CN113530726B - Energy conversion device of nanometer noble metal far infrared capable of improving energy efficiency of fuel for long time and manufacturing method thereof - Google Patents

Energy conversion device of nanometer noble metal far infrared capable of improving energy efficiency of fuel for long time and manufacturing method thereof Download PDF

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CN113530726B
CN113530726B CN202010319461.0A CN202010319461A CN113530726B CN 113530726 B CN113530726 B CN 113530726B CN 202010319461 A CN202010319461 A CN 202010319461A CN 113530726 B CN113530726 B CN 113530726B
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particles
energy conversion
far infrared
water
fuel
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CN113530726A (en
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张文礼
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/02—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/06—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by rays, e.g. infrared and ultraviolet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Abstract

The energy conversion device is installed in the fuel supply pipeline of various internal combustion engines, and the far infrared ray produced by the composite film can perform high-efficiency energy conversion treatment for long-term fuel flowing through the energy conversion device, and after the long-chain hydrocarbon fuel molecules are cracked into short-chain fuel molecules, the short-chain hydrocarbon fuel molecules are thrown into the combustion chambers of the internal combustion engines in sequence for combustion, so that the fuel can exert optimal combustion efficiency.

Description

Energy conversion device of nanometer noble metal far infrared capable of improving energy efficiency of fuel for long time and manufacturing method thereof
Technical Field
The present invention relates to an energy conversion device, and more particularly, to an energy conversion device which can smoothly infiltrate an aqueous solution containing noble metal nanoparticles and far infrared particles into densely distributed holes of the energy conversion device made of porous materials by using a permeation effect generated by a temperature difference effect, so that a composite film containing noble metal nanoparticles and far infrared particles can be formed on the surface and inner walls of the holes of the energy conversion device after the energy conversion device is completely dried by high temperature treatment, and when the energy conversion device is installed in a fuel supply pipeline of various internal combustion engines, far infrared rays generated by the composite film can flow through fuels (whether liquid or gaseous fuels) therein to perform high-efficiency conversion treatment for a long time; in addition, the invention can add cerium (Ce), ruthenium (Ru) and/or rhodium (Rh) nano particles in or outside the composite film, so that each nano platinum particle always has a clean surface through the strong oxygen absorption effect generated by the nano platinum particles, and the energy conversion material can excite the fuel flowing in the composite film to have the maximum energy conversion efficiency.
Background
Currently, combustion exhaust gases emitted by various vehicles and various industries have undoubtedly proven to be a major and important cause of air pollution. Through detailed investigation and research analysis, the exhaust gas generated by various vehicles and various industries mainly comes from combustion exhaust gas (55%) discharged by exhaust pipes of various internal combustion engines, oil gas (25%) leaked from crankcase of various internal combustion engines and oil gas (20%) leaked from oil tank volatilized, and the combustion exhaust gas and leaked oil gas all contain pollutants harmful to human body, such as: sulfur dioxide (SO) 2 ) Carbon monoxide (CO), hydrocarbon (HC)Nitrogen Oxides (NO) x ) Etc.; among them, since the common fossil fuels (gasoline, diesel oil or kerosene, etc.) and coal contain a small amount of sulfur (0.5% to 5%), when these fuels are burned, sulfur (S) therein is mixed with oxygen (O) 2 ) Chemical reaction takes place to produce sulfur dioxide (SO 2 ). Taking coal with a sulfur content of 5% as an example, a one kilomegawatt thermal power plant will produce up to six hundred tons of sulfur dioxide per day. Other sources of sulfur dioxide pollution, including metal refineries, sulfuric acid plants, petroleum refineries, etc. of sulfur mine, are SO widespread that sulfur dioxide exists in large quantities in various vehicles or industrial waste gases burning fossil fuels or coals, and is finally discharged directly into the air, whereby sulfur dioxide (SO 2 ) Is referred to as "primary contaminant"; in addition, there is also an air pollutant which is produced by a chemical reaction of primary pollutant in air, and is called "secondary pollutant", wherein sulfur trioxide (SO) 3 ) Is a typical example of a "secondary contaminant" in industrial air pollution, which is sulfur dioxide (SO 2 ) Under the irradiation of sunlight, with oxygen O in the air 2 The following chemical reaction is carried out to obtain the product:
2SO 2 +O 2 →2SO 3
in fact, sulfur trioxide (SO 3 ) The life cycle in the air is quite short, and the chemical reaction with water molecules in the air is very easy to occur, so that sulfuric acid molecules are generated; on the other hand, sulfuric acid further reacts with ammonia in the air to produce ammonium sulfate (NH) 4 ) 2 SO 4 Sulfuric acid and ammonium sulfate are therefore also secondary contaminants of industrial pollution.
Light smoke in cities is particularly serious on warm, dry and sunny days because its primary contaminant is mainly Nitric Oxide (NO), which is the nitrogen and oxygen in the air, produced by the following chemical reactions under the high temperature of various urban vehicle engines (i.e., the aforementioned internal combustion engines):
N 2 +O 2 +heat→2NO
In fact, this nitric oxide generation process is the same as the nitric oxide generation process upon lightning. Other "light smoke" primary contaminants also include Hydrocarbons (HC) and carbon monoxide (CO) produced by gasoline volatilization leakage. According to researches, general internal combustion engines often generate about 230 g of carbon monoxide pollutant after burning 1 liter of gasoline due to poor combustion efficiency of fuel, and in addition, although Nitric Oxide (NO) is a colorless gas, it slowly chemically reacts with oxygen in the air after being discharged into the air along with vehicle exhaust gas, thereby generating tan nitrogen dioxide (NO) 2 ) The method comprises the steps of carrying out a first treatment on the surface of the Subsequently, under irradiation of ultraviolet rays in sunlight, nitrogen dioxide (NO 2 ) Further, the cleavage generates Nitric Oxide (NO) and atomic oxygen O by the following photochemical reaction:
NO 2 +ultraviolet ray- & gtNO+O + & gt
At this time, since the chemical reaction ability of atomic oxygen O is quite strong, it is very easy to react with oxygen molecules O in the air 2 The following chemical reaction occurs to generate ozone (O) 3 )：
O*+O 2 +M→O 3 +M*；
Wherein M can be nitrogen molecules, oxygen molecules or solid particles, and the function of the M is to absorb heat released in the ozone molecule generation process; ozone (O) 3 ) Is a very pungent molecule whose presence can be easily identified by our nose if every hundred million gas molecules in the air contain an ozone molecule. The above-mentioned formation process of the "light smoke" also causes that different pollutants are hidden in the "light smoke", wherein, as shown in fig. 1, the periods of highest concentration occur in each working day, which are different from each other, and the concentration of nitric oxide in the air will reach the maximum value in the seven-point working period in the morning; then, the nitric oxide will decrease due to the gradual reaction with oxygen, instead the concentration of nitrogen dioxide will gradually increase until around nine points in the morning, the maximum concentration will be reached; if the sun is a sunny day, the ultraviolet rays in the sunlight can continuously catalyze the nitrogen dioxide Causing the ozone concentration in the air to reach a maximum at noon.
On the other hand, if nitrogen dioxide does not undergo the above photochemical reaction, the following chemical reaction with water molecules in the air occurs to produce nitric acid (HNO) 3 ) Nitrous acid (HNO) 2 )：
2NO 2 +H 2 O→HNO 3 +HNO 2
The chemical reaction also helps to condense water vapor in the air. However, since nitric acid and nitrous acid are extremely acidic, if air containing such liquid droplets is sucked, considerable damage to the human body is caused. Furthermore, hydrocarbon (HC) emitted by the volatilization or combustion of gasoline is also mixed with ozone (O 3 ) Or atomic oxygen (O) to produce aldehydes (RCHO) or ketones (RCOR):
HC+O*→HCO
HC+O 3 →HCO 3
HCO+O 2 →HCO 3
HCO 3 +HC→RCHO or RCOR;
wherein HC is hydrocarbon, R represents alkyl, RCHO is aldehyde compound, RCOR is ketone compound. In addition, in the oxynitride (NO) and ozone (O) 3 ) In the presence of Hydrocarbons (HCO) 3 ) The following chemical reactions are also carried out to produce peroxyacyl nitrate (peroxyacyl nitrates PANs) and other products:
HCO 3 +NO→HCO 2 +NO 2
HCO 3 +O 2 →O 3 +HCO 2
HCO 3 +NO 2 →RCO 3 NO 2 (i.e. PANs) +other products
These nitrogen dioxide (NO) 2 ) Ozone (O) 3 ) Nitric acid (HNO) 3 ) Nitrous acid (HNO) 2 ) Aldehyde (RCHO), ketone (RCOR), peroxyacyl nitrate (PANs) and various other organic compounds generated therewith are all "photosmogSecondary contamination.
