CN113457658B - Surface modification method of biomass carbon material - Google Patents
Surface modification method of biomass carbon material Download PDFInfo
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract
The invention relates to a surface modification method of a biomass carbon material, which takes biomass as a raw material and prepares the surface modified biomass carbon material through crushing, cracking, ball milling and low-temperature plasma discharge treatment. Wherein the temperature of the pyrolysis is increased from room temperature to the pyrolysis temperature of 800 to 1200 ℃ at the temperature increasing rate of 5 to 15 ℃/min, and then the temperature is kept for 2 to 4 hours; ball milling the biomass carbon material for 3 to 6 hours at a ball milling speed of 200 to 600rpm; and introducing inert gas at the pressure of 30-60Pa, and performing low-temperature plasma discharge surface treatment on the biomass carbon material for 15-60min. The preparation method is simple, mild in condition, green and environment-friendly, is easy for large-scale production, and is favorable for popularization and application; the prepared biomass carbon material is used as a catalyst, can effectively activate persulfate in a water body for degrading organic pollutants, and has a good catalytic degradation effect.
Description
Technical Field
The invention relates to a surface modification method of a biomass carbon material, and particularly belongs to the technical field of catalytic materials.
Background
The biomass carbon material has abundant raw materials, is widely concerned in the catalysis fields of electrocatalytic oxygen reduction, persulfate activation and the like after surface modification, and has become a hotspot for the research of the technical field of catalytic materials.
The surface modification of the carbon material is mainly realized by a chemical oxidation method, and is usually realized by mixing concentrated sulfuric acid and concentrated nitric acid with strong oxidizing property with the carbon material, and then carrying out oxidation reaction on carbon atoms on the surface of the carbon material by means of the strong oxidizing property of the concentrated sulfuric acid or the concentrated nitric acid and destroying the original carbon atom skeleton structure of the carbon material. However, in the treatment process, the method is easy to cause the release of toxic gas containing nitrogen, and pollutes the production site and the surrounding environment, and the waste liquid of concentrated sulfuric acid and concentrated nitric acid left after the surface treatment of the carbon material belongs to dangerous waste, and the post-treatment cost is high. Based on the above problems, there is a need to develop a safe, convenient and environment-friendly method for surface modification of biomass carbon material.
Disclosure of Invention
In order to achieve the above purpose, the present invention provides a surface modification method of biomass carbon material, which aims to solve the defects of the prior art.
The invention discloses a surface modification method of a biomass carbon material, which is characterized in that biomass is used as a raw material, the biomass carbon material is treated by low-temperature plasma discharge, and the surface modified biomass carbon material is prepared, and the method specifically comprises the following steps:
step 1: drying, crushing and sieving biomass to obtain biomass powder;
and 2, step: isolating the biomass powder from air, and performing pyrolysis to obtain a biomass carbon material; controlling cracking parameters: heating from room temperature to 800-1200 ℃ of cracking temperature at the heating rate of 5-15 ℃/min, and then keeping the temperature for 2-4 h;
and step 3: ball milling the biomass carbon material for 3 to 6 hours at a ball milling speed of 200 to 600rpm;
and 4, step 4: placing the ball-milled biomass carbon material in a reaction cavity in a low-temperature plasma, vacuumizing until the air pressure is stabilized at 30-60Pa, introducing inert gas, performing low-temperature plasma discharge in the inert atmosphere, and performing surface treatment on the ball-milled biomass carbon material for 15-60min to obtain the surface-modified biomass carbon material.
The power of the low-temperature plasma discharge is 50 to 300W.
The inert gas is nitrogen or argon.
The biomass carbon material is used as a catalyst to activate persulfate to degrade organic pollutants in a water body.
The invention has the beneficial effects that: the preparation method is simple, mild in condition, green and environment-friendly, is easy for large-scale production, and is beneficial to popularization and application. The prepared biomass carbon material is used as a catalyst, can effectively activate persulfate in a water body for degrading organic pollutants, and has a good catalytic degradation effect.
Drawings
FIG. 1 is a graph showing the comparison of the treatment effect of different biomass carbon materials on tetracycline-containing wastewater in example 3 of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. Throughout the specification and claims, unless explicitly stated otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated element or component but not the exclusion of any other element or component.
