CN113318358B - Inspection and quarantine respiratory protection device for up-conversion material - Google Patents
Inspection and quarantine respiratory protection device for up-conversion material Download PDFInfo
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- CN113318358B CN113318358B CN202110783346.3A CN202110783346A CN113318358B CN 113318358 B CN113318358 B CN 113318358B CN 202110783346 A CN202110783346 A CN 202110783346A CN 113318358 B CN113318358 B CN 113318358B
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- 239000000463 material Substances 0.000 title claims abstract description 82
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 44
- 230000000241 respiratory effect Effects 0.000 title claims description 29
- 238000007689 inspection Methods 0.000 title claims description 20
- 239000000835 fiber Substances 0.000 claims abstract description 63
- 230000001699 photocatalysis Effects 0.000 claims description 23
- -1 oxide Chemical compound 0.000 claims description 11
- 239000011941 photocatalyst Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000001228 spectrum Methods 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 229910001416 lithium ion Inorganic materials 0.000 claims description 3
- 230000010287 polarization Effects 0.000 claims description 3
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 description 24
- 238000004659 sterilization and disinfection Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
- 241000894006 Bacteria Species 0.000 description 12
- 241000700605 Viruses Species 0.000 description 11
- 239000013307 optical fiber Substances 0.000 description 9
- 238000001914 filtration Methods 0.000 description 8
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 229910052753 mercury Inorganic materials 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 206010011409 Cross infection Diseases 0.000 description 3
- 206010029803 Nosocomial infection Diseases 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- 230000009340 pathogen transmission Effects 0.000 description 3
- 230000029058 respiratory gaseous exchange Effects 0.000 description 3
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 3
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
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- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 208000001528 Coronaviridae Infections Diseases 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 102000053602 DNA Human genes 0.000 description 1
- 108020004414 DNA Proteins 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 206010069767 H1N1 influenza Diseases 0.000 description 1
- 208000002979 Influenza in Birds Diseases 0.000 description 1
- 208000025370 Middle East respiratory syndrome Diseases 0.000 description 1
- 201000003176 Severe Acute Respiratory Syndrome Diseases 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 206010064097 avian influenza Diseases 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940008718 metallic mercury Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 229920002477 rna polymer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 201000010740 swine influenza Diseases 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B9/00—Component parts for respiratory or breathing apparatus
- A62B9/06—Mouthpieces; Nose-clips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/08—Radiation
- A61L2/088—Radiation using a photocatalyst or photosensitiser
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/08—Radiation
- A61L2/10—Ultra-violet radiation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/18—Radiation
- A61L9/20—Ultra-violet radiation
- A61L9/205—Ultra-violet radiation using a photocatalyst or photosensitiser
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/02—Masks
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/08—Component parts for gas-masks or gas-helmets, e.g. windows, straps, speech transmitters, signal-devices
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B23/00—Filters for breathing-protection purposes
- A62B23/02—Filters for breathing-protection purposes for respirators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/14—Filtering means
Abstract
The invention discloses a quarantine and breath protection device for up-conversion materials, which comprises a breath protection device body (101) provided with a light generating device (102) and a luminous filter layer (103). The luminous filter layer (103) comprises filter fibers (201) and/or light conducting fibers (202), the light conducting fibers (202) are coupled to the light generating device (102), up-conversion materials (203) are contained in the filter fibers (201) and/or the light conducting fibers (202), the light generated by the light generating device (102) is guided by the light conducting fibers (202) to enter the luminous filter layer (103), ultraviolet light is generated on the up-conversion materials (203) through light irradiation, and the ultraviolet light irradiates the surfaces of the filter fibers (201) and/or the light conducting fibers (202). By adopting the invention, the filter fibers at each layer of the luminous filter layer can be disinfected and sterilized.
Description
Technical Field
The invention relates to a respiratory protection device, in particular to a quarantine respiratory protection device of an up-conversion material, which is used for exciting the up-conversion material to generate ultraviolet sterilization effect by light energy transmitted by a light transmission material.
Background
Respiratory protection devices, such as masks and breathing masks, are one of the essential items necessary for inspection and quarantine protection personnel, and are protection articles for people to prevent the harm of air pollution to body health. The up-conversion material, namely Anti-Stokes luminescent material, means that the material is excited by light with low energy and emits light with high energy, namely light with long wavelength and low frequency, and the material emits light with short wavelength and high frequency.