When the discharged exhaust gas and leaked oil gas are inhaled into human body, the light person not only hurts the organs and nerves of the human body, but also can cause poisoning and death, so that in order to avoid the harm of the discharged exhaust gas and leaked oil gas to the human body, the related industries and authorities in various countries of the world do not draw up campsite to study how to perform corresponding oxidation and reduction treatment on the discharged exhaust gas and leaked oil gas, so that the discharged exhaust gas and leaked oil gas are changed into nontoxic gas and then are safely discharged into the atmosphere. In particular, in the last three decades, the world has been under a strong pressure of increasing environmental protection, energy saving and carbon reduction, and the air pollution causes derived from various internal combustion engines (whether those combusting liquid or gaseous fuels) have been devoted to various researches and analyses, and the following important causes of air pollution are now summarized as a result of the researches and analyses:
1. fuel (whether liquid or gaseous fuel) air blend ratio: in general, when the fuel-air mixture ratio of each of the internal combustion engines is lean in comparison with the theoretical fuel-air mixture ratio, the discharged CO and HC are reduced, but NO x Will increase, when rarer, NO x Also decrease, but easily flameout increases HC; conversely, when the fuel-air mixture ratio of the fuel-air mixture ratio theory used by each of the internal combustion engines is rich, NO x Decrease, but increase CO and HC;
2. ignition period: when the ignition time is delayed, the temperature of the combustion chamber of each internal combustion engine is reduced, so that NO x The result of the slow combustion is also that the exhaust system is maintained at a high temperature, which promotes oxidation and thus reduces HC.
3. Atmospheric conditions: the increase of humidity and the decrease of oxygen concentration in the atmosphere can lower the combustion temperature and reduce NO x Is to occur. The atmospheric pressure affects the intake pressure, engine horsepower, but does not directly affect the combustion temperature, but only indirectly affects the fuel-air mixture ratio.
4. Load and number of revolutions: when the load increases, the intake air pressure increases, resulting in a combustion temperatureRaise and make NO x The concentration increases. At the same load, the discharge amount increases as the number of revolutions increases.
5. Fuel mass: the composition of the fuel has little influence on CO, and when the hydrogen to carbon ratio of the general fuel is small, the combustion temperature is high, and the olefinic and aromatic fuel NO x The emissions are relatively high and the HC emissions are also affected by fuel quality.
6. The main design of each internal combustion engine is as follows: such as: the stroke volume, stroke/inner diameter ratio, surface area/volume ratio, combustion chamber shape, spark plug position, compression ratio, intake port, intake valve configuration, valve timing, etc. have a significant impact on the composition of the exhaust contaminants.
Based on the above-mentioned important causes of air pollution caused by various internal combustion engines, the related industries of the world take different countermeasures for reducing the emission of polluted gas, depending on the design of various internal combustion engines; some of them are used for reducing CO and HC, and some are used for reducing NO x More so, CO, HC and NO can be reduced at the same time x Is contained in the composition. Various air pollution reducing devices and designs which are widely applied to various internal combustion engines at present are introduced one by one as follows:
1. and an automatic temperature adjusting type air filter is additionally arranged: as the temperature in the combustion chamber of each internal combustion engine changes, the atomization state of the fuel is changed, so that the running performance of each internal combustion engine is poor, and the concentration of harmful substances such as CO, HC and the like in the discharged exhaust gas is increased; therefore, by adding the automatic temperature-regulating air filter on each internal combustion engine, the temperature of the sucked air can be always kept at a proper temperature (such as 40 ℃), the running performance during warm-up (warm up) can be effectively improved, the atomization state of fuel can be changed along with the change of the temperature in the combustion chamber of each internal combustion engine, and the fuel atomization can be promoted, so that a stable fuel-air mixing ratio is maintained, each internal combustion engine can always operate in an optimal state, and harmful substances such as CO, HC and the like in exhaust gas are greatly reduced;
2. Improvement of intake manifold and intake hole configuration: the internal diameter and the internal shape of the steam inlet manifold and the air inlet hole of each internal combustion engine are designed and improved, so that the designed and improved steam inlet manifold and air inlet hole can lead the fuel mixture to be uniformly distributed to each combustion chamber (namely, the air cylinder), thereby leading the fuel to be fully combusted, generating the optimal combustion efficiency and effectively reducing the content of CO and HC in the waste gas;
3. improvement of carburetor configuration: the carburetor configuration of each internal combustion engine is designed and improved, so that the precision of the carburetor and each oil nozzle in the carburetor after the design improvement is increased, the efficiency of a choke valve control system, an idle speed compensation device, an idle speed fuel cut-off device and the like can be effectively improved, the fuel mixture can be uniformly distributed to each combustion chamber, the fuel can be fully combusted, the optimal combustion efficiency is generated, and the content of CO and HC in waste gas is effectively reduced;
4. improvement of carburetor control device during deceleration: the device (such as a throttle valve opener, a buffer and the like) for exhausting waste gas during deceleration is designed and improved in the carburetor of each internal combustion engine, so that the carburetor after the design improvement can effectively reduce the exhaust amount of the waste gas during deceleration, thereby greatly reducing CO, HC and NO in the waste gas x The content is as follows.
5. Improvement of combustion chamber configuration: the combustion chamber configuration of each internal combustion engine is designed and improved, so that the combustion chamber after the design improvement can fully burn fuel to generate optimal combustion efficiency, thereby greatly reducing CO, HC and NO in the discharged waste gas x The content is as follows;
6. lean fuel mixture is used: although the most fundamental method for reducing CO and HC is to use a leaner fuel mixture, once the fuel mixture is too lean, a condition that combustion is not easy easily occurs, and a problem that the speed becomes slow after combustion easily occurs; in view of this, the industry has developed and designed a new technology, namely CVCC (Compound Vortex ControlledCombustion), in which the CVCC is ignited with a relatively rich fuel mixture and then burned with a relatively lean fuel mixture;
7. adding an Exhaust Gas Recirculation (EGR): according to the research, the reduction of the highest combustion temperature in the combustion chamber can reduce NO x Therefore, can be exhausted by selfA part of exhaust gas is taken out from the manifold and then is returned to the steam inlet manifold, so that the highest combustion temperature can be reduced, and NO is greatly reduced x Is generated;
8. various devices capable of increasing the combustion speed are additionally arranged: such as: the auxiliary air inlet valve is additionally arranged, the protruding wall is additionally arranged in the combustion chamber, the two spark plugs are additionally arranged, and the like, so that the fuel can be fully combusted by increasing the combustion speed to generate the optimal combustion efficiency, thereby greatly reducing CO, HC and NO in the waste gas x The content is as follows;
9. a secondary air supply device is additionally arranged: the CO and HC discharged from the combustion chamber are fully oxidized in the exhaust manifold and the catalyst converter by the secondary air supply device, so that the oxidation reaction is performed to completely oxidize the CO and HC into CO 2 H and H 2 O, thereby greatly reducing CO, HC and NO x Discharge amount;
10. improvement of ignition device: in order to ensure that the ignition system has more reliable ignition performance, many improvements are made on the ignition device in the industry so as to enable the spark plug to emit stronger sparks by improving high-voltage power; among them, the most improvement is made to increase the energy of the ignition coil, and others are as follows: the improved designs of changing the shape of the spark plug, increasing the electrode gap, improving the wiring connection point, high-voltage wires, and the like are also not enumerated; recently, the most widely used ignition devices are electronic ignition devices, microcomputer ignition devices and direct ignition devices;
11. improvement and addition of oxidation catalyst converter: the oxidation catalyst oxidizes CO and HC in the exhaust gas to harmless CO 2 Water vapor H 2 O, while the catalyst merely promotes the progress of oxidation, itself is unchanged;
12. improvement and addition of ternary catalytic converter: the ternary catalyst converter can oxidize toxic components CO and HC in the exhaust gas into CO when the exhaust gas discharged by each internal combustion engine passes through the ternary catalyst converter 2 H and H 2 O, and NO x Reduction to N 2 . Three-way catalyst for CO, HC and NO in narrow region near theoretical fuel-air mixture ratio x The three pollution components have high purification effect, therebyCan greatly reduce CO, HC and NO x Is a discharge amount of (2);
13. adding a fuel injection device: in each internal combustion engine using the fuel injection supply device, the injection amount, injection time and fuel-air mixing ratio of the fuel can be strictly and accurately controlled, so that the generation of CO, HC and NOx can be effectively reduced at the same time;
14. adding a recovery device for leaked oil gas; by additionally arranging the reduction device, leaked and volatilized oil gas can be recovered from the crankcase and the oil tank, and the recovered oil gas is reversely thrown into the air inlet system, so that the recovered oil gas is completely burnt, and the leaked and volatilized oil gas cannot be discharged out of various internal combustion engines.
