CN113398955A - Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation - Google Patents

Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation Download PDF

Info

Publication number
CN113398955A
CN113398955A CN202110602268.2A CN202110602268A CN113398955A CN 113398955 A CN113398955 A CN 113398955A CN 202110602268 A CN202110602268 A CN 202110602268A CN 113398955 A CN113398955 A CN 113398955A
Authority
CN
China
Prior art keywords
bromide
methylimidazole
source
cadmium
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202110602268.2A
Other languages
Chinese (zh)
Other versions
CN113398955B (en
Inventor
夏杰祥
庞致远
王彬
严兴旺
尹盛
李华明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu University
Original Assignee
Jiangsu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu University filed Critical Jiangsu University
Priority to CN202110602268.2A priority Critical patent/CN113398955B/en
Publication of CN113398955A publication Critical patent/CN113398955A/en
Application granted granted Critical
Publication of CN113398955B publication Critical patent/CN113398955B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/308—Dyes; Colorants; Fluorescent agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/36—Organic compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/38—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/10—Photocatalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Catalysts (AREA)

Abstract

The invention belongs to the fields of photocatalysis technology and environmental pollution treatment, and discloses a preparation method of a Sillen-type bimetal oxyhalide for antibiotic degradation. The invention takes brominated 1-hexadecyl-3-methylimidazole as a bromine source and cadmium acetate dihydrate as a cadmium source, the synthesis is carried out in a mixed solution of water and mannitol by a solvothermal method, and the product is cooled, filtered and washed and is air-dried to obtain CdBiO2And (4) Br ultrathin nanosheets. Compared with potassium bromideCdBiO prepared from bromine source2Br, CdBiO prepared by using cadmium nitrate as cadmium source2Br, high catalytic efficiency of degrading organic dye ciprofloxacin by photocatalysis. The photocatalyst adopts a solvent thermal synthesis method, and has the advantages of simple preparation, environmental protection, low cost and easy control.