The mask sewn by adopting the multi-layer gauze can only filter out larger dust particles in the air, has poor protection effect on bacteria and viruses transmitted by spray and air, and can not meet the requirements of personnel protection when epidemic situations such as SARS, avian influenza, H1N1 influenza A, middle east respiratory syndrome and the like occur.
The mask made of the high-efficiency fiber filter material can play a good role in filtering and protecting tiny particles, bacteria and viruses. People are increasingly required for the mask, and the problem of disinfection of the mask and the air sterilization condition in the mask are more and more concerned when the filtering effect is pursued.
However, the existing mask generally does not have the effect of killing bacteria and viruses, and the filtering effect is poor after long-term use, and the problem of secondary pollution caused by microorganism breeding is easy. Although the mask can be treated by chemical, the treatment can only be carried out in a non-use state, and the mask in use cannot be disinfected in real time. The moist and warm environment of the mask is very suitable for bacteria and viruses to quickly breed and reproduce. There are also cases where the mask is irradiated with ultraviolet rays to sterilize and disinfect the mask rapidly, but the ultraviolet rays only act on the mask surface and cannot act on germs and viruses attached to the surface of the fiber material inside the filter material layer.
One common solution for surface disinfection and treatment of contaminants in public transportation and medical systems is to deposit a photocatalytic coating (PCC), i.e. a coating with photocatalytic oxidation properties on the surface to oxidize contaminants in the air and eliminate microorganisms. At present, a relatively reliable PCC is to use a photocatalytic material to generate an active oxygen coating, wherein the photocatalytic material can generate a catalytic reaction similar to photosynthesis under the irradiation of sunlight or fluorescent lamps, so that oxygen and water molecules in the air are excited to form hydroxyl free radicals and superoxide anion free radicals with extremely high oxidizing capacity. The free radicals with extremely strong oxidizing power can kill bacteria floating in the air and continuously degrade organic pollutants into water, carbon dioxide and the like, thereby achieving the purposes of purifying the environment and keeping the material clean and free from pollution. Titanium dioxide is a widely used photocatalytic material, and when anatase titanium dioxide is irradiated with ultraviolet light of a specific wavelength, its photocatalytic oxidation and antimicrobial function are activated. However, the intensity of ultraviolet light in the room is generally low, and an additional ultraviolet lamp must be installed to function as titanium dioxide, which clearly limits the application of titanium dioxide.
The ultraviolet sterilization technology is to use a specially designed ultraviolet generating device to generate UVC (200-280 nm) irradiation, and when a certain dose of UVC is irradiated to various bacteria, viruses, parasites, algae and other pathogens, the deoxyribonucleic acid or ribonucleic acid structure in cells is destroyed, replication and reproductive capacity are lost, and finally death is caused, so that the purposes of sterilization, disinfection and purification are achieved under the condition that no chemical medicine is used. From an environmental point of view, all ultraviolet lamps emit ultraviolet light by ionization of mercury vapor, energy level transitions. Metallic mercury is a toxic metal that is easily volatilized in air. In the production, sales, use and recycling of ultraviolet lamps, there is a large amount of mercury leakage, which can cause pollution to the surrounding environment. On the other hand, the ultraviolet sterilizing products which are used in the market at present are low-pressure mercury lamps which are unimodal ultraviolet light, the emission wavelength peak value of the ultraviolet sterilizing products is 253.7nm, the sterilizing effect is single, the sterilizing effect on various bacteria is poor, the medium-pressure mercury lamps with good sterilizing effect are high in power and low in photoelectric conversion efficiency, and the total sterilizing effect is also not ideal. The widely-seen alternative light source of the mercury lamp is a UV-LED, and the characteristics of no mercury, energy conservation and portability are receiving more and more attention. The UV-LED works well in a UVA (320-380 nm) wave band, but has a plurality of problems in a UVB (280-320 nm) wave band and a UVC wave band, particularly in the UVC wave band, when the wavelength is smaller than 280nm, the output power is only a few mW, and the service life is short. The Chinese patent with the application number of CN201410584398.8 discloses an LED ultraviolet sterilizing lamp, which adopts ultraviolet light with the wavelength of 250-270 nm emitted by a UVC semiconductor, and limits the application of the LED ultraviolet sterilizing lamp as an ultraviolet sterilizing light source.