No matter what kind of improvement design is performed on each internal combustion engine in the industry, in fact, up to now, harmful pollutants discharged by each internal combustion engine still continuously take poison to the fragile ecological environment, so that the ecological environment is gradually deteriorated to the extent that the ecological environment is difficult to recover, and along with the occurrence of holes and greenhouse effect on an ozone layer, extreme weather also has seriously affected normal life of human beings, and in view of the fact, countries around the world have had to make positive response to the legislation of ecological protection, pollution prevention and the like, however, while the detail examination of the various treatment strategies is good, the method can only take the effect of treating the symptoms at best, and the air pollution problem caused by each internal combustion engine cannot be fundamentally and thoroughly solved. According to the method, the most fundamental method for solving the air pollution problem caused by each internal combustion engine is to reduce the use of various internal combustion engines, and effectively improve the energy efficiency of the fuel so as to ensure that the fuel can not only obtain the optimal combustion in the combustion process to generate the maximum power, but also ensure that harmful pollutants in the fuel can be completely consumed in the optimal combustion process without remaining in the discharged exhaust gas. Therefore, the method can actively reduce the consumption of the petrochemical fuel, effectively realize the aim of low-pollution or zero-pollution exhaust emission, and only then can provide a clean and comfortable perpetual living space for the subsequent generation.
Therefore, how to utilize a new device which has a simple structure and is easy to realize on each internal combustion engine for the fuel (whether liquid or gaseous) combusted in each internal combustion engine used in the market at present, the new device can effectively improve the combustion efficiency of the fuel in the conversion place of improving the energy efficiency of the fuel for a long time before the fuel is supplied to each combustion chamber of the internal combustion engine, so that the fuel can be fully combusted after being input into each combustion chamber of the internal combustion engine, the maximum power can be generated according to the fuel, the contained harmful pollutants can be completely combusted and cannot remain in the exhaust gas discharged by the internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can be easily burdened with improved cost, and particularly realizing the best effects of saving energy, reducing carbon and preventing air pollution, thereby rapidly and effectively reducing the use amount of the petrochemical fuel and the pollution problem caused by the petrochemical pollution problem, which is an important issue to be solved by the current countries and related industries, and the invention is an important issue to be thoroughly discussed in the world.
Disclosure of Invention
In view of the above-mentioned conventional treatment strategies, the inventor has long diligently studied and tested the energy conversion device and its manufacturing method for long-term improvement of the energy efficiency of the fuel, which can utilize the noble metal nanoparticles attached to the surface of the energy conversion device as a high-efficiency energy conversion material to greatly absorb the ambient light energy and heat energy, so as to effectively excite the far infrared particles to convert the light energy and heat energy into far infrared rays, and return the far infrared rays to the fuel (whether liquid or gaseous fuel) to be supplied to the combustion chamber of an internal combustion engine, thereby enabling the long-chain hydrocarbon fuel molecules to be generated, and the short-chain hydrocarbon fuel molecules to be cracked, so as to effectively improve the combustion efficiency of the fuel, and enable the fuel to be fully combusted after being input into the combustion chamber of each internal combustion engine, and the far infrared rays to be fully combusted, wherein the most harmful substances are contained in the fuel, and the energy is polluted only before Can be completely burnt out in a sufficient combustion process without remaining in the exhaust gas (CO) 2 ) Waste water (H) 2 In O), the new and old vehicles or the new and old industries can be ensured to be capable of improving cost with easy burden, and the best effects of energy conservation, carbon reduction and air pollution prevention are realized, so that the consumption of petrochemical fuel and the air pollution problem caused by the petrochemical fuel are reduced rapidly and effectively.
The invention provides a method for manufacturing an energy conversion device of nanometer noble metal far infrared rays, which can improve the energy efficiency of fuel in a long-term way, the method utilizes the permeation effect generated by the temperature difference effect to ensure that a first aqueous solution containing nanometer noble metal particles, far infrared rays particles and medium particles can smoothly permeate into the surface and holes of an energy conversion material made of porous materials, so that after the energy conversion material is completely dried by high-temperature treatment, a layer of composite film containing nanometer platinum particles and far infrared rays particles can be formed on the surface and holes of the energy conversion material, and when the energy conversion device formed by the energy conversion material is installed in a fuel supply pipeline of each internal combustion engine, the far infrared rays generated by the composite film can perform long-term conversion treatment on fuel flowing in the fuel, and after the fuel molecules of long-chain hydrocarbons are cracked into the fuel molecules of short-chain hydrocarbons, the fuel is sequentially put into a combustion chamber of each internal combustion engine for combustion. Thus, the fuel can exert the best combustion efficiency, not only can each internal combustion engine generate the maximum power, but also various pollutants contained in the fuel can be completely eliminated due to the best combustion efficiency and are not disabled in the exhaust gas discharged by each internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can all improve the cost with easy burden, particularly realizing the best effects of saving energy, reducing carbon and preventing air pollution, and rapidly and effectively reducing the use amount of petrochemical fuel and the air pollution caused by the petrochemical fuel.
The present invention also provides a method for manufacturing a fuel supply line of an internal combustion engine, which comprises the steps of using the permeation effect generated by the temperature difference to enable a second aqueous solution containing nano gold particles and medium particles to smoothly permeate into the surface and holes of the energy conversion material, so that after the energy conversion material is completely dried by high temperature treatment, a layer of composite film containing nano platinum particles, nano gold particles and far infrared particles can be formed on the surface and holes of the energy conversion material, so that when the energy conversion device is installed on the fuel supply line of the internal combustion engine, far infrared rays generated by the composite film can not only perform conversion treatment for fuel (whether liquid or gaseous) flowing through the composite film, but also perform conversion treatment for improving energy efficiency for a long time, so that the fuel molecules of long-chain hydrocarbons are cracked into fuel molecules of short-chain hydrocarbons, and perform conversion treatment for increasing oxygen content for the short-chain fuel molecules for enabling the fuel to exert better combustion efficiency, so that not only can each internal combustion engine generate maximum power, but also various pollutants contained in the fuel can be prevented and cured by the better combustion efficiency, the fuel can be prevented from losing best and the best used fuel, the pollution can be prevented and the pollution can be prevented from being lost, the pollution can be easily realized, the energy-saving effect can be realized, the energy-saving vehicle can be realized, the waste gas can be realized, and the waste gas can be reduced, and the waste gas can be easily and the waste gas can be reduced, and the waste can be wasted, and the waste can be easily be effectively and the used by the waste and the waste can be effectively and the waste can be realized. In this way, the method can reduce the consumption of petrochemical fuel and thoroughly realize the aim of low-pollution or zero-pollution exhaust emission, thereby truly providing a clean and comfortable perpetual living space and environment for the subsequent generation.
Still another object of the present invention is to provide an energy conversion device for generating far infrared rays by using nano noble metal capable of improving energy efficiency of fuel for a long time, wherein the energy conversion device is formed by combining at least one energy conversion material, and a composite film containing nano noble metal particles and far infrared particles is formed on the surface of each energy conversion material, wherein the nano noble metal particles excite the far infrared particles to generate far infrared rays, and at least one fuel channel is formed in the energy conversion device along an axial direction; when the energy conversion devices are respectively installed on the fuel supply pipelines of the internal combustion engines, the fuel conveyed in the fuel supply pipelines can smoothly pass through each fuel channel, and the composite film is subjected to conversion treatment of lifting energy, the far infrared rays generated by the composite film are cracked into the fuel molecules of short-chain hydrocarbon, and then the fuel molecules are sequentially put into the combustion chambers of each internal combustion engine to be combusted, so that the fuel can not only exert the optimal combustion efficiency, but also generate the maximum power for each internal combustion engine, various pollutants contained in the fuel can disappear due to the optimal combustion efficiency, and the pollutants are not remained in the exhaust gas discharged by each internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can all realize the optimal effects of energy conservation, carbon reduction and air pollution prevention, and the use amount of petrochemical fuel and the air pollution problem caused by the use amount of the petrochemical fuel can be quickly and effectively reduced.
Still another object of the present invention is that the composite film of the energy conversion device further comprises nano gold particles; thus, after the energy conversion devices are respectively installed on the fuel supply pipelines of an internal combustion engine, the fuel conveyed in the fuel supply pipelines can smoothly pass through each fuel channel, so that the composite film can not only perform conversion treatment for improving energy efficiency on the fuel flowing through the fuel supply pipelines for a long time, but also perform conversion treatment for increasing oxygen content on the short-chain fuel molecules for a long time besides cracking the fuel molecules of long-chain hydrocarbon into the fuel molecules of short-chain hydrocarbon for the long-chain hydrocarbon, thereby enabling the fuel to exert better combustion efficiency, enabling each internal combustion engine to generate maximum power, enabling various pollutants contained in the fuel to disappear due to the better combustion efficiency and not to remain in exhaust gas discharged by each internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can all improve cost with extremely easy burden, and particularly realizing the best effects of energy conservation, carbon reduction and air pollution prevention, and quick and effective reduction of the using amount of fuel and the air pollution caused by the fuel.
For a further understanding and appreciation of the objects, technical features, and advantages of the present invention, the invention will now be described in more detail with reference to the accompanying drawings, in which:
drawings
FIG. 1 is a schematic illustration of the concentration profile of urban light smoke during various periods of the day;
FIG. 2 is a schematic longitudinal cross-sectional view of a screening device composed of particulate screening material mounted to a fuel supply line;
FIG. 3 is a schematic longitudinal cross-sectional view of a screening device consisting of cylindrical screening material mounted to a fuel supply line;
FIG. 4 is a flow chart of a method of fabricating a first preferred embodiment of the present invention;
FIG. 5 is a schematic cross-sectional view showing the process of performing lifting energy conversion after sintering and coating the composite material of nano platinum particles, nano gold particles and far infrared particles on the surface of the sieving material according to the present invention;
FIG. 6 is a flow chart of a method of fabricating a second preferred embodiment of the present invention;
FIG. 7 is a schematic view of an energy conversion material according to a third embodiment of the present invention; a kind of electronic device with high-pressure air-conditioning system
Fig. 8 is a schematic view of an energy conversion device according to a third embodiment of the present invention.
