device having a processor function. Therefore, in engineering practice, the technical solutions and functions thereof of the embodiments of the present invention can be packaged into various modules. Based on this actual situation, on the basis of the above embodiments, embodiments of the present invention provide an SCR denitration reactor inlet nitrogen oxide concentration prediction apparatus for performing the SCR denitration reactor inlet nitrogen oxide concentration prediction method in the above method embodiments. Referring to fig. 2, the apparatus includes: the first main module is used for acquiring the operation data of a plurality of boilers and SCR denitration reactors, eliminating abnormal values in the operation data and combining the parameters with the same type and the consistent variation trend; the second main module is used for determining input and output variables of the prediction model, constructing the prediction model by adopting a classification algorithm based on data driving, and adopting a regularization parameter with a large influence on the performance of the model by adopting a queue competition algorithm
Figure 523872DEST_PATH_IMAGE061
And kernel function width
Figure 917944DEST_PATH_IMAGE062
Proceed optimization and confirmationDetermining the optimal values of the two parameters to minimize the model error and improve the prediction precision of the model; adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, and updating the prediction model by adopting a sliding window with the time length corresponding to the minimum root mean square error in the prediction results as the lag time length; and the third main module is used for training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model.
The device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor, provided by the embodiment of the invention, adopts a plurality of modules in FIG. 2, determines the input and output variables of a prediction model by acquiring and preprocessing the operation data of a plurality of boilers and the SCR denitration reactor, constructs the prediction model by adopting a classification algorithm based on data driving, and adopts a regularization parameter which has a large influence on the performance of the model by a queue competition algorithm
Figure 345514DEST_PATH_IMAGE063
And kernel function width
Figure 938170DEST_PATH_IMAGE064
Optimizing, determining the optimal values of the two parameters, minimizing the error of the model, and improving the prediction accuracy of the model; adding a time-varying function into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, taking the time length corresponding to the minimum root mean square error in the prediction results as the lag time length, updating the prediction model by adopting a sliding window to obtain a final prediction model, accurately predicting the nitrogen oxide concentration at the inlet of the SCR denitration reactor, avoiding dependence on manual experience, and updating the prediction model in real time.
It should be noted that, the apparatus in the apparatus embodiment provided by the present invention may be used for implementing methods in other method embodiments provided by the present invention, except that corresponding function modules are provided, and the principle of the apparatus embodiment provided by the present invention is basically the same as that of the apparatus embodiment provided by the present invention, so long as a person skilled in the art obtains corresponding technical means by combining technical features on the basis of the apparatus embodiment described above, and obtains a technical solution formed by these technical means, on the premise of ensuring that the technical solution has practicability, the apparatus in the apparatus embodiment described above may be modified, so as to obtain a corresponding apparatus class embodiment, which is used for implementing methods in other method class embodiments. For example:
based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: the first sub-module is used for realizing the construction of the prediction model by adopting a data-driven-based classification algorithm and adopting a regularization parameter which has a great influence on the performance of the model by adopting a queue competition algorithm
Figure 691362DEST_PATH_IMAGE065
And kernel function width
Figure 41572DEST_PATH_IMAGE064
Performing optimization to determine the optimal values of the two parameters, including:
Figure 335150DEST_PATH_IMAGE003
Figure 985574DEST_PATH_IMAGE004
Figure 644089DEST_PATH_IMAGE005
Figure 12753DEST_PATH_IMAGE006
wherein the content of the first and second substances,
Figure 844443DEST_PATH_IMAGE007
to the eyesMinimum value of scalar function;
Figure 83794DEST_PATH_IMAGE008
the vector coefficients of (a);
Figure 178789DEST_PATH_IMAGE009
is a non-linear transformation;
Figure 565908DEST_PATH_IMAGE010
is the nth element of the vector coefficient;
Figure 404551DEST_PATH_IMAGE011
is the norm of the vector coefficient;
Figure 763988DEST_PATH_IMAGE012
is a regularization parameter;
Figure 29885DEST_PATH_IMAGE013
predicting an error vector for the ith training set; n is the number of prediction error vectors of the training set; b is a prediction model parameter;
Figure 904300DEST_PATH_IMAGE014
is the ith Lagrangian multiplier; k is a kernel function; x is an input vector;
Figure 15475DEST_PATH_IMAGE015
is the ith input vector;
Figure 494998DEST_PATH_IMAGE016
is a prediction model;
Figure 728533DEST_PATH_IMAGE017
is the ith output vector;
Figure 293507DEST_PATH_IMAGE018
are constraints.
