CN113433750B - Electrochromic device and electronic equipment - Google Patents

Electrochromic device and electronic equipment Download PDF

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Publication number
CN113433750B
CN113433750B CN202110711497.8A CN202110711497A CN113433750B CN 113433750 B CN113433750 B CN 113433750B CN 202110711497 A CN202110711497 A CN 202110711497A CN 113433750 B CN113433750 B CN 113433750B
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color
area
changing
electrochromic device
conductive
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CN113433750A (en
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熊沉璧
李佳城
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Shenzhen Guangyi Tech Co Ltd
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Shenzhen Guangyi Tech Co Ltd
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Priority to PCT/CN2022/099177 priority patent/WO2022267975A1/en
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • G02F1/155Electrodes

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

The invention discloses an electrochromic device and electronic equipment. The electrochromic device comprises a first color-changing area and at least one second color-changing area, wherein the first color-changing area and each second color-changing area can be respectively and independently changed in color and are used for simultaneously changing colors according to the same target transmittance, and the area of the first color-changing area is larger than that of each second color-changing area. According to the technical scheme provided by the invention, the smaller color-changing area in the electrochromic device is used as the preview area, and when the electrochromic device is required to be changed in color, the preview area can reach the target transmittance more quickly, so that a user can know that the electrochromic device starts to respond to the color change more timely, the final state of the electrochromic device after the color change is finished can be previewed more quickly, and the use experience of the user is greatly improved.

