CN113389044A - Anti-infrared camouflage ribbon with coating - Google Patents
Anti-infrared camouflage ribbon with coating Download PDFInfo
- Publication number
- CN113389044A CN113389044A CN202110717305.4A CN202110717305A CN113389044A CN 113389044 A CN113389044 A CN 113389044A CN 202110717305 A CN202110717305 A CN 202110717305A CN 113389044 A CN113389044 A CN 113389044A
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- CN
- China
- Prior art keywords
- infrared
- camouflage
- coating
- printing
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 claims description 8
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- 229910019142 PO4 Inorganic materials 0.000 description 1
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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- D—TEXTILES; PAPER
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides an anti-infrared camouflage ribbon with a coating, and relates to the technical field of textiles. This prevent camouflage meshbelt for infrared ray includes: the fabric comprises a woven belt layer, a camouflage printing layer arranged on the surface of the woven belt layer, a flame-retardant coating arranged on the camouflage printing layer and a red line preventing coating arranged on the flame-retardant coating; wherein the infrared-proof coating contains zinc-gallium oxynitride/zinc oxide nanoparticles and vanadium dioxide nanoparticles. Through set up fire-retardant layer and prevent infrared ray coating on preventing infrared ray with camouflage ribbon, prevent that the infrared ray effect is showing, and have fire-retardant function concurrently, have good application prospect.
Description
Technical Field
The invention relates to the technical field of textiles, in particular to an anti-infrared camouflage ribbon with a coating.
Background
The camouflage printing woven tape is mainly used for camouflage clothes, backpacks, tents and the like of military troops. To facilitate camouflage and concealment, the camouflage color should resemble the surrounding environment. However, with the exhibition of infrared surveillance technology, camouflage of camouflage colors is disappearing. The general camouflage effect can be detected by detecting with infrared rays. The infrared-proof camouflage printing for anti-infrared reconnaissance is gradually becoming a development trend. At present, the research on infrared ray prevention mainly aims at realizing infrared ray prevention camouflage by using dyes, but the process is complicated by using the dyes alone, and the ideal infrared ray prevention camouflage effect is difficult to realize.
Disclosure of Invention
In order to solve the technical problem, the invention provides an anti-infrared camouflage ribbon with a coating.
The technical problem to be solved by the invention is realized by adopting the following technical scheme.
The invention provides a coated anti-infrared camouflage ribbon, which comprises: the fabric comprises a woven belt layer, a camouflage printing layer arranged on the surface of the woven belt layer, a flame-retardant coating arranged on the camouflage printing layer and a red line preventing coating arranged on the flame-retardant coating; wherein the infrared-proof coating contains zinc-gallium oxynitride/zinc oxide nanoparticles and vanadium dioxide nanoparticles.
Further, in a preferred embodiment of the present invention, the woven belt layer is a nylon woven belt.
Further, in a preferred embodiment of the present invention, the camouflage print layer is formed by performing pretreatment, ground color dyeing, printing, color development and fixation on a woven belt layer, and the camouflage print layer is formed on both the upper surface and the lower surface of the woven belt layer.
Further, in a preferred embodiment of the present invention, the printing step includes: sequentially passing the woven belt dyed with the ground color through a plurality of color scrapers, and printing and dyeing different colors at different positions of the woven belt to form a camouflage printing layer; printing color pastes with different colors are arranged in each color scraper, and the printing color pastes comprise, by mass, 1: 1-1.2 of printing paste and an infrared-proof coloring agent, wherein the infrared-proof coloring agent contains 1.8-2.2% by mass of acidic disperse yellow, 1.4-1.8% by mass of acidic disperse blue, 0.1-0.2% by mass of acidic disperse red, 4-6 g/L of leveling agent, 0.8-1.2 g/L of penetrating agent, 0.3-0.7 g/L of glacial acetic acid, 1-3 g/L of anti-migration agent and coloring material.
Further, in a preferred embodiment of the present invention, the flame retardant coating layer is formed by dipping a flame retardant treatment liquid, and the flame retardant treatment liquid is obtained by the following steps: dispersing 2-6 g/L of N, N-dihydroxyethyl glycine and 15-20 g/L of zinc borate in water, sequentially adding 50-100 g/L of resorcinol bis-diphenyl phosphate, 10-30 g/L of dispersing agent and 100-200 g/L of waterborne polyurethane, and stirring and mixing to obtain the flame-retardant treatment liquid.
