CN113437370A - Storage battery efficiency maintenance method and equipment based on resonant pulse repair technology - Google Patents

Storage battery efficiency maintenance method and equipment based on resonant pulse repair technology Download PDF

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Publication number
CN113437370A
CN113437370A CN202110522971.2A CN202110522971A CN113437370A CN 113437370 A CN113437370 A CN 113437370A CN 202110522971 A CN202110522971 A CN 202110522971A CN 113437370 A CN113437370 A CN 113437370A
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China
Prior art keywords
storage battery
pulse
pulse current
module
parameters
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Pending
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CN202110522971.2A
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Chinese (zh)
Inventor
国家栋
孙睿
黄增柯
张豫鹏
李婧玮
周小华
唐明峰
杜珂
刘煜东
吉祥
刘梓涵
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Nanning Power Supply Bureau of Guangxi Power Grid Co Ltd
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Nanning Power Supply Bureau of Guangxi Power Grid Co Ltd
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Priority to CN202110522971.2A priority Critical patent/CN113437370A/en
Publication of CN113437370A publication Critical patent/CN113437370A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • H01M2010/4278Systems for data transfer from batteries, e.g. transfer of battery parameters to a controller, data transferred between battery controller and main controller
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Abstract

The invention provides a storage battery efficiency maintenance method and equipment based on a resonant pulse repair technology, wherein the method comprises the following steps: the detection circuit detects parameters of single storage batteries of the storage battery pack; the management module controls the pulse direct current output module to output a single-path pulse current according to the parameters of the single storage battery; and (3) smashing lead sulfate crystal grains in the storage battery by using pulse current so as to dissolve the lead sulfate crystal grains in sulfuric acid electrolyte. The invention changes the 'irreversible' of the storage battery vulcanization into 'reversible', can automatically adjust the output pulse current intensity by collecting the storage battery parameters in real time, meets the requirement of the desulfurization effect of the storage batteries with different capacities, and avoids a large amount of manual data collection and manual parameter setting errors. The labor intensity and labor cost of workers are reduced.

