CN113541524B - A triboelectric nanogenerator based on levitation-slip charge self-excitation - Google Patents

A triboelectric nanogenerator based on levitation-slip charge self-excitation Download PDF

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CN113541524B
CN113541524B CN202110881715.2A CN202110881715A CN113541524B CN 113541524 B CN113541524 B CN 113541524B CN 202110881715 A CN202110881715 A CN 202110881715A CN 113541524 B CN113541524 B CN 113541524B
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胡陈果
刘文林
龙梨
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Chongqing University
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Abstract

The invention discloses a friction nano generator based on suspension sliding type charge self-excitation, which comprises a TENG and a charge self-excitation system, wherein the charge self-excitation system is used for generating an excitation voltage so as to accumulate TENG charges; the TENG comprises a stator and a rotor, and an air gap exists between the stator and the rotor; the output end of the stator is connected with the input end of the charge self-excitation system, and the output end of the charge self-excitation system is connected with the input end of the rotor. The output charges are continuously and automatically increased through positive feedback between the rotor electrode and the stator electrode so as to improve the output power, and meanwhile, through the design of a suspension structure, the problem of contact wear is effectively avoided, and the service life of a device is prolonged.

Description

一种基于悬浮滑移式电荷自激励的摩擦纳米发电机A self-excited triboelectric nanogenerator based on levitation-slip charge

技术领域technical field

本发明涉及发电机技术领域,特别涉及一种基于悬浮滑移式电荷自激励的摩擦纳米发电机。The invention relates to the technical field of generators, in particular to a self-excited triboelectric nanogenerator based on a suspension slip type electric charge.

背景技术Background technique

分布式能源的应用引起了世界各国的广泛关注。摩擦电纳米发电机(TENG)基于摩擦带电和静电感应的耦合效应,被证明是一种更有效的分布式能量收集策略,如在人体运动、微风、振动等机械能的收集中,可以为个人/小型电子设备提供能量。由于TENG具有成本低、结构简单、材料多样、灵活性和适应性强等突出优点,目前在生物传感、人工智能、高压应用和蓝色能源等方面展现出巨大的应用潜力。The application of distributed energy has attracted widespread attention from all over the world. Triboelectric nanogenerator (TENG) based on the coupling effect of triboelectrification and electrostatic induction has been proved to be a more effective strategy for distributed energy harvesting, such as in the collection of mechanical energy such as human motion, breeze, vibration, etc., which can be used for personal/small Electronic devices provide energy. Due to the outstanding advantages of low cost, simple structure, diverse materials, flexibility and adaptability, TENG has shown great application potential in biosensing, artificial intelligence, high-voltage applications, and blue energy.

TENG在走向实际应用和商业化的进程中,很大程度上受制与较低的输出功率,而TENG的输出功率与其摩擦面电荷密度成二次正比关系。针对滑移式TENG,接触摩擦会导致摩擦面热损失和磨损,从而降低TENG的表面电荷密度,影响其输出性能。一般是通过添加界面润滑油以延缓磨损,但不能有效的避免,且驱动力增大,不利于微能量的收集。非接触的悬浮滑移模式TENG具有很高的耐久性和几乎100%的理论转换效率(摩擦损失为零),可以轻松获取轻微的运动能量,显示了TENG在商业过程中最大的潜力。然而,非接触模式TENG的感应介质层上预先存在的电荷会快速衰减,导致非常小的输出,因此需要通过电荷补充、模式自动转换等方法使非接触TENG的电荷密度和输出功率有了明显的提高,但其目前的电输出到实现实际应用要求之间仍然是一个很大的挑战。因此,有必要发明一种具有高耐久性和高输出性能的新结构摩擦纳米发电机,实现更广泛和更有效的微能量收集与应用。In the process of practical application and commercialization of TENG, it is largely restricted by low output power, and the output power of TENG is quadratically proportional to its tribosurface charge density. For sliding TENG, contact friction will lead to heat loss and wear on the friction surface, thereby reducing the surface charge density of TENG and affecting its output performance. Generally, interface lubricating oil is added to delay wear, but it cannot be effectively avoided, and the driving force increases, which is not conducive to the collection of micro energy. The non-contact levitation-slip mode TENG with high durability and almost 100% theoretical conversion efficiency (zero friction loss) can easily harvest slight motion energy, showing the greatest potential of TENG in commercial processes. However, the pre-existing charges on the sensing medium layer of non-contact mode TENG will decay rapidly, resulting in very small output, so it is necessary to make the charge density and output power of non-contact TENG significantly improved by means of charge replenishment and automatic mode switching. However, it is still a big challenge between its current electrical output and the realization of practical application requirements. Therefore, it is necessary to invent a new structural triboelectric nanogenerator with high durability and high output performance to achieve wider and more efficient micro-energy harvesting and application.

发明内容Contents of the invention

针对现有技术中摩擦发电机耐久性和输出功率较低的问题,本发明提出一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,通过动子电极与定子电极之间的正反馈实现输出电荷连续自增以提高输出功率,同时通过悬浮结构设计,有效避免接触磨损问题,延长器件的使用寿命。Aiming at the problems of low durability and low output power of the triboelectric generator in the prior art, the present invention proposes a triboelectric nanogenerator based on the levitation slip type charge self-excitation, which is realized by the positive feedback between the mover electrode and the stator electrode The output charge increases continuously to increase the output power. At the same time, the design of the suspension structure can effectively avoid the problem of contact wear and prolong the service life of the device.

为了实现上述目的,本发明提供以下技术方案:In order to achieve the above object, the present invention provides the following technical solutions:

一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,包括具有TENG和电荷自激励系统,所述电荷自激励系统用于产生激励电压,从而使TENG电荷累积;所述TENG包括定子和动子,定子和动子之间存在空气间隙;定子的输出端与电荷自激励系统的输入端连接,电荷自激励系统的输出端与动子的输入端连接。A triboelectric nanogenerator based on suspension slip type electric charge self-excitation, including TENG and electric charge self-excitation system, described electric charge self-excitation system is used for generating excitation voltage, thereby makes TENG charge accumulation; Said TENG includes stator and dynamic There is an air gap between the stator, the stator and the mover; the output of the stator is connected to the input of the charge self-excitation system, and the output of the charge self-excitation system is connected to the input of the mover.