Based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: a second submodule, configured to implement the time-varying function, including:
Figure 228881DEST_PATH_IMAGE066
Figure 828490DEST_PATH_IMAGE054
Figure 232926DEST_PATH_IMAGE055
wherein z is a time-varying function;
Figure 754037DEST_PATH_IMAGE022
is the parameter value at the time t;
Figure 738174DEST_PATH_IMAGE067
the input vector at the K-th moment is taken as the input vector;
Figure 989027DEST_PATH_IMAGE024
the time-varying function output quantity at the K time is obtained; f is a time-varying function expression.
Based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: a third sub-module for implementing the minimum root mean square error comprises:
Figure 502048DEST_PATH_IMAGE068
wherein RMSE is the root mean square error; m is the number of samples;
Figure 776034DEST_PATH_IMAGE026
is the ith predicted value;
Figure 298282DEST_PATH_IMAGE060
is the ith true value.
Based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: a fourth sub-module, configured to update the prediction model with a sliding window, where the updating includes: the method comprises the steps that a sliding window technology is used for updating a nitrogen oxide concentration prediction model at an SCR denitration inlet in real time, the prediction model is initialized at the starting stage, the prediction model adopts a self-contained historical database to establish an initial model for initial prediction, the self-contained historical database for initialization modeling of the prediction model is gradually replaced by latest actual operation data along with the operation of the prediction model, and the prediction model is updated after a time interval corresponding to a sliding window.
Based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: a fifth sub-module, configured to implement, after the prediction model is updated, further comprising: the size of the sliding window is adjusted according to the frequency of data acquired by the data acquisition system and the precision of the prediction model, and meanwhile, the operation duration of the prediction model is controlled to be millisecond level, so that the concentration of nitrogen oxides at the inlet of the SCR denitration reactor is predicted in real time.
Based on the content of the foregoing device embodiment, as an optional embodiment, the device for predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor provided in the embodiment of the present invention further includes: the sixth sub-module is configured to realize that after the final prediction model is used to predict the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time, the method further includes: updating a prediction model by taking real-time acquired data and an actual value of the concentration of nitrogen oxides at an inlet of the SCR denitration reactor calculated by adopting a time-varying function as latest historical data; the real-time data acquisition and the actual value of the concentration of nitrogen oxides at the inlet of the SCR denitration reactor calculated by adopting a time-varying function are stored in a database.
The method of the embodiment of the invention is realized by depending on the electronic equipment, so that the related electronic equipment is necessarily introduced. To this end, an embodiment of the present invention provides an electronic apparatus, as shown in fig. 3, including: the system comprises at least one processor (processor), a communication Interface (communication Interface), at least one memory (memory) and a communication bus, wherein the at least one processor, the communication Interface and the at least one memory are communicated with each other through the communication bus. The at least one processor may invoke logic instructions in the at least one memory to perform all or a portion of the steps of the methods provided by the various method embodiments described above.
In addition, the logic instructions in the at least one memory may be implemented in software functional units and stored in a computer readable storage medium when sold or used as a stand-alone product. Based on such understanding, the technical solution of the present invention may be embodied in the form of a software product, which is stored in a storage medium and includes instructions for causing a computer device (which may be a personal computer, a server, or a network device) to execute all or part of the steps of the method according to the method embodiments of the present invention. And the aforementioned storage medium includes: a U-disk, a removable hard disk, a Read-Only Memory (ROM), a Random Access Memory (RAM), a magnetic disk or an optical disk, and other various media capable of storing program codes.