In order to reduce the harm to human bodies and the environment, development of a mercury-free ultraviolet light source which has low cost, no pollution and high efficiency and can replace the traditional mercury-containing ultraviolet lamp is needed, and the mercury-free ultraviolet light source has important practical significance and research value in the sterilization and disinfection fields.
Disclosure of Invention
The invention aims to overcome the defects in the prior art, and provides a quarantine and breathing protection device for up-conversion materials, which efficiently solves the problem that the filtering materials of all layers of the breathing protection device are subjected to real-time ultraviolet and photocatalysis disinfection and sterilization.
In order to achieve the above purpose, the technical scheme of the invention is as follows:
the inspection and quarantine respiratory protection device of the up-conversion material comprises a respiratory protection device body, wherein a light generating device and a luminous filter layer are arranged in the respiratory protection device body; the light emitting filter layer comprises light conducting fibers, the light conducting fibers are coupled with the light generating device, the light conducting fibers contain up-conversion materials, the light conducting fibers guide light generated by the light generating device to enter the light emitting filter layer, and the light entering the light emitting filter layer irradiates the up-conversion materials to generate ultraviolet light, so that the ultraviolet light irradiates the surface of the light conducting fibers; the light generating device comprises a light emitting module, wherein the light emitting module comprises a light emitting diode, and the spectrum range of light generated by the light emitting module is 420 nm-490 nm; the light-conductive fiber contains a photocatalyst, and is uniformly coated on the surfaces of the filtering fiber and/or the light-conductive fiber in a granular and/or fibrous and/or film form; the photocatalyst is any combination of one or more of oxide photocatalytic materials, sulfide photocatalytic materials, bismuth oxide photocatalytic materials and nonmetallic photocatalytic materials.
The light conduction fiber is an optical fiber, and the optical fiber is subjected to resident polarization treatment.
The light guide fiber is a side-emitting light guide fiber.
The up-conversion material is any combination of one or more of fluoride, oxide, sulfur-containing compound, oxyfluoride and halide doped rare earth ion compound.
The up-conversion material is NaYF4, and the wavelength range of ultraviolet light emitted by the up-conversion material is 200 nm-280 nm.
The light generating device further comprises a power module, and a control switch, a charging interface and an indicator lamp are arranged on the power module.
The power module further comprises a rechargeable lithium ion battery electrically connected with the control switch, the charging interface and the indicator lamp.
Compared with the prior art, the inspection and quarantine respiratory protection device of the up-conversion material has the following beneficial effects:
light is introduced into the mask filter material layer by using a light conducting material, and in the scheme of the application, the up-conversion material is used as a converter, absorbs visible light for illumination and emits ultraviolet light which can be sterilized and disinfected efficiently and is enough to activate the photocatalysis function of the titanium dioxide. The generated ultraviolet rays can kill the microorganisms such as bacteria and viruses trapped by the whole filtering material layer, and the ultraviolet rays have strong sterilization and disinfection functions and extremely strong sterilization effects on bacteria and viruses transmitted along with air; the overflowed and scattered ultraviolet rays irradiate photocatalytic materials such as titanium dioxide, the photocatalytic oxidation function is activated, and the sterilizing and disinfecting effects can be exerted, so that the sterilizing and disinfecting of the filter material fibers at each layer of the filter material layer are realized, the pathogen transmission and cross infection risks are reduced, secondary pollution is avoided, and the health level of a user is improved. Is especially suitable for inspection and quarantine treatment personnel, medical epidemic prevention personnel and personnel working and living under high-dust and high-pollution environments. The effect can be achieved only by ordinary illumination and no ultraviolet lamp is required to be installed, so that the generation of extra installation cost and operation cost is avoided; and the ultraviolet lamp is not required to be installed, and the worry of harm to people and livestock caused by ultraviolet light is avoided.
Drawings
The invention will be further described with reference to the drawings and examples.
FIG. 1 is a schematic diagram of a quarantine respiratory protection device for up-conversion materials of the present invention;
FIG. 2 is an enlarged view of the effect of the luminescent filter material layer structure of the inspection and quarantine respiratory protection device of the up-conversion material of the present invention;
fig. 3 is a schematic diagram of a light generating device of the inspection and quarantine respiratory protection device of the up-conversion material.