Further, in a preferred embodiment of the present invention, the step of impregnating the flame retardant treatment liquid comprises: and (3) placing the product into the flame-retardant treatment liquid, dipping for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the dipping and rolling processes for a plurality of times, and then drying to form the flame-retardant coating.
Further, in a preferred embodiment of the present invention, the infrared-shielding coating layer is formed by dipping an infrared-shielding treatment liquid, and the infrared-shielding treatment liquid is obtained by the following steps: mixing and ball-milling 5-10 parts by weight of zinc-gallium oxynitride/zinc oxide nanoparticles and 1-6 parts by weight of a dispersing agent, adding 1-5 parts by weight of vanadium dioxide nanoparticles and 1-2 parts by weight of the dispersing agent, and continuously grinding to obtain a mixture; and mixing and grinding the mixture, 60-90 parts by weight of water, 50-60 parts by weight of waterborne polyurethane and 0.5-2 parts by weight of defoaming agent to obtain the anti-infrared treatment liquid.
Further, in a preferred embodiment of the present invention, the zinc-gallium oxynitride/zinc oxide nanoparticles are obtained by the following steps: dissolving gallium nitrate nonahydrate and zinc nitrate hexahydrate in water according to the mass ratio of 1: 1-1.1, then quickly pouring into 1-2 mol/L sodium carbonate solution, stirring while pouring, and obtaining mixed solution after pouring; and adjusting the pH value of the mixed solution to 8, magnetically stirring for 4-6 h, separating, washing and drying to obtain a precipitate, grinding the precipitate, introducing ammonia gas at 700-900 ℃, and sintering for 0.5-1 h to obtain the zinc-gallium oxynitride/zinc oxide nanoparticles.
Further, in a preferred embodiment of the present invention, the step of impregnating with the infrared-proof treatment liquid includes: and (3) soaking the product in the anti-infrared treatment liquid for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the soaking and rolling processes for several times, and then drying to form the anti-infrared coating.
Further, in a preferred embodiment of the present invention, before dipping in the infrared-proof treatment liquid, a stabilizing liquid is coated on the product in advance, and then the product is dried; the stabilizing solution contains 5-10 g/L of poly (diallyldimethylammonium chloride) and 20-30 g/L of sodium chloride.
The camouflage ribbon for preventing infrared rays in the embodiment of the invention has the beneficial effects that:
through set up fire-retardant layer and anti infrared ray coating on anti infrared ray is with camouflage braid, anti infrared ray coating utilizes zinc gallium nitrogen oxide/zinc oxide nanoparticle and vanadium dioxide nanoparticle complex, forms anti infrared ray coating jointly to can make this anti infrared ray coating have thermal variation emissivity performance, realize the infrared ray effect of preventing dynamically. Meanwhile, the camouflage woven belt is provided with the flame-retardant layer, so that the camouflage woven belt has a flame-retardant function and a good application prospect.
Furthermore, the camouflage printing layer adopts printing paste and infrared-proof dye as printing paste, and the camouflage pattern is dyed through the processes of printing, color development, color fixation and the like, so that the effect of forming the camouflage pattern at one time is realized. The anti-infrared dye is used, so that the camouflage printing layer has a good anti-infrared camouflage function.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
Fig. 1 is a schematic structural view of a coated infrared-shielding camouflage tape according to an embodiment of the present invention.
Fig. 2 is a schematic view of the printing process of the coated infrared-shielding camouflage tape according to the present embodiment of the invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
The camouflage tape for infrared ray shielding according to the embodiment of the present invention will be specifically described below.
Referring to fig. 1, the present invention provides a coated anti-infrared camouflage tape, comprising: the textile belt comprises a textile belt layer 10, a camouflage printing layer 20 arranged on the surface of the textile belt layer 10, a flame-retardant coating 30 arranged on the camouflage printing layer 20, and a red line preventing coating 40 arranged on the flame-retardant coating 30. Wherein, the infrared-proof coating 40 contains zinc gallium oxynitride/zinc oxide nanoparticles and vanadium dioxide nanoparticles.