优选的,所述动子包括第一硬质基板1、第一绝缘介电膜2和金属感应电极3,第一绝缘介电膜1和金属感应电极3分别设置在第一硬质基板1的下表面且第一绝缘介电膜2和金属感应电极3之间有间隙,金属感应电极3的下表面还覆盖有第二绝缘介电膜4。Preferably, the mover includes a first hard substrate 1, a first insulating dielectric film 2 and a metal sensing electrode 3, and the first insulating dielectric film 1 and the metal sensing electrode 3 are respectively arranged on the first hard substrate 1. There is a gap between the lower surface and the first insulating dielectric film 2 and the metal sensing electrode 3 , and the lower surface of the metal sensing electrode 3 is also covered with a second insulating dielectric film 4 .

优选的,所述第一绝缘介电膜2采用驻极体材料,第二绝缘介电膜4采用尼龙膜。Preferably, the first insulating dielectric film 2 is made of electret material, and the second insulating dielectric film 4 is made of nylon film.

优选的,第二绝缘介电膜4的尺寸大于金属感应电极3的尺寸。Preferably, the size of the second insulating dielectric film 4 is larger than the size of the metal sensing electrode 3 .

优选的,所述定子包括第二硬质基板8、第一电极6、第二电极7和第三绝缘介电膜5,第一电极6、第二电极7分别设置第二硬质基板8的上表面,第一电极6、第二电极7的上表面覆盖有第三绝缘介电膜5。Preferably, the stator includes a second hard substrate 8, a first electrode 6, a second electrode 7 and a third insulating dielectric film 5, and the first electrode 6 and the second electrode 7 are respectively arranged on the second hard substrate 8. The upper surfaces, the upper surfaces of the first electrode 6 and the second electrode 7 are covered with a third insulating dielectric film 5 .

优选的,所述第三绝缘介电膜5采用尼龙膜。Preferably, the third insulating dielectric film 5 is a nylon film.

优选的,所述电荷自激励系统包括串联的自倍压整流电路和耐高压的整流二极管,自倍压整流电路的具体电路为:Preferably, the charge self-excitation system includes a series self-voltage doubler rectifier circuit and a high-voltage-resistant rectifier diode, and the specific circuit of the self-voltage doubler rectifier circuit is:

定子上的第一电极通过第一输入端与第一电容的一端连接,定子上的第二电极通过第二输入端分别与第一二极管的正极和第四电容的一端连接,第一二极管的负极和第一电容的另一端并联后分别与第二二极管的正极和第二电容的一端连接,第二二极管的负极和第四电容的另一端并联后分别与第三二极管的正极和第五电容的一端连接,第三二极管的负极和第二电容的另一端并联后分别和第四二极管的正极和第三电容的一端连接,第四二极管的负极和第五电容的另一端并联后与第五二极管的正极连接,第五二极管的负极和第三电容的另一端并联后与整流二极管的正极连接,整流二极管的负极连接输出端。The first electrode on the stator is connected to one end of the first capacitor through the first input end, and the second electrode on the stator is respectively connected to the anode of the first diode and one end of the fourth capacitor through the second input end. The negative electrode of the pole tube is connected in parallel with the other end of the first capacitor, respectively connected with the positive electrode of the second diode and one end of the second capacitor, and the negative electrode of the second diode is connected in parallel with the other end of the fourth capacitor respectively with the third capacitor. The anode of the diode is connected to one end of the fifth capacitor, the cathode of the third diode is connected in parallel with the other end of the second capacitor, and is respectively connected to the anode of the fourth diode and one end of the third capacitor, and the fourth diode The cathode of the tube and the other end of the fifth capacitor are connected in parallel to the anode of the fifth diode, the cathode of the fifth diode and the other end of the third capacitor are connected in parallel to the anode of the rectifier diode, and the cathode of the rectifier diode is connected to output.

优选的,所述电荷自激励系统产生的激励电压与TENG电荷累积Q的关系如下:Preferably, the relationship between the excitation voltage generated by the charge self-excitation system and the TENG charge accumulation Q is as follows:

Figure BDA0003192607240000031
Figure BDA0003192607240000031

公式(1)中,Q表示TENG的电荷累积;d1是第二绝缘介质膜和第三绝缘介质膜之间的距离,ε0是真空介电常数;S是动子上金属感应电极的面积,VE表示电荷自激励系统产生的激励电压。In formula (1), Q represents the charge accumulation of TENG; d1 is the distance between the second insulating dielectric film and the third insulating dielectric film, ε0 is the vacuum permittivity; S is the area of the metal sensing electrode on the mover, VE represents the excitation voltage generated by the charge self-excitation system.

优选的,TENG电荷累积最大电荷密度QMax满足:Preferably, the TENG charge accumulation maximum charge density Q Max satisfies:

Figure BDA0003192607240000032
Figure BDA0003192607240000032

公式(2)中,P表示气体的压强;d2是定子上的第二电极和动子上的金属感应电极之间的距离;ε0是真空介电常数;S是动子上金属感应电极的面积;A和B是由气体的组成成分和压强决定的常数,标准大气压为101kPa时,A为2.87×105V(atm·m)-1,B为12.6。In the formula (2), P represents the pressure of the gas; d2 is the distance between the second electrode on the stator and the metal induction electrode on the mover; ε0 is the vacuum dielectric constant; S is the distance between the metal induction electrode on the mover Area; A and B are constants determined by the composition and pressure of the gas. When the standard atmospheric pressure is 101kPa, A is 2.87×105V(atm·m) -1 and B is 12.6.