Example 1
Drying, crushing and sieving the camellia oleifera shells to obtain biomass powder; carrying out anaerobic pyrolysis on the biomass powder at 800 ℃, heating the biomass powder from room temperature to a preset pyrolysis temperature at a heating rate of 5 ℃/min, and carrying out heat preservation for 2h after heating to the preset pyrolysis temperature to obtain a biomass carbon material; performing ball milling treatment on the biomass carbon material, wherein the ball milling rotation speed is 200rpm, and the ball milling time is 3h; and placing the ball-milled biomass carbon material in a reaction cavity in low-temperature plasma, vacuumizing until the air pressure is stabilized at 30Pa, introducing nitrogen, and performing low-temperature plasma discharge treatment for 15min at the discharge power of 50w to obtain the surface-treated biomass carbon material.
The biomass carbon material after surface treatment is applied to the treatment of tetracycline-containing wastewater, and a comparison test is carried out:
100ml of tetracycline wastewater with the concentration of 20mg/L is respectively placed in three beakers, and the three beakers are placed in a bath kettle to be continuously stirred at room temperature, wherein the temperature is always kept at 30 ℃, and the stirring speed is 400rmp.
0.1g of oxone was added to each of three beakers containing tetracycline wastewater, and then 40mg of untreated biomass carbon material, ball-milled biomass carbon material, and ball-milled and plasma-discharged biomass carbon material were added thereto.
2.5ml of the solution was sampled at a constant time interval under conditions of 30 ℃ and a stirring speed of 400rmp, the obtained sample was filtered, and the obtained clear solution was immediately added to a methanol solution to quench and terminate the reaction.
Experiments show that: quenching is carried out, the reaction is terminated after 75min, and the degradation rates of tetracycline are respectively 52.2% (biomass carbon material without ball milling before treatment), 51.1% (biomass carbon material after ball milling treatment) and 73.5% (biomass carbon material after plasma discharge treatment), which shows that the effect of the biomass carbon material subjected to plasma discharge treatment on tetracycline-containing wastewater treatment is remarkable.
Example 2
Drying, crushing and screening passion fruit shells to obtain biomass powder; carrying out anaerobic pyrolysis on the biomass powder at 900 ℃, heating up to a preset pyrolysis temperature from room temperature at a heating rate of 7 ℃/min, and keeping the temperature for 2.5 hours after heating up to the preset pyrolysis temperature to obtain a biomass carbon material; performing ball milling treatment on the biomass carbon material, wherein the ball milling rotation speed is 300rpm, and the ball milling time is 3.5 hours; placing the ball-milled biomass carbon material in a reaction cavity in low-temperature plasma, vacuumizing until the air pressure is stabilized at 35Pa, introducing nitrogen, and performing low-temperature plasma discharge treatment for 30min to obtain the biomass carbon material rich in surface defects; the power of the low-temperature plasma discharge was 100w.
The biomass carbon material after surface treatment is applied to the treatment of tetracycline-containing wastewater, and a comparative test is carried out:
100ml of tetracycline waste water with the concentration of 20mg/L is respectively placed in three beakers, and the three beakers are placed into a bath kettle to be continuously stirred at room temperature, wherein the temperature is always kept at 30 ℃, and the stirring speed is 400rmp.
0.1g of oxone was added to each of three beakers containing tetracycline wastewater, and then 40mg of untreated biomass carbon material, ball-milled biomass carbon material, and ball-milled and plasma-discharged biomass carbon material were added thereto.
2.5ml of the solution was sampled at a constant time interval under conditions of 30 ℃ and a stirring speed of 400rmp, the obtained sample was filtered, and the obtained clear solution was immediately added to a methanol solution to quench and terminate the reaction.
Experiments show that: after quenching and reaction termination after 75min, the degradation rates of tetracycline are 67.4% (biomass carbon material without ball milling), 66.6% (biomass carbon material subjected to ball milling) and 87.2% (biomass carbon material subjected to plasma discharge treatment), respectively, which indicates that the effect of the biomass carbon material subjected to plasma discharge treatment on tetracycline-containing wastewater treatment is remarkable.
Example 3
Drying, crushing and sieving the peanut shells to obtain biomass powder; carrying out anaerobic pyrolysis on the biomass powder at 1000 ℃, heating the biomass powder from room temperature to a preset pyrolysis temperature at a heating rate of 10 ℃/min, and carrying out heat preservation for 3h after heating to the preset pyrolysis temperature to obtain a biomass carbon material; performing ball milling treatment on the biomass carbon material, wherein the ball milling rotation speed is 400rpm, and the ball milling time is 4 hours; placing the ball-milled biomass carbon material in a reaction cavity in low-temperature plasma, vacuumizing until the air pressure is stabilized at 40Pa, introducing nitrogen, and performing low-temperature plasma discharge treatment for 40min to obtain the biomass carbon material rich in surface defects; the power of the low-temperature plasma discharge was 150w.
