CN113308136A - Material for electric power fault early warning and early warning indication method thereof - Google Patents

Material for electric power fault early warning and early warning indication method thereof Download PDF

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Publication number
CN113308136A
CN113308136A CN202110607174.4A CN202110607174A CN113308136A CN 113308136 A CN113308136 A CN 113308136A CN 202110607174 A CN202110607174 A CN 202110607174A CN 113308136 A CN113308136 A CN 113308136A
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China
Prior art keywords
parts
early warning
power failure
transmission line
power
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CN202110607174.4A
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Chinese (zh)
Inventor
杜宇
程展
刘杨
杜思量
秦瑜苒
王凯
李彬
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Xishan Power Supply Co Of State Grid Henan Electric Power Co
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Xishan Power Supply Co Of State Grid Henan Electric Power Co
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Priority to CN202110607174.4A priority Critical patent/CN113308136A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/18Status alarms

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a material for electric power failure early warning, which consists of the following components in parts by weight: 120-320 parts of resin base material, 80-200 parts of discolor, 45-70 parts of filling material, 15-36 parts of dispersing agent, 8-22 parts of defoaming agent, 10-42 parts of antioxidant, 10-60 parts of temperature-sensitive adhesive, 20-35 parts of curing agent, 50-150 parts of diluent and 10-25 parts of film-forming assistant. The power failure early warning material is used for a power system high-voltage overhead transmission line failure early warning method, a layer of power failure early warning material coating is arranged on the surface of a high-voltage overhead transmission line, and color change can occur when the coating meets high temperature to serve as an indication of failure early warning. The power failure early warning material is obvious in color change and reversible in color change, the material can be repeatedly utilized for many times, resources are saved, the failure early warning method is simple and rapid, accurate early warning and positioning can be performed on high-temperature failures, failures are prevented in time, and a large amount of manpower and material resources are saved to a certain extent.