优选的,所述定子和动子之间的排列方式包括绕圆周放射性排列、直线排列或者曲线排列,形成可以收集转动或者滑动能量的摩擦纳米发电机。Preferably, the arrangement between the stator and the mover includes a radial arrangement around the circumference, a linear arrangement or a curved arrangement, forming a frictional nanogenerator that can collect rotational or sliding energy.

综上所述,由于采用了上述技术方案,与现有技术相比,本发明至少具有以下有益效果:In summary, due to the adoption of the above technical solution, compared with the prior art, the present invention at least has the following beneficial effects:

本发明的悬浮滑移式电荷自激励摩擦发电机设计新颖合理,结构简单、成本低、适用场景广。采用悬浮滑移式结构和自倍压整流电路设计的结合,使得发电机能快速的产生高激励电压和快速的电荷累积;电极表面的绝缘介电膜能有效的减小电极上电荷的衰减和避免空气击穿,实现较大的能量输出。The suspension-sliding charge self-excited friction generator of the present invention is novel and reasonable in design, simple in structure, low in cost and wide in applicable scenarios. The combination of floating-slip structure and self-voltage rectification circuit design enables the generator to quickly generate high excitation voltage and rapid charge accumulation; the insulating dielectric film on the electrode surface can effectively reduce the attenuation of charges on the electrode and avoid Air breakdown to achieve greater energy output.

由于悬浮结构设计,极大地减小了接触摩擦阻力,提高了能量转化效率,且介质膜表面没有任何磨损,最大限度地延长发电机的使用寿命。动子和定子的设计灵活可变,可以变形为转动式,用于直接收集转动能量,且电极数量和尺寸均可调整以实现不同的需求。悬浮滑移式电荷自激励摩擦发电机在正常环境中能够有效的收集环境中的微风能量,在驱动电子设备和自供能系统等方面具有一定潜力。Due to the design of the suspension structure, the contact friction resistance is greatly reduced, the energy conversion efficiency is improved, and there is no wear on the surface of the dielectric film, which maximizes the service life of the generator. The design of the mover and stator is flexible and variable, and can be transformed into a rotary type for direct collection of rotational energy, and the number and size of electrodes can be adjusted to meet different needs. The levitation-slip charge self-excited triboelectric generator can effectively collect the breeze energy in the environment in normal environments, and has certain potential in driving electronic equipment and self-powered systems.

附图说明:Description of drawings:

图1为根据本发明示例性实施例的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机结构示意图。Fig. 1 is a schematic structural diagram of a self-excited triboelectric nanogenerator based on levitation-slip charge according to an exemplary embodiment of the present invention.

图2为根据本发明示例性实施例的电荷自激励系统电路示意图。Fig. 2 is a schematic circuit diagram of a charge self-excitation system according to an exemplary embodiment of the present invention.

图3为根据本发明示例性实施例的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机工作电荷积累示意图。Fig. 3 is a schematic diagram of working charge accumulation of a triboelectric nanogenerator based on levitation-slip charge self-excitation according to an exemplary embodiment of the present invention.

图4为根据本发明示例性实施例的一种基于空间电荷积累的摩擦发电机不同工作情况下动态输出电荷密度曲线对比示意图。Fig. 4 is a schematic diagram showing a comparison of dynamic output charge density curves under different working conditions of a triboelectric generator based on space charge accumulation according to an exemplary embodiment of the present invention.

图5为根据本发明示例性实施例的转动式发电机结构俯视示意图。Fig. 5 is a schematic top view of the structure of a rotary generator according to an exemplary embodiment of the present invention.

图6为根据本发明示例性实施例的一种基于空间电荷积累的摩擦发电机输出性能示意图。Fig. 6 is a schematic diagram of the output performance of a triboelectric generator based on space charge accumulation according to an exemplary embodiment of the present invention.

图7为根据本发明示例性实施例的一种基于空间电荷积累的摩擦发电机在不同风速驱动下的电荷输出情况。Fig. 7 shows the charge output of a triboelectric generator based on space charge accumulation driven by different wind speeds according to an exemplary embodiment of the present invention.

具体实施方式Detailed ways

下面结合实施例及具体实施方式对本发明作进一步的详细描述。但不应将此理解为本发明上述主题的范围仅限于以下的实施例,凡基于本发明内容所实现的技术均属于本发明的范围。The present invention will be further described in detail below in conjunction with examples and specific implementation methods. However, it should not be understood that the scope of the above subject matter of the present invention is limited to the following embodiments, and all technologies realized based on the content of the present invention belong to the scope of the present invention.

在本发明的描述中,需要理解的是,术语“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In describing the present invention, it should be understood that the terms "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", The orientation or positional relationship indicated by "horizontal", "top", "bottom", "inner", "outer", etc. are based on the orientation or positional relationship shown in the drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than Nothing indicating or implying that a referenced device or element must have a particular orientation, be constructed, and operate in a particular orientation should therefore not be construed as limiting the invention.

如图1所示,本发明提供一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,包括具有电荷积累电极的悬浮滑移式TENG和电荷自激励系统。As shown in Figure 1, the present invention provides a triboelectric nanogenerator based on levitation-slip charge self-excitation, including a levitation-slip TENG with charge accumulation electrodes and a charge self-excitation system.

其中,TENG包括动子和定子,动子是相对于定子滑动,定子可以固定和运动,转子和定子互相配合,利用静电感应效应产生交流电输出,为负载提供电能。Among them, TENG includes a mover and a stator. The mover slides relative to the stator. The stator can be fixed and move. The rotor and the stator cooperate with each other to generate alternating current output by using the electrostatic induction effect to provide electric energy for the load.