The biomass carbon material after surface treatment is applied to the treatment of tetracycline-containing wastewater, and a comparative test is carried out:
100ml of tetracycline wastewater with the concentration of 20mg/L is respectively placed in three beakers, and the three beakers are placed in a bath kettle to be continuously stirred at room temperature, wherein the temperature is always kept at 30 ℃, and the stirring speed is 400rmp.
0.1g of oxone was added to each of three beakers containing tetracycline wastewater, and then 40mg of untreated biomass carbon material, ball-milled biomass carbon material, and ball-milled and plasma-discharged biomass carbon material were added thereto.
2.5ml of the solution was sampled at a constant time interval under conditions of 30 ℃ and a stirring speed of 400rmp, the obtained sample was filtered, and the obtained clear solution was immediately added to a methanol solution to quench and terminate the reaction.
Experiments show that: after quenching and reaction termination after 75min, the degradation rates of tetracycline are respectively 75.9% (biomass carbon material without ball milling), 75.5% (biomass carbon material subjected to ball milling) and 95.1% (biomass carbon material subjected to plasma discharge treatment), which indicates that the biomass carbon material subjected to plasma discharge treatment has a remarkable effect in treating wastewater containing tetracycline.
Example 4
Drying, crushing and sieving the camellia oleifera shells to obtain biomass powder; carrying out anaerobic pyrolysis on the biomass powder at 1100 ℃, heating the biomass powder from room temperature to a preset pyrolysis temperature at a heating rate of 12 ℃/min, heating the biomass powder to the preset pyrolysis temperature, and then preserving heat for 3.5h to obtain a biomass carbon material; performing ball milling treatment on the biomass carbon material, wherein the ball milling rotation speed is 500rpm, and the ball milling time is 5 hours; placing the ball-milled biomass carbon material in a reaction cavity in low-temperature plasma, vacuumizing until the air pressure is stabilized at 50Pa, introducing nitrogen, and performing low-temperature plasma discharge treatment for 50min to obtain the biomass carbon material rich in surface defects; the power of the low-temperature plasma discharge was 200w.
The biomass carbon material after surface treatment is applied to the treatment of tetracycline-containing wastewater, and a comparison test is carried out:
100ml of tetracycline wastewater with the concentration of 20mg/L is respectively placed in three beakers, and the three beakers are placed in a bath kettle to be continuously stirred at room temperature, wherein the temperature is always kept at 30 ℃, and the stirring speed is 400rmp.
0.1g of potassium hydrogen persulfate was added to each of three beakers containing tetracycline wastewater, and then 40mg of untreated biomass carbon material, ball-milled biomass carbon material, and ball-milled biomass carbon material and plasma discharge-treated biomass carbon material were added.
Sampling 2.5ml at 30 deg.C and stirring speed of 400rmp, filtering the obtained sample, adding the obtained clear liquid into methanol solution immediately, quenching, and terminating the reaction.
The experiment shows that: after quenching and reaction termination after 75min, the degradation rates of tetracycline are respectively 68.7% (biomass carbon material without ball milling), 70.1% (biomass carbon material subjected to ball milling) and 90.2% (biomass carbon material subjected to plasma discharge treatment), which indicates that the effect of the biomass carbon material subjected to plasma discharge treatment on tetracycline-containing wastewater treatment is remarkable.
Example 5
Drying, crushing and screening passion fruit shells to obtain biomass powder; carrying out anaerobic pyrolysis on the biomass powder at 1200 ℃, heating the biomass powder from room temperature to a preset pyrolysis temperature at a heating rate of 15 ℃/min, and keeping the temperature for 4h after heating to the preset pyrolysis temperature to obtain a biomass carbon material; performing ball milling treatment on the biomass carbon material, wherein the ball milling rotation speed is 600rpm, and the ball milling time is 6 hours; placing the ball-milled biomass carbon material in a reaction cavity in low-temperature plasma, vacuumizing until the air pressure is stabilized at 60Pa, introducing nitrogen, and performing low-temperature plasma discharge treatment for 60min to obtain a biomass carbon material rich in surface defects; the power of the low-temperature plasma discharge was 300w.
The biomass carbon material after surface treatment is applied to the treatment of tetracycline-containing wastewater, and a comparison test is carried out:
100ml of tetracycline waste water with the concentration of 20mg/L is respectively placed in three beakers, and the three beakers are placed into a bath kettle to be continuously stirred at room temperature, wherein the temperature is always kept at 30 ℃, and the stirring speed is 400rmp.