Further, the woven belt layer is a nylon woven belt.
Further, the camouflage printing layer is formed by preprocessing a woven belt, dyeing ground color, printing, color development and fixation, and the camouflage printing layer is formed on the upper surface and the lower surface of the woven belt layer.
Specifically, the pretreatment steps are as follows: adding 3-6 g/L degreasing agent into a dye vat, setting the front pressure of the dye vat to be 3Pa and the rear pressure to be 2Pa, performing degreasing treatment at the speed of 20m/min at the temperature of 100-110 ℃, then enabling the degreased woven belt to enter a plurality of washing water tanks for cleaning, and then drying; wherein, the first and last wash tank adopt normal atmospheric temperature flowing water to wash, and the wash tank in the middle adopts 80 ~ 90 ℃ flowing water to wash. Furthermore, 6 washing water tanks are arranged in the middle, and the temperature is 85 ℃. Specifically, the degreasing agent may be, for example, a commercially available 308 degreasing agent, and the amount of the degreasing agent is preferably 5g/L, and the temperature of the degreasing treatment is preferably 105 ℃.
Specifically, the step of dyeing the ground color is as follows: and adding a base color dye solution into the dye vat, carrying out base color dyeing treatment on the pretreated woven belt, setting the front pressure of the dye vat to be 3Pa, setting the rear pressure to be 2Pa, setting the temperature to be 100-110 ℃, and setting the speed of the woven belt to be 25 m/min. Wherein the base color dye solution contains 1.8-2.2% of acidic disperse yellow, 2.4-2.8% of acidic disperse blue, 0.2-0.4% of acidic disperse red, 1-3 g/L of glacial acetic acid and 4-6 g/L of anti-migration agent. Further preferably, the base color dye solution comprises 2.0 wt% of acid disperse yellow, 2.6 wt% of acid disperse blue, 0.3 wt% of acid disperse red, 2g/L of glacial acetic acid and 5g/L of anti-migration agent, and the balance is water. Wherein, the anti-migration agent is selected from other commercially available products such as polyglycol ether and the like, and is used for preventing the dye from generating the migration phenomenon in the dyeing process.
Specifically, the printing step comprises: and sequentially passing the woven belt dyed with the ground color through a plurality of color scrapers, and printing and dyeing different colors at different positions of the woven belt to form a camouflage printing layer. And printing color pastes with different colors are arranged in each color scraper. The printing color paste comprises the following components in percentage by mass of 1:1 to 1.2 of printing paste and an infrared ray-proof coloring agent. Preferably, the infrared-proof coloring agent contains 1.8-2.2% by mass of acidic disperse yellow, 1.4-1.8% by mass of acidic disperse blue, 0.1-0.2% by mass of acidic disperse red, 4-6 g/L of a leveling agent, 0.8-1.2 g/L of a penetrating agent, 0.3-0.7 g/L of glacial acetic acid, 1-3 g/L of an anti-migration agent and a coloring material. Further preferably, the infrared-proof coloring agent comprises 2.0 wt% of acid disperse yellow, 1.6 wt% of acid disperse blue, 0.2 wt% of acid disperse red, 5g/L of leveling agent, 1.0g/L of penetrating agent, 0.5g/L of glacial acetic acid, 2g/L of migration-proof agent and coloring material, and the balance of water. It can be understood that in different color scrapers, different pigments are selected according to different color requirements, so that printing paste with different colors is obtained. For example, black printing paste is prepared by using black FBRN paint, while light green printing paste is prepared by using Loran green S-GLN paint and NHF-S paint; the brown printing color paste is prepared by selecting yellow-brown S-RL and the like, and the dark green printing color paste is prepared by selecting Gekko Swinhonis, dark blue AMF, Gekko Swinhonis, M-BW and the like; the earthy yellow printing paste is prepared by using, for example, Essolvon NHF-S, red-brown HF-G, disperse black P-G and the like.