Description

Electrochromic device and electronic equipment
Technical Field
The invention relates to the technical field of electrochromic, in particular to an electrochromic device and electronic equipment.
Background
In the current electrochromic device, voltage is generally applied to the electrochromic layer through the conductive layers at two sides of the electrochromic layer to realize the transmittance change of the electrochromic layer, so that in order to ensure the transparency of the conductive layer, the material of the conductive layer can be selected to be very limited, and Indium Tin Oxide (ITO) materials are generally adopted in the prior art. Although ITO is conductive, it is far less conductive than materials such as metals, and therefore, when electrochromic devices change color, there is typically a phenomenon that the periphery has begun to change color, but the center area has not changed color. Particularly in some larger size devices, it often takes seconds for the user to perceive that the edge begins to change color after the voltage is applied to the electrochromic device. In this case, it is difficult to timely determine whether the expected transmittance of the electrochromic device can achieve the desired effect of the user, thereby prolonging the waiting time of the user, and in addition, the user may misunderstand that the electrochromic device is not successfully started, thereby enabling the user to repeatedly operate, resulting in poor user experience.
In order to accelerate the color-changing response speed, the prior art generally adopts a mode of increasing the applied voltage, so that the edge of the electrochromic device changes color rapidly under the drive of high voltage. However, in this state, the edge of the electrochromic device is often in an overcharged state, and the lifetime of the electrochromic device is greatly reduced in long-term use.
Disclosure of Invention
The invention provides an electrochromic device and electronic equipment, so that a user can know that the electrochromic device starts to respond to the color change in time, and quickly preview the final state of the electrochromic device after the color change is finished.
In a first aspect, the present invention provides an electrochromic device, including a first color-changing region and at least one second color-changing region, where the first color-changing region and each of the second color-changing regions are capable of being color-changed independently, and are configured to simultaneously change colors according to the same target transmittance, and an area of the first color-changing region is larger than an area of each of the second color-changing regions.
Optionally, the electrochromic device comprises a first substrate layer, a first conductive layer, an electrochromic layer, a second conductive layer and a second substrate layer which are sequentially stacked; the first conductive layer comprises a first etching groove, the first etching groove is used for dividing the first conductive layer into a first conductive area and a second conductive area which are mutually independent, the first conductive area corresponds to the first color-changing area, and the second conductive area corresponds to the second color-changing area.
Optionally, the first conductive area is connected with the first extraction electrode, the second conductive area is connected with the second extraction electrode, and the second conductive layer is connected with the third extraction electrode.
Optionally, the second conductive layer includes a second etching groove, where the second etching groove is configured to divide the second conductive layer into a third conductive area and a fourth conductive area that are independent of each other, the third conductive area corresponds to the first color-changing area, and the fourth conductive area corresponds to the second color-changing area.
Optionally, the first conductive area is connected with the first extraction electrode, the second conductive area is connected with the second extraction electrode, the third conductive area is connected with the fourth extraction electrode, and the fourth conductive area is connected with the fifth extraction electrode.
Optionally, the second color-changing region is disposed along an edge of the electrochromic device.
Optionally, the electrochromic device further includes a pattern layer, and the pattern layer is disposed at a position of the second color-changing area and/or beside the second color-changing area on the surface of the electrochromic device, and is used for marking the position of the second color-changing area.
Optionally, the area ratio of the first color-changing area to the second color-changing area is greater than or equal to 10, or greater than or equal to 50, or greater than or equal to 100.
Optionally, the area of the second color-changing area is less than or equal to 0.1 square meter.
In a second aspect, the present invention further provides an electronic device, including an electrochromic device provided by any embodiment of the present invention.
The invention provides an electrochromic device which comprises a first color-changing area and at least one second color-changing area, wherein the first color-changing area and each second color-changing area can be respectively and independently changed in color and are used for changing colors according to the same target transmittance, and the area of the first color-changing area is larger than that of each second color-changing area. According to the electrochromic device provided by the invention, the smaller color-changing area in the electrochromic device is used as the preview area, and when the electrochromic device is required to be changed, the preview area can reach the target transmittance more quickly, so that a user can know that the electrochromic device starts to respond to the color change more timely, the final state of the electrochromic device after the color change is finished can be previewed more quickly, and the use experience of the user is greatly improved.
Drawings
Fig. 1 is a schematic structural diagram of an electrochromic device according to a first embodiment of the present invention;
fig. 2 is a schematic structural diagram of another electrochromic device according to a first embodiment of the present invention;
fig. 3 is a schematic structural diagram of an electrochromic device according to a second embodiment of the present invention;
fig. 4 is a schematic structural diagram of another electrochromic device according to the second embodiment of the present invention;
fig. 5 is a schematic structural diagram of another electrochromic device according to the second embodiment of the present invention;
fig. 6 is a schematic structural diagram of another electrochromic device according to the second embodiment of the present invention;
fig. 7 is a schematic structural diagram of another electrochromic device according to the second embodiment of the invention;
fig. 8 is a schematic structural diagram of another electrochromic device according to the second embodiment of the invention;
fig. 9 is a schematic structural diagram of another electrochromic device according to the second embodiment of the invention;
fig. 10 is a schematic structural diagram of another electrochromic device according to the second embodiment of the invention;
fig. 11 is a schematic structural diagram of another electrochromic device according to the second embodiment of the invention.
Detailed Description
The invention is described in further detail below with reference to the drawings and examples. It is to be understood that the specific embodiments described herein are merely illustrative of the invention and are not limiting thereof. It should be further noted that, for convenience of description, only some, but not all of the structures related to the present invention are shown in the drawings.
