CN113331199A - 植物保护液及其制备方法 - Google Patents
植物保护液及其制备方法 Download PDFInfo
- Publication number
- CN113331199A CN113331199A CN202110570301.8A CN202110570301A CN113331199A CN 113331199 A CN113331199 A CN 113331199A CN 202110570301 A CN202110570301 A CN 202110570301A CN 113331199 A CN113331199 A CN 113331199A
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- CN
- China
- Prior art keywords
- parts
- solution
- plant protection
- pyraclostrobin
- azadirachtin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
Abstract
本发明公开了一种植物保护液及其制备方法，包括以下重量份的原料：0.5‑15份印楝素、1‑18份甲壳胺、1‑20份吡唑醚菌酯、1‑18份磷酸二氢钾、0.5‑18份甲氨基阿维菌素苯甲酸盐、3‑30份甲基吡咯烷酮、0.1‑3份白糖、8.61‑101.5份助剂和10‑60份水。本申请对农作物上最难防治的害虫蓟马的杀灭效果在98％以上，该产品不仅能防治刺吸式口器的害虫还能防治咀嚼式口器的害虫。防治病毒蔬菜、果木上发生的叶斑病，灰霉病的防治效果达99％，凡是真菌和细菌引起的病毒都能防治。
Description
技术领域
本发明涉及植物杀虫剂和防治病害的药剂领域，尤其涉及一种植物保护液及其制备方法。
背景技术
当前，诸多防治病害的农药不能和防治虫害的农药混合施用，因为防治病害的农药多含碱性，防治虫害的农药酸含量较高PH值差异大的农药混用会失去杀菌灭虫的效果，有时还会造成药害，给农民造成无可挽回的损失；还有的农药杀虫治病的效果不理想，农民就加重施药量，增加施药的次数，甚至3—5天施一次哟，这样既增加了农民的耕作成本，又严重污染了自然环境；还降低了农产品的产品质量。有毒的施药环境，使得空气、水域的重金属严重超标，高农残的农作物产品使得消费者望而生畏。严重影响了人们的健康安全，这就阻碍了农村振兴和国民经济的发展。
申请号为201110226530.4的专利公开了一种生物活素与植物素复方茶叶除菌杀虫剂，用于茶叶的除菌和杀虫作用。本发明具有以下优点：(1)茶叶的除菌和杀虫一步完成；(2)天然的海洋生物和植物源活性物质，针对性强、低毒、对人、畜无害；(3)化学性质稳定，易降解、无污染、环保的绿色产品；(4)工艺简单、减少农药使用量、成本低。所述生物活素与植物素复方茶叶除菌杀虫剂，具有如下配方(组分及其重量百分比％)：生物活素6.0—8.0；甲壳质4.0—6.0；褐藻酸酌2.0—3.0；印悚素4.0—6.0；除虫菊2.0—3.0；苦参碱3.0—5.0；净化水至100。该专利利用印悚素、除虫菊和苦参碱的互配进行杀虫，同时利用生物活素、甲壳胺对茶叶进行除菌，实现对茶叶的杀菌。该专利中杀虫的主要作用成分为印悚素，杀虫的效果有待提升，同时采用的苦参碱属于低毒杀虫剂，仍然会对环境造成一定的残留和污染。生物活素和甲壳胺的杀菌效果也需进一步加强，才能实现防治病害。