Description

Storage battery efficiency maintenance method and equipment based on resonant pulse repair technology
Technical Field
The invention relates to the technical field of storage battery efficiency guarantee, in particular to a storage battery efficiency guarantee method and equipment based on a resonant pulse restoration technology.
Background
The lead-acid storage battery has the outstanding advantages of low price, good high-low temperature performance, safety, reliability and the like, has very wide application field, and is applied to various fields of electric power, automobile starting, communication, railways, traction and the like. At present, lead-acid storage batteries are also mostly adopted as backup power sources for direct current system equipment of transformer substations. The design life of the lead-acid storage battery is 8-10 years. However, in daily use, the actual service life is generally 3-4 years due to improper maintenance, abuse and the like. The early scrapping of the lead-acid storage battery not only wastes energy seriously, but also pollutes the environment seriously, and becomes a hot point concerned in the field. Therefore, the method is very meaningful for the research on the repair technology of the waste lead-acid storage battery.
Battery performance is currently restored by discharging the battery pack using a resistive load. The field discharge operation flow is complicated, and the working strength is high. Although regular discharge maintenance has a certain effect on improving the activity of the storage battery, the problem of capacity reduction of the battery pack caused by sulfation of the storage battery in a long-term floating charge state cannot be prevented at all. Because, according to principles of atomic and solid physics, sulfur ions in lead acid batteries have 5 different energy level states, ions that are normally in a metastable energy level state tend to exist migrating down to the most stable covalent bond energy level. At the lowest energy level (i.e., covalent bond level state), sulfur exists in the form of a ring-shaped molecule containing 8 atoms, and the ring-shaped molecular pattern of 8 atoms is a stable combination and is difficult to break up, forming irreversible sulfation-vulcanization of the battery. This occurs many times and a layer of lead sulfate crystals is formed, similar to the insulating layer. The lead sulfate crystals are not repaired by the discharge operation.
In addition, frequent maintenance discharges also create safety issues, as well as problems of increased labor intensity, increased labor costs, increased energy consumption, and the like.
Disclosure of Invention
The invention aims to provide a storage battery efficiency maintenance method and equipment based on a resonance pulse restoration technology, which can solve a series of problems caused by restoring the storage battery efficiency by performing discharge operation on a storage battery pack in the prior art.
The purpose of the invention is realized by the following technical scheme:
in a first aspect, the invention provides a storage battery efficiency maintenance method based on a resonant pulse repair technology, which comprises the following steps:
step 1, detecting parameters of single storage batteries of a storage battery pack by a detection circuit;
step 2, the management module controls the pulse direct current output module to output a single-path pulse current according to the parameters of the single storage battery;
and 3, smashing lead sulfate crystal grains in the storage battery by using pulse current to dissolve the lead sulfate crystal grains in sulfuric acid electrolyte.
Further, the pulse frequency of the pulse current generates resonance with the natural frequency of the lead sulfate crystal grains, so that the lead sulfate crystal grains are broken.
Furthermore, the pulse direct current output module comprises at least one working module, and only one working module works at the same time.
Furthermore, in the storage battery pack, a plurality of 12V series circuits are formed by single storage batteries, and each series circuit receives a pulse signal injected by one working module.
Furthermore, the intensity of the single-path pulse direct current is determined according to the parameters of the single storage battery.
In a first aspect, the present invention provides a storage battery efficiency maintenance apparatus based on a resonant pulse repair technology, including a detection circuit, a management module and a pulse current output module, wherein:
the detection circuit is used for detecting parameters of the single storage battery in the storage battery pack;
the management module is used for managing the pulse current output module and controlling the intensity of the pulse current output by the pulse current output module according to the parameters of the single storage battery;
and the pulse current output module outputs the single-path pulse current with specific intensity according to the control of the management module.
Furthermore, the pulse current output module comprises a plurality of working modules, and each working module is independently controlled by the management module and independently outputs pulse current.
Furthermore, only one working module works at the same time.
According to the principle that pulse current with specific frequency has a destructive effect on lead sulfate crystals generated by the storage battery, the invention utilizes the resonance pulse repairing technology and utilizes the composite harmonic pulse energy to impact lead sulfate coarse grains to interfere the existence and growth of the lead sulfate crystals so as to change the 'irreversible' of the storage battery vulcanization into 'reversible'. The method of the invention can automatically adjust the output pulse current intensity according to the real-time collection of the storage battery parameters, meet the requirement of the sulfur removal effect of the storage batteries with different capacities, and avoid a large amount of manual data collection and manual parameter setting errors. The labor intensity and labor cost of workers are reduced.
Drawings
FIG. 1 is a diagram of the steps of a method for maintaining the efficiency of a storage battery based on resonant pulse repairing technology according to the present invention;
FIG. 2 is a schematic diagram of an application of the apparatus for maintaining the efficiency of a storage battery based on the resonant pulse repairing technology according to the present invention;
FIG. 3 is a schematic diagram of the internal structure of the apparatus for maintaining the efficiency of a storage battery based on the resonant pulse repairing technology according to the present invention;
FIG. 4 is a schematic diagram of a series circuit formed by every 12V of the single battery packs;
FIG. 5 is one of comparative plots of the discharge capacity of a battery before and after repair;
fig. 6 is a second graph comparing the discharge capacity of the battery before and after repair.
Detailed Description
The embodiments of the present disclosure are described in detail below with reference to the accompanying drawings.
The embodiments of the present disclosure are described below with specific examples, and other advantages and effects of the present disclosure will be readily apparent to those skilled in the art from the disclosure in the specification. It is to be understood that the described embodiments are merely illustrative of some, and not restrictive, of the embodiments of the disclosure. The disclosure may be embodied or carried out in various other specific embodiments, and various modifications and changes may be made in the details within the description without departing from the spirit of the disclosure. It is to be noted that the features in the following embodiments and examples may be combined with each other without conflict. All other embodiments, which can be derived by a person skilled in the art from the embodiments disclosed herein without making any creative effort, shall fall within the protection scope of the present disclosure.
