CN113458408A - Electrocatalysis with nano-wire structure and carbon dioxide reduction function and preparation method thereof - Google Patents
Electrocatalysis with nano-wire structure and carbon dioxide reduction function and preparation method thereof Download PDFInfo
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000002070 nanowire Substances 0.000 title claims abstract description 30
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 25
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010411 electrocatalyst Substances 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000000725 suspension Substances 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 8
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims abstract description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 7
- 239000008103 glucose Substances 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 6
- MPTQRFCYZCXJFQ-UHFFFAOYSA-L copper(II) chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Cu+2] MPTQRFCYZCXJFQ-UHFFFAOYSA-L 0.000 claims abstract description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims abstract description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims abstract description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 229910002708 Au–Cu Inorganic materials 0.000 abstract description 11
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000010189 synthetic method Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 239000010949 copper Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 238000006722 reduction reaction Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 229910000510 noble metal Inorganic materials 0.000 description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 6
- 238000000527 sonication Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000003917 TEM image Methods 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 229960003280 cupric chloride Drugs 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011943 nanocatalyst Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
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- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
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Abstract
The invention discloses an electrocatalyst with an electrocatalytic carbon dioxide reduction function and a preparation method thereof, wherein the electrocatalyst has a nanowire structure and comprises the following specific steps: dissolving chloroauric acid, copper chloride dihydrate and glucose in water, and stirring and mixing uniformly to obtain a solution A; dissolving oleylamine in water, and stirring and mixing uniformly to obtain a solution B; adding the solution A into the solution B at room temperature, performing ultrasonic treatment for 30min, stirring and mixing uniformly at room temperature, transferring the suspension obtained by stirring into a high-pressure reaction kettle lined with polytetrafluoroethylene, performing sealed reaction at 120 ℃, and then performing centrifugal washing with ethanol and deionized water respectively at 10000rpm to obtain the carbon dioxide reduction function electrocatalyst. Au-Cu nanowire junction synthesized by the inventionHas excellent electrocatalytic CO2The synthetic method has simple operation, high reaction efficiency and low energy consumption.
Description
Technical Field
The invention belongs to the technical field of electrocatalysis carbon dioxide reduction, and particularly relates to an electrocatalysis carbon dioxide reduction function electrocatalyst with a nanowire structure and a preparation method thereof.
Background
Excess CO emitted from fossil fuel combustion2Causing serious global environmental problems such as greenhouse effect, forest fire, melting of icebergs, and the like. Catalytic reduction of CO2The conversion of the carbon dioxide into a series of valuable products is the relief of excessive CO in the atmosphere2One of the ways of (1). The carbon dioxide reduction reaction may be carried out by thermal catalysis, photocatalysis, electrocatalysis or biocatalysis, but wherein CO is produced as a result of the electrocatalysis2Compared with other catalytic modes, the reaction has the advantages of mild conditions, simple and easily-operated reaction device, low cost and the like, and is concerned by more and more researchers. Ideal CO2The RR electrocatalyst has the characteristics of excellent activity, high selectivity, stability and the like, and most importantly, the RR electrocatalyst can inhibit the hydrogen evolution reaction so as to realize the high-efficiency and high-selectivity catalytic reduction of CO2. Therefore, an efficient electrocatalyst was developed to electrocatalytic CO2One of the important problems to be solved in the technical field of reductive catalyst synthesis.
Recently, it has been found that alloyed nanomaterials are effective in increasing CO2One of the methods of catalytic activity and selectivity of electrocatalytic reduction. In addition, the Au-Cu nano alloy catalyst is more favorable for guiding CO2Besides converting into target products and inhibiting side reactions, the catalyst is more economical and applicable than a single noble metal catalyst. The Au-Cu nanowire has large specific surface area and quantum confinement effect, can be in better contact with electrolyte, and has good CO2RR activity. In addition, the Au-based alloy has higher faraday efficiency than a single metal such as Au or Cu.