Description

Material for electric power fault early warning and early warning indication method thereof
Technical Field
The invention belongs to the field of fault early warning materials, particularly relates to a power fault early warning material and an early warning indication method thereof, and particularly relates to a power fault early warning material and an indication method thereof for fault early warning of a high-voltage overhead transmission line of a power system.
Background
In recent years, along with the continuous rise of power consumption, the obsolescence and aging speed of power equipment is accelerated, the deterioration of a working environment causes the continuous increase of load, the abnormal rise of the temperature of the equipment occurs sometimes, particularly in summer with the highest environmental temperature and the worst weather conditions, the abnormal rise of the temperature of the power equipment is frequent just in a peak period of the power load, and the abnormal rise of the temperature of the power equipment poses great threat to the safe operation of a power system and a power grid, and particularly, a high-voltage overhead transmission line exposed to the outdoor environment for a long time is easy to break down and generate danger in summer with high temperature and heat.
How to ensure the safe and stable operation of the power system and the high-voltage overhead transmission line becomes a great subject. In reality, the recovery of power supply every night after a fault causes huge social financial loss, and for severe patients in hospitals, the recovery may also mean a life cost. Especially, when a high-voltage overhead transmission line breaks down, the maintenance is difficult and slow, and the loss is increased. Because the high-voltage overhead transmission lines are generally distributed in remote and complex mountain areas and even in many remote unmanned mountain areas with steep and dangerous terrain, in order to ensure normal and safe operation and work of the power system, a large amount of manpower and material resources are consumed to inspect and maintain the lines at ordinary times, but the high-voltage overhead transmission lines with the severe terrain consume time and labor during inspection and maintenance, particularly, inspection personnel are easy to have personal danger and even pay life cost. At present, a common inspection method for a high-voltage overhead transmission line is manual inspection, and the method is time-consuming and labor-consuming, has safety problems and is low in efficiency. Although the scheme of adopting the infrared inspection of unmanned aerial vehicle is proposed at present, but infrared temperature measurement is because the influence of external factors such as measuring distance, dust and aqueous vapor, and its measuring accuracy is not high, has the shortcoming that equipment is expensive, operation requirement is higher simultaneously, so can't satisfy future smart power grids's demand. In order to monitor the high temperature of a high-voltage overhead transmission line and locate a fault position, and quickly realize early warning indication of the fault to prevent the fault, a material capable of early warning the power fault and an early warning method thereof are urgently needed to be researched. At present, many power failure indicating materials in the prior art, but these materials discolour unobviously and irreversible, cause a large amount of wastes of material, if not change indicating material in time after every power failure takes place, will not in time or can't make the instruction to power failure instruction, cause the emergence of electric power accident easily, threaten national and individual's life and property safety. Therefore, it is urgent to research a material for early warning of power failure and an early warning method thereof.
Disclosure of Invention
In order to solve the defects in the prior art, the invention aims to provide a material for early warning of power failure and an early warning indication method thereof. The material has simple components and no toxicity, and can quickly give early warning indication to power failure; the early warning method is simple and quick, and can accurately give early warning indication to the fault position to prevent the fault.
In order to achieve the purpose, the invention adopts the following technical scheme:
the power failure early warning material is composed of the following components in parts by weight: 120-320 parts of resin base material, 80-200 parts of discolor, 45-70 parts of filling material, 15-36 parts of dispersing agent, 8-22 parts of defoaming agent, 10-42 parts of antioxidant, 10-60 parts of temperature-sensitive adhesive, 20-35 parts of curing agent, 50-150 parts of diluent and 10-25 parts of film-forming assistant.
Further, the resin base material is any one or more of polyolefin resin, epoxy resin and hydroxy acrylic resin.
Further, the color change material is cobalt salt; the cobalt salt is CoCl2·6H2O、CoSO4·7H2Either or both of O.
Further, the filling material is a mixture of alumina, titanium dioxide, talcum powder and kaolin.
Further, the antioxidant is any one or more of N, N' -1, 6-hexylene-bis- [3, 5-di-tert-butyl-4-hydroxy hydrocinnamamide ], tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester and tris (2, 4-di-tert-butylphenyl) phosphite.
Further, the defoaming agent is tributyl phosphate or polydimethylsiloxane.
Further, the temperature sensitive adhesive is lauryl acrylate.
Further, the film forming auxiliary agent is one or two of propylene glycol butyl ether and propylene glycol methyl ether acetate.
Further, the power failure early warning material is applied to early warning of the failure of the high-voltage overhead transmission line of the power system.
Further, the power failure early warning material coating is arranged on the surface of the high-voltage overhead transmission line, and color change can occur on the power failure early warning material coating when the power failure early warning material coating meets high temperature to serve as an indication of failure early warning.
Compared with the prior art, the invention has the following beneficial effects:
1. many existing fault indication coating materials are small in adhesion and poor in oxidation resistance, and the coating is easy to fall off and oxidize after being exposed to the external environment for a long time, so that the color of the coating is changed, and the fault early warning indication effect cannot be achieved; the power failure early warning indicating material disclosed by the invention forms strong adhesive force under the interaction of the resin base material and the curing agent, is not easy to fall off in a severe external environment, can keep the color of a color-changing substance basically unchanged for a long time under the action of an antioxidant and in a normal temperature environment, can change the color only when encountering continuous high temperature, and can quickly and accurately give early warning indication to the failure of a high-voltage overhead transmission line.
2. The high-voltage overhead transmission line can bear certain high-temperature operation in a short time, and can only break down when the high-voltage overhead transmission line continuously works at high temperature for a long time, but the fault indication coating in the prior art can immediately or very short-time send out fault indication when meeting high temperature, and a maintainer can overhaul or replace the high-voltage overhead transmission line when finding out the fault indication, so that the waste of materials of the high-voltage overhead transmission line is easily caused; however, the color change of the fault early warning material has reversibility, the color change can occur when the temperature rises, the color can be recovered to the previous color after the temperature falls, the fault early warning material can be recycled, and the material is saved; the fault early warning material has obvious color change and good stability.