作为现有技术，在混配植物保护液时，通常会加入助剂，使植物保护液混配成乳状。公开号为CN1402998A的专利公开了一种印楝素与吡蚜酮混配农药制剂，其中加入助剂使印楝素与吡蚜酮的混配农药制剂制成混配成乳油，或可湿性粉剂，或油悬浮剂，或微乳剂，或水分散性粉剂，或微胶囊剂，或泡腾片剂。在配制微乳剂时，其助剂包括溶剂、乳化剂、稳定剂、防冻剂。乳化剂为烷基苯磺酸钙盐、烷基苯磺酸镁盐、烷基苯磺酸铝盐、烷基苯磺酸钠盐、烷基苯磺酸钡盐、C8-C20烷基硫酸钠盐、苯乙烯聚氧乙烯醚硫酸铵盐、苄基联苯酚聚氧乙烯醚、苯乙基酚聚氧乙烯(N＝15～30)醚、苯乙基酚聚氧乙烯聚氧丙烯、壬基酚聚氧乙烯醚、烷基酚聚氧乙烯醚甲缩合物、联苯酚聚氧乙烯醚、国产农乳700号、300号中的一种或多种。稳定剂为3-氯-1，2-环氧丙烷、丁基缩水甘油醚、苯基缩水甘油醚、甲苯基缩水甘油醚、聚乙烯基乙二醇二缩水甘油醚、山梨醇钠中的一种或多种。混配时通常还会加入增效剂、渗透剂、香精等助剂，增效剂为增效醚、增效砜、碳酸烷基酯、氯化脂肪、甲醛中的一种或多种。渗透剂为月桂氮卓酮、JFC-2、顺丁烯二酸二仲辛酯磺酸钠中的一种或多种。
发明内容
本发明所要解决的技术问题是，针对现有技术不足，解决防治病害和虫害不能一起防治的问题，提供一种病虫同防同治无毒低农残，无污染的植物保护液及其制备方法。
为解决上述技术问题，本发明所采用的技术方案是：一种植物保护液，包括以下重量份的原料：0.5-15份印楝素、1-18份甲壳胺、1-20份吡唑醚菌酯、1-18份磷酸二氢钾、0.5-18份甲氨基阿维菌素苯甲酸盐、3-30份甲基吡咯烷酮、0.1-3份白糖、8.61-101.5份助剂和10-60份水。
本申请采用印楝素和甲维盐互配，协同增强杀虫的效果。甲壳胺、吡唑醚菌酯和磷酸二氢钾互配，达到防治灰霉病的效果。本申请的杀虫原料和防病原料混合在一起，不会相互影响效果，能同时起到杀虫和抗病的效果。
进一步地，所述助剂包括以下重量份的原料：3-28份乳化剂、2-20份渗透剂、2.5-30份稳定剂、1-20份增效剂、0.01-0.5份香精。
优选地，植物保护液包括以下重量份的原料：0.5-5份印楝素、1-5份甲壳胺、1-8份吡唑醚菌酯、1-8份磷酸二氢钾、0.5-5份甲氨基阿维菌素苯甲酸盐、3-20份甲基吡咯烷酮、0.1-2份白糖、8.61-50份助剂和10-40份水。
进一步优选地，植物保护液包括以下重量份的原料：印楝素3份、甲壳胺3份、吡唑醚菌酯4份、磷酸二氢钾5份、甲氨基阿维菌素苯甲酸盐3份、甲基吡咯烷酮12份、乳化剂15份、渗透剂10份、稳定剂6份、增效剂8份、白糖1份、香精0.2份、蒸馏水29.8份。
进一步地，所述植物保护液的PH值为6.0—7.0。本申请对原料进行筛选，选择的原料为溶于水或者溶剂之后，溶液的PH值位于6.0—7.0之间，使得混配得到的植物保护液的PH值为6.0—7.0，混配过程中，杀虫和防病的原料之间不会因为原料的酸碱性发生反应，可以同时实现杀虫和防病。
本发明还公开了一种植物保护液的制备方法，包括以下步骤：
分别将甲壳胺、印楝素和白糖溶于水，分别得到甲壳胺水溶液、印楝素溶液、白糖溶液；
加水使吡唑醚菌酯与磷酸二氢钾相互溶解，得到吡唑醚菌酯磷酸二氢钾溶液；
将甲氨基阿维菌素苯甲酸盐溶于甲基吡咯烷酮中，得到甲基吡咯烷酮溶解甲维盐溶液；
分别将甲壳胺水溶液、印楝素溶液、白糖溶液、吡唑醚菌酯磷酸二氢钾溶液、甲基吡咯烷酮溶解甲维盐溶液和其它原料缓慢加入容器中，并进行搅拌，制得植物保护液。
本申请中吡唑醚菌酯与磷酸二氢钾需先相互溶解，得到吡唑醚菌酯磷酸二氢钾溶液，不仅能协同增强防病效果，而且可以解决分别单独加入导致的分层、不稳定现象。本申请利用甲基吡咯烷酮溶解甲氨基阿维菌素苯甲酸盐，相比采用丙酮等溶剂，无毒、无味，而且甲基吡咯烷酮可同时作为渗透剂。
其中，甲壳胺水溶液、印楝素溶液、白糖溶液、吡唑醚菌酯磷酸二氢钾溶液、甲基吡咯烷酮溶解甲维盐溶液以及其它助剂的PH值均为6.0—7.0，使得制得的植物保护液的PH值为6.0—7.0。
优选地，按先后顺序将乳化剂、甲壳胺水溶液、吡唑醚菌酯磷酸二氢钾溶液、甲基吡咯烷酮溶解甲维盐溶液、印楝素溶液、增效剂、渗透剂、稳定剂、白糖溶液、香精依次缓慢加入容器中。