Reference numerals illustrate:
energy conversion devices … 1, 2, 8
Energy conversion materials …, 20, 70, 80A, 80B
Holes …, 201, 701
Fuel passages …, 102, 202
Fuel supply line … 3
Fuel … 4
Media particles … 50
Far infrared ray particles … 51
Nano platinum particles … 52
Nano gold particles … 54
Optical energy … 60
Thermal energy … 61
Far infrared … 62
Composite films …, 802, 803
Auxiliary film … 703
Steps …, 401-404, 601-604
Detailed Description
The present invention will be further described in detail below with reference to specific embodiments and with reference to the accompanying drawings, in order to make the objects, technical solutions and advantages of the present invention more apparent.
Far infrared raw materials commonly used today can be classified into two types, one is natural ores having far infrared radiation energy, such as: medical stone, granite, dolomite, serpentine, silicon ore and the like, and the other is far infrared ceramics formed by sintering special raw materials at high temperature, at present, the far infrared raw materials are mainly ground into powder and then mixed into polymer fiber raw materials, and far infrared heat-accumulating and heat-preserving fiber products are manufactured through processes of spinning, weaving and the like; the far infrared ray product with the wavelength of 4-14 mu m (namely, the fertility light) which is most beneficial to human bodies is most attractive, particularly, for the elderly living in cold climates, a plurality of lesions are easy to generate due to the fact that the quantity of exercise is small and the physical strength is weak, so that the far infrared ray heat storage and insulation fiber product is used for absorbing the solar energy and the heat energy released by the human bodies, and then converting the far infrared ray with the wavelength of 4-14 mu m to emit the far infrared ray, so that the heat insulation effect of the bodies of the elderly can be effectively improved, and the functions and effects of promoting blood circulation, activating cells and promoting the health of the bodies are achieved.
In general, water molecules in blood are usually mixed by single water molecules and large water molecules, when far infrared rays or electromagnetic waves with the wavelength of 4-14 μm) irradiate the large water molecules, the large water molecules are induced to vibrate and disperse, so that the large water molecules are cracked and refined into single water molecules; after the far infrared ray is supplied with energy, the refined single water molecules are gradually agglomerated and restored to be the big water molecular groups, so that if the far infrared ray can be continuously generated on the surface of the human body, the far infrared ray can continuously generate resonance action with the water molecules, so that the big water molecular groups in the water are continuously decomposed and refined, and then the water molecules in the human body are activated, thereby effectively activating tissue cells in the human body, promoting blood circulation and improving metabolism.
There are various materials with far infrared radiation characteristics, and the materials capable of generating far infrared radiation substances (hereinafter referred to as "far infrared materials") are generally classified into the following five materials according to their chemical structures:
(1) Oxide: such as: alumina (Al) 2 O 3 ) Zirconium oxide (ZrO) 2 ) Magnesium oxide (MgO), titanium oxide (TiO) 2 ) Silicon oxide (SiO) 2 ) Etc.;
(2) Carbide: such as: zirconium carbide (ZrC), silicon carbide (SiC), boron carbide (B) 4 C) Tantalum carbide (TaC), etc.;
(3) Boride: such as: titanium boride (TiB) 2 ) Zirconium boride (ZrB) 2 ) Chromium boride (CrB) 2 ) Etc.;
(4) Silicide: such as: titanium silicide (TiSi) 2 ) Molybdenum silicide (MoSi) 2 ) Tungsten silicide (WSi) 2 ) Etc.; a kind of electronic device with high-pressure air-conditioning system
(5) Nitride: such as: silicon nitride (Si) 3 N4), titanium nitride (TiN), and the like.
Among these far infrared ray materials, the oxide and the carbide are the most used in the industry, and therefore, in the following examples of the present invention, only the above-mentioned oxide type far infrared ray material particles are exemplified, but the present invention is not limited thereto, and in other examples of the present invention, carbide type or other type far infrared ray material particles may be substituted for the oxide type far infrared ray material particles according to actual needs, and accordingly, the far infrared ray particles mentioned in the following description and claims of the present invention refer to any of the above-mentioned type far infrared ray material particles, or a mixture of the above-mentioned types of far infrared ray material particles, and are revealed in advance.
Generally, gasoline (petroleum) is a part of crude oil distillation products, and is a hydrocarbon compound mainly composed of five to ten carbons, and has a boiling point of fifteen to two hundred degrees celsius. Typically, oil fields produce crude oil containing only ten to forty percent (on average about twenty-seven percent) of gasoline. Hydrocarbon structures constituting gasoline are paraffin hydrocarbons (i.e., chain hydrocarbons (Paraffins)), cyclic hydrocarbons (napthenes), aromatic hydrocarbons (aromatic), and the like; wherein paraffin hydrocarbon is used as the main component of gasoline. Since the last century, the number of automobiles is rapidly increasing, and the demand for gasoline is increasing, and in order to increase the gasoline ratio of crude oil, the industry particularly utilizes high temperature to crack high molecular hydrocarbon into smaller molecular gasoline; conversely, larger molecule gasoline can also be polymerized from smaller molecule gasoline. Thus, in addition to the gasoline originally present in the crude oil, the addition of the gasoline formed by cracking or polymerization can increase the gasoline content of the crude oil to seventy percent. Then, in order to improve the quality of the gasoline, the gasoline can have better combustion effect when being combusted in an engine. Some very Olympic refineries have also been developed, such as cyclizing long chain hydrocarbons to form cyclic hydrocarbons, and dehydrogenating (dehydgenation) the cyclic hydrocarbons to aromatic hydrocarbons by three reactions:
1. Cleavage (Cracking);
2. polymerization (Polymerization); a kind of electronic device with high-pressure air-conditioning system
3. Dehydrogenation (Dehydrogenation).
Because the gasoline formed by changing the molecular structure of hydrocarbon has higher Octane number (Octane Rating), the gasoline does not need to be added with tetra-ethylene Lead (Pb (C) 2 H 5 ) 4 ) To increase its octane number. In general, when gasoline is ignited in a cylinder of an automobile engine (i.e., the aforementioned internal combustion engine), it is first ignited in each cylinder, and then secondary explosion which damages the engine is caused, and since the secondary explosion causes vibration of the engine, in order to reduce the engine's shock, chemists try to add different chemical reagents in a laboratory to observe the shock resistanceThe experimental result shows that the tetra-ethane lead has obvious shockproof effect, and the engine shock can be reduced to the degree of almost complete disappearance by only adding one to three cc of tetra-ethane lead into one gallon of gasoline; at the same time, chemists also observe the effect of gasoline with different components on engine knock, and found that the gasoline composed of pure isooctane produces the smallest knock, the octane number of isooctane is defined as one hundred, n-heptane which is enough to cause equivalent knock is zero, and all the knock caused by burning hydrocarbon or fuel is compared with the index defined by isooctane and n-heptane according to the index of octane number.
In 1951, li Wensi ton (Livingston) discovered that all hydrocarbons containing Structural groups (Structural groups) have the property of suppressing oxidation of gasoline and reducing shock. Thus, hydrocarbons having a ring bond, such as: aromatic hydrocarbons and cyclic hydrocarbons are oxidized at relatively high temperatures due to branched isoalkanes; in the case of long chain paraffin hydrocarbons, they oxidize at low temperatures, resulting in subsequent combustion which can produce shock and damage to the engine. Accordingly, increasing the number of branches in the chain hydrocarbon increases the oxidation temperature and octane number, such as C 8 H 18 Depending on the number of branches contained, the oxidation temperature and octane number will increase due to the increase of the number of branches; as for cyclic hydrocarbons and aromatic hydrocarbons, they generally have higher octane numbers than paraffin hydrocarbons, because they have a cyclic structure and are dense in structure; conversely, if a long chain paraffin is added to a cyclic hydrocarbon, the octane number is reduced.
Symmetrical molecules in cyclic hydrocarbons have a higher octane number than asymmetrical molecules; therefore, in order to increase the octane number of gasoline without adding any additional additives, the best methods developed in the industry to convert paraffin and cyclic hydrocarbons into aromatic hydrocarbons have become an important technology in the refinery process. In addition, benzene is the most useful hydrocarbon constituting gasoline, and benzene is a main raw material of petrochemistry; many petroleum byproducts can be refined from benzene; benzene itself can also be prepared from methylcyclopentane (methylcyclohexane), cyclohexane (Cyclohexane), hexane, etc. under the catalysis of platinum as catalyst.