Further, the printing paste comprises, by weight, 10-15 parts of etherified guar gum, 3-8 parts of modified starch, 1-3 parts of hydrogenated castor oil and 80-90 parts of water. The modified starch may be, for example, a crosslinked starch. The preparation process of the printing paste comprises the steps of injecting warm water into a container, starting a stirrer, mixing etherified guar gum with 1.2 times of kerosene in batches, adding water for stirring, adding modified starch and hydrogenated castor oil, and stirring for 1-2 hours to obtain the printing paste. In the printing paste, the etherified guar gum can replace common sodium alginate paste, the cost is reduced, better viscosity is provided, hydrogenated castor oil and modified starch are added to be compounded with the etherified guar gum, a cross-linked network structure is formed between paste polymers or at the joint of molecular chain segments through Van der Waals force, the color yield can be effectively improved, and the printing outline is clear. The printing paste has good net penetration and fluidity, and can keep proper viscosity in acid and alkali environments.
Specifically, the color development step comprises: preheating the printed woven belt for 4-7 min at 155-165 ℃ in infrared heating equipment, and then steaming in continuous steaming equipment at 100-110 ℃ for 6-10 min. The color development effect of the woven belt is excellent by a mode of preheating and then continuously steaming.
Specifically, the fixation step comprises: after being cleaned by normal-temperature flowing water, the colored woven tape sequentially enters a de-pasting washing water tank, a cleaning washing water tank, a color fixing washing water tank and a cleaning washing water tank at the temperature of 80-90 ℃ for treatment, then is washed by the normal-temperature flowing water, and finally is dried to form a camouflage printing layer. Wherein, the paste removing agent is added into the paste removing washing tank at a concentration of 4-6 g/L, and the acidic color fixing agent is added into the color fixing washing tank at a concentration of 3-5 g/L. Furthermore, the dosage of the desizing agent is 5g/L, and the dosage of the acidic color fixing agent is 4 g/L. The desizing agent and the acidic color fixing agent are both selected from commercial products. Furthermore, take off paste wash bowl and ancient color wash bowl and all be equipped with 2, be favorable to taking off paste and fixation effect. The temperature of the water tank of the cleaning water tank is 80-90 ℃.
Further, the flame-retardant coating is formed by dipping a flame-retardant treatment liquid, and the flame-retardant treatment liquid is obtained by the following steps: dispersing 2-6 g/L of N, N-dihydroxyethyl glycine and 15-20 g/L of zinc borate in water, sequentially adding 50-100 g/L of resorcinol bis-diphenyl phosphate, 10-30 g/L of dispersing agent and 100-200 g/L of waterborne polyurethane, and stirring and mixing to obtain the flame-retardant treatment liquid. The inorganic zinc borate and the organic resorcinol bis-diphenyl phosphate are compounded, the zinc borate has excellent high-temperature resistance, and can form the functions of high temperature resistance and rapid heat dissipation when being dispersed in the phosphate, so that the flame retardant effect is effectively improved.
Further, the step of impregnating the flame retardant treatment liquid comprises: and (3) placing the woven belt with the camouflage print layer into the flame-retardant treatment liquid, dipping for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the dipping and rolling processes for a plurality of times, and then drying to form the flame-retardant coating 30.
Further, the infrared ray shielding coating 40 is formed by dipping an infrared ray shielding treatment liquid. Specifically, the infrared-proof treatment liquid is obtained by the following steps: mixing and ball-milling 5-10 parts by weight of zinc-gallium oxynitride/zinc oxide nanoparticles and 1-6 parts by weight of a dispersing agent for 2-3 hours, adding 1-5 parts by weight of vanadium dioxide nanoparticles and 1-2 parts by weight of the dispersing agent, and continuously grinding for 2-3 hours to obtain a mixture; and mixing and grinding the mixture with 60-90 parts by weight of water, 50-60 parts by weight of waterborne polyurethane and 0.5-2 parts by weight of defoaming agent for 5-8 hours to obtain the anti-infrared treatment liquid. Specifically, the dispersant is BKY110 in mass ratio, and the defoaming agent is an organic silicon defoaming agent. After a plurality of times of grinding treatment, the effective dispersion of the nano particles is ensured, and the agglomeration is avoided.