Noble metal nanocatalysts are widely used in many important fields of contemporary organic chemistry, fine chemistry, fuel cells, and the like. The price and rare reserves of precious metals limit their practical application. In order to solve these problems, many studies have been focused on reducing the amount of noble metal used and improving the utilization rate of the noble metal. Alloying of noble metals with non-noble metals is one of the ways to reduce the loading of noble metals and can significantly improve the catalytic activity and selectivity of the catalyst. Such as Au, Pt, Ag, Pd and their alloys, and can be used as high-efficiency catalyst. Metal nanowires are of particular interest due to their unique electrical, optical, and catalytic properties. And compared with bulk materials, one-dimensional nanowire materials are better in performance. Due to the large specific surface area and the quantum confinement effect of the one-dimensional nanowire material, the nanowire material has unique electrical, thermal, mechanical and optical properties.
Disclosure of Invention
The invention solves the technical problem of providing an electrocatalyst with an electrocatalytic carbon dioxide reduction function of a nanowire structure and a preparation method thereof.
The invention adopts the following technical scheme for solving the technical problems, and the electro-catalyst with the nano-wire structure and the electro-catalytic carbon dioxide reduction function and the preparation method thereof are characterized by comprising the following specific steps:
step S1: dissolving chloroauric acid, copper chloride dihydrate and glucose in water, and stirring and mixing uniformly to obtain a solution A;
step S2: dissolving oleylamine in water, and stirring and mixing uniformly to obtain a solution B;
step S3: adding the solution A into the solution B at room temperature, performing ultrasonic treatment for 30min, stirring and mixing uniformly at room temperature, transferring the suspension obtained by stirring into a high-pressure reaction kettle lined with polytetrafluoroethylene, performing sealed reaction at 120 ℃, and then performing centrifugal washing with ethanol and deionized water respectively at 10000rpm to obtain the carbon dioxide reduction function electrocatalyst which is in a uniform-diameter nanowire structure and has an average diameter of 20-30 nm.
Further limiting, the feeding molar ratio of the chloroauric acid to the copper chloride dihydrate in the step S1 is 1: 1.
Further, the sealing reaction time in step S3 is 12 h.
Compared with the prior art, the invention has the following beneficial effects:
1. the Au-Cu nanowire structure synthesized by the method has excellent electrocatalytic CO2The synthetic method has simple operation, high reaction efficiency and low energy consumption.
2. The Au-Cu electrocatalyst has a uniform diameter nanowire structure, has a large specific surface area and a quantum confinement effect, can be in better contact with an electrolyte, and has excellent CO2RR activity, can effectively improve the electrocatalytic activity of the catalyst.
3. In the invention, glucose is used as a reducing agent, oleylamine is used as a guiding agent, and the Au-Cu nanowire is formed.
4. Au-Cu electrocatalytic CO with nanowire structure synthesized by using method2 The reduction catalyst can not only improve the stability and prevent agglomeration, but also the catalytic activity of Au-Cu is higher than that of pure Au or pure Cu, which is due to the electronic effect and synergistic effect among different metals. Therefore, the method has wide application prospect in the electrocatalytic reduction catalyst technology.
Drawings
FIG. 1 shows Au prepared in example 1 of the present invention25Cu75TEM image of the nanowires;
FIG. 2 shows Au prepared in example 2 of the present invention50Cu50TEM image of the nanowires;
FIG. 3 shows Au prepared in example 3 of the present invention75Cu25TEM image of the nanowires;
FIG. 4 is a graph showing electrochemical properties of products obtained in example 1, example 2 and example 3 of the present invention.
Detailed Description
The present invention is described in further detail below with reference to examples, but it should not be construed that the scope of the above subject matter of the present invention is limited to the following examples, and that all the technologies realized based on the above subject matter of the present invention belong to the scope of the present invention.