In view of the fact that Platinum (Platinum) is an inert noble metal which is extremely stable in chemical nature, and is silver in its normal form, but if it is made into nano-sized particles, its color will be changed from silver to black, and is also called "Platinum black", at this time, due to the size effect and the large-scale surface area effect, platinum will be converted from an inert substance to an active excellent catalyst, which can generate the characteristic of approximate atoms, and has a potential, and can achieve the antioxidation effect by transmitting the potential to active oxygen, and in addition, since the reflectivity of nano Platinum particles to light energy and heat energy is extremely low, usually less than 1%, that is, the diameter of about several micrometers can be completely quenched, and thus becomes a high-efficiency energy conversion material.
Based on the characteristics of nano platinum particles, far infrared particles and gasoline, the inventor thought to develop an energy conversion device of nano noble metal far infrared capable of improving the energy efficiency of fuel for a long time and a manufacturing method thereof by utilizing the characteristics of nano platinum particles, far infrared particles and gasoline, so that nano platinum particles can be firmly attached to far infrared particles to form a nano composite film, the nano composite film can effectively absorb heat energy or light energy emitted from the environment through the nano platinum particles in the light or no light environment to excite far infrared particles to generate far infrared rays for a long time, the nano composite film can be sintered and coated on the surface and holes of an energy conversion material or device made of porous materials, and when the energy conversion material or device is installed on a fuel supply pipeline of an internal combustion engine, the far infrared rays generated by excitation can be input into the fuel to be supplied to the combustion chamber of the various internal combustion engines to be combusted, so as to perform conversion treatment for improving the energy on the fuel, thereby effectively exciting the optimal energy efficiency of the fuel, enabling the far infrared rays to be generated by the nano composite film to be sintered and coated on the surface of the energy conversion material or the far infrared particles to be completely burnt in the combustion chambers of the internal combustion engine, and the far infrared rays can be completely lost due to the fact that the waste gas is completely burnt in the combustion chamber of the combustion engine.
In addition, since other noble metals (such as palladium (Pd) and nickel (Ni)) are changed to black (such as palladium black or nickel black) after being nanocrystallized, the present invention is described by taking nano platinum particles as an example in the following embodiments of the present invention, but the present invention is not limited thereto, and other nano noble metal particles can be used according to actual needs in other embodiments of the present invention. Accordingly, the nano noble metal particles described in the following description and claims of the present invention are not limited to nano platinum particles, but refer to all nano noble metal particles which are changed into black after being nanocrystallized, or the nano noble metal particles are mixed together, and are revealed in advance.
Referring to fig. 2 and 3, the energy transforming device 1 of the present invention may be composed of a plurality of energy transforming materials 10, or the energy transforming device 2 may be composed of only a single energy transforming material, that is, the energy transforming device 1 of the present invention may be composed of a plurality of energy transforming materials 10, and the energy transforming device 2 itself may be equivalent to the energy transforming material, which is described before. The energy conversion material may be in the form of particles (as shown in fig. 2) or cylinders (as shown in fig. 3), which may be made of porous material (such as ceramic material or other porous material with far infrared radiation property), so that the surface and the holes 101, 201 are uniformly distributed therein, and at least one fuel channel 102, 202 is formed in the energy conversion device 1, 2 along the axial direction, so that, as shown in fig. 2 and 3, when the energy conversion device 1, 2 is installed in the fuel supply pipeline 3 of an internal combustion engine, respectively, the fuel 4 (whether liquid or gaseous) transported in the fuel supply pipeline 3 can smoothly pass through each fuel channel 102, 202, and after the energy conversion device 1, 2 applies conversion treatment for improving energy efficiency, the fuel can be sequentially thrown into the combustion chamber (i.e. cylinder) of each internal combustion engine (i.e. engine) for combustion.
Referring to fig. 2 and 3, in the first embodiment, the worker can add nano platinum particles, far infrared particles and medium particles (such as a reducing agent, water-soluble acrylic powder and an aqueous adhesive) into an aqueous solution to make use of the penetration effect generated by the temperature difference effect, so that the nano platinum particles, the far infrared particles and the medium particles can penetrate into the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 along with the aqueous solution; and then melting the medium particles permeated into the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201) at high temperature, so that the medium particles are combined with nano platinum particles and far infrared particles, and the nano platinum particles and the far infrared particles are uniformly sintered and coated in the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201) to form a layer of nano platinum particles and far infrared particle film. In particular, the present invention can perform the above-described manufacturing method for each energy conversion material 10 one by one, or can combine a plurality of energy conversion materials 10 into the energy conversion device 1, and then perform the above-described manufacturing method.
With reference to fig. 2 and 4, the manufacturing method of the first embodiment includes the following steps:
(401) Uniformly mixing water-soluble platinum salt, far infrared particles, medium particles and the like into water according to a preset weight percentage to form a first mixed solution, wherein the water-soluble platinum salt can be completely dissolved in the first mixed solution to dissociate platinum ions in the first mixed solution, and each platinum ion is extremely easy to bond with each far infrared particle so as to be uniformly and firmly attached to the surface of each far infrared particle in the preparation process of the first mixed solution; the reducing agent can provide electrons in the first mixed solution, so that each platinum ion can be reduced into nano platinum particles respectively by acquiring electrons and gradually and firmly attached to the surfaces of each far infrared ray particle; after the components are uniformly mixed in the first mixed solution, the first mixed solution is kept at a first temperature (for example, the room temperature is 25-30 ℃);
(402) Placing each energy conversion material 10 into an oven, baking to a second temperature (for example, 75-95 ℃) and keeping the second temperature for 1-2 hours, and placing each energy conversion material 10 into the first mixed solution, so that the first mixed solution can utilize the penetration effect generated by the temperature difference effect to enable the nano platinum particles, far infrared ray particles and medium particles to uniformly penetrate into the surface of each energy conversion material 10 and the holes 101 along with the first mixed solution;
(403) Putting each energy conversion material 10 into an oven again, baking to the second temperature (for example, 75-95 ℃), keeping the second temperature for 1-2 hours, volatilizing the water contained in each energy conversion material 10, and standing to room temperature; a kind of electronic device with high-pressure air-conditioning system
(404) Finally, placing each energy conversion material 10 into a high-temperature sintering furnace, and heating each energy conversion material 10 to a third temperature (for example, 175-200 ℃ C.) within two hours; then, heating each of the energy conversion materials 10 to a fourth temperature (e.g., 500-600 degrees celsius) within six hours; at this time, since the material properties of the dielectric particles are similar to those of the energy conversion materials 10, the dielectric particles are melted by the high temperature applied from the high temperature sintering furnace, and sintered together with the nano platinum particles and the far infrared ray particles and applied to the surface and the holes 101 of the energy conversion materials 10, thereby forming a composite film containing the nano platinum particles and the far infrared ray particles.
Referring to fig. 4 again, in the first embodiment, the first mixed solution is prepared by uniformly mixing water, far infrared particles of oxides, water-soluble platinum salt, reducing agent, water-soluble acrylic powder, aqueous adhesive and the like according to the following weight percentages:
(1) Water: the weight percentage is 35-97%;
(2) Far infrared ray particles of oxide type: in the first embodiment, the oxide far infrared particles with larger particles are firstly ground into particles with the size of about 1-100 microns;
(3) Water-soluble platinum salts: the weight percentage of the platinum-gold salt is 0.001-5%, and the platinum-gold salt can be hydrogen chloroplatinic acid (H) 2 PtCl 6 ) Potassium chloroplatinate (k) 2 PtCl 6 ) Or potassium chloroplatinite (K) 2 PtCl 4 ) In the first embodiment, only potassium chloroplatinate is taken as an example, and the platinum salt has the characteristics of being completely dissolved in water and dissociating platinum ions in the water, and the platinum ions have the characteristics of being hydrophilic, so that the platinum ions are extremely easy to bond with oxygen on far infrared particles, and are uniformly and firmly attached on the surfaces of the far infrared particles in the preparation process of the first mixed solution;
(4) Reducing agent: the weight percentage is 0.5-10%, which is made up of disodium ethylenediamine tetraacetate (EDTA.2Na), potassium hydroxide (KOH) and potassium bicarbonate (KHCO) 3 ) Equal components, according to the preset weight percentage, mixing to obtain the aqueous solution; wherein, the weight percentage of ethylenediamine tetraacetic acid disodium salt in the reducing agent is 0.15-3%, the weight percentage of potassium hydroxide is 0.08-1.5%, the weight percentage of potassium bicarbonate is 0.3-6%, the reducing agent can provide electrons needed by the reduction of platinum ions into nano platinum particles in the first mixed solution, so that the platinum ions can gradually and firmly form nano platinum particles on the surfaces of the far infrared particles respectively through the oxidation of the reducing agent;
(5) Water-soluble acryl powder: the weight percentage of the water-soluble acrylic powder is 2-30%, the water-soluble acrylic powder is a water-soluble dispersing agent, and after the water-soluble dispersing agent acts in water, far infrared particles can be uniformly and dispersedly suspended in the first mixed solution, in the first embodiment, the water-soluble acrylic powder is a polyacrylic acid derivative (Polyacrylic acid derivative), and the far infrared particles can be uniformly dispersed in the first mixed solution without precipitation or agglomeration; a kind of electronic device with high-pressure air-conditioning system
(6) Water-soluble adhesive: the weight percentage of the water-soluble adhesive is 0.2-10%, the water-soluble adhesive is used for coating the surfaces of far infrared particles and platinum nano particles which are uniformly and dispersed in the first mixed solution, and in the first embodiment, the water-soluble adhesive comprises components such as polyurethane resin (urethane), N-methyl pyrrolidone (N-Methyl Pyrrolidinone), triethylamine (Triethylamine) and the like.