Furthermore, the terms "first," "second," and the like, may be used herein to describe various directions, acts, steps, or elements, etc., but these directions, acts, steps, or elements are not limited by these terms. These terms are only used to distinguish one direction, action, step or element from another direction, action, step or element. The terms "first," "second," and the like, are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature.
Example 1
Fig. 1 is a schematic structural diagram of an electrochromic device according to an embodiment of the present invention. As shown in fig. 1, the electrochromic device includes a first color-changing region 11 and at least one second color-changing region 12 (shown in fig. 1 as including one second color-changing region 12 as an example), the first color-changing region 11 and each second color-changing region 12 being independently color-changeable, respectively, and for simultaneously changing colors according to the same target transmittance, wherein the area of the first color-changing region 11 is larger than the area of each second color-changing region 12.
Specifically, the display color-changing area of the electrochromic device may be divided into a first color-changing area 11 and at least one second color-changing area 12, where the first color-changing area 11 and each second color-changing area 12 may be controlled to change color independently, and the area of the first color-changing area 11 is larger than the area of each second color-changing area 12. The second color-changing region 12 can complete the color change more quickly when the first color-changing region 11 and the second color-changing region 12 are controlled to change colors using the same or similar voltages, respectively. When the electrochromic device provided in this embodiment is required to be used for color change, if the corresponding control signal is received, the control signal may carry a corresponding value of the target transmittance, and then the first color-changing area 11 and the second color-changing area 12 may be controlled to be respectively color-changed according to the target transmittance. Since the area of the second color-changing region 12 is smaller than that of the first color-changing region 11, and since the same target transmittance is used for both the second color-changing region 12 and the first color-changing region 11 and the second color-changing region 12 are the same or similar to each other (since the conductive layer used by the electrochromic device has a surface resistance and thus has a certain loss, the absolute value of the control voltage used by the first color-changing region 11 may need to be larger than that of the control voltage of the second color-changing region 12), the second color-changing region 12 can reach the target transmittance faster to complete the color-changing process, and since the same target transmittance is used, the first color-changing region 11 and the second color-changing region 12 will also change to the same state finally without affecting the use of the electrochromic device. The second color-changing region 12 can be used as a preview region to provide faster feedback to the user during the color change using the electrochromic device so that the user knows that the electrochromic device has begun to respond to the color change and previews in advance the final state of the entire electrochromic device after the color change has been completed. The shape of the second color-changing region 12 may be circular, square, ring-shaped, bar-shaped, or the like.
Optionally, as shown in fig. 2, the number of the second color-changing areas 12 may be multiple, and may be distributed around the electrochromic device, and may also be disposed at a central position of the electrochromic device, so that the second color-changing areas 12 are located at a more obvious position according to an actual use situation of the electrochromic device, so that a user can quickly obtain a preview result.
Optionally, the area ratio of the first color-changing area 11 to the second color-changing area 12 is greater than or equal to 10, further optionally, the area ratio of the first color-changing area 11 to the second color-changing area 12 is greater than or equal to 50, further optionally, the area ratio of the first color-changing area 11 to the second color-changing area 12 is greater than or equal to 100, so that the time required for the second color-changing area 12 to reach the target transmittance is shorter than that of the first color-changing area 11, the user can obtain the preview result faster, and the area ratio between the first color-changing area 11 and the second color-changing area 12 can be determined according to the size of the electrochromic device, so that the second color-changing area 12 can complete color change within the time range acceptable to the user.
Or alternatively, the area of the second color-changing area 12 is smaller than or equal to 0.1 square meter, that is, the area of the second color-changing area 12 is fixedly set to be smaller than or equal to 0.1 square meter regardless of the size of the electrochromic device, so that the second color-changing area 12 can be ensured to complete color changing within a time range acceptable to a user, that is, the second color-changing area 12 can be better used as a preview area for providing a preview function for the user for the electrochromic device with any size.
On the basis of the above technical solution, optionally, the electrochromic device provided in this embodiment may further include a pattern layer, where the pattern layer is disposed at a position of the second color-changing area 12 and/or beside the second color-changing area 12 on the surface of the electrochromic device, and is used for marking a position of the second color-changing area 12. Specifically, when the electrochromic device is not in the process of changing color or after the process of changing color has been completed, because the color between the first color changing area 11 and the second color changing area 12 is consistent, it is difficult for the user to determine the specific position of the second color changing area 12, especially when the entire area of the electrochromic device is large, if the electrochromic device is required to change color, the attention of the user is difficult to be quickly focused on the second color changing area 12, so that the effect of the second color changing area 12 as a preview area is weakened. Therefore, the pattern layer can be arranged on the electrochromic device to indicate the position of the second color-changing area 12 to the user, and can be specifically arranged to be partially or completely overlapped with the second color-changing area 12 to accurately indicate the position of the second color-changing area 12, can also be arranged beside the second color-changing area 12 and point to the second color-changing area 12 to reduce shielding to the second color-changing area 12, so as to provide a clearer preview color-changing effect for the user, and can also be arranged beside the second color-changing area 12 and the second color-changing area 12 to provide a clearer indication effect for the user.
The electrochromic device provided by the embodiment of the invention comprises a first color-changing area and at least one second color-changing area, wherein the first color-changing area and each second color-changing area can be respectively and independently changed in color and are used for changing colors according to the same target transmittance, and the area of the first color-changing area is larger than that of each second color-changing area. Through regard as the preview area with a less region that discolours in the electrochromic device, when needs make electrochromic device take place to discolour, the preview area can be faster reach the target transmissivity to make the user can more timely know electrochromic device has started response discolour, and can be more quick preview reaches electrochromic device and accomplish the final state after discolour, promoted user's use experience greatly.
Example two
