CN113427644A - Engineering ceramic complex frequency ultrasonic processing device - Google Patents

Engineering ceramic complex frequency ultrasonic processing device Download PDF

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Publication number
CN113427644A
CN113427644A CN202110814572.3A CN202110814572A CN113427644A CN 113427644 A CN113427644 A CN 113427644A CN 202110814572 A CN202110814572 A CN 202110814572A CN 113427644 A CN113427644 A CN 113427644A
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CN
China
Prior art keywords
ultrasonic
ultrasonic probe
ring
groups
engineering ceramic
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Pending
Application number
CN202110814572.3A
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Chinese (zh)
Inventor
郑雷
宋春阳
刘子文
董香龙
韦文东
陈远晟
聂承敏
胡俊杰
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Yancheng Institute of Technology
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Yancheng Institute of Technology
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Application filed by Yancheng Institute of Technology filed Critical Yancheng Institute of Technology
Priority to CN202110814572.3A priority Critical patent/CN113427644A/en
Publication of CN113427644A publication Critical patent/CN113427644A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D1/00Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor
    • B28D1/14Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor by boring or drilling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B37/00Boring by making use of ultrasonic energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D1/00Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor
    • B28D1/14Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor by boring or drilling
    • B28D1/146Tools therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D7/00Accessories specially adapted for use with machines or devices of the preceding groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D7/00Accessories specially adapted for use with machines or devices of the preceding groups
    • B28D7/005Devices for the automatic drive or the program control of the machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D7/00Accessories specially adapted for use with machines or devices of the preceding groups
    • B28D7/04Accessories specially adapted for use with machines or devices of the preceding groups for supporting or holding work or conveying or discharging work

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mining & Mineral Resources (AREA)
  • Grinding And Polishing Of Tertiary Curved Surfaces And Surfaces With Complex Shapes (AREA)

Abstract

The invention discloses an engineering ceramic complex frequency ultrasonic processing device which comprises an ultrasonic punching device, wherein the ultrasonic punching device consists of a processing table, a rotary lifting table and a lifting ultrasonic device, two groups of table tops which are respectively a first table top and a second table top are formed on the surface of the processing table, a controller is arranged between the first table top and the second table top, the rotary lifting table is arranged on the first table top, an annular dirt guide port is formed in the lower edge of the rotary lifting table, a dirt storage box is arranged below the annular dirt guide port in a drawing mode, the rotary lifting table is of a double-layer structure and is respectively a base and a top ring from bottom to top, a driving motor is arranged inside the base, and a rotating disc is arranged at the power output end of the driving motor. According to the invention, the lifting mechanism is arranged at the upper end of the ultrasonic probe, the ultrasonic probe is clamped through the manipulator, the adjusting mechanism is designed in the ultrasonic probe, the position of the tail end probe body can be adjusted through the operation of the adjusting mechanism, and the automatic adjustment can be conveniently carried out according to the hole diameter size to be punched.