In addition, according to the actual requirement, 500-2,000ppm of nano platinum particles are directly added in the process of preparing the first mixed solution according to the preset weight percentage so as to replace the water-soluble platinum salt and the reducing agent, and the first mixed solution required by the invention can be obtained after the water-soluble platinum salt and the reducing agent are uniformly mixed.
Since the nano platinum particles in the first mixed solution can be uniformly and firmly attached to the surface of each far infrared particle during the preparation process of the first mixed solution, when the far infrared particles are sintered and coated on the surface of the energy conversion material 10 and the holes 101 to manufacture the energy conversion device 1, referring to fig. 5, the far infrared particles 51 in the nano composite film can be uniformly distributed on the surface of each energy conversion material 10 and the holes 101 through the medium particles 50, and at this time, the nano platinum particles 52 are uniformly and firmly attached to the surface of the far infrared particles 51, and the nano platinum particles 52 have very low reflectivity (less than 1%) to the light energy 60 and the heat energy 61. Thus, referring back to fig. 2 and 3, after the energy conversion devices 1, 2 are installed in the fuel supply line 3 of an internal combustion engine, the fuel 4 transported in the fuel supply line 3 can smoothly pass through the energy conversion devices 1, 2, and after the energy conversion devices 1, 2 apply the conversion treatment for improving the energy efficiency to the fuel 4, the energy conversion devices are sequentially input into the combustion chambers of the internal combustion engines for combustion.
In addition, in the conversion treatment process for improving energy efficiency, the far infrared particles 51 of the energy conversion devices 1 and 2 can fully utilize the platinum nanoparticles 52 as a high-efficiency energy conversion material, fully absorb the light energy 60 and the heat energy 61 of each internal combustion engine and the surrounding thereof, convert and excite the far infrared rays 62 with the wavelength of 4 μm to 14 μm, and return the far infrared rays to the fuel 4, so that the molecules and atoms of the fuel 4 flowing through the energy conversion devices 1 and 2 resonate to promote the molecules of the fuel with long-chain oxyhydrogen compounds to be cracked into the molecules of the fuel with short-chain oxyhydrogen compounds due to vibration, and excite the maximum energy efficiency of the fuel 4, thereby enabling the fuel 4 to exert the optimal combustion efficiency, not only enabling each internal combustion engine to generate the maximum power, but also enabling the pollutants contained in the combustion 4 to be lost due to the optimal combustion efficiency, and not to remain in the exhaust gas discharged by each internal combustion engine. The energy conversion devices 1 and 2 manufactured according to the invention are proved by experimental tests to be capable of actually reducing the fuel consumption of each internal combustion engine by 8%.
In addition, gold (Au) is a very stable material, but based on the unique potential characteristics of nano gold particles, it has very strong adsorption force to oxygen, so it can be used as a catalyst, and according to the discovery of japanese scientists, nano gold particles are a catalyst capable of oxidizing carbon monoxide into carbon dioxide, so it is often used for manufacturing products such as masks, respirators, water heaters, etc. to effectively avoid and prevent carbon monoxide poisoning. In addition, compared with the platinum catalyst commonly used in industry, the gold catalyst needs to react at high temperature and cannot contain water vapor; on the contrary, the nano gold catalyst can react at room temperature and is not affected by water vapor; the photocatalyst effect of the nano platinum particles and the nano gold particles is now described below:
In general, platinum and gold are nanosized, and since the grain size of platinum and gold becomes equal to or smaller than that of light waves, the size effect will increase the interval between the conduction band and the valence band, so that the light absorption capacity of platinum and gold is significantly enhanced, and thus, when a photon with a certain energy or a photon with energy exceeding the band gap of a semiconductor is irradiated into the semiconductor electronic structure of platinum nanoparticle or gold nanoparticle, an electron is excited from the valence band to the conduction band, leaving a hole, and the hole of the valence band will rob the hydroxyl electron in the surrounding environment, so that the hydroxyl group becomes a free radical, thereby being capable of being used as a strong oxidant.
Based on the photocatalyst and strong oxidation characteristics of the nano platinum particles and the nano gold particles, the inventors also think that the energy conversion efficiency of the far infrared particles can be effectively improved by utilizing the characteristics, and the energy conversion devices 1 and 2 of the invention can have better catalyst or catalysis, so that the oxygen content in the fuel 4 flowing through the energy conversion devices 1 and 2 can be effectively increased due to the better catalyst or catalysis, and the energy conversion devices 1 and 2 can provide the best conversion effect for improving the energy efficiency for the fuel 4 more quickly and more stably; accordingly, referring to fig. 2 and 3, in a second embodiment of the present invention, the present invention further includes uniformly mixing the components of the nano gold particles and the medium particles (such as the water-soluble acrylic powder and the water-based adhesive) into an aqueous solution according to a predetermined weight percentage, so as to form a second mixed solution required by the present invention; then, by utilizing the penetration effect generated by the temperature difference effect, the nano gold particles and the medium particles can permeate into the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201) along with the second aqueous solution; finally, the medium particles penetrating into the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201) are melted at a high temperature, so that the nano gold particles can be combined with the nano platinum particles and the far infrared particles thereon, and sintered together and coated on the energy conversion material 10 (or the energy conversion device 2) to form a composite film containing the nano gold particles, the nano platinum particles and the far infrared particles, as shown in fig. 6, the manufacturing method of the second embodiment comprises the following steps:
(601) Uniformly mixing the components such as nano gold particles and medium particles into water according to a preset weight percentage to form a second mixed solution, and keeping the second mixed solution at the first temperature (for example, the room temperature is 25-30 ℃);
(602) Placing the energy conversion material 10 (or the energy conversion device 2) manufactured in the first embodiment into an oven, baking to a second temperature (for example, 75-95 ℃), and maintaining the second temperature for 1-2 hours, placing the energy conversion material 10 (or the energy conversion device 2) into the second mixed solution, so that the second mixed solution can utilize the penetration effect generated by the temperature difference effect, and the nano gold particles and the medium particles can uniformly penetrate into the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201) along with the second mixed solution;
(603) Then, the energy conversion material 10 (or the energy conversion device 2) is put into an oven again, baked to the second temperature (for example, 75-95 ℃) and kept at the second temperature for 1-2 hours, so that the water contained in the energy conversion material 10 (or the energy conversion device 2) is volatilized completely, and then the energy conversion material is kept stand to the room temperature; a kind of electronic device with high-pressure air-conditioning system
(604) Finally, the energy conversion material 10 (or the energy conversion device 2) is put into a high-temperature sintering furnace, and the energy conversion material 10 (or the energy conversion device 2) is heated to the third temperature (for example, 175-200 ℃ C.) within two hours; then, the energy conversion material 10 (or the energy conversion device 2) is heated to the fourth temperature (for example, 500-700 ℃) within six hours, and at this time, the material characteristics of the medium particles are similar to the material characteristics of the energy conversion material 10 (or the energy conversion device 2), so that the medium particles can be melted by the high temperature applied by the high temperature sintering furnace, and the nano gold particles can be sintered together with the nano platinum particles and the far infrared particles and coated on the surface of the energy conversion material 10 (or the energy conversion device 2) and the hole 101 (or the hole 201), so that a composite film containing the nano gold particles, the nano platinum particles and the far infrared particles is formed.
Referring to fig. 6 again, in the second embodiment, the second mixed solution is prepared by uniformly mixing the following components by weight:
(1) Water: the weight percentage is 35-97%;
(2) Nano gold particles: the content of the nano gold particles is 500-1 and 500ppm, and the nano gold particles have an oxygen-philic characteristic, so that the nano gold particles are extremely easy to bond with oxygen on far infrared particles in the sintering process and uniformly adhere to the surfaces of the far infrared particles;
(3) Water-soluble acryl powder: the weight percentage of the water-soluble acrylic powder is 2-30%, and the water-soluble dispersing agent acts on the water to uniformly and dispersedly suspend the nano gold particles in the second mixed solution after the water-soluble acrylic powder is dissolved in the water, in the previous embodiment of the invention, the water-soluble acrylic powder is a polyacrylic acid derivative (Polyacrylic acid derivative), so that the nano gold particles can be uniformly dispersed in the second mixed solution without precipitation or agglomeration; a kind of electronic device with high-pressure air-conditioning system
(4) Water-soluble adhesive: the weight percentage of the water-soluble adhesive is 0.2% -10%, the water-soluble adhesive is used for coating the surfaces of the nano gold particles uniformly dispersed in the second mixed solution, and in the second embodiment, the water-soluble adhesive comprises components such as polyurethane resin (urea polymer), N-methyl pyrrolidone (N-Methyl Pyrrolidinone), triethylamine (Triethylamine) and the like.