Further, the zinc-gallium oxynitride/zinc oxide nanoparticles are obtained according to the following steps: dissolving gallium nitrate nonahydrate and zinc nitrate hexahydrate in water according to the mass ratio of 1: 1-1.1, then quickly pouring the solution into 1-2 mol/L sodium carbonate solution, stirring the solution while pouring, and obtaining mixed solution after the pouring is finished. Adjusting the pH value of the mixed solution to 8 by using a sodium hydroxide solution, magnetically stirring for 4-6 h, then carrying out centrifugal separation, washing and drying to obtain a precipitate, grinding the precipitate, introducing ammonia gas at 700-900 ℃, and sintering for 0.5-1 h to obtain the zinc-gallium oxynitride/zinc oxide nano particles. The zinc-gallium oxynitride and zinc oxide composite structure obtained by the method has lower emissivity in an infrared band with the wavelength of 8-14 mu m. Specifically, in the following examples, the preparation steps of the zinc-gallium oxynitride/zinc oxide nanoparticles are as follows: 0.12mg/L gallium nitrate nonahydrate and 0.13mg/L zinc nitrate hexahydrate are dissolved in water, and then the solution is quickly poured into 1mol/L sodium carbonate solution while stirring, and after the pouring is finished, mixed solution is obtained. And (3) adjusting the pH value of the mixed solution to 8 by using 2mol/L sodium hydroxide solution, magnetically stirring for 5 hours at the oil bath temperature of 85 ℃, and then centrifugally separating, washing and drying to obtain a precipitate. And grinding the precipitate for 2h, putting the precipitate into a tube furnace, introducing ammonia gas at 850 ℃, and sintering for 0.5h to obtain the zinc-gallium oxynitride/zinc oxide nanoparticles.
Further, the step of impregnating with the infrared-proof treatment liquid comprises: and (3) soaking the product in the anti-infrared treatment liquid for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the soaking and rolling processes for several times, and then drying to form the anti-infrared coating.
Further, before the product is soaked in the anti-infrared treatment liquid, a stabilizing liquid is coated on the product in advance, and then the product is dried; the stabilizing solution contains 5-10 g/L of poly (diallyldimethylammonium chloride) and 20-30 g/L of sodium chloride. And coating a stabilizing solution in advance, and utilizing the electrostatic adsorption effect of poly diallyl dimethyl ammonium chloride to ensure that the nano particles in the anti-infrared treatment solution can be stably and uniformly adsorbed.
The features and properties of the present invention are described in further detail below with reference to examples.
Example 1
The coated anti-infrared camouflage ribbon provided by the embodiment is obtained by the following steps:
(1) preparing a camouflage printing layer:
adding 5g/L degreasing agent 308 into the dye vat, setting the front pressure of the dye vat to be 3Pa, the rear pressure of the dye vat to be 2Pa, setting the temperature to be 105 ℃, putting the white nylon woven tape into the dye vat, and performing degreasing treatment at the speed of 20 m/min. Then the deoiled woven belt enters eight washing water tanks for cleaning and then is dried. The first water washing tank is normal temperature flowing water, the second to seventh water washing tanks are 85 ℃ flowing water, and the eighth water washing tank is flowing water.
Setting the front pressure of the dye vat to be 3Pa, the rear pressure to be 2Pa and the temperature to be 105 ℃, placing the woven tape into the dye vat, dyeing at the speed of 25m/min, and drying after the dyeing is finished. Wherein the dye vat contains 2.0 wt% of acid disperse yellow, 2.6 wt% of acid disperse blue, 0.3 wt% of acid disperse red, 2g/L of glacial acetic acid and 5g/L of anti-migration agent.