Description

Engineering ceramic complex frequency ultrasonic processing device
Technical Field
The invention relates to the technical field of engineering ceramic ultrasonic processing equipment, in particular to an engineering ceramic complex frequency ultrasonic processing device.
Background
The engineering ceramic, also called silicon nitride ceramic or high-strength ceramic, is made up by using silicon powder as raw material and adopting two technological processes of reaction sintering and hot-pressing respectively. It has almost all the advantages of modern ceramic family, high strength, excellent wear resistance and chemical corrosion resistance, and is one excellent electric insulating material. The wear resistance of the ceramic working surface is more than 100 times that of manganese steel and more than 20 times that of high-chromium cast iron; compared with wear-resistant rubber, the wear-resistant rubber is several times to dozens of times higher, and along with the wider application of the engineering ceramics in the fields of aerospace, electronics, automobiles and the like, the requirements on the processing methods of the materials are higher and higher. However, due to the hard and brittle nature of engineered ceramic materials, they are often difficult to machine using conventional machining methods, and most ceramics are poorly conductive, thereby limiting the use of electrical discharge machining. In view of this, ceramic materials are greatly limited in terms of processing. At present, the methods for processing ceramics mainly include mechanical processing, laser processing, ultrasonic processing and the like, wherein the ultrasonic processing is widely applied. Ultrasonic machining is mainly with the oscillation signal that ultrasonic generator produced, converts high frequency mechanical vibration signal into through the transducer, makes the instrument produce the vibration to drive the suspension grit and constantly strike the processing surface. Currently, the ultrasonic machining is mainly applied to rotary machining, namely, the tool is rotated at a certain speed while being vibrated continuously to crush workpiece materials into small particles for removal.
However, the conventional engineering ceramics have the following problems in the process of processing by ultrasonic drilling: (1) the structure of the ultrasonic probe of the conventional ultrasonic equipment for engineering ceramics is fixed, and can not be correspondingly adjusted according to the specification of required punching in the use process, generally, the probe with one specification can only process the aperture with one specification, and the ultrasonic probe has poor universality and can not meet the actual requirement; (2) the processing mode that mostly exposes the formula in the process of current ultrasonic probe processing, receive external factor's influence easily, influence the effect of probe processing, lack the machining accuracy of measuring mechanism to the aperture relatively poor on the probe in addition. For this reason, a corresponding technical scheme needs to be designed to solve the existing technical problems.
Disclosure of Invention
The invention aims to provide an engineering ceramic complex frequency ultrasonic processing device, which solves the technical problems that the structure of an ultrasonic probe of the traditional ultrasonic equipment for engineering ceramics is fixed, the ultrasonic probe can not be correspondingly adjusted according to the specification of required punching in the using process, the common probe with one specification can only process the aperture with one specification, the universal type of the ultrasonic probe is poor, and the actual requirement can not be met.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides an engineering ceramic multiple-frequency ultrasonic machining device, includes ultrasonic perforating device, ultrasonic perforating device comprises processing platform, rotatory elevating platform and lift ultrasonic ware, the surface machining shaping of processing platform has two sets of mesas and is mesa one, mesa two respectively, be provided with the controller between mesa one and the mesa two, rotatory elevating platform is installed on mesa one and is followed to have seted up the annular and lead dirty mouthful down, the annular is led dirty mouthful below pull formula and is provided with the dirt storage box, rotatory elevating platform is bilayer structure and from the bottom up is base and apical ring respectively, the inside of base is provided with driving motor, driving motor's power take off end installs the rolling disc, the periphery of rolling disc is connected with the apical ring through the metal pole, the top of apical ring is provided with the lift ring, the lift ultrasonic ware is by pneumatic cylinder, push rod, backup pad, Pole setting, manipulator and ultrasonic probe device constitute, the pneumatic cylinder is installed on mesa two and power take off end is connected with the push rod, the top of push rod is connected with the backup pad that the level set up, the pole setting is installed perpendicularly in the outer end of backup pad, the manipulator is installed in the end of pole setting, the ultrasonic probe device is got to the terminal clamp of manipulator, the ultrasonic probe device includes the ultrasonic probe body and installs in the terminal ultrasonic head of ultrasonic probe body, the ultrasonic head is located rotatory elevating platform.
As a preferred embodiment of the present invention, the lifting ring includes a main ring and a cylindrical outer curtain fixed below the main ring, four groups of electric rods are uniformly installed on the periphery of the top ring, and power output ends of the four groups of electric rods are connected to the main ring.
In a preferred embodiment of the present invention, the cylindrical outer screen has a cylindrical structure and is made of a rubber material, and a surface of the cylindrical outer screen has a corrugated structure.
As a preferred embodiment of the present invention, a through hole is longitudinally formed in the ultrasonic probe body, a screw rod is inserted into the through hole, a servo motor is disposed on one side of the upper end of the screw rod, a belt is mounted at the power output end of the servo motor, the belt is embedded on the screw rod, and the lower end of the screw rod is connected with the ultrasonic head.
As a preferred embodiment of the present invention, the ultrasonic head includes a movable disk movably sleeved at the lower end of the screw rod and a probe body uniformly installed on the periphery of the movable disk, and two sets of distance sensors are further disposed on the inner side of the probe body and connected to the controller through a line.
As a preferred embodiment of the invention, the movable disc comprises an inner disc with a movable groove in the middle and four groups of movable blocks movably arranged on the periphery of the inner disc through hinges, ejector rods are vertically arranged above the four groups of movable blocks, and the upper ends of the ejector rods are connected with the lower edge of the ultrasonic probe body.
In a preferred embodiment of the present invention, four sets of the probe bodies are uniformly mounted on four sets of the movable blocks.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention designs an ultrasonic probe capable of being flexibly adjusted, a lifting mechanism is arranged at the upper end of the ultrasonic probe and clamps the ultrasonic probe through a manipulator, an adjusting mechanism is designed in the ultrasonic probe, the position of a tail end probe body can be adjusted through the operation of the adjusting mechanism, the automatic adjustment can be conveniently carried out according to the aperture size of the required hole, in addition, a special distance sensor is designed at the lower end of the ultrasonic probe, the detection can be carried out when the probe body extends into the hole, and the punching accuracy is improved.