Referring to fig. 2, 3 and 5 again, after the second embodiment of the present invention is completed, the energy conversion devices 1 and 2 can respectively utilize the nano platinum particles 52 and the nano gold particles 54 attached to the far infrared particles 51 to perform the conversion treatment for improving the energy efficiency, so that the light energy 60 and the heat energy 61 around the internal combustion engine and the internal combustion engine can be absorbed very effectively in the light or no light environment, and the light energy is converted and excited to far infrared rays 62 with the wavelength of 4 μm to 14 μm smoothly, and then the far infrared rays are returned to the fuel 4, so that the molecules and atoms of the fuel 4 flowing through the energy conversion devices 1 and 2 resonate to accelerate the chemical reaction rate of the conversion treatment, the fuel 4 is promoted to be rapidly, smoothly and stably cracked into the molecular structure of the short-chain oxyhydrogen compound due to the vibration, and meanwhile, the oxygen content in the molecular structure of the short-chain oxyhydrogen compound can be greatly increased through the strong oxidation of the nano gold particles 54, so that the oxygen content in the molecular structure of the short-chain oxyhydrogen compound can be excited most effectively after the conversion treatment of the fuel 4.
In addition, the experimental tests prove that the energy conversion devices 1, 2 according to the second embodiment of the present invention can substantially reduce the fuel consumption of each internal combustion engine by 15%. Accordingly, the energy conversion devices 1 and 2 of the present invention can obviously make the fuel 4 exert the optimal combustion efficiency, not only can make the internal combustion engines generate the maximum power, but also can make the pollutants contained in the fuel 4 disappear due to the optimal combustion efficiency, and do not remain in the exhaust gas discharged by the internal combustion engines. Therefore, the method can actively reduce the consumption of the petrochemical fuel, effectively realize the aim of low-pollution or zero-pollution exhaust emission, and only then can provide a clean and comfortable perpetual living space and environment for the subsequent generation.
As described above, only the preferred embodiments of the present invention are described, but the present invention is not limited thereto, and any person skilled in the art can perform the conversion treatment for improving the energy efficiency and oxygen content for a long time in the fuel 4 flowing through the energy conversion devices 1 and 2 according to the design concept of the present invention, no matter how the steps of the first preferred embodiment and the second preferred embodiment are modified, as long as the nano gold particles, the nano platinum particles and the far infrared particles are sintered together and coated on the surfaces of the energy conversion devices 1 and 2 and the holes 101 and 201, a composite film containing the nano gold particles, the nano platinum particles and the far infrared particles is formed. Furthermore, any person skilled in the art, according to the design concept of the present invention, should also use the other far infrared particles instead of the oxide far infrared particles, or use other equivalent nano noble metal particles instead of the nano platinum particles or the nano gold particles, which are covered in the following claims of the present invention.
Furthermore, although the nano gold particles used in the foregoing embodiments of the present invention have strong oxidation properties, they absorb oxygen and at the same time attract other contaminants (such as dust, etc.), so that the surfaces of the energy conversion devices 1 and 2 are covered by the contaminants and the subsequent energy conversion efficiency is negatively affected, so that in other embodiments of the present invention, the composite film further comprises nano cerium (Ce) particles, wherein the nano cerium (Ce) particles can be converted between Ce/CeO, and the cerium oxide (CeO) itself has self-cleaning (self-cleaning) properties, so that the contaminants absorbed by the surfaces of the energy conversion material 10 (or the energy conversion device 2) can be effectively removed, and the surfaces of the energy conversion material 10 (or the energy conversion device 2) can be always kept in a clean state, so that the energy conversion devices 1 and 2 can always exert the desired energy conversion efficiency for a long time. In addition, in other embodiments of the present invention, since nano-particles such as ruthenium (Ru) and rhodium (Rh) can also generate a strong oxygen absorption effect after being matched with nano-platinum particles, only nano-ruthenium particles are taken as an example, and chemical reactions between the nano-ruthenium particles and the nano-platinum particles are formed as shown in the following formula, so that each nano-platinum particle always has a clean surface, and therefore the energy conversion materials 10 (or the energy conversion devices 2) can excite the fuel flowing through the nano-platinum particles to have the maximum energy efficiency:
2Ru OH +Pt -CO →Pt+2Ru+CO 2 +H 2 O。
In addition to adding cerium nanoparticles, ruthenium nanoparticles, and rhodium nanoparticles to the composite film, the energy conversion device of the present invention further includes the following embodiments to achieve the desired effects, as shown in fig. 7, and in the third embodiment of the present invention, the energy conversion material 70 is further coated with at least one auxiliary film 703 on the surface and the hole 701 of the composite film 702, wherein the other precious metal nanoparticles contained in the auxiliary film 703 are different from the precious metal nanoparticles contained in the composite film 702, for example, the composite film 702 includes platinum nanoparticles and gold nanoparticles, and the auxiliary film 703 includes cerium nanoparticles, that is, in practical use, the energy conversion material of the present invention can have a single film layer (i.e., the composite film) or multiple film layers, and in particular, the auxiliary film of the present invention refers to a film layer that does not contain far infrared ray particles.
In addition, in the fourth embodiment of the present invention, referring to fig. 8, the energy transforming device 8 can include more than two energy transforming materials 80A, 80B, and the types or amounts of the nano noble metal particles contained on each energy transforming material 80A, 80B are different from each other, and the various forms of the fourth embodiment are listed below for reference only:
(a1) All kinds are different, the number is also different: the composite film 802 of the energy conversion material 80A contains nano platinum particles and nano gold particles, and the composite film 803 of the energy conversion material 80B contains nano cerium particles;
(a2) All kinds are different, but the number is the same: the composite film 802 of the energy conversion material 80A contains nano platinum particles, and the composite film 803 of the energy conversion material 80B contains nano gold particles; or (b)
(a3) The parts are the same in kind but different in number: the composite film 802 of the energy conversion material 80A includes nano platinum particles, nano gold particles and nano cerium particles, and the composite film 803 of the energy conversion material 80B includes nano gold particles and nano cerium particles.
Furthermore, although the energy conversion materials 80A and 80B in fig. 8 are provided with only a single layer, in other embodiments of the present invention, the energy conversion materials 80A and 80B can also be multi-layer (including composite films and/or auxiliary films), so that the number of the energy conversion materials 80A and 80B can be adjusted by the operator according to the requirements of different vehicles, in terms of the applicant's practical tests, 180 energy conversion materials are used to form an energy conversion device, wherein the surface layers (composite films and/or auxiliary films) of 22 energy conversion materials contain nano ruthenium (Ru) particles, the surface layers of 53 energy conversion materials contain nano gold (Au) particles, the surface layers of 55 energy conversion materials contain nano platinum (Pt) particles, the surface layers of 50 energy conversion materials contain nano cerium (Ce) particles, and the nano noble metal particles occupy about 1000ppm in the respective layers; thus, the fuel saving rate is greater than 96% compared with a vehicle without the energy conversion device.
The foregoing description of the embodiments has been provided for the purpose of illustrating the general principles of the invention, and is not meant to limit the invention thereto, but to limit the invention thereto, and any modifications, equivalents, improvements and equivalents thereof may be made without departing from the spirit and principles of the invention.

Claims (14)

1. The method for manufacturing the energy conversion device of the nanometer noble metal far infrared capable of improving the energy efficiency of fuel for a long time comprises the following steps of:
uniformly mixing all components in a first mixed solution containing at least nano noble metal particles, far infrared particles and medium particles, and keeping the first mixed solution at a first temperature, wherein the range of the first temperature is 25-30 ℃ of room temperature;
Placing the energy conversion material into an oven, baking to a second temperature which is 75-95 ℃ in the range of room temperature and is kept at the second temperature for 1-2 hours, and placing the energy conversion material into the first mixed solution, so that the first mixed solution can utilize the penetration effect generated by the temperature difference effect to enable each component particle in the first mixed solution to uniformly penetrate into the surface of the energy conversion material and each hole along with the first mixed solution;
then, putting the energy conversion material into the oven again, baking to the second temperature, and keeping the second temperature for 1-2 hours so as to volatilize the moisture contained in the energy conversion material, and standing the energy conversion material to the room temperature; a kind of electronic device with high-pressure air-conditioning system
Finally, the energy conversion material is put into a high-temperature sintering furnace, and is heated to a third temperature within 2 hours, wherein the range of the third temperature is 175-200 ℃ of room temperature; then, heating the energy conversion material to a fourth temperature within 6 hours, wherein the fourth temperature is 500-600 ℃ in the room temperature range; at this time, since the material properties of the medium particles are similar to those of the energy conversion material, the medium particles can be melted by the high temperature applied by the high temperature sintering furnace, and sintered together with the nano noble metal particles and the far infrared particles and coated on the surface of the energy conversion material and in each hole to form a composite film;
The nanometer noble metal particles in the composite film can excite the far infrared particles to generate far infrared rays, so that the composite film can apply conversion treatment of lifting energy to the far infrared rays under the condition that the fuel passes through the fuel channel, and the far infrared rays generated by the composite film can crack fuel molecules of long-chain hydrocarbon into fuel molecules of short-chain hydrocarbon and then are sequentially put into a combustion chamber of the internal combustion engine for combustion.