Description

Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation
Technical Field
The invention belongs to the fields of photocatalysis technology and environmental pollution treatment, and particularly relates to a preparation method of a Sillen-type bimetal oxyhalide for antibiotic degradation.
Background
Antibiotic pollution, i.e. the pollution caused by the discharge of a large amount of antibiotic into the environment in the original state, metabolites, etc. This is mainly due to the difficulty of complete absorption of the administered antibiotic by humans or animals. According to the analysis of the Chinese river antibiotic pollution map, the main mountain rivers from north to south of China are in antibiotic pollution, and the average concentration of antibiotics also reaches 303 ng/L. In addition, the antibiotic pollution condition in the global water environment is also very serious, so that the antibiotic is ubiquitous in the global water environment and gradually develops into a water pollution problem to be responded to by all mankind. Therefore, the search for a simple and efficient method for removing antibiotics from water has yet to be further discussed and studied.
The photocatalysis technology is a new technology for degrading environmental pollutants, can effectively utilize inexhaustible solar energy resources, generates holes and free radicals with high reaction activity, and makes the degradation of the environmental pollutants possible. The photocatalysis technology has the advantages of simple operation, mild conditions, high reaction speed and the like, provides an effective way for degrading antibiotic pollution in water environment, and has wide research space and application prospect.
The layered structure material has great application potential in the fields of catalysis, energy storage and conversion, electronics and the like, and the layered bismuth-based semiconductor photocatalytic material has attracted people's extensive interest by its unique layered structure, strong photooxidation capability, excellent photocatalytic performance and the like. Comprising Bi of Aurivillius type2MO6(M ═ W, Mo, Cr), Silen-type BiOX (X ═ Cl, Br, I), mixed cation Silen-type PbBiO2X (X ═ Cl, Br), Bi of pyrochlore structure2MNbO7(M ═ Al, Ga, In, Fe), Bi associated with the newly developed Sillen structure2O2(OH)(NO3) And Bi2O2[BO2(OH)]. At present, the modification of the laminated bismuth-based semiconductor photocatalytic material mainly focuses on the aspects of microstructure and morphology control, special crystal face synthesis, heterogeneous/homogeneous junction structure and the like, and the research on the crystal structure design for improving the photocatalytic performance of the laminated bismuth-based semiconductor is less. In particular, the relationship between crystal structure and photoactivity is not well understood at present. In view of the structural diversity, a mixed cation Sillen-type quaternary bismuth-based material BiMO2X (M ═ Cd, Pb, Ca, Ba, Sr, and X ═ Cl, Br, I) may be a good exploratory system.
On the basis of a typical Silen structure BiOBr, a visible light response Silen type mixed cation layered catalyst CdBiO is developed2Br, and for the first time proposes a new strategy for the design of a layered structure to promote charge separation and oxygen activation reactions. Is different from [ Bi ]2O2]2+Layers and interleaved Br-BiOBr, CdBiO characterised by a double layer tablet2The crystal structure of Br includes [ CdBiO ]2]+Layers and interleaved individual Br-The interlayer spacing is narrowed, and the CdBiO is greatly shortened2Photo-generated electrons (e) in Br-) And a cavity (h)+) Thereby allowing advantageous migration of the support from the body to the catalyst surface. Not only the application of visible light active layered materials in environmental chemistry/biochemistry, but also the great potential of crystal structure manipulation in controlling charge transport behavior and photo (electro) chemical properties are revealed.
CdBiO as a novel layered quaternary oxide semiconductor2Br has attracted great attention because of its low cost, corrosion resistance, excellent photocatalytic performance, high chemical and optical stability, and other features. However, CdBiO is currently available for the ultrathin nanosheets concerned2The literature on the preparation method of Br and the regulation strategy of the crystal structure is less reported. Therefore, a simple and efficient ultrathin nano-sheet CdBiO is explored2Br is significant in improving the efficiency of photocatalytic degradation of organic pollutants.
Disclosure of Invention
Objects of the inventionAims to provide a method for preparing Sillen-type bimetal oxyhalides for antibiotic degradation. The photocatalyst CdBiO2The specific surface area and oxygen vacancies of the Br nano-sheet are increased by doping, and the oxygen defect concentration is improved, so that the efficiency of degrading organic pollutants in a water body by visible light catalysis is improved. The catalyst is synthesized by a solvothermal method, the reaction condition is mild, and the operation is simple.
The technical scheme of the invention is as follows:
a method for preparing a sillen-type bimetallic oxyhalide for antibiotic degradation, comprising the steps of:
(1) bismuth nitrate pentahydrate, bismuth acetate or bismuth ammonium citrate are used as bismuth sources; cadmium acetate dihydrate or cadmium nitrate is used as a cadmium source, and then mannitol and deionized water are added to prepare a solution A;
(2) taking brominated ionic liquid or inorganic bromine salt as a bromine source, and then adding mannitol and deionized water to prepare a solution B;