The above-described embodiments of the apparatus are merely illustrative, and the units described as separate parts may or may not be physically separate, and parts displayed as units may or may not be physical units, may be located in one place, or may be distributed on a plurality of network units. Some or all of the modules may be selected according to actual needs to achieve the purpose of the solution of the present embodiment. One of ordinary skill in the art can understand and implement it without inventive effort.
Through the above description of the embodiments, those skilled in the art will clearly understand that each embodiment can be implemented by software plus a necessary general hardware platform, and certainly can also be implemented by hardware. With this understanding in mind, the above-described technical solutions may be embodied in the form of a software product, which can be stored in a computer-readable storage medium such as ROM/RAM, magnetic disk, optical disk, etc., and includes instructions for causing a computer device (which may be a personal computer, a server, or a network device, etc.) to execute the methods described in the embodiments or some parts of the embodiments.
The flowchart and block diagrams in the figures illustrate the architecture, functionality, and operation of possible implementations of systems, methods and computer program products according to various embodiments of the present invention. Based on this recognition, each block in the flowchart or block diagrams may represent a module, a program segment, or a portion of code, which comprises one or more executable instructions for implementing the specified logical function(s). It should also be noted that, in some alternative implementations, the functions noted in the block may occur out of the order noted in the figures. For example, two blocks shown in succession may, in fact, be executed substantially concurrently, or the blocks may sometimes be executed in the reverse order, depending upon the functionality involved. It will also be noted that each block of the block diagrams and/or flowchart illustration, and combinations of blocks in the block diagrams and/or flowchart illustration, can be implemented by special purpose hardware-based systems which perform the specified functions or acts, or combinations of special purpose hardware and computer instructions.
In this patent, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.

Claims (10)

1. A method for predicting the concentration of nitrogen oxides at an inlet of an SCR denitration reactor is characterized by comprising the following steps: acquiring operation data of a plurality of boilers and SCR denitration reactors, removing abnormal values in the operation data, and combining parameters of the same type with consistent variation trend; determining input and output variables of a prediction model, constructing the prediction model by adopting a classification algorithm, adding a time-varying function in the prediction model to obtain the prediction results of the concentration of the nitric oxide under different lag time lengths, and updating the prediction model by adopting a sliding window by taking the time length corresponding to the minimum root-mean-square error in the prediction results as the lag time length; and training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model.
2. The method for predicting the concentration of nitrogen oxides at the inlet of an SCR denitration reactor according to claim 1, wherein the constructing a prediction model by using a classification algorithm comprises the following steps:
Figure DEST_PATH_IMAGE001
Figure 131135DEST_PATH_IMAGE002
Figure DEST_PATH_IMAGE003
Figure 815057DEST_PATH_IMAGE004
wherein the content of the first and second substances,
Figure DEST_PATH_IMAGE005
is the minimum value of the objective function;
Figure 576340DEST_PATH_IMAGE006
the vector coefficients of (a);
Figure DEST_PATH_IMAGE007
is a non-linear transformation;
Figure 105541DEST_PATH_IMAGE008
is the nth element of the vector coefficient;
Figure DEST_PATH_IMAGE009
is the norm of the vector coefficient;
Figure 534249DEST_PATH_IMAGE010
is a regularization parameter;
Figure DEST_PATH_IMAGE011
predicting an error vector for the ith training set; n is the number of prediction error vectors of the training set; b is a prediction model parameter;
Figure 389072DEST_PATH_IMAGE012
is the ith Lagrangian multiplier; k is a kernel function; x is an input vector;
Figure DEST_PATH_IMAGE013
is the ith input vector;
Figure 372072DEST_PATH_IMAGE014
is a prediction model;
Figure DEST_PATH_IMAGE015
is the ith output vector;
Figure 967613DEST_PATH_IMAGE016
are constraints.