2. The method of claim 1, wherein the first mixed solution comprises water, far infrared particles, water-soluble platinum salt, reducing agent, water-soluble acrylic powder and water-based adhesive, and is prepared by uniformly mixing the following components in percentage by weight:
water with the weight percentage of 35-97 percent;
far infrared particles, the weight percentage of which is 0.2-10%, the particles are grinded into the size of 1-100 micrometers;
the water-soluble platinum salt comprises 0.001-5% by weight, wherein the platinum salt is hydrogen chloroplatinic acid, potassium chloroplatinate or potassium chloroplatinite, platinum ions are dissociated in water after the platinum salt is dissolved in the water, and the platinum ions have the characteristic of being hydrophilic, so that the platinum ions are bonded with oxygen on the far infrared particles, and are uniformly and firmly attached on the surfaces of the far infrared particles in the preparation process of the first mixed solution;
The reducer is 0.5-10% by weight, and is an aqueous solution prepared by mixing components of disodium ethylenediamine tetraacetate, potassium hydroxide and potassium bicarbonate according to a preset weight percentage; wherein, the weight percentage of ethylenediamine tetraacetic acid disodium salt in the reducing agent is 0.15-3%, the weight percentage of potassium hydroxide is 0.08-1.5%, the weight percentage of potassium bicarbonate is 0.3-6%, the reducing agent can provide electrons needed by the reduction of platinum ions into nano platinum particles in the first mixed solution, so that the platinum ions can gradually and firmly form nano platinum particles on the surfaces of the far infrared particles respectively through the oxidation of the reducing agent;
the water-soluble acrylic powder comprises 2-30% by weight of a water-soluble dispersing agent and a polyacrylic acid derivative, and is used for uniformly and dispersedly suspending the far infrared ray particles and the nano platinum particles in the first mixed solution after being dissolved in water, and uniformly dispersing the far infrared ray particles and the nano platinum particles in the first mixed solution without precipitation or agglomeration; a kind of electronic device with high-pressure air-conditioning system
The water-soluble adhesive comprises 0.2-10 wt% of polyurethane resin, N-methyl pyrrolidone and triethylamine, wherein the water-soluble adhesive is used for coating the surfaces of far infrared particles and platinum nanoparticles which are uniformly and dispersed in the first mixed solution.
3. The method of claim 1, wherein the first mixed solution comprises water, far infrared particles, nano platinum particles, water-soluble acrylic powder and water-based adhesive, and is prepared by uniformly mixing the following components in percentage by weight:
water with the weight percentage of 35-97 percent;
far infrared particles, the weight percentage of which is 0.2-10%, the particles are grinded into the size of 1-100 micrometers;
nano platinum particles with the weight percentage of 500 to 2,000ppm;
the water-soluble acrylic powder comprises 2-30% by weight of a water-soluble dispersing agent and a polyacrylic acid derivative, and is used for uniformly and dispersedly suspending the far infrared ray particles and the nano platinum particles in the first mixed solution after being dissolved in water, and uniformly dispersing the far infrared ray particles and the nano platinum particles in the first mixed solution without precipitation or agglomeration; a kind of electronic device with high-pressure air-conditioning system
The water-soluble adhesive comprises 0.2-10 wt% of polyurethane resin, N-methyl pyrrolidone and triethylamine, wherein the water-soluble adhesive is used for coating the surfaces of far infrared particles and nano platinum particles which are uniformly and dispersed in the first mixed solution.
4. A method of making as claimed in claim 2 or 3 wherein the composite film further comprises nano gold particles, the method comprising the steps of:
the second aqueous solution containing nano gold particles and medium particles can smoothly infiltrate into the surface and the holes of the energy conversion material by utilizing the penetration effect generated by the temperature difference effect, so that the composite film can be formed on the surface and the holes of the energy conversion material after the energy conversion material is completely dried by high-temperature treatment, and the composite film can perform conversion treatment for improving energy efficiency and treatment for increasing oxygen content for a long time on the fuel flowing through the composite film when the energy conversion device is arranged on a fuel supply pipeline of the internal combustion engine.
5. The method of manufacturing of claim 4, further comprising:
uniformly mixing the components of the nano gold particles and the medium particles into water to form a second mixed solution, and keeping the second mixed solution at the first temperature after the components are uniformly mixed in the second mixed solution;
Placing the energy conversion materials into the oven, baking to the second temperature, and keeping the second temperature for 1-2 hours, and then placing the energy conversion materials into the second mixed solution, so that the second mixed solution can utilize the penetration effect generated by the temperature difference effect to enable the nano gold particles and medium particles to uniformly penetrate into the surface of the energy conversion material and each hole along with the second mixed solution;
then, putting the energy conversion materials into an oven again, baking to the second temperature, and keeping the second temperature for 1-2 hours so as to volatilize the water contained in the energy conversion materials, and standing the energy conversion materials to room temperature; a kind of electronic device with high-pressure air-conditioning system
Finally, the energy conversion materials are put into a high-temperature sintering furnace, and the energy conversion materials are heated to the third temperature within 2 hours; then, the energy conversion material is heated to the fourth temperature within 6 hours, at this time, since the material properties of the medium particles are similar to those of the energy conversion material, the medium particles can be melted by the high temperature applied by the high temperature sintering furnace, so that the nano gold particles, the nano platinum particles and far infrared particles are sintered together and coated on the surface of the energy conversion material or the device and in each hole, and the composite film is formed.
6. The method of claim 5, wherein the second mixed solution is prepared by uniformly mixing water, nano gold particles, water-soluble acrylic powder, aqueous adhesive and the like according to the following weight percentage:
water with the weight percentage of 35-97 percent;
nano gold particles with 500-1,500 ppm content and having an oxygen-philic property, and bonded with oxygen on far infrared particles and uniformly adhered to the surfaces of the far infrared particles during the sintering process;
the water-soluble acrylic powder is 2-30% by weight, is a water-soluble dispersing agent and is a polyacrylic acid derivative, and the water-soluble acrylic powder is used for uniformly and dispersedly suspending nano gold particles in the second mixed solution after being dissolved in water, and uniformly dispersing the nano gold particles in the second mixed solution without precipitation or agglomeration; a kind of electronic device with high-pressure air-conditioning system
The water-soluble adhesive comprises 0.2-10 wt% of polyurethane resin, N-methyl pyrrolidone and triethylamine, wherein the water-soluble adhesive is used for coating the surfaces of the nano gold particles uniformly dispersed in the second mixed solution.
7. An energy conversion device of nanometer noble metal far infrared capable of improving energy efficiency of fuel for a long time, which forms at least one fuel channel along the axial direction for the fuel transported in a fuel supply pipeline of an internal combustion engine to pass through, the energy conversion device comprises:
at least one energy conversion material, which is a granular or columnar body, the surface and the inside of which are uniformly distributed with a plurality of holes, a layer of composite film and at least one auxiliary film are covered on the surface of the energy conversion material, the composite film is covered on the surface of the energy conversion material and in each hole, and the composite film at least contains nano noble metal particles and far infrared particles, wherein the nano noble metal particles excite the far infrared particles to generate far infrared rays; each auxiliary film is positioned on the outer layer of the composite film, and contains another nano noble metal particle which is different from the nano noble metal particle in the composite film;
in the state that the fuel passes through the fuel channel, the composite film can apply conversion treatment of lifting energy to the fuel, wherein far infrared rays generated by the composite film can enable fuel molecules of long-chain hydrocarbon to be cracked into fuel molecules of short-chain hydrocarbon, and then the fuel molecules are sequentially put into a combustion chamber of the internal combustion engine for combustion.
8. The energy conversion device according to claim 7, wherein the energy conversion device comprises two or more energy conversion materials, and the types or amounts of the nano noble metal particles contained in each energy conversion material are different from each other.
9. The energy transforming device of claim 8, wherein the composite film of one energy transforming material comprises gold nanoparticles, platinum nanoparticles and cerium nanoparticles, and the composite film of the other energy transforming material comprises gold nanoparticles and cerium nanoparticles.
10. The energy conversion device of claim 7, wherein the composite film further comprises nano gold particles.
11. The energy transforming device of claim 10, wherein the energy transforming material is made of ceramic material or other porous material having far infrared radiation characteristics.
12. The energy conversion device of claim 11, wherein the far infrared material comprises an oxide, carbide, boride, silicide and/or nitride far infrared material and mixtures thereof.
13. The energy conversion device of claim 12, wherein the nano-noble metal particles further comprise platinum, palladium, nickel, rhodium, ruthenium or other nano-noble metal particles that turn black after nanocrystallization, and mixtures thereof.
14. The energy conversion device of claim 13, wherein the composite film further comprises nano-cerium particles.
CN202010319461.0A 2020-04-21 2020-04-21 Energy conversion device of nanometer noble metal far infrared capable of improving energy efficiency of fuel for long time and manufacturing method thereof Active CN113530726B (en)

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