Fig. 3 is a schematic structural diagram of an electrochromic device according to a second embodiment of the present invention. The technical solution of this embodiment is further refined on the basis of the technical solution of the foregoing embodiment, and optionally, as shown in fig. 3, the electrochromic device includes a first substrate layer 21, a first conductive layer 22, an electrochromic layer 23, a second conductive layer 24, and a second substrate layer 25 that are sequentially stacked; the first conductive layer 22 includes a first etching groove 221, where the first etching groove 221 is configured to divide the first conductive layer 22 into a first conductive area and a second conductive area that are independent of each other, the first conductive area corresponds to the first color-changing area, and the second conductive area corresponds to the second color-changing area.
Specifically, the first etching groove 221 may enable the first conductive layer 22 to be divided into a plurality of conductive areas independent of each other, including a first conductive area corresponding to the first color-changing area and a second conductive area corresponding to the second color-changing area, that is, the first conductive area of the first color-changing area and the second conductive area of the second color-changing area are separated by the first etching groove 221, so that independent control of the first color-changing area and the second color-changing area can be achieved. The number of the first etching grooves 221 may be the same as the number of the second color change regions to obtain the same number of the second conductive regions.
Further optionally, as shown in fig. 4 and fig. 5, the electrochromic layer at the corresponding position of the first etching groove 221 may be partially or fully etched, so as to further ensure independent control between the first color-changing region and the second color-changing region.
Further alternatively, as shown in fig. 6, the first conductive region is connected to the first extraction electrode 222, the second conductive region is connected to the second extraction electrode 223, and the second conductive layer 24 is connected to the third extraction electrode 241. The first color change region can be controlled to change color by applying voltages to the first extraction electrode 222 and the third extraction electrode 241, and the second color change region can be controlled to change color by applying voltages to the second extraction electrode 223 and the third extraction electrode 241, so that the first color change region and the second color change region can be independently changed.
Further alternatively, as shown in fig. 7, the second conductive layer 24 includes a second etched groove 242, where the second etched groove 242 is configured to divide the second conductive layer 24 into a third conductive area and a fourth conductive area that are independent of each other, where the third conductive area corresponds to the first color-changing area, and the fourth conductive area corresponds to the second color-changing area. Specifically, the second etching groove 242 may also divide the second conductive layer 24 into a plurality of conductive areas that are independent of each other, including a third conductive area corresponding to the first color-changing area and a fourth conductive area corresponding to the second color-changing area, that is, the third conductive area of the first color-changing area and the fourth conductive area of the second color-changing area are separated by the second etching groove 242, and correspond to the first conductive area and the second conductive area respectively, so that accuracy of independent control between the first color-changing area and the second color-changing area can be further improved. The number of second etched grooves 242 may be the same as the number of second color change regions to obtain the same number of fourth conductive regions.
Further optionally, as shown in fig. 8 and fig. 9, the electrochromic layer at the corresponding position of the first etching groove 221 and the second etching groove 242 may be partially or fully etched, so as to further ensure independent control between the first color-changing region and the second color-changing region.
Further alternatively, as shown in fig. 10, the first conductive region is connected to the first extraction electrode 222, the second conductive region is connected to the second extraction electrode 223, the third conductive region is connected to the fourth extraction electrode 243, and the fourth conductive region is connected to the fifth extraction electrode 244. The first color change region can be controlled to change color by applying voltages to the first and fourth lead electrodes 222 and 243, and the second color change region can be controlled to change color by applying voltages to the second and fifth lead electrodes 223 and 244, thereby realizing that the first and second color change regions can change color independently.
On the basis of the above technical solution, optionally, as shown in fig. 11, the second color-changing region 12 is disposed along an edge of the electrochromic device. When the second color-changing region 12 is disposed along the edge of the electrochromic device, the extraction electrodes (such as the second extraction electrode and the fifth extraction electrode described above) required for the conductive region corresponding to the second color-changing region 12 can be directly extracted from the edge of the electrochromic device, so that visual discomfort caused by the extraction electrodes can be avoided, and convenience in setting the extraction electrodes is also improved.
According to the electrochromic device provided by the embodiment of the invention, the first etching groove is formed in the first conductive layer of the electrochromic device, so that the first conductive layer is divided into the first conductive area corresponding to the first color-changing area and the second conductive area corresponding to the second color-changing area, and independent control between the first color-changing area and the second color-changing area is realized. Furthermore, a second etching groove is formed in the second conductive layer of the electrochromic device, so that the second conductive layer is divided into a third conductive area corresponding to the first color-changing area and a fourth conductive area corresponding to the second color-changing area, and accuracy of independent control between the first color-changing area and the second color-changing area is further improved.
Example III
The third embodiment of the invention also provides electronic equipment, which comprises the electrochromic device provided by any embodiment of the invention, and has the corresponding functional structure and beneficial effects. Specifically, the electronic device may be architectural glass, window glass, a dimming diaphragm and the like, and specifically may at least include a first glass, a first adhesive layer, an electrochromic device, a second adhesive layer and a second glass which are laminated in sequence, and a controller for controlling the discoloration of the electrochromic device, a power supply for supplying power and the like. In particular, when the electrochromic device needs to include a pattern layer, the pattern layer may be disposed on a surface of the electrochromic device, may be disposed on a surface of the first glass or the second glass, or the like.
Note that the above is only a preferred embodiment of the present invention and the technical principle applied. It will be understood by those skilled in the art that the present invention is not limited to the particular embodiments described herein, but is capable of various obvious changes, rearrangements and substitutions as will now become apparent to those skilled in the art without departing from the scope of the invention. Therefore, while the invention has been described in connection with the above embodiments, the invention is not limited to the embodiments, but may be embodied in many other equivalent forms without departing from the spirit or scope of the invention, which is set forth in the following claims.