3. The early warning indication method can simply and quickly carry out accurate early warning on high-temperature faults, prevent the faults from occurring in time and save a large amount of manpower and material resources to a certain extent.
Detailed Description
The technical solution of the present invention is described in detail by the following specific examples.
The material for early warning of power failure is prepared into the coating by the following method: firstly, weighing the raw materials according to the parts by weight described in the following embodiments; and then placing the resin base material, the filling material, the dispersing agent, the defoaming agent and the curing agent into a dispersing container, stirring uniformly, fully grinding, adding the temperature-sensitive adhesive, the antioxidant and the film-forming aid, stirring uniformly, and finally adding the diluent, stirring fully at a high speed to mix the materials to obtain the required coating.
Example 1
A material for early warning of power failure is prepared from the following components in parts by weightComprises the following components: polyolefin resin 120 parts CoCl2·6H280 parts of O, 45 parts of mixture of aluminum oxide, titanium dioxide, talcum powder and kaolin, 15 parts of dispersant, 10 parts of tributyl phosphate, N' -1, 6-hexylidene-bis- [3, 5-di-tert-butyl-4-hydroxy hydrocinnamamide]15 parts of lauryl acrylate, 20 parts of a curing agent, 60 parts of a diluent and 12 parts of propylene glycol butyl ether. The material for power failure early warning is prepared into paint according to the preparation method for later use.
The prepared coating is sprayed on the surface layer of the high-voltage overhead transmission line in a spraying mode, after the coating is formed and dried, the initial color of the coating is pink, and a discolor CoCl in the coating layer2·6H2With the gradual rise of the temperature, O gradually loses hydrated molecules and becomes CoCl2The color of the coating on the surface of the high-voltage overhead power transmission line can be changed from the initial pink color to the blue color, and when the coating is kept unchanged at high temperature for a long time, the color of the coating on the surface of the high-voltage overhead power transmission line can be kept unchanged for a long time; after the high temperature is reduced, CoCl2Will absorb the water in the air and gradually become CoCl2·6H2O, the color of the surface coating of the high-voltage overhead transmission line can be restored to pink under a normal temperature state from blue under high temperature, so that when an overhaul person monitors the high-voltage overhead transmission line through monitoring equipment, if the surface coating of the high-voltage overhead transmission line is stable to blue for a long time, the section of the high-voltage overhead transmission line works under the high-temperature state for a long time, faults can occur, the overhaul person needs to pay attention to the high-voltage overhead transmission line constantly, overhaul preparation is made in advance, and dangers and faults are prevented.
Example 2
The power failure early warning material is composed of the following components in parts by weight: epoxy resin 200 parts, CoSO4·7H2130 parts of O, 60 parts of a mixture of aluminum oxide, titanium dioxide, talcum powder and kaolin, 22 parts of a dispersing agent, 15 parts of polydimethylsiloxane and tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]30 parts of pentaerythritol ester, 38 parts of lauryl acrylate, 25 parts of curing agent, 98 parts of diluent and 19 parts of propylene glycol monomethyl ether acetate.
The prepared coating is sprayed on the surface layer of the high-voltage overhead transmission line in a spraying mode, after the coating is formed and dried, the initial color of the coating is pink, and a color change substance CoSO in the coating layer4·7H2With the gradual rise of the temperature, the O gradually loses the hydrated molecules and becomes CoSO42The color of the coating on the surface of the high-voltage overhead power transmission line can be changed from initial pink to red, and when the coating is kept unchanged at high temperature for a long time, the color of the coating on the surface of the high-voltage overhead power transmission line can be kept unchanged for a long time; after the high temperature is reduced, CoSO4Will absorb the moisture in the air and gradually become CoSO4·7H2O, the pink that the colour of high tension overhead transmission line surface coating also can resume under the normal atmospheric temperature state by red when high temperature, so the maintainer passes through supervisory equipment when monitoring high tension overhead transmission line, if discover high tension overhead transmission line surface coating stable for a long time always for red, explain this section high tension overhead transmission line is in work under the high temperature state for a long time, probably break down, need the maintainer to pay attention to constantly, make the maintenance preparation in advance, prevent the emergence of danger and trouble.
Example 3
A material for electric power fault early warning is composed of the following components in parts by weight: 320 parts of mixed resin of epoxy resin and hydroxyacrylic resin, CoCl2·6H2200 parts of O, 70 parts of a mixture of alumina, titanium dioxide, talcum powder and kaolin, 36 parts of a dispersing agent, 22 parts of polydimethylsiloxane, 40 parts of tris (2, 4-di-tert-butylphenyl) phosphite, 58 parts of lauryl acrylate, 35 parts of a curing agent, 150 parts of a diluent, and 25 parts of a mixture of propylene glycol butyl ether and propylene glycol methyl ether acetate. The material for power failure early warning is prepared into paint according to the preparation method for later use.
The prepared coating is sprayed on the surface layer of the high-voltage overhead transmission line in a spraying mode, after the coating is formed and dried, the initial color of the coating is pink, and a discolor CoCl in the coating layer2·6H2With the gradual rise of the temperature, O gradually loses hydrated molecules and becomes CoCl2The color will change from the initial pink to blue when highWhen the temperature is kept unchanged for a long time, the color of the surface coating of the high-voltage overhead power transmission line can be kept unchanged for a long time; after the high temperature is reduced, CoCl2Will absorb the water in the air and gradually become CoCl2·6H2O, the color of the surface coating of the high-voltage overhead transmission line can be restored to pink under a normal temperature state from blue under high temperature, so that when an overhaul person monitors the high-voltage overhead transmission line through monitoring equipment, if the surface coating of the high-voltage overhead transmission line is stable to blue for a long time, the section of the high-voltage overhead transmission line works under the high-temperature state for a long time, faults can occur, the overhaul person needs to pay attention to the high-voltage overhead transmission line constantly, overhaul preparation is made in advance, and dangers and faults are prevented.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (10)