2. According to the invention, the rotary placing table is designed on the operating table, and the lifting mechanism is designed on the periphery of the rotary placing table, so that when the engineering ceramics are required to be punched, the rotary placing table can be lifted and subjected to ultrasonic treatment, the external influence is reduced, and the ultrasonic punching effect is improved.
Drawings
FIG. 1 is an overall block diagram of the present invention;
FIG. 2 is a view of the structure of the rotary elevating platform in the unfolded state;
FIG. 3 is a view of the structure of the ultrasonic probe body according to the present invention;
FIG. 4 is a partial structure diagram of the present invention.
In the figure, 1, a first table top; 2. a second table surface; 3. a controller; 4. an annular dirt guide port; 5. a sewage storage box; 6. a base; 7. a top ring; 8. a drive motor; 9. rotating the disc; 11. a lifting ring; 12. a hydraulic cylinder; 13. a push rod; 14. a support plate; 15. erecting a rod; 16. a manipulator; 17. an ultrasonic probe body; 18. an ultrasonic head; 19. a main ring; 20. a cylindrical outer curtain; 21. an electric rod; 22. perforating; 23. a screw; 24. a servo motor; 25. a belt; 26. a movable tray; 27. a probe body; 28. a distance sensor; 29. a movable groove; 30. an inner disc; 31. a movable block; 32. and a push rod.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1-4, the present invention provides a technical solution: the utility model provides an engineering ceramics multifrequency ultrasonic machining device, including ultrasonic perforating device, ultrasonic perforating device comprises processing platform, rotatory elevating platform and lift ultrasonic, the surface machining shaping of processing platform has two sets of mesas and is mesa one 1 respectively, mesa two 2, be provided with controller 3 between mesa one 1 and the mesa two 2, rotatory elevating platform is installed on mesa one 1 and along seting up annular dirt mouth 4 that leads, the below pull formula of annular dirt mouth 4 is provided with stores up dirty box 5, rotatory elevating platform is bilayer structure and from the bottom up is base 6 and apical ring 7 respectively, the inside of base 6 is provided with driving motor 8, driving motor 8's power take off end installs rolling disc 9, the periphery of rolling disc 9 is connected with apical ring 7 through the metal pole, the top of apical ring 7 is provided with lift ring 11, lift ultrasonic is by pneumatic cylinder 12, push rod 13, backup pad 14, The ultrasonic probe device comprises an upright rod 15, a manipulator 16 and an ultrasonic probe device, wherein a hydraulic cylinder 12 is installed on the table top II 2, a power output end of the hydraulic cylinder is connected with a push rod 13, the top of the push rod 13 is connected with a horizontally arranged supporting plate 14, the upright rod 15 is vertically installed at the outer end of the supporting plate 14, the manipulator 16 is installed at the tail end of the upright rod 15, the tail end of the manipulator 16 is clamped with the ultrasonic probe device, the ultrasonic probe device comprises an ultrasonic probe body 17 and an ultrasonic head 18 installed at the tail end of the ultrasonic probe body 17, and the ultrasonic head 18 is located in a rotary lifting platform.
Further improved, as shown in fig. 2: the lifting ring 11 comprises a main ring 19 and a cylindrical outer curtain 20 fixed below the main ring 19, four groups of electric rods 21 are uniformly installed on the periphery of the top ring 7, power output ends of the four groups of electric rods 21 are connected with the main ring 19, and the top ring 7 is driven by the electric rods 21 to move upwards, so that the purpose of unfolding the cylindrical outer curtain 20 is achieved.
Further improved, as shown in fig. 2: the cylindrical outer curtain 20 is of a cylindrical structure and made of rubber materials, and the surface of the cylindrical outer curtain 20 is of a corrugated structure, so that the influence of the outside on the ultrasonic probe can be reduced.
In a further improvement, as shown in fig. 3: the inside of ultrasonic probe body 17 has vertically seted up and has worn mouthful 22, it has screw rod 23 to wear to insert in the mouth 22, upper end one side of screw rod 23 is provided with servo motor 24, belt 25 is installed to servo motor 24's power take off end, belt 25 cover inlays on screw rod 23, the lower extreme of screw rod 23 is connected with ultrasonic head 18, it rotates to drive belt 25 through servo motor 24, belt 25 drives screw rod 23 synchronous rotation at the pivoted in-process, thereby reach the purpose to the ultrasonic head 18 position control of lower extreme.
In a further improvement, as shown in fig. 3: the ultrasonic head 18 comprises a movable disc 26 embedded at the lower end of the screw 23 and a probe body 27 uniformly installed on the periphery of the movable disc 26, two groups of distance sensors 28 are further arranged on the inner side of the probe body 27, the distance sensors 28 are connected with the controller 3 through circuits, the distance between the probe body 27 and the inner wall of the hole to be punched can be detected through the distance sensors 28, and the punching accuracy is improved.
Further improved, as shown in fig. 4: the movable disc 26 comprises an inner disc 30 and four groups of movable blocks 31, wherein the middle part of the inner disc 30 is provided with a movable groove 29, the four groups of movable blocks 31 are movably arranged on the periphery of the inner disc 30 through hinges, ejector rods 32 are vertically arranged above the four groups of movable blocks 31, the upper ends of the ejector rods 32 are connected with the lower edge of the ultrasonic probe body 17, the ejector rods 32 of the movable disc 26 abut against the movable blocks 31 in the upward moving process, the movable blocks 31 rotate and drive the probe body 27 on the surface to perform position adjustment, and the distance between the probe bodies 27 is adjusted.
Specifically, the four groups of probe bodies 27 are uniformly mounted on the four groups of movable blocks 31, so that the purpose of adjusting the positions of the probe bodies 27 can be achieved by adjusting the movable blocks 31.
When in use: when the engineering ceramic is required to be processed, a worker can open the electric rod 21, the electric rod 21 drives the main ring 19 to ascend, the cylindrical outer curtain 20 is unfolded in the ascending process of the main ring 19, then the hydraulic cylinder 12 drives the push rod 13 to adjust the height, the purpose of adjusting the height of the ultrasonic probe device is achieved, the ultrasonic probe device extends into the main cylindrical outer curtain 20, the ultrasonic head 4 at the end part is moved to the position of the engineering ceramic to be punched and carries out ultrasonic punching treatment, when the inner diameter of the punched hole is required to be adjusted, the worker can open the servo motor 24 through the controller 3, drive the belt 25 to rotate through the servo motor 24, drive the screw rod 23 to synchronously rotate in the rotating process of the belt 25, and therefore, the purpose of adjusting the position of the ultrasonic head 18 at the lower end is achieved, the ultrasonic head 18 is abutted by the ejector rod 32 in the upward moving process, thereby making the interval between the probe bodies 27 become small, making the specification of the punched hole become small, and the scraps generated by punching are discharged into the dirt storage box 5 through the annular dirt guide port 4.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (7)

1. The utility model provides an engineering ceramic multifrequency ultrasonic machining device, includes ultrasonic perforating device, its characterized in that: the ultrasonic punching device comprises a processing table, a rotary lifting table and a lifting ultrasonic device, wherein two groups of table tops are formed on the surface of the processing table and are a first table top (1) and a second table top (2) respectively, a controller (3) is arranged between the first table top (1) and the second table top (2), the rotary lifting table is installed on the first table top (1) and is provided with an annular dirt guide opening (4) from bottom to top, a dirt storage box (5) is arranged below the annular dirt guide opening (4), the rotary lifting table is of a double-layer structure and is respectively a base (6) and a top ring (7) from bottom to top, a driving motor (8) is arranged inside the base (6), a rotating disc (9) is installed at the power output end of the driving motor (8), the periphery of the rotating disc (9) is connected with the top ring (7) through a metal rod, a lifting ring (11) is arranged above the top ring (7), the lift ultrasonic apparatus comprises pneumatic cylinder (12), push rod (13), backup pad (14), pole setting (15), manipulator (16) and ultrasonic probe device, pneumatic cylinder (12) are installed on mesa two (2) and power take off end is connected with push rod (13), the top of push rod (13) is connected with backup pad (14) that the level set up, pole setting (15) are installed perpendicularly in the outer end of backup pad (14), the end in pole setting (15) is installed in manipulator (16), the ultrasonic probe device is got to the terminal clamp of manipulator (16), the ultrasonic probe device includes ultrasonic probe body (17) and installs in terminal ultrasonic head (18) of ultrasonic probe body (17), ultrasonic head (18) are located rotatory elevating platform.
2. The engineering ceramic complex frequency ultrasonic processing device according to claim 1, characterized in that: the lifting ring (11) comprises a main ring (19) and a cylindrical outer curtain (20) fixed below the main ring (19), four groups of electric rods (21) are uniformly installed on the periphery of the top ring (7), and power output ends of the electric rods (21) are connected with the main ring (19).
3. The engineering ceramic complex frequency ultrasonic processing device according to claim 2, characterized in that: the outer curtain (20) of tube-shape is the tubular structure and adopts rubber materials, the surface of the outer curtain (20) of tube-shape is flute column structure.
4. The engineering ceramic complex frequency ultrasonic processing device according to claim 1, characterized in that: the ultrasonic probe is characterized in that a penetrating opening (22) is longitudinally formed in the ultrasonic probe body (17), a screw rod (23) is inserted into the penetrating opening (22), a servo motor (24) is arranged on one side of the upper end of the screw rod (23), a belt (25) is installed at the power output end of the servo motor (24), the belt (25) is embedded on the screw rod (23) in a sleeved mode, and the lower end of the screw rod (23) is connected with an ultrasonic head (18).
5. The engineering ceramic complex frequency ultrasonic processing device according to claim 4, characterized in that: the ultrasonic head (18) comprises a movable disc (26) embedded at the lower end of the screw rod (23) and a probe body (27) uniformly arranged on the periphery of the movable disc (26) in a sleeved mode, two groups of distance sensors (28) are further arranged on the inner side of the probe body (27), and the distance sensors (28) are connected with the controller (3) through circuits.
6. The engineering ceramic complex frequency ultrasonic processing device according to claim 5, characterized in that: the movable disc (26) comprises an inner disc (30) with a movable groove (29) formed in the middle and four groups of movable blocks (31) movably arranged on the periphery of the inner disc (30) through hinges, ejector rods (32) are vertically arranged above the movable blocks (31), and the upper ends of the ejector rods (32) are connected with the lower edge of the ultrasonic probe body (17).
7. The engineering ceramic multi-frequency ultrasonic processing device according to claim 6, wherein: the four groups of probe bodies (17) are uniformly arranged on the four groups of movable blocks (31).
CN202110814572.3A 2021-07-19 2021-07-19 Engineering ceramic complex frequency ultrasonic processing device Pending CN113427644A (en)