Example 1
Cupric chloride dihydrate (11.625 mg), chloroauric acid (9.37 mg), and glucose (15.8 mg) were added to 5 mL of water and mixed uniformly to obtain a uniform solution a. Dissolve 160. mu.L oleylamine in 3 mL water and mix well to obtain solution B. The solution A was added to the solution B for 30min under sonication at room temperature, followed by stirring overnight. The suspension obtained by stirring was transferred to a 25 mL autoclave lined with polytetrafluoroethylene, and the autoclave was sealed at 120 ℃ for 12 hours. Thereafter, the Au — Cu nanowires were obtained by centrifugation three to four times with a certain volume of ethanol and deionized water, respectively, at 10000rpm, and dispersed in ethanol for future use.
Supporting Au-Cu nanowires on carbon to prepare Au25Cu75 NWs/C catalyst, which is then activated. Briefly, Vulcan XC-72 carbon was dispersed in ethanol by sonication and 4 mg Au was added by stirring25Cu75NWs was added to the carbon suspension. The mixed solution is ultrasonically and uniformly coated on the surface of a carbon paper electrode, an H-shaped electrolytic cell system is adopted, the performance of the catalyst is measured through an electrochemical workstation, and the electrical property test result is shown in figure 4.
Example 2
Cupric chloride dihydrate (7.75 mg), chloroauric acid (18.74 mg), and glucose (15.8 mg) were added to 5 mL of water and mixed uniformly to obtain a uniform solution a. Dissolve 160. mu.L oleylamine in 3 mL water and mix well to obtain solution B. The solution A was added to the solution B for 30min under sonication at room temperature, followed by stirring overnight. The suspension obtained by stirring was transferred to a 25 mL autoclave lined with polytetrafluoroethylene, and the autoclave was sealed at 120 ℃ for 12 hours. Thereafter, the Au — Cu nanowires were obtained by centrifugation three to four times with a certain volume of ethanol and deionized water, respectively, at 10000rpm, and dispersed in ethanol for future use.
Preparation of Au by loading Au-Cu nanowire on carbon50Cu50 NWs/C catalyst, which is then activated. Briefly, Vulcan XC-72 carbon was dispersed in ethanol by sonication and 4 mg Au was added by stirring50Cu50 NWs was added to the carbon suspension. The mixed solution is ultrasonically and uniformly coated on the surface of a carbon paper electrode, and an H-shaped electrolytic cell system is adopted and passes through an electrochemical workstationThe performance of the catalyst was measured, and the results of the electrical property test are shown in FIG. 4
Example 3
Cupric chloride dihydrate (3.875 mg), chloroauric acid (28.11 mg), and glucose (15.8 mg) were added to 5 mL of water and mixed well to obtain a homogeneous solution a. Dissolve 160. mu.L oleylamine in 3 mL water and mix well to obtain solution B. The solution A was added to the solution B for 30min under sonication at room temperature, followed by stirring overnight. The suspension obtained by stirring was transferred to a 25 mL autoclave lined with polytetrafluoroethylene, and the autoclave was sealed at 120 ℃ for 12 hours. Thereafter, the Au — Cu nanowires were obtained by centrifugation three to four times with a certain volume of ethanol and deionized water, respectively, at 10000rpm, and dispersed in ethanol for future use.
Preparation of Au by loading Au-Cu nanowire on carbon75Cu25NWs/C catalyst, which is then activated. Briefly, Vulcan XC-72 carbon was dispersed in ethanol by sonication and 4 mg Au was added by stirring75Cu25NWs was added to the carbon suspension. The mixed solution is ultrasonically and uniformly coated on the surface of a carbon paper electrode, an H-shaped electrolytic cell system is adopted, the performance of the catalyst is measured through an electrochemical workstation, and the electrical property test result is shown in figure 4
The foregoing embodiments illustrate the principles, principal features and advantages of the invention, and it will be understood by those skilled in the art that the invention is not limited to the foregoing embodiments, which are merely illustrative of the principles of the invention, and that various changes and modifications may be made therein without departing from the scope of the principles of the invention.