The resonance pulse repairing technology, also called composite harmonic pulse resonance repairing technology, used in the invention is based on the principle that pulses with specific frequency have destructive effect on lead sulfate crystals generated by the storage battery, and the existence and growth of lead sulfate coarse grains are interfered by using composite harmonic pulse energy to impact the lead sulfate coarse grains, so that the 'irreversible' of the storage battery vulcanization is changed into 'reversible'. When the system equipment with the technology works, the pulse current with specific frequency and specific amplitude can be continuously output, only the pulse current which is relatively acted on lead sulfate crystals with different sizes in the storage battery can enable the pulse frequency and the natural frequency of the lead sulfate crystals to generate resonance, and when the energy is enough, the lead sulfate crystals are smashed and decomposed and dissolved in sulfuric acid electrolyte to participate in chemical reaction again without damaging battery plates.
The invention discloses a storage battery efficiency maintenance method based on a resonant pulse repair technology, which comprises the following steps of:
step 1, a detection circuit detects parameters of single storage batteries of a storage battery pack.
The parameters of the single storage battery include internal resistance, voltage, temperature and current of the storage battery.
The internal resistance of the storage battery is measured by an alternating current injection method, and the internal resistance value is calculated by measuring the voltage feedback of the storage battery to an alternating current signal with certain frequency input to the storage battery. The internal resistance test can be carried out on the storage battery in any states of charging, discharging and the like, and the frequency of the selected signal can adapt to different types of storage batteries. Meanwhile, a related filtering algorithm is adopted, and only the response signal of the injection signal is reserved through filtering, so that various harmonic interference is eliminated in principle, and the accuracy and the stability of the internal resistance detection result are ensured.
And 2, adjusting the output intensity of the pulse current according to the parameters of the single storage battery.
The pulse current is generated by combining a pulse current and a current type composite harmonic generation circuit, is pulse current with the magnitude above KHZ in the true sense, and has the pulse frequency resonant with the natural frequency of the lead sulfate crystals. The output pulse current intensity is designed according to 0.01-0.05C, and the requirements of the Chinese Ministry of industry and information YD/T2064-2009 are completely met.
The storage battery efficiency maintenance device is designed by adopting a time-sharing gap cycle working technology, namely, a pulse current output module in the device comprises a plurality of working modules, only one working module outputs pulse current at each moment, and the storage battery efficiency maintenance device has the following advantages:
output power energy consumption value is low: when the battery pack with more series single batteries is managed, no matter how many circuit working modules exist in the product, the output power consumption is only the power consumption of one circuit module in working output, and compared with the product without the technology, the output power consumption is smaller.
The output ripple interference value is low: by adopting the technology, a single amplitude value of the output pulse, namely a ripple interference value, can be effectively suppressed.
According to the real-time acquisition of the storage battery parameters, the output pulse current intensity can be automatically adjusted, the requirement on the sulfur removal effect of the storage batteries with different capacities is met, and a large amount of manual data acquisition and manual parameter setting errors are avoided.
And 3, smashing lead sulfate grains in the storage battery by using pulse current, dissolving the lead sulfate grains in sulfuric acid electrolyte, and participating in chemical reaction again.
In order to avoid injecting pulse signals into the total voltage pole terminal of the battery pack and reduce the risk of false operation of triggering other devices of the power supply system, in the battery pack, every 12V of the single battery pack forms a series circuit, and each series circuit is injected with pulse signals by a working module, as shown in fig. 4. And only one working module in the pulse current output modules works at the same time.
After the storage battery is repaired by the method, the discharge capacity of the storage battery, such as discharge voltage, discharge time and the like, is greatly improved, as shown in fig. 5 to 6.
The invention discloses a storage battery efficiency maintenance device based on a resonant pulse repairing technology, which comprises a detection circuit, a management module and a pulse current output module, wherein:
the detection circuit is used for detecting parameters of the single storage battery in the storage battery pack. The parameters of the single storage battery comprise internal resistance, voltage, temperature and current of the storage battery.
And the management module is used for managing the pulse current output module and controlling the pulse current output by the pulse current output module according to the parameters of the single storage battery.
And the pulse current output module outputs pulse current with specific magnitude according to the control of the management module. The pulse current output module comprises a plurality of working modules, and each working module is independently controlled by the management module and independently outputs pulse current. And only one working module works at the same time. When the battery pack with more series single storage batteries is managed, no matter how many working modules exist, the output power consumption is only the output power consumption of one working module in working, and the output power consumption is smaller. And the output ripple interference value is low, and by adopting the technology, the single amplitude value of the output pulse, namely the ripple interference value, can be effectively inhibited.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; may be mechanically coupled, may be electrically coupled or may be in communication with each other; they may be directly connected or indirectly connected through intervening media, or they may be connected internally or in any other suitable relationship, unless expressly stated otherwise. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations. A plurality in the present invention means at least 1.
The above description is for the purpose of illustrating embodiments of the invention and is not intended to limit the invention, and it will be apparent to those skilled in the art that any modification, equivalent replacement, or improvement made without departing from the spirit and principle of the invention shall fall within the protection scope of the invention.