0.1g of oxone was added to each of three beakers containing tetracycline wastewater, and then 40mg of untreated biomass carbon material, ball-milled biomass carbon material, and ball-milled and plasma-discharged biomass carbon material were added thereto.
2.5ml of the solution was sampled at a constant time interval under conditions of 30 ℃ and a stirring speed of 400rmp, the obtained sample was filtered, and the obtained clear solution was immediately added to a methanol solution to quench and terminate the reaction.
Experiments show that: after quenching and reaction termination after 75min, the degradation rates of tetracycline are 72.1% (biomass carbon material without ball milling), 70.9% (biomass carbon material subjected to ball milling) and 92.2% (biomass carbon material subjected to plasma discharge treatment), respectively, which indicates that the effect of the biomass carbon material subjected to plasma discharge treatment on tetracycline-containing wastewater treatment is remarkable.
Claims (4)
1. A surface modification method of a biomass carbon material is characterized by comprising the following steps: the surface modification method is characterized in that biomass is used as a raw material, and a biomass carbon material is treated by low-temperature plasma discharge to prepare the surface-modified biomass carbon material, and specifically comprises the following steps:
step 1: drying, crushing and sieving biomass to obtain biomass powder;
step 2: isolating the biomass powder from air, and performing pyrolysis to obtain a biomass carbon material; controlling cracking parameters: heating from room temperature to a cracking temperature of 800 to 1200 ℃ at a heating rate of 5 to 15 ℃/min, and then insulating for 2 to 4h;
and step 3: ball milling the biomass carbon material for 3 to 6 hours at a ball milling speed of 200 to 600rpm;
and 4, step 4: and placing the ball-milled biomass carbon material in a reaction cavity in a low-temperature plasma, vacuumizing until the air pressure is stabilized at 30-60Pa, introducing inert atmosphere, discharging the low-temperature plasma in the inert atmosphere, and performing surface treatment on the ball-milled biomass carbon material for 15-60min to obtain the surface-modified biomass carbon material.
2. The method for surface modification of biomass carbon material according to claim 1, wherein: the power of the low-temperature plasma discharge is 50 to 300W.
3. The method for surface modification of biomass carbon material according to claim 1, wherein: the inert atmosphere is nitrogen or argon.
4. The use of the biomass carbon material obtained by the method for modifying the surface of a biomass carbon material according to claim 1, wherein: the biomass carbon material is used as a catalyst to activate persulfate so as to degrade organic pollutants in a water body.
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| CN101525177A (en) * | 2008-12-16 | 2009-09-09 | 中国海洋大学 | Method of using active persulphate for processing difficult-biodegradability organic waste water |
| CN104419485A (en) * | 2013-08-23 | 2015-03-18 | 钱玉明 | Manufacture method for machine-made charcoal |
| CN105060293B (en) * | 2015-07-17 | 2017-04-05 | 安徽中烟工业有限责任公司 | It is a kind of based on the low-temperature plasma modified method for producing Nicotiana tabacum L. activated carbon |
| CN105056882A (en) * | 2015-07-20 | 2015-11-18 | 昆明理工大学 | Preparation method of modified charcoal-based adsorbent for removing hydrogen sulfide |
| CN107487890A (en) * | 2017-08-21 | 2017-12-19 | 武汉和尔环保科技有限公司 | A kind of method using persulfate and active carbon purifying sewage |
| CN109926021A (en) * | 2019-03-15 | 2019-06-25 | 新疆农业大学 | A kind of preparation method and applications of ball milling modification chicken manure charcoal |
| CN110227534B (en) * | 2019-07-16 | 2022-03-22 | 河南省科学院化学研究所有限公司 | Magnetic nitrogen-doped biochar catalyst based on sludge and preparation method thereof |
| CN110508244A (en) * | 2019-08-27 | 2019-11-29 | 中国科学院合肥物质科学研究院 | A kind of charcoal adsorbent material and its preparation method and application that surface is modified |
| CN112028073A (en) * | 2020-07-24 | 2020-12-04 | 盐城工学院 | Preparation method of biomass charcoal-based material |
| CN111790399B (en) * | 2020-08-10 | 2022-02-15 | 厦门大学 | Catalyst for treating wastewater by cooperating with low-temperature plasma technology, preparation and application thereof, and method for treating phenol wastewater |
| CN111974450B (en) * | 2020-08-17 | 2022-04-08 | 杭州电子科技大学 | Fly ash-based catalytic cracking catalyst and preparation method thereof |
| CN111939874A (en) * | 2020-08-21 | 2020-11-17 | 徐州工程学院 | Method for removing tetracycline in water by using sludge-based biochar activated persulfate in synergistic manner |
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