Claims (3)
1. An electrocatalysis with a nanowire structure and a carbon dioxide reduction function and a preparation method thereof are characterized by comprising the following specific steps:
step S1: dissolving chloroauric acid, copper chloride dihydrate and glucose in water, and stirring and mixing uniformly to obtain a solution A;
step S2: dissolving oleylamine in water, and stirring and mixing uniformly to obtain a solution B;
step S3: adding the solution A into the solution B at room temperature, performing ultrasonic treatment for 30min, stirring and mixing uniformly at room temperature, transferring the suspension obtained by stirring into a high-pressure reaction kettle lined with polytetrafluoroethylene, performing sealed reaction at 120 ℃, and then performing centrifugal washing with ethanol and deionized water respectively at 10000rpm to obtain the carbon dioxide reduction function electrocatalyst which is in a uniform-diameter nanowire structure and has an average diameter of 20-30 nm.
2. The electrocatalytic carbon dioxide reduction functional electrocatalyst of nanowire structure and the preparation method thereof according to claim 1, characterized in that: in the step S1, the feeding molar ratio of the chloroauric acid to the copper chloride dihydrate is 1: 1.
3. The electrocatalytic carbon dioxide reduction functional electrocatalyst of nanowire structure and the preparation method thereof according to claim 1, characterized in that: the sealing reaction time in step S3 was 12 h.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115142075A (en) * | 2022-07-14 | 2022-10-04 | 电子科技大学 | Preparation method of ZnO nanowire catalyst with controllable crystal face |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104162657A (en) * | 2014-07-21 | 2014-11-26 | 江苏大学 | Super-long copper nanowire and preparing method thereof |
| CN107639235A (en) * | 2017-09-07 | 2018-01-30 | 浙江工业大学 | A kind of preparation method and applications of golden copper nano-wire material |
| WO2018140226A1 (en) * | 2017-01-24 | 2018-08-02 | The Regents Of The University Of California | Conductive core-shell metal nanowires for transparent conductors |
| CN108470603A (en) * | 2018-04-23 | 2018-08-31 | 天津大学 | A kind of preparation method of copper nano-wire transparent electrode |
| WO2019034623A1 (en) * | 2017-08-16 | 2019-02-21 | Rhodia Operations | Process for the manufacture of metal nanowires |
| CN111229253A (en) * | 2020-03-14 | 2020-06-05 | 北京工业大学 | Electro-catalytic reduction of CO2Preparation method of nano Cu-Au alloy catalyst as energy source |
-
2021
- 2021-06-04 CN CN202110626403.7A patent/CN113458408A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104162657A (en) * | 2014-07-21 | 2014-11-26 | 江苏大学 | Super-long copper nanowire and preparing method thereof |
| WO2018140226A1 (en) * | 2017-01-24 | 2018-08-02 | The Regents Of The University Of California | Conductive core-shell metal nanowires for transparent conductors |
| WO2019034623A1 (en) * | 2017-08-16 | 2019-02-21 | Rhodia Operations | Process for the manufacture of metal nanowires |
| CN107639235A (en) * | 2017-09-07 | 2018-01-30 | 浙江工业大学 | A kind of preparation method and applications of golden copper nano-wire material |
| CN108470603A (en) * | 2018-04-23 | 2018-08-31 | 天津大学 | A kind of preparation method of copper nano-wire transparent electrode |
| CN111229253A (en) * | 2020-03-14 | 2020-06-05 | 北京工业大学 | Electro-catalytic reduction of CO2Preparation method of nano Cu-Au alloy catalyst as energy source |
Non-Patent Citations (3)
| Title |
|---|
| RUBÉN MENDOZA-CRUZ等: "Helical Growth of Ultrathin Gold−Copper Nanowires", 《NANO LETTERS》 * |
| SHENJIE LI等: "Large-Scale Synthesis of Well-Dispersed Copper Nanowires in an Electric Pressure Cooker and Their Application in Transparent and Conductive Networks", 《INORGANIC CHEMISTRY》 * |
| SRAVAN THOTA等: "Colloidal Au–Cu alloy nanoparticles: synthesis,optical properties and applications", 《MATERIALS CHEMISTRY》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115142075A (en) * | 2022-07-14 | 2022-10-04 | 电子科技大学 | Preparation method of ZnO nanowire catalyst with controllable crystal face |
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Application publication date: 20211001 |
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