[ reference numerals description ]:
101: a respiratory protection device body; 102: a light generating device; 103: a light emitting filter layer;
201: filtering the fiber; 202: a light conducting fiber; 203: an up-conversion material; 204: a photocatalyst;
301: a power module; 302: a control switch; 303: a charging interface; 304: and a charging indicator lamp.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
For a clearer description and description of embodiments of the invention, reference is made to one or more drawings, but the accompanying details or examples used to describe the drawings are not limiting the scope of any one of the presently described embodiments or preferred modes of carrying out the invention of the application. Unless defined otherwise, all technical or scientific terms used in the specification of the present invention have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Example 1
Fig. 1 is a schematic diagram of a quarantine respiratory protection device of an up-conversion material according to the present invention, and fig. 2 is an enlarged effect diagram of a light emitting filter material layer structure of the quarantine respiratory protection device of the up-conversion material according to the present invention.
As shown in fig. 1 and 2, the inspection and quarantine respiratory protection device of the up-conversion material comprises a respiratory protection device body 101, a light generating device 102 and a light emitting filter layer 103, wherein the light generating device 102 and the light emitting filter layer 103 are arranged on the respiratory protection device body 101. Wherein:
the luminescent filter layer 103 comprises filter fibers 201 and light conducting fibers 202. In another embodiment, the luminescent filter layer 103 may also include only the light conductive fibers 202. The light-transmitting fiber 202 has a function of filtering and adsorbing particles, liquid droplets, and the like in a fluid (e.g., air stream) by a filter material by van der waals force, electrostatic force, and the like.
The light-transmitting fiber 202 is coupled to the light-generating device 102, and when the light generated by the light-generating device 102 is transmitted in the light-transmitting fiber 202, the total reflection condition of the light transmission is destroyed due to bending, breakage, foreign matter, etc., the light continuously leaks from the surface of the light-transmitting fiber 202, and the light is introduced into the light-emitting filter layer 103. The filter fiber 201 and/or the light-conducting fiber 202 contains an up-conversion material 203, the light-conducting fiber 202 guides the light generated by the light generating device 102 to enter the light-emitting filter layer 103, the light entering the light-emitting filter layer 103 irradiates on the up-conversion material 203, the up-conversion material 203 generates ultraviolet rays, and the ultraviolet rays irradiate on the surfaces of the filter fiber 201 and/or the light-conducting fiber 202.
Here, the light-conducting fiber 202 is an optical fiber that is subjected to a resident polarization treatment. Preferably, the light guide fiber is a side-emitting light guide fiber. The optical fiber is convenient to manufacture and low in cost, the optical fiber can realize high-efficiency transmission of light, avoid strong absorption of the light, ensure the intensity of the light reaching the surface of the filter fiber 201 and ensure the disinfection and sterilization effect. The light guide fiber can conveniently achieve a very small diameter, and particles, liquid drops and the like in the fluid are filtered and adsorbed by means of the surface adsorption force. Particles, liquid drops and the like attached to the surface of the optical fiber change the total reflection condition of the surface of the optical fiber, light conducted inside the optical fiber overflows, the particles, the liquid drops and the like are irradiated, and the effect that the light rays are transmitted and conducted along with the distribution of the number of the particles and the liquid drops in the filtered and adsorbed fluid of the optical fiber is achieved.
Here, the up-conversion material 203 may be one of compounds doped with rare earth ions, including fluoride, oxide, sulfur-containing compound, oxyfluoride, halide, and the like; the up-conversion material 203 may be any combination of two, three or more compounds doped with rare earth ions, such as fluoride, oxide, sulfur-containing compound, oxyfluoride, and halide. In practical applications, the up-conversion material 203 is uniformly distributed on the surface of the filter fibers 201 and/or the light conductive fibers 202 in the form of fine particles and/or fibers and/or films. For example, naYF4 is currently the most efficient host material for up-conversion luminescence, such as nano-sized NaYF4: er (Er) 3+ ,Yb 3+ The method comprises the steps of carrying out a first treatment on the surface of the When ytterbium and erbium are doubly doped, er is used as an activator, and Yb is used as a sensitizer. The up-conversion material 203 has an emission spectrum range of 200 nm-280 nm and has strong disinfection and sterilization effects. The NaYF4 up-conversion material can be excited to generate ultraviolet light only under the condition of common illumination light, and a special ultraviolet lamp is not required to be installed, so that the NaYF4 up-conversion material has no additional installation cost and operation cost and has no worry about harm to people and livestock caused by ultraviolet light.