定子和动子的边缘设置0.35mm厚的亚克力垫片,从而形成空气间隙,进而构成悬浮式滑移结构,可以有效的避免接触磨损,最大限度地延长器件的使用寿命。同时由于定子和动子的非接触结构,TENG的运行阻力较小,需要的驱动力也小,可以用来有效的收集环境中的微风能量。The edges of the stator and the mover are provided with 0.35mm thick acrylic gaskets to form an air gap, thereby forming a floating sliding structure, which can effectively avoid contact wear and maximize the service life of the device. At the same time, due to the non-contact structure of the stator and the mover, the running resistance of TENG is small, and the driving force required is also small, which can be used to effectively collect the breeze energy in the environment.

动子包括第一硬质基板1、第一绝缘介电膜2和金属感应电极3,第一绝缘介电膜2和金属感应电极3分别设置在第一硬质基板1的下表面且第一绝缘介电膜2和金属感应电极3中间有间隙,金属感应电极3的下表面还覆盖有第二绝缘介电膜4。The mover includes a first rigid substrate 1, a first insulating dielectric film 2 and a metal sensing electrode 3, the first insulating dielectric film 2 and the metal sensing electrode 3 are respectively arranged on the lower surface of the first rigid substrate 1 and the first There is a gap between the insulating dielectric film 2 and the metal sensing electrode 3 , and the lower surface of the metal sensing electrode 3 is also covered with a second insulating dielectric film 4 .

本实施例中,第一绝缘介电膜2可采用驻极体材料(例如聚四氟乙烯),可以长时间地保存电荷,为电荷自激励系统提供初始电荷量。In this embodiment, the first insulating dielectric film 2 can be made of an electret material (such as polytetrafluoroethylene), which can store charges for a long time and provide initial charge for the charge self-excitation system.

定子包括第二硬质基板8、第一电极6、第二电极7和第三绝缘介电膜5,第一电极6、第二电极7为电子对(中间有间隙,例如2mm),分别位于第二硬质基板8的上表面,第一电极6、第二电极7的上表面覆盖有第三绝缘介电膜5。The stator includes a second hard substrate 8, a first electrode 6, a second electrode 7 and a third insulating dielectric film 5. The first electrode 6 and the second electrode 7 are electron pairs (there is a gap in the middle, such as 2mm), respectively located at The upper surface of the second hard substrate 8 , the upper surfaces of the first electrode 6 and the second electrode 7 are covered with a third insulating dielectric film 5 .

本实施例中,第二绝缘介电膜4和第三绝缘介电膜5可选用保存电荷能力差的介电膜(例如尼龙),避免膜上电荷积累形成高电势,从而产生静电屏蔽。第二绝缘介电膜4的尺寸应大于金属感应电极3的尺寸,第三绝缘介电膜5的尺寸应大于第一电极6和第二电极7形成的电子对尺寸,以防止边缘空气击穿。In this embodiment, the second insulating dielectric film 4 and the third insulating dielectric film 5 can be selected from dielectric films with poor charge storage capacity (such as nylon), so as to avoid the accumulation of charges on the films to form a high potential, thereby generating electrostatic shielding. The size of the second insulating dielectric film 4 should be larger than the size of the metal sensing electrode 3, and the size of the third insulating dielectric film 5 should be larger than the size of the electron pair formed by the first electrode 6 and the second electrode 7 to prevent edge air breakdown .

第一电极6的输出端连接到电荷自激励系统9的第一输入端,第二电极7的输出端连接到电荷自激励系统9的第二输入端,电荷自激励系统9的输出端连接到动子的金属感应电极3的输入端。第一输入端和第二输入端位于同侧,通过设计电荷自激励系统9中两个输入单同侧的连接方式,实现电荷的连续增长。The output end of the first electrode 6 is connected to the first input end of the charge self-excitation system 9, the output end of the second electrode 7 is connected to the second input end of the charge self-excitation system 9, and the output end of the charge self-excitation system 9 is connected to The input end of the metal sensing electrode 3 of the mover. The first input terminal and the second input terminal are located on the same side, and the continuous growth of charge is realized by designing the connection mode of the two input terminals on the same side in the charge self-excitation system 9 .

如图2所示,所述电荷自激励系统9包括串联的自倍压整流电路和整流二极管:As shown in Figure 2, the charge self-excitation system 9 includes a series self-voltage doubler rectification circuit and a rectifier diode:

第一输入端与第一电容C1的一端连接,第二输入端分别与第一二极管D1的正极和第四电容C4的一端连接,第一二极管D1的负极和第一电容C1的另一端并联后分别与第二二极管D2的正极和第二电容C2的一端连接,第二二极管D2的负极和第四电容C4的另一端并联后分别与第三二极管的正极和第五电容C5的一端连接,第三二极管的的负极和第二电容的另一端并联后分别和第四二极管D4的正极和第三电容C3的一端连接,第四二极管D4的负极和第五电容C5的另一端并联后与第五二极管D5的正极连接,第五二极管D5的负极和第三电容C3的另一端并联后与整流二极管D6的正极连接,整流二极管D6的负极连接输出端。整流二极管D6具有单向导通作用,可保证金属感应电极3中只被连续注入一种极性的电荷,达到电荷积累的效果。D1-D5的型号为1N4007;整流二极管D6型号为2CL20KV;C1、C2、C3、C4、C5的电容为2.2nF,但电容大小可以改变,电容值越小,激励速度越快。The first input end is connected to one end of the first capacitor C1, the second input end is respectively connected to the anode of the first diode D1 and one end of the fourth capacitor C4, and the negative electrode of the first diode D1 is connected to the end of the first capacitor C1. The other end is connected in parallel with the anode of the second diode D2 and one end of the second capacitor C2 respectively, and the cathode of the second diode D2 and the other end of the fourth capacitor C4 are respectively connected in parallel with the anode of the third diode It is connected to one end of the fifth capacitor C5, the negative pole of the third diode is connected in parallel with the other end of the second capacitor, and is respectively connected to the positive pole of the fourth diode D4 and one end of the third capacitor C3, and the fourth diode The negative pole of D4 and the other end of the fifth capacitor C5 are connected in parallel to the positive pole of the fifth diode D5, and the negative pole of the fifth diode D5 and the other end of the third capacitor C3 are connected in parallel to the positive pole of the rectifier diode D6. The cathode of the rectifier diode D6 is connected to the output terminal. The rectifier diode D6 has a one-way conduction function, which can ensure that only one polarity of charge is continuously injected into the metal induction electrode 3 to achieve the effect of charge accumulation. The model of D1-D5 is 1N4007; the model of rectifier diode D6 is 2CL20KV; the capacitance of C1, C2, C3, C4, and C5 is 2.2nF, but the capacitance can be changed. The smaller the capacitance value, the faster the excitation speed.