Claims (8)

1. The storage battery efficiency maintenance method based on the resonance pulse repair technology is characterized by comprising the following steps of:
step 1, detecting parameters of single storage batteries of a storage battery pack by a detection circuit;
step 2, the management module controls the pulse direct current output module to output a single-path pulse current according to the parameters of the single storage battery;
and 3, smashing lead sulfate crystal grains in the storage battery by using pulse current to dissolve the lead sulfate crystal grains in sulfuric acid electrolyte.
2. The method for maintaining the efficiency of a storage battery based on the resonance pulse restoration technology according to claim 1, wherein the pulse frequency of the pulse current and the natural frequency of the lead sulfate crystal grains generate resonance, so as to break up the lead sulfate crystal grains.
3. The battery performance maintenance method based on the resonant pulse repairing technology of claim 1, wherein the pulse dc output module comprises at least one working module, and only one working module works at a time.
4. The battery efficiency maintenance method based on the resonance pulse repairing technology as claimed in claim 3, wherein in the battery pack, a plurality of 12V series circuits are formed by single batteries, and each series circuit receives a pulse signal injected by one working module.
5. The method according to claim 1, wherein the intensity of the single pulse dc is determined according to the parameters of the battery cell.
6. Device is maintained to battery efficiency based on resonance pulse repair technique, its characterized in that, including detection circuitry, management module and pulse current output module, wherein:
the detection circuit is used for detecting parameters of the single storage battery in the storage battery pack;
the management module is used for managing the pulse current output module and controlling the intensity of the pulse current output by the pulse current output module according to the parameters of the single storage battery;
and the pulse current output module outputs the single-path pulse current with specific intensity according to the control of the management module.
7. The apparatus for maintaining the efficiency of a storage battery based on resonant pulse repairing technology of claim 6, wherein said pulse current output module comprises a plurality of working modules, each of which is individually controlled by the management module to independently output pulse current.
8. The apparatus for maintaining battery efficiency according to claim 7, wherein only one working module is operated at the same time.
CN202110522971.2A 2021-05-13 2021-05-13 Storage battery efficiency maintenance method and equipment based on resonant pulse repair technology Pending CN113437370A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114236242A (en) * 2021-11-23 2022-03-25 广西电网有限责任公司北海供电局 Accumulator internal resistance tester and testing method based on composite frequency
CN115343637A (en) * 2022-10-20 2022-11-15 武汉源畅科技有限公司 Storage battery internal resistance testing device and testing method
CN115692882A (en) * 2022-10-27 2023-02-03 北京洲海能环科技有限公司 Storage battery pack online restoration balance control method and device

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102751543A (en) * 2011-04-18 2012-10-24 肖敏 Pulse current method for repairing lead-acid battery and lead-acid storage battery sulphur remover
CN204315686U (en) * 2014-12-25 2015-05-06 航天科工海鹰集团有限公司 Accumulator on-line maintenance system

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102751543A (en) * 2011-04-18 2012-10-24 肖敏 Pulse current method for repairing lead-acid battery and lead-acid storage battery sulphur remover
CN204315686U (en) * 2014-12-25 2015-05-06 航天科工海鹰集团有限公司 Accumulator on-line maintenance system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114236242A (en) * 2021-11-23 2022-03-25 广西电网有限责任公司北海供电局 Accumulator internal resistance tester and testing method based on composite frequency
CN115343637A (en) * 2022-10-20 2022-11-15 武汉源畅科技有限公司 Storage battery internal resistance testing device and testing method
CN115692882A (en) * 2022-10-27 2023-02-03 北京洲海能环科技有限公司 Storage battery pack online restoration balance control method and device

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Application publication date: 20210924