Claims (10)

1. The electrochromic device is characterized by comprising a first color-changing area and a second color-changing area which are mutually independent and correspond to the conductive areas, wherein the first color-changing area and the second color-changing area are respectively and independently controlled to change color, the area of the first color-changing area is larger than that of the second color-changing area, and the first color-changing area and the second color-changing area are respectively used for receiving the same or similar voltage control and simultaneously changing color according to the same target transmittance when the electrochromic device changes color.
2. The electrochromic device according to claim 1, comprising a first substrate layer, a first conductive layer, an electrochromic layer, a second conductive layer and a second substrate layer, stacked in that order; the first conductive layer comprises a first etching groove, the first etching groove is used for dividing the first conductive layer into a first conductive area and a second conductive area which are mutually independent, the first conductive area corresponds to the first color-changing area, and the second conductive area corresponds to the second color-changing area.
3. The electrochromic device according to claim 2, wherein the first conductive area is connected to a first extraction electrode, the second conductive area is connected to a second extraction electrode, and the second conductive layer is connected to a third extraction electrode.
4. The electrochromic device according to claim 2, wherein the second conductive layer comprises a second etched trench for dividing the second conductive layer into third and fourth conductive regions independent of each other, the third conductive region corresponding to the first color-changing region and the fourth conductive region corresponding to the second color-changing region.
5. The electrochromic device according to claim 4, wherein the first conductive area is connected to a first extraction electrode, the second conductive area is connected to a second extraction electrode, the third conductive area is connected to a fourth extraction electrode, and the fourth conductive area is connected to a fifth extraction electrode.
6. The electrochromic device according to claim 3 or 5, wherein the second color-changing region is disposed along an edge of the electrochromic device.
7. The electrochromic device according to claim 1, further comprising a patterned layer disposed on the surface of the electrochromic device at and/or beside the second color-changing region for marking the position of the second color-changing region.
8. The electrochromic device according to claim 1, wherein the area ratio of the first color-changing region to the second color-changing region is 10 or greater, or 50 or greater, or 100 or greater.
9. The electrochromic device according to claim 1, wherein the area of the second color-changing region is less than or equal to 0.1 square meters.
10. An electronic device comprising an electrochromic device according to any one of claims 1-9.
CN202110711497.8A 2021-06-25 2021-06-25 Electrochromic device and electronic equipment Active CN113433750B (en)

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PCT/CN2022/099177 WO2022267975A1 (en) 2021-06-25 2022-06-16 Electrochromic device, control method and apparatus therefor

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CN111323979A (en) * 2020-01-03 2020-06-23 深圳市光羿科技有限公司 Electrochromic device and preparation method
CN112904636A (en) * 2021-02-06 2021-06-04 深圳市光羿科技有限公司 Electrochromic device and electronic terminal comprising same
CN112859474A (en) * 2021-03-24 2021-05-28 维沃移动通信有限公司 Electrochromic device and electronic apparatus

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