本实施例中,自倍压整流电路可根据需要选用不同的单元数目以达到更快的电荷增加(激励)速度,本发明为两个单元的自倍压整流电路。自倍压整流电路的激励电压VE与动子的金属感应电极3表面电荷的关系如下:

Figure BDA0003192607240000071
d1是第二绝缘介质膜和第三绝缘介质膜之间的距离,ε0是真空介电常数;S是金属感应电极3的面积。由式可知,动子金属感应电极3上的电荷与自倍压整流电路的激励电压成正比,说明激励电压越大,动子的金属感应电极3上的电荷越大。In this embodiment, the self-voltage doubler rectifier circuit can select different numbers of units according to needs to achieve a faster charge increase (excitation) speed. The present invention is a self-voltage doubler rectifier circuit with two units. The relationship between the excitation voltage V E of the self-voltage doubler rectifier circuit and the surface charge of the metal induction electrode 3 of the mover is as follows:
Figure BDA0003192607240000071
d1 is the distance between the second insulating dielectric film and the third insulating dielectric film, ε 0 is the vacuum dielectric constant; S is the area of the metal sensing electrode 3 . It can be seen from the formula that the charge on the metal sensing electrode 3 of the mover is proportional to the excitation voltage of the self-voltage doubler rectifier circuit, indicating that the greater the excitation voltage, the greater the charge on the metal sensing electrode 3 of the mover.

本实施例中,金属感应电极3、第一电极6、第二电极7可以为金属材料电极,也可以是其他导电硅胶、ITO等非金属导电材料。In this embodiment, the metal sensing electrode 3 , the first electrode 6 , and the second electrode 7 may be metal material electrodes, or other non-metallic conductive materials such as conductive silica gel and ITO.

本实施例中,定子和动子之间存在空气间隙(即第二绝缘介质膜和第三绝缘介质膜之间的距离,距离为d1),从而构成悬浮式滑移结构,并利用静电感应效应产生电能。In this embodiment, there is an air gap between the stator and the mover (that is, the distance between the second insulating dielectric film and the third insulating dielectric film, the distance is d1), thereby forming a floating sliding structure, and using the electrostatic induction effect to generate electrical energy.

本实施例中,在周期性的滑移过程中电荷自激励系统9的工作过程如图3所示。In this embodiment, the working process of the charge self-excitation system 9 in the periodical slipping process is shown in FIG. 3 .

在初始状态下(图3a),第一绝缘介电膜2提前注入较少的电荷(例如负电荷),自倍压整流电路(VMC)两端电压为零。当动子开始周期性运转时,定子电极之间的电位差导致交流输出(图3b、图3c),同时VMC的两端开始充电(例如增加到Vo),输出电压随着运行时间的增加而增加(例如增加到3Vo),电荷自激励系统9输出到动子的金属感应电极3的电荷(正电荷)也在不断累积。动子上第一绝缘介质膜2初始注入的电荷与金属感应电极3上的电荷极性相反,恰好能协同作用,感应定子电极中的电子移动,最后使悬浮滑移式TENG的感应输出不断增加。经过几次循环,VMC的两端电压趋于稳定,输出到动子的金属感应电极3的电荷趋于饱和状态,输出达到最大值(例如增加到5Vo),从而实现了电荷自激工作模式,如图3d所示。In the initial state ( FIG. 3 a ), the first insulating dielectric film 2 injects less charge (for example, negative charge) in advance, and the voltage across the self-voltage doubler rectifier circuit (VMC) is zero. When the mover starts to run periodically, the potential difference between the stator poles leads to an AC output (Fig. 3b, Fig. 3c), and at the same time both ends of the VMC start to charge (for example, increase to Vo), and the output voltage increases with the running time Increase (for example, increase to 3Vo), the charge (positive charge) output from the charge self-excitation system 9 to the metal induction electrode 3 of the mover is also constantly accumulating. The charge initially injected into the first insulating dielectric film 2 on the mover is opposite to the charge on the metal sensing electrode 3, which can work together to induce the movement of electrons in the stator electrodes, and finally increase the induction output of the levitation-slip TENG. . After several cycles, the voltage at both ends of the VMC tends to be stable, the charge output to the metal sensing electrode 3 of the mover tends to be saturated, and the output reaches the maximum value (for example, increased to 5Vo), thereby realizing the charge self-excitation working mode, As shown in Figure 3d.

图4为四种工作情况下动态输出电荷密度曲线对比。图4-①为传统的非接触式TENG输出电荷密度曲线,图4-②为TENG的定子输出连接自倍压整流电路但没有整流二极管D6的输出电荷密度曲线,此时,正负电子将同时注入到金属感应电极3,且自倍压整流电路将消耗部分能量,导致输出下降;图4-③为本发明的输出电荷密度曲线,在整流二极管D6的作用下,金属感应电极3的表面电荷密度迅速上升到一个稳定值;图4-④为本发明电荷自激励系统9关断的情况下,曲线迅速下降到初始值。因此,本发明设计的悬浮滑移式电荷自激励发电机具有强大的电输出能力。Figure 4 is a comparison of dynamic output charge density curves under four working conditions. Figure 4-① is the output charge density curve of the traditional non-contact TENG, and Figure 4-② is the output charge density curve of the TENG stator output connected to the self-voltage doubler rectifier circuit but without the rectifier diode D6. At this time, the positive and negative electrons will be simultaneously Injected into the metal induction electrode 3, and the self-voltage doubler rectification circuit will consume part of the energy, resulting in a drop in output; Figure 4-③ is the output charge density curve of the present invention, under the action of the rectifier diode D6, the surface charge of the metal induction electrode 3 The density rises rapidly to a stable value; Figure 4-④ shows that the curve drops rapidly to the initial value when the charge self-excitation system 9 of the present invention is turned off. Therefore, the suspension-slip electric charge self-excited generator designed in the present invention has a strong electric output capability.