(3) dropwise adding the solution B obtained in the step (2) into the solution A obtained in the step (1), quickly stirring, adjusting the pH to 8-12 by using ammonia water after dropwise adding, continuously stirring for 20-60 minutes, pouring the solution into a high-pressure reaction kettle with a polytetrafluoroethylene lining, reacting for 12-24 hours at the temperature of 150-2Br ultrathin nanoplatelet photocatalyst.
In the step (1), mixing a bismuth source in the solution A: a cadmium source: mannitol: the dosage ratio of the deionized water is as follows: 0.5mmol, 1.8mmol, 18 mL.
In the step (2), mixing the brominated ionic liquid or inorganic bromine salt in the solution B: mannitol: the dosage ratio of the deionized water is as follows: 0.5mmol, 1.8mmol, 18 mL. In the step (2), the brominated ionic liquid is 1-hexadecyl-3-methylimidazole bromide, 1-dodecyl-3-methylimidazole bromide, 1-tetradecyl-3-methylimidazole bromide, 1-hexyl-2, 3-methylimidazole bromide, 1-hexyl-3-methylimidazole bromide, 1-allyl-3-butylimidazole bromide, 1-allyl-3-ethylimidazole bromide, 1-allyl-3-methylimidazole bromide, 1-decyl-3-methylimidazole bromide, 1-carboxyethyl-3-methylimidazole bromide, 1-carboxymethyl-3-methylimidazole bromide, 1-aminopropyl-3-methylimidazole bromide, or mixtures thereof, Brominating 1-aminoethyl-3-methylimidazole or brominating 1-benzyl-3-methylimidazole; the inorganic bromine salt is potassium bromide or sodium bromide.
The ratio of the amount of the brominated ionic liquid in the step (2) to the amount of the bismuth source substance in the step (1) is 1: 1.
In the step (3), a bismuth source: a cadmium source: the mass ratio of the bromine source is 1:1: 1; the drying temperature is 50-80 ℃, and the reaction time is 12-24 hours.
The invention relates to a CdBiO2The Br ultrathin nanosheet photocatalyst is used for photocatalytic degradation of organic dye ciprofloxacin.
The invention has the beneficial effects that:
the invention prepares CdBiO controllably by mild solvothermal method for the first time2And (4) Br ultrathin nanosheets.
Compared with BiOBr ultrathin nanosheets, cadmium-doped CdBiO2The Br ultrathin nanosheet exhibits excellent visible light photocatalytic ciprofloxacin degradation activity.
Drawings
FIG. 1 shows CdBiO2XRD pattern of Br nanoplates;
FIG. 2 shows CdBiO2TEM images of Br nanoplates;
FIG. 3 shows CdBiO under visible light irradiation2Degradation curve of Br on ciprofloxacin.
Detailed Description
The invention will be further described with reference to the following figures and specific examples, but the scope of the invention is not limited thereto.
Example 1:
CdBiO is prepared by using brominated 1-hexadecyl-3-methylimidazole as a bromine source and cadmium acetate dihydrate as a cadmium source2Br nanosheet step:
0.5mmol of bismuth nitrate pentahydrate and 0.5mmol of cadmium acetate dihydrate are taken, 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution A, 0.5mmol of 1-hexadecyl-3-methylimidazole bromide is taken, and 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution B. Dropwise adding the solution B into the solution A, quickly stirring, adjusting the pH to 8 by using ammonia water after dropwise adding, continuously stirring for 20-60 minutes, pouring the solution into a high-pressure reaction kettle with a polytetrafluoroethylene lining, reacting for 24 hours at 150 ℃, centrifuging the obtained product, respectively washing with deionized water and absolute ethyl alcohol for three times, and finally drying at 50-80 ℃.
Example 2:
CdBiO is prepared by using brominated 1-hexadecyl-3-methylimidazole as a bromine source and cadmium nitrate as a cadmium source2Br nanosheet step:
0.5mmol of bismuth nitrate pentahydrate and 0.5mmol of cadmium nitrate are taken, 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution A, 0.5mmol of 1-hexadecyl-3-methylimidazole bromide is taken, and 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution B. Dropwise adding the solution B into the solution A, quickly stirring, adjusting the pH to 10 by using ammonia water after dropwise adding, continuously stirring for 20-60 minutes, pouring the solution into a high-pressure reaction kettle with a polytetrafluoroethylene lining, reacting for 20 hours at 180 ℃, centrifuging the obtained product, respectively washing with deionized water and absolute ethyl alcohol for three times, and finally drying at 50-80 ℃.
Example 3:
CdBiO is prepared by using potassium bromide as bromine source and cadmium acetate dihydrate as cadmium source2Br nanosheet step:
0.5mmol of bismuth nitrate pentahydrate and 0.5mmol of cadmium acetate dihydrate are taken, 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution A, and 0.5mmol of potassium bromide is taken, 1.8mmol of mannitol and 18mL of deionized water are added to prepare a solution B. Dropwise adding the solution B into the solution A, quickly stirring, adjusting the pH to 12 by using ammonia water after dropwise adding, continuously stirring for 20-60 minutes, pouring the solution into a high-pressure reaction kettle with a polytetrafluoroethylene lining, reacting for 12 hours at 200 ℃, centrifuging the obtained product, respectively washing with deionized water and absolute ethyl alcohol for three times, and finally drying at 50-80 ℃.
FIG. 1 shows CdBiO prepared in examples 1 to 3 of the present invention2XRD pattern of Br. It can be seen that the catalyst prepared is pure CdBiO2A Br material.
FIG. 2 is CdBiO2TEM image of Br ultrathin nanosheets.
FIG. 3 is prepared byPrepared CdBiO2And degrading the ciprofloxacin activity diagram of the Br ultrathin nanosheet under the irradiation of visible light. After 210 minutes of visible light irradiation, CdBiO2The Br ultrathin nanosheet material can achieve 79.44% degradation of the target pollutant. Undoped BiOBr ultrathin nanoplates achieved only 9.82% degradation of the target contaminant (ciprofloxacin).