The up-conversion material 203, which is used as a converter, absorbs the irradiated light (i.e. is excited by low energy light) and emits ultraviolet light which can be sterilized and disinfected efficiently. The ultraviolet light generated by the ultraviolet light can kill microorganisms such as bacteria, viruses and the like trapped and attached on the whole luminous filter layer 103, so that the filter fibers 201 on each layer of the luminous filter layer 103 are disinfected and sterilized, the pathogen transmission and cross infection risks are reduced, secondary pollution is avoided, and the health level of a user is protected.
The inspection and quarantine respiratory protection device is particularly suitable for inspection and quarantine treatment personnel, medical epidemic prevention personnel and personnel working and living under high-dust and high-pollution environments. As only ordinary light illumination conditions are needed, the ultraviolet lamp is not needed to be arranged, and the ultraviolet sterilization and disinfection effects can be exerted. Therefore, no extra installation cost and operation cost are generated, and the worry that the ultraviolet light is generated by installing the ultraviolet light lamp and the health of people and livestock is endangered is avoided.
Example two
This embodiment is substantially the same as the first embodiment, and the details are not repeated, except that the filter fibers 201 and the light-conductive fibers 202 further include a photocatalyst 204. The photocatalyst 204 may be titanium dioxide (TiO 2 ) Zinc oxide (ZnO), tungsten trioxide (WO) 3 ) Ferric oxide (Fe) 2 O 3 ) Tin oxide (SnO) 2 ) The photocatalyst material comprises an equal oxide photocatalyst material, a sulfide photocatalyst material such as cadmium sulfide (CdS), and any combination of one, two, three or more of bismuth-based oxide and nonmetal photocatalyst materials.
In this embodiment, the photocatalytic material 204 is uniformly coated on the surface of the filter fibers 201 and/or the light conductive fibers 202 in the form of particles and/or fibers and/or films. The overflowed and scattered ultraviolet light of the light-conducting fiber 202 irradiates the photocatalytic material such as titanium dioxide, activates the photocatalytic oxidation function of the photocatalytic material, generates strong oxidation free radicals, and kills bacteria, viruses and the like in a contact mode.
The photocatalytic oxidation sterilization function is strong, the sterilization effect on bacteria and viruses transmitted along with air is extremely strong, the convenient and efficient prevention and sterilization function is realized, the pathogen transmission and cross infection risks are reduced, the secondary pollution is avoided, and the health level of a user is improved, so that the novel high-dust-content high-pollution sterilization device is particularly suitable for inspection and quarantine inspection workers, medical epidemic prevention workers and workers working and living under high-dust high-pollution environments.
Example III
Fig. 3 is a schematic diagram of a light generating device of the inspection and quarantine respiratory protection device of the up-conversion material.
Referring to fig. 1, 2 and 3, this embodiment is basically the same as the first embodiment, and the details are not repeated, except that the light generating device 102 further includes a light emitting module. The light emitting module is a Light Emitting Diode (LED). The LED has the characteristics of small volume and high conversion efficiency, and can efficiently generate light. The spectrum range of the light generated by the light emitting module is 420 nm-490 nm, the LED has high luminous efficiency in the spectrum range of 420 nm-490 nm, and meanwhile, the light in the spectrum range of 420 nm-490 nm irradiates the up-conversion material 203 to efficiently excite the ultraviolet light with the emission spectrum range of 200 nm-280 nm.
Example IV
The embodiment is basically the same as the first embodiment, and the details are not repeated, except that the light generating device 102 may further include a power module 301. The power module 30 may be provided with a control switch 302, a charging interface 303, and an indicator lamp 304. The sterilization effect can be controlled to be turned on or off, the power module 301 can be charged through the charging interface 303, and the charging state, the electric quantity change and the like can be displayed through the indicator lamp 304. The power module 301 may further include a lithium ion rechargeable battery, which has the advantages of being rechargeable, high in energy density, and suitable for use with wearable devices.
The above description is only of the preferred embodiments of the invention, and the names of the parts may be different, so that the equivalent or simple changes of the structure, features and principles described in the conception of the present invention are included in the protection scope of the present invention. Those skilled in the art may make various modifications or additions to the described embodiments or substitutions in a similar manner without departing from the scope of the invention as defined in the accompanying claims.