依靠滑移过程中电荷自激励系统9中电容组串并联状态的自动切换,TENG中的感应电荷将成指数形式增加。对于悬浮式TENG,由于气隙的存在,动子和定子之间会发生空气击穿,因此在金属感应电极3表面存在一个最大电荷密度(QMax),满足:

Figure BDA0003192607240000081
P是气体的压强;d2是定子上的第二电极和动子上的金属感应电极之间的距离,ε0是真空介电常数;S是金属感应电极3的面积;A和B是由气体的组成成分和压强决定的常数,标准大气压为101kPa时,A为2.87×105V(atm·m)-1,B为12.6。显然,悬浮式TENG的最大电荷密度随着气隙的增大而减小。Relying on the automatic switching of the series-parallel state of the capacitor group in the charge self-excitation system 9 during the slipping process, the induced charge in the TENG will increase exponentially. For the suspended TENG, due to the existence of the air gap, air breakdown will occur between the mover and the stator, so there is a maximum charge density (Q Max ) on the surface of the metal sensing electrode 3, which satisfies:
Figure BDA0003192607240000081
P is the pressure of the gas; d2 is the distance between the second electrode on the stator and the metal induction electrode on the mover, ε0 is the vacuum dielectric constant; S is the area of the metal induction electrode 3; A and B are formed by the gas The constants determined by the composition and pressure, when the standard atmospheric pressure is 101kPa, A is 2.87×105V(atm·m) -1 , and B is 12.6. Obviously, the maximum charge density of the suspended TENG decreases with the increase of the air gap.

本实施例中,定子和动子可以绕圆周放射性排列、直线排列或者曲线排列,形成可以收集转动或者滑动能量的悬浮式电荷自激励摩擦发电机;收集转动能量的摩擦发电机如图5所示。In this embodiment, the stator and the mover can be arranged radially, in a straight line or in a curve around the circumference to form a suspended charge self-excited friction generator that can collect rotational or sliding energy; the friction generator that collects rotational energy is shown in Figure 5 .

动子和定子的基板15可采用内径、外径、厚分别为19mm、210mm、4mm亚克力板,中心的圆孔用于安装连接转轴。定子上的扇形电极对16和17均为铝电极,电极16的内径、外径、径向角分别为72mm、200mm、30°,电极17的内径、外径、径向角分别为70mm、198mm、30°,电极16和17之间的间隙为2mm;第三介电膜5采用30微米厚的尼龙膜完整的覆盖在电极对表面。动子上,电极18内径、外径、径向角分别为70mm、198mm、30°,厚度为20微米;电极18上覆盖一层第三介电膜5;每块独立的绝缘介质膜19为聚四氟乙烯薄膜(PTFE),厚度为50微米,绝缘介质膜19的内径、外径、径向角分别为72mm、200mm、30°。定子和动子通过转轴相连,一个额外的电刷被使用,连接激励路径,避免绕线问题。The base plate 15 of the mover and the stator can be an acrylic plate with an inner diameter, an outer diameter, and a thickness of 19mm, 210mm, and 4mm respectively, and the central circular hole is used for installing and connecting the rotating shaft. The sector electrode pairs 16 and 17 on the stator are all aluminum electrodes, the inner diameter, outer diameter, and radial angle of the electrode 16 are 72mm, 200mm, and 30° respectively, and the inner diameter, outer diameter, and radial angle of the electrode 17 are 70mm, 198mm, respectively , 30°, the gap between the electrodes 16 and 17 is 2 mm; the third dielectric film 5 is completely covered on the surface of the electrode pair by a 30 micron thick nylon film. On the mover, the inner diameter, outer diameter, and radial angle of the electrode 18 are 70mm, 198mm, and 30° respectively, and the thickness is 20 microns; the electrode 18 is covered with a third dielectric film 5; each independent insulating dielectric film 19 is The polytetrafluoroethylene film (PTFE) has a thickness of 50 microns, and the inner diameter, outer diameter, and radial angle of the insulating dielectric film 19 are 72mm, 200mm, and 30°, respectively. The stator and mover are connected by a shaft, and an additional brush is used to connect the excitation path and avoid winding problems.

为了测试本发明发电机的输出性能,用步进电机在不同转速模式下驱动发电机,同时用吉时利静电计(Keithley 6514)和高速静电电压表(Trek model 370)测量发电机输出性能。In order to test the output performance of the generator of the present invention, a stepper motor was used to drive the generator at different speed modes, and a Keithley electrometer (Keithley 6514) and a high-speed electrostatic voltmeter (Trek model 370) were used to measure the output performance of the generator.