优选地，每一种原料加入的间隔时间为5—20分钟，制得稳定的水乳剂型，溶解非常稳定不会分层。
以下对本发明进一步说明：
本发明的植物保护液是采用下列原料混合配料而成的：
1、印楝素
分子式：C35H44016
分子量:720.71
植物源杀虫剂，对昆虫具有强烈的拒食作用。
2、甲壳胺溶于水，增加植物的免疫力，预防真菌和细菌的侵入、繁殖。增强农作物抵抗病毒的能力。
3、吡唑醚菌酯，纯品为白色或浅米色，无味结晶体熔点63.7—65.2度溶解度20℃g/100m通过阻止病菌细胞中细胞色素b和cl间电子传递而抑制线粒体呼吸作用，具有保护治疗农作物叶电的渗透传导作用。吡唑醚菌酯的作用机理是，通过细胞色素合成中阻止电子转移，它能控制子囊菌纲、担子菌纲、半知菌纲、卵菌纲等大多数病菌，对孢子萌发及叶内菌丝体的生长有很强的抑制作用。
4、磷酸二氢钾，化学式：KH2PO4有潮解性，加热至400度是熔化成透明的液体，在空气中稳定，溶于水用作缓冲剂、培养剂。
相对分子量：136.09g/m0l 熔点252.6度
水溶性83.58-100ml 密度2.338g/L
可增加农作物的磷钾元素，提高农作物防治病虫害的能力，提高作物的抗逆性、抗旱、抗热、抗涝、抗冻、抗病害侵染、保果壮果、提高农产品质量。
5、甲氨基阿维菌素苯甲酸盐(以下简称甲维盐)原药为白色或淡黄色结晶粉来，熔点141度—149度溶于丙酮甲醇微溶于水，甲维盐可以增强神经质如氨酸和y一氨基丁酸GABA的作用，使大量氯离子进入神经细胞，使细胞功能丧失，是一种新型高效半合成抗生素杀虫剂，具有高效低毒、低残留无毒等生物农药的特点。
6、甲基吡咯烷酮:完全溶于水的万能溶剂，不易发挥、无腐蚀性、有良好的稳定性、低毒、安全、渗透性强。无色、无味、无臭。既是亲水型溶剂又是高强度渗透剂。
7、白糖：害虫蓟马的引诱剂，可以把躲在花苞里的蓟马引诱出来，全部杀死，多次喷施，可以提高果实的甜度，提高农产品品质。
将原料配制成水乳剂型，配制原料时溶解非常稳定不能分层，配制后各种原料的效果有显著增强和充分的发挥。
与现有技术相比，本发明所具有的有益效果为：1、无毒：经湖南省劳动卫生院毒理检测经口LD50>10000mg/kg经皮LD50>5000mg/kg属化学级无毒产品。2、高效：经过近几年的上百次试验，农作物上最难防治的害虫蓟马的杀灭效果在98％以上，该产品不仅能防治刺吸式口器的害虫还能防治咀嚼式口器的害虫。3、防治病毒蔬菜、果木上发生的叶斑病，灰霉病的防治效果达99％，凡是真菌和细菌引起的病毒都能防治。4、安全环保：本发明采用的是以水为基础的配方水乳剂，既能快速的吸收，又能快速的分解，对环境是友好的。在生产和使用过程中，没有“三废”排出。
具体实施方式
实施例中助剂包括乳化剂、渗透剂、稳定剂、增效剂和香精。其中乳化剂采用木梨醇，渗透剂的型号为JHD，稳定剂的型号为DMF，增效剂的型号为OS-3。
实施例一(未加磷酸二氢钾、甲维盐、甲基吡咯烷酮)
取印楝素3kg、甲壳胺3kg、木梨醇15kg、渗透剂JHD10kg、稳定剂DMF6kg、增效剂OS-3 8kg、吡唑醚菌酯4kg、白糖1kg、香精0.2kg、蒸馏水49.8kg，将上述原料用水充分溶解后，再依次倒入搅拌机搅拌，搅拌3小时后，PH值为6—7，常温后密封包装，经田间药效试验，稀释1000倍喷杀害虫蓟马，死亡率40％，防治灰霉病的效果为60％。
实施例二(未加印楝素、吡唑醚菌酯)
取甲维盐3kg、甲基吡咯烷酮12kg、甲壳胺3kg、木梨醇15kg、磷酸二氢钾5kg、渗透剂JHD10kg、DMF稳定剂6kg、增效剂OS-3 8kg、白糖1kg、香精0.2kg、蒸馏水36.8kg、用1:4的甲基吡咯烷酮充分溶解甲维盐、用蒸馏水溶解甲壳胺。然后依次将原料溶液倒入搅拌机，搅拌3小时后，PH值为6—7，常温后密封包装，经田间药效试验，稀释1000倍喷杀害虫蓟马，死亡率80％，防治灰霉病的效果为50％。