As shown in fig. 2, the mesh belt 1 after the background color passes through the guide pulley 2, and sequentially enters the first color scraper 3 (black printing color paste), the second color scraper 4 (brown printing color paste), the third color scraper 5 (green printing color paste), the fourth color scraper 6 (yellow-green printing color paste) and the fifth color scraper 7 (yellow-soil printing color paste) which are added with printing color paste, and the mesh belt is colored at the set position of the mesh belt through the screen printing plate on the color scraper, so as to form the multicolor camouflage mesh belt. Then drying in an oven at 90 ℃. Wherein the printing color paste is 50 percent of printing paste and 50 percent of infrared-proof coloring agent. The printing paste comprises 10 parts of etherified guar gum, 4 parts of modified starch, 2 parts of hydrogenated castor oil and 84 parts of water. The infrared-proof coloring agent comprises 2.0 wt% of acid disperse yellow, 1.6 wt% of acid disperse blue, 0.2 wt% of acid disperse red, 5g/L of leveling agent, 1.0g/L of penetrating agent, 0.5g/L of glacial acetic acid, 2g/L of migration-proof agent, coloring material and the balance of water. The pigment of the printing paste in the scraper plates with different colors is configured according to the requirements of different colors.
Preheating the printed woven tape for 5min at 160 ℃ in infrared heating equipment, and then steaming in continuous steaming equipment at 105 ℃ for 5 min.
And (3) sequentially putting the steamed braid into eight washing tanks for treatment, wherein the first washing tank is normal-temperature flowing water, the second washing tank and the third washing tank are 85 ℃, 5g/L of desizing agent is added, the fourth washing tank is 85 ℃ hot water, the fifth washing tank and the sixth washing tank are 85 ℃, 4g/L of color fixing agent is added, the seventh washing tank is 85 ℃ hot water, and the eighth washing tank is normal-temperature flowing water. Then drying, and forming a camouflage printing layer 20 on the upper surface and the lower surface of the nylon woven tape 1.
(2) Preparing a flame-retardant layer:
and (2) placing the woven belt obtained in the step (1) into flame-retardant treatment liquid, soaking for 50min, then rolling, wherein the rolling residual rate is 95%, then continuing to soak in the flame-retardant treatment liquid for 40min, then rolling and drying to form the flame-retardant layer 30. The flame-retardant treatment fluid is obtained by the following steps: dispersing 4g/L N, N-dihydroxyethyl glycine and 16g/L zinc borate in water, sequentially adding 80g/L resorcinol bis-diphenyl phosphate, 150g/L dispersing agent and 150g/L waterborne polyurethane, and stirring and mixing to obtain the flame-retardant treatment liquid.
(3) Preparing an infrared-proof coating:
and (3) placing the woven belt obtained in the step (2) into the infrared-proof treatment liquid for soaking for 50min, then rolling, wherein the rolling residual rate is 95%, then continuing to roll after the infrared-proof treatment liquid is soaked for 40min, and drying to form the infrared-proof coating 40. The anti-infrared treatment liquid is obtained by the following steps: and mixing and ball-milling 80g of zinc-gallium oxynitride/zinc oxide nanoparticles and 40g of dispersing agent for 2h, adding 40g of vanadium dioxide nanoparticles and 20g of dispersing agent, and continuously grinding for 2h to obtain a mixture. Then, the mixture was mixed with 800g of water, 500g of aqueous polyurethane, and 20g of a defoaming agent and ground for 7 hours to obtain an infrared ray-blocking treatment liquid.
Example 2
The present embodiment provides a coated anti-infrared camouflage ribbon, which is different from embodiment 1 in that:
and (3):
and (3) coating a layer of stabilizing liquid on the upper surface and the lower surface of the woven belt obtained in the step (2), drying, soaking in the infrared-proof treatment liquid (same as the example 1) for 50min, rolling with the rolling residual rate of 95%, then continuing to soak in the infrared-proof treatment liquid for 40min, rolling, and drying to form the infrared-proof coating 40. Wherein the stabilizing solution comprises 8g/L of poly (diallyldimethylammonium chloride) and 22g/L of sodium chloride, and the balance of water.
Comparative example 1
The comparison example provides a coated anti-infrared camouflage ribbon, which is different from the embodiment 1 in that:
and (3):
and (3) placing the woven belt obtained in the step (2) into the infrared-proof treatment liquid for soaking for 50min, then rolling, wherein the rolling residual rate is 95%, then continuing to roll after the infrared-proof treatment liquid is soaked for 40min, and drying to form the infrared-proof coating 40. The anti-infrared treatment liquid is obtained by the following steps: 120g of vanadium dioxide nanoparticles and 20g of dispersant were ground for 2h to obtain a mixture. Then, the mixture was mixed with 800g of water, 500g of aqueous polyurethane, and 20g of a defoaming agent and ground for 7 hours to obtain an infrared ray-blocking treatment liquid.