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CN202110814572.3A CN113427644A (en) 2021-07-19 2021-07-19 Engineering ceramic complex frequency ultrasonic processing device

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115159587A (en) * 2022-07-21 2022-10-11 江苏先丰纳米材料科技有限公司 Preparation method of molybdenum trioxide nanosheet loaded ferroferric oxide magnetic nanoparticle

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CN204221530U (en) * 2014-11-13 2015-03-25 广东海洋大学 Pearl, pearl core ultrasonic drilling and patterning apparatus
CN104943002A (en) * 2015-07-08 2015-09-30 常州市金海基机械制造有限公司 Ultrasonic drilling machine
CN106313340A (en) * 2016-11-24 2017-01-11 太原理工大学 Engineering-ceramic complex-frequency ultrasonic processing device
CN107511938A (en) * 2017-09-25 2017-12-26 华侨大学 Precision ultrasonic puncher and its tool heads angle adjusting method
CN210968100U (en) * 2019-10-31 2020-07-10 东莞信柏结构陶瓷股份有限公司 Micropore machining device
CN112248705A (en) * 2020-10-10 2021-01-22 四会市金东泰机械设备有限公司 Jade ultrasonic engraving machine
CN212443209U (en) * 2020-04-01 2021-02-02 东莞市恒生超声波设备有限公司 Turntable ultrasonic machine

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202964920U (en) * 2012-12-13 2013-06-05 上海坤腾光电科技有限公司 Adjustable ultrasonic wave horn opening expanding device
CN204221530U (en) * 2014-11-13 2015-03-25 广东海洋大学 Pearl, pearl core ultrasonic drilling and patterning apparatus
CN104943002A (en) * 2015-07-08 2015-09-30 常州市金海基机械制造有限公司 Ultrasonic drilling machine
CN106313340A (en) * 2016-11-24 2017-01-11 太原理工大学 Engineering-ceramic complex-frequency ultrasonic processing device
CN107511938A (en) * 2017-09-25 2017-12-26 华侨大学 Precision ultrasonic puncher and its tool heads angle adjusting method
CN210968100U (en) * 2019-10-31 2020-07-10 东莞信柏结构陶瓷股份有限公司 Micropore machining device
CN212443209U (en) * 2020-04-01 2021-02-02 东莞市恒生超声波设备有限公司 Turntable ultrasonic machine
CN112248705A (en) * 2020-10-10 2021-01-22 四会市金东泰机械设备有限公司 Jade ultrasonic engraving machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115159587A (en) * 2022-07-21 2022-10-11 江苏先丰纳米材料科技有限公司 Preparation method of molybdenum trioxide nanosheet loaded ferroferric oxide magnetic nanoparticle

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