实施例三(未加吡唑醚菌酯、磷酸二氢钾)
取印楝素5kg、甲壳胺3kg、甲维盐3kg、甲基吡咯烷酮8kg、木梨醇15kg、渗透剂JHD10kg、稳定剂DMF 6kg、增效剂OS-3 8kg、白糖1kg、香精0.2kg、蒸馏水44kg、将甲壳胺用水溶解、将甲维盐和甲基吡咯烷酮1:4的比例充分溶解，然后将上述原料依次倒入搅拌机中进行搅拌，搅拌3小时后，PH值为6—7，常温后用灌装机密封包装，经田间药效试验稀释1000倍液喷杀害虫蓟马，杀虫效果为95％，防治灰霉病的效果为30％。
实施例四(未加甲维盐、甲基吡咯烷酮)
取印楝素3kg、甲壳胺3kg、吡唑醚菌酯4kg、磷酸二氢钾5kg、木梨醇15kg、渗透剂JHD10kg、稳定剂DMF 6kg、增效剂OS-3 8kg、白糖1kg、香精0.2kg、蒸馏水46kg，将印楝素，甲壳胺充分溶解、再将吡唑醚菌酯与磷酸二氢钾相互溶解，按上述顺序依次倒入搅拌机中进行搅拌，搅拌3小时后，PH值为6—7，常温后用灌装机密封包装，经田间药效试验稀释1000倍液喷杀害虫蓟马，杀虫效果为30％，防治灰霉病的效果为90％。
实施例五：取印楝素3kg、甲壳胺3kg、吡唑醚菌酯4kg、磷酸二氢钾5kg、乳化剂木梨醇15kg、甲维盐3kg、甲基吡咯烷酮12kg，渗透剂JHD10kg、稳定剂DMF6kg、增效剂OS-3 8kg、白糖1kg、香精0.2kg、蒸馏水39.8kg、用1:4倍的蒸馏水将甲壳胺充分溶解，吡唑醚菌酯与磷酸二氢钾相互溶解，用1:4倍的甲基吡咯烷酮充分溶解甲维盐，按上述顺序依次倒入搅拌机中进行搅拌，每种原料倒入搅拌机的间隔时间为5—20分钟，搅拌3小时后，PH值为6—7，常温后用灌装机密封包装，经田间药效试验稀释1000倍对田间害虫蓟马喷杀，死亡率98％以上，持效时间可达20天之久，防治灰霉病的效果为99％，持效时间可达40天。该药剂在农作物病虫害发生前施用，可长时间保护农作物不受病虫害的侵害，增强农作物防虫抗病的能力，可见实施例五的配方和生产工艺是配制植物保护液最为理想的方案。
任何一种作物病虫的发生，不可能是菌类唱罢虫登场，病和虫是狼与狈的关系，杀虫剂和杀菌剂的混合是天作之合，是现代化农业发展的必然结果。植物保护液完全可以取代现有的高毒、高农残农药，为振兴农村发展农业经济作出重大贡献。
表1实施例一至五各原料的质量表
如表1所述，上述实施例中，实施例五为完整的配方，与实施例五相比，实施例一中未加磷酸二氢钾、甲维盐、甲基吡咯烷酮，防病的成分中未加磷酸二氢钾，防治灰霉病的效果仅能达到60％。杀虫的成分中未加甲维盐，实施例一中仅依靠印楝素进行杀虫，杀害虫蓟马死亡率仅能达到40％。
与实施例五相比，实施例二中未加印楝素、吡唑醚菌酯。防病的成分中未加吡唑醚菌酯，防治灰霉病的效果仅能达到50％。杀虫的成分中未加印楝素，杀害虫蓟马死亡率仅能达到80％。
实施例三中未加吡唑醚菌酯、磷酸二氢钾。防病的成分中未加吡唑醚菌酯、磷酸二氢钾，防治灰霉病的效果仅能达到30％。
实施例四中未加甲维盐、甲基吡咯烷酮。杀虫的成分中未加甲维盐、甲基吡咯烷酮，杀害虫蓟马死亡率仅能达到30％。
实施例五的效果能达到死亡率98％以上，持效时间可达20天之久，防治灰霉病的效果为99％，持效时间可达40天。在实施例五中，印楝素和甲维盐互配，协同增强杀虫的效果，其中甲维盐需用甲基吡咯烷酮溶解后，再与印楝素进行组合。实施例五中添加了白糖，可以把躲在花苞里的蓟马引诱出来，全部杀死。实施例五中，起防病作用的主要成分为甲壳胺、吡唑醚菌酯、磷酸二氢钾，达到防治灰霉病的效果。实施例五中的杀虫成分和抗病成分不会相互影响，能同时起到杀虫和抗病的效果。
Claims (8)
1.一种植物保护液，其特征在于包括以下重量份的原料：0.5-15份印楝素、1-18份甲壳胺、1-20份吡唑醚菌酯、1-18份磷酸二氢钾、0.5-18份甲氨基阿维菌素苯甲酸盐、3-30份甲基吡咯烷酮、0.1-3份白糖、8.61-101.5份助剂和10-60份水。