Claims (8)

1. A method for preparing Sillen-type bimetal oxyhalide for antibiotic degradation, which is characterized by comprising the following steps:
(1) bismuth nitrate pentahydrate, bismuth acetate or bismuth ammonium citrate are used as bismuth sources; cadmium acetate dihydrate or cadmium nitrate is used as a cadmium source, and then mannitol and deionized water are added to prepare a solution A;
(2) taking brominated ionic liquid or inorganic bromine salt as a bromine source, and then adding mannitol and deionized water to prepare a solution B;
(3) dropwise adding the solution B obtained in the step (2) into the solution A obtained in the step (1), quickly stirring, adjusting the pH to 8-12 by using ammonia water after dropwise adding, continuously stirring for 20-60 minutes, pouring the solution into a high-pressure reaction kettle with a polytetrafluoroethylene lining, reacting for 12-24 hours at the temperature of 150-.
2. The production method according to claim 1, wherein in the step (1), the bismuth source in the solution a is mixed: a cadmium source: mannitol: the dosage ratio of the deionized water is as follows: 0.5mmol, 1.8mmol, 18 mL.
3. The production method according to claim 1, wherein in the step (2), the ionic bromide liquid or inorganic bromide salt in the mixed solution B: mannitol: the dosage ratio of the deionized water is as follows: 0.5mmol, 1.8mmol, 18 mL.
4. The method according to claim 1, wherein in the step (2), the ionic liquid bromide is 1-hexadecyl-3-methylimidazole bromide, 1-dodecyl-3-methylimidazole bromide, 1-tetradecyl-3-methylimidazole bromide, 1-hexyl-2, 3-methylimidazole bromide, 1-hexyl-3-methylimidazole bromide, 1-allyl-3-butylimidazole bromide, 1-allyl-3-ethylimidazole bromide, 1-allyl-3-methylimidazole bromide, 1-decyl-3-methylimidazole bromide, 1-carboxyethyl-3-methylimidazole bromide, 1-carboxymethyl-3-methylimidazole bromide, 1-dodecyl-3-methylimidazole, Brominated 1-aminopropyl-3-methylimidazole, brominated 1-aminoethyl-3-methylimidazole or brominated 1-benzyl-3-methylimidazole; the inorganic bromine salt is potassium bromide or sodium bromide.
5. The preparation method according to claim 1, wherein the ratio of the amount of the ionic liquid bromide in the step (2) to the amount of the bismuth source substance in the step (1) is 1: 1.
6. The production method according to claim 1, wherein in the step (3), the bismuth source: a cadmium source: the mass ratio of the bromine source is 1:1: 1; the drying temperature is 50-80 ℃, and the reaction time is 12-24 hours.
7. A Sillen-type bimetallic oxyhalide for antibiotic degradation, characterized in that it is obtained by the process according to any one of claims 1 to 6.
8. Use of the Sillen-type bimetallic oxyhalide for antibiotic degradation according to claim 7 for the photocatalytic degradation of the organic dye ciprofloxacin.
CN202110602268.2A 2021-05-31 2021-05-31 Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation Active CN113398955B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110602268.2A CN113398955B (en) 2021-05-31 2021-05-31 Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110602268.2A CN113398955B (en) 2021-05-31 2021-05-31 Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation

Publications (2)

Publication Number Publication Date
CN113398955A true CN113398955A (en) 2021-09-17
CN113398955B CN113398955B (en) 2023-02-17

Family

ID=77675422

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110602268.2A Active CN113398955B (en) 2021-05-31 2021-05-31 Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation

Country Status (1)

Country Link
CN (1) CN113398955B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115814837A (en) * 2023-01-06 2023-03-21 太原理工大学 Hollow flower-ball-shaped Z-shaped heterojunction BCN/Bi 2 O 2 [BO 2 (OH)]Photocatalyst and process for producing the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107684918A (en) * 2017-08-11 2018-02-13 江苏大学 A kind of Porous hollow PbBiO2The preparation method and its usage of Cl catalysis materials
CN109794271A (en) * 2019-01-28 2019-05-24 江苏大学 A kind of ultra-thin PbBiO of oxygen-enriched defect2The preparation method and its usage of Br nanometer sheet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107684918A (en) * 2017-08-11 2018-02-13 江苏大学 A kind of Porous hollow PbBiO2The preparation method and its usage of Cl catalysis materials
CN109794271A (en) * 2019-01-28 2019-05-24 江苏大学 A kind of ultra-thin PbBiO of oxygen-enriched defect2The preparation method and its usage of Br nanometer sheet