如图6所示:通过电荷自激励,在300rpm的驱动频率下悬浮滑移式摩擦纳米发电机的感应输出电荷能达到1μC,有效电荷密度达到了71.5μC m-2(图6a),图6b、图6c是相应的输出电流和输出电压曲线,分别能达到76μA和470V,这里需要说明由于自励过程需要回路中有电流的存在,因此这里的电压是在外接10MΩ负载下测量得到。图6d展示了输出电荷随着转速的增加而变化的情况,可以看出转移电荷呈现先增加后减少的趋势,这是由于转速较低时电荷激励在短时间内没有达到饱和,当转速增大时,由于制造工艺的不完善,转子的离心力和垂直振动也相应增大,导致转子与定子之间的间隙增大,因此最大输出电荷随着速度的增加而下降。此外,不同外负载电阻下,发电机在300rpm时的功率如图6e所示,在30MΩ时的峰值功率为34.68mW。图6f为对不同电容的充电能力,例如100μF的电容在180s可以充电到50V,220μF的电容在300s可以充电到30V,470μF的电容在300s可以充电到15V,1mF的电容在300s可以充电到5V。As shown in Figure 6: through charge self-excitation, the induced output charge of the suspension-slip triboelectric nanogenerator can reach 1 μC at a driving frequency of 300 rpm, and the effective charge density can reach 71.5 μC m-2 (Figure 6a), Figure 6b , Figure 6c is the corresponding output current and output voltage curves, which can reach 76μA and 470V respectively. Here, it needs to be explained that since the self-excitation process requires the existence of current in the loop, the voltage here is measured under an external 10MΩ load. Figure 6d shows the change of the output charge with the increase of the rotational speed. It can be seen that the transferred charge first increases and then decreases. This is because the charge excitation does not reach saturation in a short time when the rotational speed is low. When the rotational speed increases At this time, due to the imperfection of the manufacturing process, the centrifugal force and vertical vibration of the rotor also increase accordingly, resulting in an increase in the gap between the rotor and the stator, so the maximum output charge decreases with the increase of speed. In addition, under different external load resistances, the power of the generator at 300rpm is shown in Figure 6e, and the peak power at 30MΩ is 34.68mW. Figure 6f shows the charging capabilities of different capacitors. For example, a 100μF capacitor can be charged to 50V in 180s, a 220μF capacitor can be charged to 30V in 300s, a 470μF capacitor can be charged to 15V in 300s, and a 1mF capacitor can be charged to 5V in 300s. .

如图7所示,本发明的发电机,在3m/s的低风速下就能驱动,因此可用于收集微风能量。图7a显示了发电机在不同风速驱动下的电荷输出情况,转移电荷量保持在420nC左右;这里不同于电机驱动的趋势,主要是因为即使在高风速下,相应的转速仍然相对较低。此外,风力的不均匀力和大的波动容易导致较大的垂直振动,降低了低速时的转移电荷。因此,在风力驱动时,由于上述两个因素的偏移,悬浮滑移式电荷自激励摩擦纳米发电机的输出电荷呈现出恒定的趋势。图7b在120MΩ的阻力下,发电机在7m/s风速下实现了16.7mW的峰值功率。As shown in Figure 7, the generator of the present invention can be driven at a low wind speed of 3m/s, so it can be used to collect breeze energy. Figure 7a shows the charge output of the generator driven by different wind speeds, and the amount of transferred charge remains around 420nC; here it is different from the trend of motor drive, mainly because the corresponding rotational speed is still relatively low even at high wind speeds. In addition, the uneven force and large fluctuations of the wind force tend to cause large vertical vibrations, reducing the transfer charge at low speeds. Therefore, when driven by wind, due to the offset of the above two factors, the output charge of the levitation-slip charge self-excited triboelectric nanogenerator presents a constant trend. Figure 7b Under a resistance of 120MΩ, the generator achieved a peak power of 16.7mW at a wind speed of 7m/s.

本实施例中,悬浮滑移式电荷自激励摩擦发电机在5m/s的风速驱动力下,分别点亮912个5mm直径串联绿色LED灯,发出较为明亮的灯光。In this embodiment, under the driving force of the wind speed of 5m/s, the suspension-sliding self-excited triboelectric generator lights up 912 series-connected green LED lights with a diameter of 5mm to emit relatively bright lights.

本领域的普通技术人员可以理解,上述各实施方式是实现本发明的具体实施例,而在实际应用中,可以在形式上和细节上对其作各种改变,而不偏离本发明的精神和范围。Those of ordinary skill in the art can understand that the above-mentioned embodiments are specific examples for realizing the present invention, and in practical applications, various changes can be made to it in form and details without departing from the spirit and spirit of the present invention. scope.

Claims (8)