1. The material for early warning of the power failure is characterized by comprising the following components in parts by weight: 120-320 parts of resin base material, 80-200 parts of discolor, 45-70 parts of filling material, 15-36 parts of dispersing agent, 8-22 parts of defoaming agent, 10-42 parts of antioxidant, 10-60 parts of temperature-sensitive adhesive, 20-35 parts of curing agent, 50-150 parts of diluent and 10-25 parts of film-forming assistant.
2. The power failure early warning material according to claim 1, wherein the resin base material is any one or more of polyolefin resin, epoxy resin and hydroxy acrylic resin.
3. The power failure warning material of claim 1The material is characterized in that the color-changing substance is cobalt salt; the cobalt salt is CoCl2.6H2O、CoSO4·7H2O, either or both.
4. The power failure warning material of claim 1, wherein the filler material is a mixture of alumina, titanium dioxide, talc and kaolin.
5. The power failure early warning material according to claim 1, wherein the antioxidant is any one or more of N, N' -1, 6-hexylene-bis- [3, 5-di-tert-butyl-4-hydroxy hydrocinnamamide ], tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] pentaerythritol ester and tris (2, 4-di-tert-butylphenyl) phosphite.
6. The power failure warning material of claim 1, wherein the defoaming agent is tributyl phosphate or polydimethylsiloxane.
7. The power failure warning material of claim 1, wherein the temperature sensitive adhesive is lauryl acrylate.
8. The power failure warning material of claim 1, wherein the film forming additive is one or two of propylene glycol butyl ether and propylene glycol methyl ether acetate.
9. Use of the power failure early warning material of any one of claims 1 to 8 in the early warning of failure of a high voltage overhead transmission line of a power system.
10. A power system high-voltage overhead transmission line fault early warning method is characterized in that a power fault early warning material coating layer according to any one of claims 1 to 8 is arranged on the surface of a high-voltage overhead transmission line, and color change can occur on the power fault early warning material coating layer when the power fault early warning material coating layer meets high temperature to serve as fault early warning indication.
CN202110607174.4A 2021-05-30 2021-05-30 Material for electric power fault early warning and early warning indication method thereof Pending CN113308136A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114031966A (en) * 2021-11-24 2022-02-11 国网辽宁省电力有限公司朝阳供电公司 Heating color-changing coating for power transmission line
CN115537115A (en) * 2022-09-20 2022-12-30 国网湖南省电力有限公司 Coating capable of rapidly identifying early thermal runaway fault of lithium ion battery and application of coating
CN116731549A (en) * 2023-08-07 2023-09-12 广东电网有限责任公司湛江供电局 High-voltage transmission line induction electrochromic paint, preparation method and early warning method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724364A (en) * 2019-11-16 2020-01-24 李字明 300-900 ℃ multi-color-changing irreversible temperature indicating material and preparation method and application thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724364A (en) * 2019-11-16 2020-01-24 李字明 300-900 ℃ multi-color-changing irreversible temperature indicating material and preparation method and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114031966A (en) * 2021-11-24 2022-02-11 国网辽宁省电力有限公司朝阳供电公司 Heating color-changing coating for power transmission line
CN115537115A (en) * 2022-09-20 2022-12-30 国网湖南省电力有限公司 Coating capable of rapidly identifying early thermal runaway fault of lithium ion battery and application of coating
CN116731549A (en) * 2023-08-07 2023-09-12 广东电网有限责任公司湛江供电局 High-voltage transmission line induction electrochromic paint, preparation method and early warning method

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