Test example 1
The infrared ray shielding properties of the products obtained in examples 1 to 2 were measured, and the results are shown in Table 1.
TABLE 1
Test example 2
The emissivity of the product in a wave band of 8-14 mu m is measured by an IR-2 dual-wave-band infrared emissivity tester, the test temperature is 30 ℃, and the test result is shown in Table 2.
TABLE 2
| Example 1 | Example 2 | Comparative example 1 | |
| Emissivity (8 to 14 μm) | 0.48 | 0.52 | 0.92 |
As can be seen from tables 1 and 2, the camouflage tape obtained in this example has excellent infrared shielding performance.
The embodiments described above are some, but not all embodiments of the invention. The detailed description of the embodiments of the present invention is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Claims (10)
1. The utility model provides a take anti infrared ray of coating with camouflage meshbelt which characterized in that includes: the fabric comprises a woven belt layer, a camouflage printing layer arranged on the surface of the woven belt layer, a flame-retardant coating arranged on the camouflage printing layer and a red line preventing coating arranged on the flame-retardant coating; wherein the infrared-proof coating contains zinc-gallium oxynitride/zinc oxide nanoparticles and vanadium dioxide nanoparticles.
2. The coated infrared resistant camouflage webbing of claim 1, wherein said webbing layer is a nylon webbing.
3. The coated anti-infrared camouflage tape according to claim 1, wherein said camouflage print layer is formed by pretreating, dyeing a base color, printing, coloring and fixing the tape, and said camouflage print layer is formed on both the upper and lower surfaces of said tape layer.
4. The coated infrared-resistant camouflage webbing of claim 3 wherein said step of priming comprises: printing and dyeing different colors at different positions of the woven tape by sequentially passing the printed woven tape through a plurality of color scrapers to form a camouflage printing layer; printing color pastes with different colors are arranged in each color scraper, and the printing color pastes comprise, by mass, 1: 1-1.2 of printing paste and an infrared-proof coloring agent, wherein the infrared-proof coloring agent contains 1.8-2.2% by mass of acidic disperse yellow, 1.4-1.8% by mass of acidic disperse blue, 0.1-0.2% by mass of acidic disperse red, 4-6 g/L of leveling agent, 0.8-1.2 g/L of penetrating agent, 0.3-0.7 g/L of glacial acetic acid, 1-3 g/L of anti-migration agent and coloring material.
5. The coated infrared-resistant camouflage ribbon as recited in claim 1 wherein said flame retardant coating is formed by impregnation with a flame retardant treatment fluid obtained by the steps of: dispersing 2-6 g/L of N, N-dihydroxyethyl glycine and 15-20 g/L of zinc borate in water, sequentially adding 50-100 g/L of resorcinol bis-diphenyl phosphate, 10-30 g/L of dispersing agent and 100-200 g/L of waterborne polyurethane, and stirring and mixing to obtain the flame-retardant treatment liquid.
6. The coated infrared resistant camouflage tape according to claim 5, wherein said step of impregnating with said fire retardant treatment fluid comprises: and (3) placing the product into the flame-retardant treatment liquid, dipping for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the dipping and rolling processes for a plurality of times, and then drying to form the flame-retardant coating.
7. The coated infrared-resistant camouflage ribbon as recited in claim 1 wherein said infrared-resistant coating is formed by immersion in an infrared-resistant treatment fluid obtained by the steps of: mixing and ball-milling 5-10 parts by weight of zinc-gallium oxynitride/zinc oxide nanoparticles and 1-6 parts by weight of a dispersing agent, adding 1-5 parts by weight of vanadium dioxide nanoparticles and 1-2 parts by weight of the dispersing agent, and continuously grinding to obtain a mixture; and mixing and grinding the mixture, 60-90 parts by weight of water, 50-60 parts by weight of waterborne polyurethane and 0.5-2 parts by weight of defoaming agent to obtain the anti-infrared treatment liquid.
8. The coated infrared-resistant camouflage ribbon of claim 7, wherein said zinc gallium oxynitride/zinc oxide nanoparticles are obtained by: dissolving gallium nitrate nonahydrate and zinc nitrate hexahydrate in water according to the mass ratio of 1: 1-1.1, then quickly pouring into 1-2 mol/L sodium carbonate solution, stirring while pouring, and obtaining mixed solution after pouring; and adjusting the pH value of the mixed solution to 8, magnetically stirring for 4-6 h, separating, washing and drying to obtain a precipitate, grinding the precipitate, introducing ammonia gas at 700-900 ℃, and sintering for 0.5-1 h to obtain the zinc-gallium oxynitride/zinc oxide nanoparticles.
9. The coated infrared resistant camouflage tape according to claim 7 wherein said step of impregnating with said infrared resistant treatment comprises: and (3) soaking the product in the anti-infrared treatment liquid for 40-60 min, rolling, wherein the rolling residual rate is 90-100%, repeating the soaking and rolling processes for several times, and then drying to form the anti-infrared coating.
10. The coated infrared radiation protection camouflage tape according to claim 9, wherein a stabilizing solution is applied to said product in advance before being impregnated into said infrared radiation protection treatment solution and then dried; the stabilizing solution contains 5-10 g/L of poly (diallyldimethylammonium chloride) and 20-30 g/L of sodium chloride.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201473453U (en) * | 2009-06-01 | 2010-05-19 | 曾宇 | Novel one-way glass |
| CN103290703A (en) * | 2013-03-14 | 2013-09-11 | 厦门求特新材料有限公司 | Processing technology for polyester infrared ray-shielding camouflage printed ribbon |
| CN105289694A (en) * | 2015-12-03 | 2016-02-03 | 厦门理工学院 | Method for preparing ZnO/ZnGaNO two-phase composite structure photocatalytic powder |
| CN107141907A (en) * | 2017-06-22 | 2017-09-08 | 中国人民解放军国防科学技术大学 | A kind of visible/infrared compatible adaptive camouflage coating and preparation method thereof |
| US20180267382A1 (en) * | 2017-03-02 | 2018-09-20 | Korea Electronics Technology Institute | Reflective display device for visible light and infrared camouflage and active camouflage device using the same |
| JP2018173164A (en) * | 2017-03-30 | 2018-11-08 | 日東電工株式会社 | Heat barrier heat insulation base plate |
| CN110747666A (en) * | 2019-11-15 | 2020-02-04 | 四川鑫敬业化纤织带有限公司 | Nylon 56 flame-retardant infrared-resistant camouflage ribbon |
-
2021
- 2021-06-28 CN CN202110717305.4A patent/CN113389044B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201473453U (en) * | 2009-06-01 | 2010-05-19 | 曾宇 | Novel one-way glass |
| CN103290703A (en) * | 2013-03-14 | 2013-09-11 | 厦门求特新材料有限公司 | Processing technology for polyester infrared ray-shielding camouflage printed ribbon |
| CN105289694A (en) * | 2015-12-03 | 2016-02-03 | 厦门理工学院 | Method for preparing ZnO/ZnGaNO two-phase composite structure photocatalytic powder |
| US20180267382A1 (en) * | 2017-03-02 | 2018-09-20 | Korea Electronics Technology Institute | Reflective display device for visible light and infrared camouflage and active camouflage device using the same |
| JP2018173164A (en) * | 2017-03-30 | 2018-11-08 | 日東電工株式会社 | Heat barrier heat insulation base plate |
| CN107141907A (en) * | 2017-06-22 | 2017-09-08 | 中国人民解放军国防科学技术大学 | A kind of visible/infrared compatible adaptive camouflage coating and preparation method thereof |
| CN110747666A (en) * | 2019-11-15 | 2020-02-04 | 四川鑫敬业化纤织带有限公司 | Nylon 56 flame-retardant infrared-resistant camouflage ribbon |
Non-Patent Citations (1)
| Title |
|---|
| 曹小丽: "红外隐身材料的制备及红外发射率性能研究", 《中国优秀硕士学位论文全文数据库 (工程科技I辑)》 * |
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