1.一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,包括定子、动子和电荷自激励系统,定子和动子之间存在空气间隙;所述电荷自激励系统包括串联的自倍压整流电路和整流二极管;1. A triboelectric nanogenerator based on the self-excitation of suspension slip type charge, it is characterized in that, comprises stator, mover and charge self-excitation system, there is air gap between stator and mover; Described charge self-excitation system comprises A self-voltage doubler rectifier circuit and a rectifier diode connected in series; 所述动子包括第一硬质基板(1)、第一绝缘介电膜(2)和金属感应电极(3),第一绝缘介电膜(2)和金属感应电极(3)分别设置在第一硬质基板(1)的下表面且第一绝缘介电膜(2)和金属感应电极(3)之间有间隙,金属感应电极(3)的下表面还覆盖有第二绝缘介电膜(4);The mover includes a first hard substrate (1), a first insulating dielectric film (2) and a metal sensing electrode (3), and the first insulating dielectric film (2) and the metal sensing electrode (3) are respectively arranged on There is a gap between the lower surface of the first hard substrate (1) and the first insulating dielectric film (2) and the metal sensing electrode (3), and the lower surface of the metal sensing electrode (3) is also covered with a second insulating dielectric film. film(4); 所述定子包括第二硬质基板(8)、第一电极(6)、第二电极(7)和第三绝缘介电膜(5),第一电极(6)、第二电极(7)分别设置第二硬质基板(8)的上表面,第一电极(6)、第二电极(7)的上表面覆盖有第三绝缘介电膜(5);The stator includes a second hard substrate (8), a first electrode (6), a second electrode (7) and a third insulating dielectric film (5), the first electrode (6), the second electrode (7) The upper surfaces of the second hard substrate (8) are respectively provided, and the upper surfaces of the first electrode (6) and the second electrode (7) are covered with a third insulating dielectric film (5); 所述第一电极(6)连接自倍压整流电路的第一输入端,第二电极(7)连接自倍压整流电路的第二输入端;自倍压整流电路的输出端连接整流二极管的正极,整流二极管的负极连接金属感应电极(3)。The first electrode (6) is connected to the first input terminal of the self-voltage doubler rectifier circuit, and the second electrode (7) is connected to the second input terminal of the self-voltage doubler rectifier circuit; the output terminal of the self-voltage doubler rectifier circuit is connected to the rectifier diode The anode and the cathode of the rectifier diode are connected to the metal sensing electrode (3). 2.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述第一绝缘介电膜(2)采用驻极体材料,第二绝缘介电膜(4)采用尼龙膜。2. A kind of triboelectric nanogenerator based on self-excitation of levitation slip type electric charge as claimed in claim 1, it is characterized in that, described first insulating dielectric film (2) adopts electret material, the second insulating dielectric film Electric film (4) adopts nylon film. 3.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,第二绝缘介电膜(4)的尺寸大于金属感应电极(3)的尺寸。3. A self-excited triboelectric nanogenerator based on levitation-slip charge as claimed in claim 1, characterized in that the size of the second insulating dielectric film (4) is greater than the size of the metal induction electrode (3). 4.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述第三绝缘介电膜(5)采用尼龙膜。4. The self-excited triboelectric nanogenerator based on suspension-slip electric charges as claimed in claim 1, wherein the third insulating dielectric film (5) is a nylon film. 5.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述自倍压整流电路的具体电路为:5. A kind of self-excited frictional nanogenerator based on suspension slip type electric charge as claimed in claim 1, it is characterized in that, the concrete circuit of described self-voltage doubler rectification circuit is: 定子上的第一电极通过第一输入端与第一电容的一端连接,定子上的第二电极通过第二输入端分别与第一二极管的正极和第四电容的一端连接,第一二极管的负极和第一电容的另一端并联后分别与第二二极管的正极和第二电容的一端连接,第二二极管的负极和第四电容的另一端并联后分别与第三二极管的正极和第五电容的一端连接,第三二极管的负极和第二电容的另一端并联后分别和第四二极管的正极和第三电容的一端连接,第四二极管的负极和第五电容的另一端并联后与第五二极管的正极连接,第五二极管的负极和第三电容的另一端并联后与整流二极管的正极连接。The first electrode on the stator is connected to one end of the first capacitor through the first input end, and the second electrode on the stator is respectively connected to the anode of the first diode and one end of the fourth capacitor through the second input end. The negative electrode of the pole tube is connected in parallel with the other end of the first capacitor, respectively connected with the positive electrode of the second diode and one end of the second capacitor, and the negative electrode of the second diode is connected in parallel with the other end of the fourth capacitor respectively with the third capacitor. The anode of the diode is connected to one end of the fifth capacitor, the cathode of the third diode is connected in parallel with the other end of the second capacitor, and is respectively connected to the anode of the fourth diode and one end of the third capacitor, and the fourth diode The cathode of the tube and the other end of the fifth capacitor are connected in parallel to the anode of the fifth diode, and the cathode of the fifth diode and the other end of the third capacitor are connected in parallel to the anode of the rectifier diode. 6.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述电荷自激励系统产生的激励电压与金属感应电极的电荷累积Q的关系如下:6. A kind of triboelectric nanogenerator based on suspension slip type charge self-excitation as claimed in claim 1, is characterized in that, the relation of the excitation voltage that described electric charge self-excitation system produces and the charge accumulation Q of metal induction electrode is as follows :
Figure FDA0003878266030000021
Figure FDA0003878266030000021
公式(1)中,Q表示金属感应电极的电荷累积;d1是第二绝缘介质膜和第三绝缘介质膜之间的距离,ε0是真空介电常数;S是动子上金属感应电极的面积,VE表示电荷自激励系统产生的激励电压。In the formula (1), Q represents the charge accumulation of the metal sensing electrode; d1 is the distance between the second insulating dielectric film and the third insulating dielectric film, ε0 is the vacuum permittivity; S is the electric charge of the metal sensing electrode on the mover Area, VE represents the excitation voltage generated by the charge self-excitation system.
7.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述金属感应电极的电荷累积最大电荷密度QMax满足:7. A kind of self-excited triboelectric nanogenerator based on levitation slip type charge as claimed in claim 1, is characterized in that, the electric charge accumulation maximum charge density Q Max of described metal induction electrode satisfies:
Figure FDA0003878266030000022
Figure FDA0003878266030000022
公式(2)中,P表示气体的压强;d2是定子上的第二电极和动子上的金属感应电极之间的距离;ε0是真空介电常数;S是动子上金属感应电极的面积;A和B是由气体的组成成分和压强决定的常数,标准大气压为101kPa时,A为2.87×105V(atm·m)-1,B为12.6。In the formula (2), P represents the pressure of the gas; d2 is the distance between the second electrode on the stator and the metal induction electrode on the mover; ε0 is the vacuum dielectric constant; S is the distance between the metal induction electrode on the mover Area; A and B are constants determined by the composition and pressure of the gas. When the standard atmospheric pressure is 101kPa, A is 2.87×105V(atm·m) -1 and B is 12.6.
8.如权利要求1所述的一种基于悬浮滑移式电荷自激励的摩擦纳米发电机,其特征在于,所述定子和动子之间的排列方式包括绕圆周放射性排列、直线排列或者曲线排列,形成收集转动或者滑动能量的摩擦纳米发电机。8. A self-excited triboelectric nanogenerator based on a levitation-slip charge as claimed in claim 1, wherein the arrangement between the stator and the mover includes a radial arrangement around the circumference, a linear arrangement or a curved line Arranged to form triboelectric nanogenerators that collect rotational or sliding energy.
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