2.根据权利要求1所述的植物保护液，其特征在于，所述助剂包括以下重量份的原料：3-28份乳化剂、2-20份渗透剂、2.5-30份稳定剂、1-20份增效剂、0.01-0.5份香精。
3.根据权利要求1所述的植物保护液，其特征在于包括以下重量份的原料：0.5-5份印楝素、1-5份甲壳胺、1-8份吡唑醚菌酯、1-8份磷酸二氢钾、0.5-5份甲氨基阿维菌素苯甲酸盐、3-20份甲基吡咯烷酮、0.1-2份白糖、8.61-50份助剂和10-40份水。
4.根据权利要求1所述的植物保护液，其特征在于包括以下重量份的原料：印楝素3份、甲壳胺3份、吡唑醚菌酯4份、磷酸二氢钾5份、甲氨基阿维菌素苯甲酸盐3份、甲基吡咯烷酮12份、乳化剂15份、渗透剂10份、稳定剂6份、增效剂8份、白糖1份、香精0.2份、蒸馏水29.8份。
5.根据权利要求1-4任一项所述的植物保护液，其特征在于，所述植物保护液的PH值为6.0—7.0。
6.一种权利要求1所述的植物保护液的制备方法，其特征在于包括以下步骤：
分别将甲壳胺、印楝素和白糖溶于水，分别得到甲壳胺水溶液、印楝素溶液、白糖溶液；
加水使吡唑醚菌酯与磷酸二氢钾相互溶解，得到吡唑醚菌酯磷酸二氢钾溶液；
将甲氨基阿维菌素苯甲酸盐溶于甲基吡咯烷酮中，得到甲基吡咯烷酮溶解甲维盐溶液；
分别将甲壳胺水溶液、印楝素溶液、白糖溶液、吡唑醚菌酯磷酸二氢钾溶液、甲基吡咯烷酮溶解甲维盐溶液和其它原料缓慢加入容器中，并进行搅拌，制得植物保护液。
7.根据权利要求6所述的植物保护液的制备方法，其特征在于，按先后顺序将乳化剂、甲壳胺水溶液、吡唑醚菌酯磷酸二氢钾溶液、甲基吡咯烷酮溶解甲维盐溶液、印楝素溶液、增效剂、渗透剂、稳定剂、白糖溶液、香精依次缓慢加入容器中。
8.根据权利要求6或7所述的植物保护液的制备方法，其特征在于，每一种原料加入的间隔时间为5—20分钟。
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1726779A (zh) * | 2004-07-28 | 2006-02-01 | 中国科学院生态环境研究中心 | 一种含有甲胺基阿维菌素苯甲酸盐和印楝素的杀虫组合物 |
| CN103271049A (zh) * | 2013-04-27 | 2013-09-04 | 广东中迅农科股份有限公司 | 吡唑醚菌酯和氟啶胺农药组合物 |
| CN107668055A (zh) * | 2017-10-24 | 2018-02-09 | 安徽丰乐农化有限责任公司 | 一种含有阿维菌素、杀螟丹与吡唑醚菌酯的悬浮种衣剂 |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1726779A (zh) * | 2004-07-28 | 2006-02-01 | 中国科学院生态环境研究中心 | 一种含有甲胺基阿维菌素苯甲酸盐和印楝素的杀虫组合物 |
| CN103271049A (zh) * | 2013-04-27 | 2013-09-04 | 广东中迅农科股份有限公司 | 吡唑醚菌酯和氟啶胺农药组合物 |
| CN107668055A (zh) * | 2017-10-24 | 2018-02-09 | 安徽丰乐农化有限责任公司 | 一种含有阿维菌素、杀螟丹与吡唑醚菌酯的悬浮种衣剂 |
Non-Patent Citations (1)
| Title |
|---|
| 李宗全: "《三农问答https://ask.zhifure.com/a/23863.html》", 13 May 2020 * |
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