Claims (7)
1. A quarantine respiratory protection device for up-conversion materials, comprising a respiratory protection device body (101), characterized in that: a light generating device (102) and a luminous filter layer (103) are arranged in the respiratory protection device body (101); the luminous filter layer (103) comprises a light conduction fiber (202), the light conduction fiber (202) is coupled with the light generation device (102), the light conduction fiber (202) contains an up-conversion material (203), the light generated by the light generation device (102) is guided to enter the luminous filter layer (103) by the light conduction fiber (202), and the light entering the luminous filter layer (103) irradiates the up-conversion material (203) to generate ultraviolet light so that the ultraviolet light irradiates the surface of the light conduction fiber (202); the light generating device (102) comprises a light emitting module, wherein the light emitting module comprises a light emitting diode, and the spectrum range of the light generated by the light emitting module is 420 nm-490 nm; the light conductive fiber (202) contains a photocatalyst (204) and is uniformly coated on the surface of the light conductive fiber (202) in a granular and/or fibrous and/or film form; the photocatalyst (204) is any combination of one or more of oxide photocatalytic materials, sulfide photocatalytic materials, bismuth oxide photocatalytic materials and nonmetallic photocatalytic materials.
2. The inspection and quarantine respiratory protection device for upconverting materials according to claim 1, wherein: the light conducting fiber (202) is a light conducting fiber, and the light conducting fiber is subjected to resident polarization treatment.
3. The inspection and quarantine respiratory protection device for upconverting materials according to claim 2, wherein: the light guide fiber is a side-emitting light guide fiber.
4. The inspection and quarantine respiratory protection device for upconverting materials according to claim 1, wherein: the up-conversion material (203) is any combination of one or more of fluoride, oxide, sulfur-containing compound, oxyfluoride, halide doped with rare earth ions.
5. The inspection and quarantine respiratory protection device for upconverting materials according to claim 4, wherein: the up-conversion material (203) is NaYF 4 The wavelength range of the emitted ultraviolet light is 200 nm-280 nm.
6. The inspection and quarantine respiratory protection device for upconverting materials according to claim 1, wherein: the light generating device (102) further comprises a power supply module (301), and a control switch (302), a charging interface (303) and an indicator lamp (304) are arranged on the power supply module (301).
7. The inspection and quarantine respiratory protection device for upconverting materials according to claim 6, wherein: the power module further includes a rechargeable lithium ion battery electrically connected to the control switch (302), the charging interface (303), and the indicator light (304).
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003210998A (en) * | 2002-01-25 | 2003-07-29 | Japan Science & Technology Corp | Photocatalyst system |
JP2012139478A (en) * | 2011-01-04 | 2012-07-26 | Nisshin Denki:Kk | Safe mask with purple lighting |
CN104927864A (en) * | 2015-07-06 | 2015-09-23 | 河北大学 | Rare earth ions doped fluoride matrix visible-ultraviolet upconversion luminescence material, preparation method therefor and application thereof |
CN208030338U (en) * | 2016-11-09 | 2018-11-02 | 北京出入境检验检疫局 | A kind of inspection and quarantine protection mask |
CN111084446A (en) * | 2020-02-25 | 2020-05-01 | 济南大学 | Fiber conduction ultraviolet sterilization mask |
CN111388698A (en) * | 2020-03-23 | 2020-07-10 | 苏州星烁纳米科技有限公司 | Filter element and protective product |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013095302A1 (en) * | 2011-12-19 | 2013-06-27 | Nanyang Technological University | Synthesis of upconvension nanocomposites for photodynamic therapy |
-
2021
- 2021-07-12 CN CN202110783346.3A patent/CN113318358B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003210998A (en) * | 2002-01-25 | 2003-07-29 | Japan Science & Technology Corp | Photocatalyst system |
JP2012139478A (en) * | 2011-01-04 | 2012-07-26 | Nisshin Denki:Kk | Safe mask with purple lighting |
CN104927864A (en) * | 2015-07-06 | 2015-09-23 | 河北大学 | Rare earth ions doped fluoride matrix visible-ultraviolet upconversion luminescence material, preparation method therefor and application thereof |
CN208030338U (en) * | 2016-11-09 | 2018-11-02 | 北京出入境检验检疫局 | A kind of inspection and quarantine protection mask |
CN111084446A (en) * | 2020-02-25 | 2020-05-01 | 济南大学 | Fiber conduction ultraviolet sterilization mask |
CN111388698A (en) * | 2020-03-23 | 2020-07-10 | 苏州星烁纳米科技有限公司 | Filter element and protective product |
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