3. The SCR denitration reactor inlet nox concentration prediction method of claim 2, wherein the time-varying function comprises:
Figure DEST_PATH_IMAGE017
Figure 250827DEST_PATH_IMAGE018
Figure DEST_PATH_IMAGE019
wherein z is a time-varying function;
Figure 276552DEST_PATH_IMAGE020
is the parameter value at the time t;
Figure DEST_PATH_IMAGE021
the input vector at the K-th moment is taken as the input vector;
Figure 746848DEST_PATH_IMAGE022
the time-varying function output quantity at the K time is obtained; f is a time-varying function expression.
4. The method of predicting the inlet nitrogen oxide concentration of an SCR denitration reactor of claim 3, wherein the minimum root mean square error comprises:
Figure DEST_PATH_IMAGE023
wherein RMSE is the root mean square error; m is the number of samples;
Figure 149010DEST_PATH_IMAGE024
is the ith predicted value;
Figure DEST_PATH_IMAGE025
is the ith true value.
5. The method of predicting the inlet nitrogen oxide concentration of an SCR denitration reactor according to claim 4, wherein the updating the prediction model by using a sliding window comprises: the method comprises the steps that a sliding window technology is used for updating a nitrogen oxide concentration prediction model at an SCR denitration inlet in real time, the prediction model is initialized at the starting stage, the prediction model adopts a self-contained historical database to establish an initial model for initial prediction, the self-contained historical database for initialization modeling of the prediction model is gradually replaced by latest actual operation data along with the operation of the prediction model, and the prediction model is updated after a time interval corresponding to a sliding window.
6. The SCR denitration reactor inlet nox concentration prediction method of claim 5, further comprising, after the prediction model is updated: the size of the sliding window is adjusted according to the frequency of data acquired by the data acquisition system and the precision of the prediction model, and meanwhile, the operation duration of the prediction model is controlled to be millisecond level, so that the concentration of nitrogen oxides at the inlet of the SCR denitration reactor is predicted in real time.
7. The method of predicting the inlet nitrogen oxide concentration of an SCR denitration reactor according to claim 6, further comprising, after predicting the inlet nitrogen oxide concentration of the SCR denitration reactor in real time by using the final prediction model: updating a prediction model by taking real-time acquired data and an actual value of the concentration of nitrogen oxides at an inlet of the SCR denitration reactor calculated by adopting a time-varying function as latest historical data; the real-time data acquisition and the actual value of the concentration of nitrogen oxides at the inlet of the SCR denitration reactor calculated by adopting a time-varying function are stored in a database.
8. An apparatus for predicting concentration of nitrogen oxides at inlet of SCR denitration reactor, comprising: the first main module is used for acquiring the operation data of a plurality of boilers and SCR denitration reactors, eliminating abnormal values in the operation data and combining the parameters with the same type and the consistent variation trend; the second main module is used for determining input and output variables of the prediction model, constructing the prediction model by adopting a classification algorithm, adding time-varying functions into the prediction model to obtain the nitrogen oxide concentration prediction results under different lag time lengths, and updating the prediction model by adopting a sliding window by taking the time length corresponding to the minimum root mean square error in the prediction results as the lag time length; and the third main module is used for training and testing the updated prediction model to obtain a final prediction model, and predicting the concentration of nitrogen oxides at the inlet of the SCR denitration reactor in real time by adopting the final prediction model.
9. An electronic device, comprising:
at least one processor, at least one memory, and a communication interface; wherein the content of the first and second substances,
the processor, the memory and the communication interface are communicated with each other;
the memory stores program instructions executable by the processor, the processor invoking the program instructions to perform the method of any of claims 1 to 7.
10. A non-transitory computer-readable storage medium storing computer instructions for causing a computer to perform the method of any one of claims 1 to 7.
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