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HONGWEI HUANG ET AL: "Visible-Light-Responsive Sillén-Structured Mixed-Cationic CdBiO2Br Nanosheets: Layer Structure Design Promoting Charge Separation and Oxygen Activation Reactions", 《J. PHYS. CHEM. C》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115814837A (en) * 2023-01-06 2023-03-21 太原理工大学 Hollow flower-ball-shaped Z-shaped heterojunction BCN/Bi 2 O 2 [BO 2 (OH)]Photocatalyst and process for producing the same
CN115814837B (en) * 2023-01-06 2024-02-20 太原理工大学 Hollow flower-ball-shaped Z-shaped heterojunction BCN/Bi 2 O 2 [BO 2 (OH)]Photocatalyst

Also Published As

Publication number Publication date
CN113398955B (en) 2023-02-17

Similar Documents

Publication Publication Date Title
US20200354235A1 (en) Heterojunction composite material consisting of one-dimensional in2o3 hollow nanotube and two-dimensional znfe2o4 nanosheet, and application thereof in water pollutant removal
Zhang et al. Construction of a novel BON-Br-AgBr heterojunction photocatalysts as a direct Z-scheme system for efficient visible photocatalytic activity
CN102698775A (en) BiOI-graphene visible light catalyst and preparation method thereof
WO2021212923A1 (en) P-n heterojunction composite material supported on surface of nickel foam, preparation method therefor and use thereof
CN108686665B (en) Preparation method of nanorod zinc ferrite in-situ composite lamellar titanium dioxide photocatalytic material
CN102000584A (en) Method for preparing cobalt-doped improved beta-bismuth oxide photocatalyst
CN106925304B (en) Bi24O31Br10/ZnO composite visible light catalyst and preparation method thereof
CN104226339A (en) Visible-light-induced photocatalyst Bi4O5Br2 and preparation method thereof
CN111632615A (en) 2D/2DBiOI/Ti3C2Composite photocatalyst and preparation method and application thereof
CN113351221B (en) Preparation method and application of graphene-based bismuth-based heterostructure catalyst
CN106807411B (en) A kind of preparation method of ferrous acid La doped silver bromide compound photocatalyst
CN105536819A (en) Graphene/antimony sulfide composite photocatalyst preparation method
CN105195131A (en) Preparation method of graphene quantum dot/vanadium-doped mesoporous titanium dioxide composite photocatalyst
CN106552651A (en) A kind of Bi12O17Br2The synthesis of photochemical catalyst and application process
CN107262132A (en) A kind of sulfur doping g C3N4The preparation method of/zinc-cadmium sulfide composite photo-catalyst
CN106111114B (en) A kind of In2O3/Bi2Sn2O7Composite visible light catalyst and preparation method thereof
CN113398955B (en) Preparation method of Sillen-type bimetal oxyhalide for antibiotic degradation
CN109759122A (en) A kind of bismuth oxybromide ternary heterojunction structure photochemical catalyst and its preparation method and application
CN109794271B (en) Ultra-thin PbBiO with oxygen-enriched defect2Preparation method and application of Br nanosheet
CN113856703A (en) Indium zinc sulfide and bismuth molybdate nanosheet composite photocatalyst with nanoflower structure and preparation method and application thereof
CN113976148A (en) Z-shaped C60/Bi/BiOBr composite photocatalyst and preparation method and application thereof
CN111135838B (en) Bi 2 MoO 6 And Co (OH) 2 Composite material for forming heterogeneous structure and preparation method thereof
Qin et al. Oxygen vacancy-rich C/Ti3C2/(001) TiO2 hollow microspheres and the photocatalytic degradation of organic pollutants
CN110180572B (en) N-doped BiVO 4 -OVs/GO nano composite structured photocatalytic material and application thereof
CN111359648A (en) HTiNbO5nanosheet/g-C3N4Multifunctional composite photocatalyst and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant