CN113368818A - 一种复合火山岩填料及其制备方法 - Google Patents
一种复合火山岩填料及其制备方法 Download PDFInfo
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- 239000000945 filler Substances 0.000 title claims abstract description 39
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims description 15
- 239000000843 powder Substances 0.000 claims abstract description 21
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010959 steel Substances 0.000 claims abstract description 7
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
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- 230000004048 modification Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
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Abstract
本发明公开了一种复合火山岩填料,包括以下重量份组成的原料:玄武岩10~15份、粘土20~30份、活性炭5~8份、沸石7~12份、硅藻土10~15份、钢料废渣5~8份以及贝壳粉5~8份,本发明涉及填料制备技术领域,本发明通过使用气孔状玄武岩,其上具备较多的微孔,从而有效增大比表面积,且使填料具备一定的吸附性,利于污水中有机污染物的吸附,填料内部添加沸石,可有效吸附污水中的腐殖酸,通过混入钢料废渣以及贝壳等废料使填料具备一定的钙、铁等元素,不仅实现了废物回收利用,同时使填料具备一定的净水功能,活性炭的设置提高了填料的吸附性,给人们的使用带来了方便。
Description
技术领域
本发明涉及填料制备技术领域,具体为一种复合火山岩填料及其制备方法。
背景技术
随着社会的发展与进步,大量工厂的兴建导致工业废水排放变多,水资源的污染与缺失也渐渐引起了世界各国对水资源保护的重视,填料作为污水处理中常见的微生物附着的载体,是污水处理系统中必不可少的一环,现有填料组成成分较为简单,本身不具备足够的除磷、除氨的功能,使用不方便。
发明内容
本发明的目的在于提供一种复合火山岩填料及其制备方法,本发明主要是为了解决现有填料仅可附着微生物,本身不具备较好的净水功能的问题。
实现上述目的本发明的技术方案为,一种复合火山岩填料,包括以下重量份组成的原料:玄武岩10~15份、粘土20~30份、活性炭5~8份、沸石7~12份、硅藻土10~15份、钢料废渣5~8份以及贝壳粉5~8份。
优选的,所述玄武岩采用气孔状玄武岩。
优选的,所述粘土为高岭土。
优选的,所述贝壳粉由贝壳高温煅烧下破碎制成。
一种复合火山岩填料的制备方法,包括以下步骤:
S1、按重量配比取各原料分别进行破碎处理,破碎研磨后过400~600目筛,得到粉末备用;
S2:将步骤S1得到的原料粉末在搅拌釜中加水机械均匀混合,得到混合料;
S3:将步骤S2得到的混合料通入挤压设备中制粒,得到颗粒料;
S4、将步骤S3得到的颗粒料在室温下静置冷却;
S5、将步骤S4冷却完毕的颗粒料送入窑炉中煅烧,冷却后即得颗粒状填料。
优选的,步骤S2中搅拌时间为15~30min。
优选的,步骤S2中,加水后的物料含水量为12~16%。
优选的,步骤S4冷却时间为6~8h。
优选的,步骤S5中煅烧温度为1000~1200℃,煅烧时间为12~18min。
优选的,所述颗粒状填料的直径为8~12mm。
本发明的有益效果是:
本发明通过使用气孔状玄武岩,其上具备较多的微孔,从而有效增大比表面积,且使填料具备一定的吸附性,利于污水中有机污染物的吸附,填料内部添加沸石,可有效吸附污水中的腐殖酸,通过混入钢料废渣以及贝壳等废料使填料具备一定的钙、铁等元素,不仅实现了废物回收利用,同时使填料具备一定的净水功能,活性炭的设置提高了填料的吸附性,给人们的使用带来了方便。
具体实施方式
下面结合实施例对本发明作进一步说明。
实施例1:一种复合火山岩填料,包括以下重量份组成的原料:玄武岩10份、粘土20份、活性炭5份、沸石7份、硅藻土10份、钢料废渣5份以及贝壳粉5份。
玄武岩采用气孔状玄武岩;粘土为高岭土;贝壳粉由贝壳高温煅烧下破碎制成。
一种复合火山岩填料的制备方法,包括以下步骤:
S1、按重量配比取各原料分别进行破碎处理,破碎研磨后过400目筛,得到粉末备用;
S2:将步骤S1得到的原料粉末在搅拌釜中加水机械均匀混合,搅拌时间为15min,得到混合料,加水后的物料含水量为12%;
S3:将步骤S2得到的混合料通入挤压设备中制粒,得到颗粒料;
S4、将步骤S3得到的颗粒料在室温下静置冷却,冷却时间为6h;
S5、将步骤S4冷却完毕的颗粒料送入窑炉中煅烧,煅烧温度为1000℃,煅烧时间为12min,冷却后即得颗粒状填料,颗粒状填料的直径为8mm。
实施例2:一种复合火山岩填料,包括以下重量份组成的原料:玄武岩12份、粘土25份、活性炭6份、沸石10份、硅藻土12份、钢料废渣6份以及贝壳粉6份。
玄武岩采用气孔状玄武岩、粘土为高岭土、贝壳粉由贝壳高温煅烧下破碎制成。
一种复合火山岩填料的制备方法,包括以下步骤:
S1、按重量配比取各原料分别进行破碎处理,破碎研磨后过500目筛,得到粉末备用;
S2:将步骤S1得到的原料粉末在搅拌釜中加水机械均匀混合,搅拌时间为25min,得到混合料,加水后的物料含水量为14%;
S3:将步骤S2得到的混合料通入挤压设备中制粒,得到颗粒料;
S4、将步骤S3得到的颗粒料在室温下静置冷却,冷却时间为7h;
S5、将步骤S4冷却完毕的颗粒料送入窑炉中煅烧,煅烧温度为1100℃,煅烧时间为15min,冷却后即得颗粒状填料,颗粒状填料的直径为10mm。
实施例3:一种复合火山岩填料,包括以下重量份组成的原料:玄武岩15份、粘土30份、活性炭8份、沸石12份、硅藻土15份、钢料废渣8份以及贝壳粉8份。
玄武岩采用气孔状玄武岩、粘土为高岭土、贝壳粉由贝壳高温煅烧下破碎制成。
一种复合火山岩填料的制备方法,包括以下步骤:
S1、按重量配比取各原料分别进行破碎处理,破碎研磨后过600目筛,得到粉末备用;
S2:将步骤S1得到的原料粉末在搅拌釜中加水机械均匀混合,搅拌时间为30min,得到混合料,加水后的物料含水量为16%;
S3:将步骤S2得到的混合料通入挤压设备中制粒,得到颗粒料;
S4、将步骤S3得到的颗粒料在室温下静置冷却,冷却时间为8h;
S5、将步骤S4冷却完毕的颗粒料送入窑炉中煅烧,煅烧温度为1200℃,煅烧时间为18min,冷却后即得颗粒状填料,颗粒状填料的直径为12mm。
上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。
Claims (10)
1.一种复合火山岩填料,其特征在于,包括以下重量份组成的原料:玄武岩10~15份、粘土20~30份、活性炭5~8份、沸石7~12份、硅藻土10~15份、钢料废渣5~8份以及贝壳粉5~8份。
2.根据权利要求1所述的一种复合火山岩填料,其特征在于,所述玄武岩采用气孔状玄武岩。
3.根据权利要求1所述的一种复合火山岩填料,其特征在于,所述粘土为高岭土。
4.根据权利要求1所述的一种复合火山岩填料,其特征在于,所述贝壳粉由贝壳高温煅烧下破碎制成。
5.一种复合火山岩填料的制备方法,其特征在于,包括以下步骤:
S1、按重量配比取各原料分别进行破碎处理,破碎研磨后过400~600目筛,得到粉末备用;
S2:将步骤S1得到的原料粉末在搅拌釜中加水机械均匀混合,得到混合料;
S3:将步骤S2得到的混合料通入挤压设备中制粒,得到颗粒料;
S4、将步骤S3得到的颗粒料在室温下静置冷却;
S5、将步骤S4冷却完毕的颗粒料送入窑炉中煅烧,冷却后即得颗粒状填料。
6.根据权利要求5所述的一种复合火山岩填料的制备方法,其特征在于,步骤S2中搅拌时间为15~30min。
7.根据权利要求6所述的一种复合火山岩填料的制备方法,其特征在于,步骤S2中,加水后的物料含水量为12~16%。
8.根据权利要求5所述的一种复合火山岩填料的制备方法,其特征在于,步骤S4冷却时间为6~8h。
9.根据权利要求5所述的一种复合火山岩填料的制备方法,其特征在于,步骤S5中煅烧温度为1000~1200℃,煅烧时间为12~18min。
10.根据权利要求5所述的一种复合火山岩填料的制备方法,其特征在于,所述颗粒状填料的直径为8~12mm。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117700025A (zh) * | 2023-12-26 | 2024-03-15 | 爱土工程环境科技有限公司 | 一种用于含锑污水处理的复合型填料及其制备方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008050214A (ja) * | 2006-08-25 | 2008-03-06 | Denki Kagaku Kogyo Kk | セメント組成物及びそれを用いた補修方法 |
CN101885620A (zh) * | 2009-05-12 | 2010-11-17 | 程丽 | 多级孔道结构的陶瓷材料及其制造方法 |
CN103274755A (zh) * | 2013-06-12 | 2013-09-04 | 许庆华 | 粉煤灰复合型阻燃发泡剂 |
CN104229982A (zh) * | 2014-09-29 | 2014-12-24 | 滁州友林科技发展有限公司 | 无机复合水处理填料及其制备方法 |
CN104828933A (zh) * | 2015-04-30 | 2015-08-12 | 上海寄绿生物环保科技有限公司 | 用于污水处理的复合火山岩填料及其制备方法 |
CN107021561A (zh) * | 2017-04-07 | 2017-08-08 | 上海野马环保设备工程有限公司 | 一种具备物理、化学及生物协同作用的生物除臭填料 |
CN208166653U (zh) * | 2017-11-17 | 2018-11-30 | 北京石油化工学院 | 一种水处理专用球形组合填料装置 |
CN112500189A (zh) * | 2020-12-21 | 2021-03-16 | 苏州中材非金属矿工业设计研究院有限公司 | 一种人工湿地填料及其制备方法和用途 |
-
2021
- 2021-05-25 CN CN202110570367.7A patent/CN113368818A/zh active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008050214A (ja) * | 2006-08-25 | 2008-03-06 | Denki Kagaku Kogyo Kk | セメント組成物及びそれを用いた補修方法 |
CN101885620A (zh) * | 2009-05-12 | 2010-11-17 | 程丽 | 多级孔道结构的陶瓷材料及其制造方法 |
CN103274755A (zh) * | 2013-06-12 | 2013-09-04 | 许庆华 | 粉煤灰复合型阻燃发泡剂 |
CN104229982A (zh) * | 2014-09-29 | 2014-12-24 | 滁州友林科技发展有限公司 | 无机复合水处理填料及其制备方法 |
CN104828933A (zh) * | 2015-04-30 | 2015-08-12 | 上海寄绿生物环保科技有限公司 | 用于污水处理的复合火山岩填料及其制备方法 |
CN107021561A (zh) * | 2017-04-07 | 2017-08-08 | 上海野马环保设备工程有限公司 | 一种具备物理、化学及生物协同作用的生物除臭填料 |
CN208166653U (zh) * | 2017-11-17 | 2018-11-30 | 北京石油化工学院 | 一种水处理专用球形组合填料装置 |
CN112500189A (zh) * | 2020-12-21 | 2021-03-16 | 苏州中材非金属矿工业设计研究院有限公司 | 一种人工湿地填料及其制备方法和用途 |
Non-Patent Citations (6)
Title |
---|
匡颖等: "海绵铁与火山岩填料A/O生物滴滤池脱氮除磷的中试研究", 《水处理技术》 * |
孙越英等: "《河南省西北地区铝土矿床资源特征及开发利用综合研究》", 31 May 2017, 黄河水利出版社 * |
巫小云等: "钢渣沸石强化冬季人工湿地处理生活污水的应用研究", 《四川环境》 * |
郑永林等: "《粉体表面改性(第四版)》", 30 June 2019, 中国建材工业出版社 * |
郝晓地等: "火山岩填料曝气生物滤池内循环强化脱氮试验研究", 《环境工程学报》 * |
龚鸣等: "火山岩和沸石填料BAF深度处理印染废水的效能比较", 《绿色科技》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117700025A (zh) * | 2023-12-26 | 2024-03-15 | 爱土工程环境科技有限公司 | 一种用于含锑污水处理的复合型填料及其制备方法 |
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