CN113307452A - Novel system for treating coal washing wastewater - Google Patents

Novel system for treating coal washing wastewater Download PDF

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Publication number
CN113307452A
CN113307452A CN202110637388.6A CN202110637388A CN113307452A CN 113307452 A CN113307452 A CN 113307452A CN 202110637388 A CN202110637388 A CN 202110637388A CN 113307452 A CN113307452 A CN 113307452A
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CN
China
Prior art keywords
coal washing
heavy metal
sludge
washing wastewater
sewage
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Pending
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CN202110637388.6A
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Chinese (zh)
Inventor
徐连满
姜笑楠
路凯旋
魏豪
康馨月
吕祎珂
李英特
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Liaoning University
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Liaoning University
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Publication date
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Priority to CN202110637388.6A priority Critical patent/CN113307452A/en
Publication of CN113307452A publication Critical patent/CN113307452A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2846Anaerobic digestion processes using upflow anaerobic sludge blanket [UASB] reactors

Abstract

The invention relates to a novel system for treating coal washing wastewater, which comprises a water collecting area, a coagulation sedimentation tank and a water collecting device, wherein the water collecting area is used for collecting the coal washing wastewater discharged by a coal washing device, collecting the coal washing wastewater to the water collecting area, and the coagulation sedimentation tank is connected with the water collecting area through a pipeline; coal washing wastewater gets into coagulating sedimentation tank, is equipped with first automatic reagent feeding device in the coagulating sedimentation tank, and heavy metal precipitation device passes through the pipeline with coagulating sedimentation tank and links to each other, and first sewage gets into heavy metal precipitation device, is equipped with second automatic reagent feeding device among the heavy metal precipitation device, obtains second sewage and first mud, and clear water processing system and sludge processing system are connected respectively through two branches to heavy metal precipitation device. The coal washing wastewater is deeply purified, a large amount of water resources are saved, and heavy metal ions in the coal washing wastewater are recycled for effective utilization.

Description

Novel system for treating coal washing wastewater
Technical Field
The invention relates to a system for treating coal washing wastewater, and belongs to the technical field of water treatment equipment.
Background
Coal washing wastewater containing a large amount of suspended matters, coal slime and heavy metal substances is generated in the coal mining and washing processes. The coal washing wastewater has the characteristics of high turbidity, fine solid particle size, negative charge on the surface of solid particles and the like. If the coal washing wastewater does not reach the standard for discharge, not only the ecological environment and water resources are seriously polluted, but also a large amount of coal slime and heavy metals are lost. The development speed of the coal mining industry in each region of China is stably increased, and the whole discharge amount of coal washing wastewater is also continuously increased.
The coal washing wastewater contains various harmful substances such as heavy metals, but the existing coal washing wastewater treatment system cannot completely remove the heavy metals in the wastewater, most of the treated water does not reach the recycling standard, and the coal slime generated after treatment also causes waste and pollution, so that a set of efficient treatment system is needed to remove the heavy metals in the coal washing wastewater and enable the heavy metals to be recycled, and the treated water resource can be reused in the coal washing system for coal washing again.
Disclosure of Invention
The invention aims to provide a novel system for treating coal washing wastewater, which can deeply purify the coal washing wastewater, save a large amount of water resources and recover heavy metal ions in the coal washing wastewater for effective utilization.
In order to solve the above problems, the specific technical scheme of the invention is as follows: a novel system for treating coal washing wastewater comprises a water collecting area, wherein the water collecting area is used for collecting coal washing wastewater discharged by a coal washing device, collecting the coal washing wastewater to the water collecting area, and a coagulating sedimentation tank connected with the water collecting area through a pipeline; coal washing wastewater gets into coagulating sedimentation tank, is equipped with first automatic reagent feeding device in the coagulating sedimentation tank, and heavy metal precipitation device passes through the pipeline with coagulating sedimentation tank and links to each other, and first sewage gets into heavy metal precipitation device, is equipped with second automatic reagent feeding device among the heavy metal precipitation device, obtains second sewage and first mud, and clear water processing system and sludge processing system are connected respectively through two branches to heavy metal precipitation device.
The clear water processing system comprises: and the second sewage enters the neutralization tank, and excess liquid caustic soda preparation in the second sewage is neutralized to enable the pH value of the water to be neutral, so that third sewage is obtained.
And the neutralization tank is connected with a UASB reactor through a pipeline, and the UASB reactor operates to obtain fourth sewage.
The UASB reactor have the disinfection pond through pipe connection, fourth sewage gets into the disinfection pond, obtains first processing clear water.
The disinfection pond has the clean water basin through the pipe connection, and first processing clear water gets into the clean water basin, has the backwash pump in the clean water basin, and the backwash pump is recycled in water reflux to the coal washing device in with the clean water basin.
The sludge treatment system comprises: and the sludge caching device is connected with the heavy metal precipitation device through a pipeline, and the first sludge enters the sludge caching device.
The sludge caching device is connected with a chelating agent spraying device through a pipeline, the first sludge enters the chelating agent spraying device, and the upper part of the chelating agent spraying device is provided with an automatic spraying device which is used for automatically detecting heavy metals and adding an IDS chelating agent to generate a heavy metal chelate; the lower part of the chelating agent spraying device is provided with a stirrer which stirs and breaks up the sludge to ensure that heavy metal ions in the precipitate are better contacted with the IDS chelating agent sprayed by the automatic spraying device, and the heavy metal ions are completely chelated with the chelating agent to form heavy metal chelates, thereby obtaining second sludge.
The chelating agent spraying device is connected with a sludge filter press through a pipeline, a second sludge passing through a sludge pump is arranged in the sludge filter press, the second sludge is uniformly distributed in the gravity dehydration zone through the sludge pump, free water in the sludge is quickly discharged along with the movement of the filter belt, the maximum gravity dehydration is realized in the middle-force dehydration zone, and fifth sewage is obtained;
the sludge filter press have heavy metal collection device through the pipe connection, the fifth sewage gets into heavy metal collection device, is equipped with the plate electrode among the heavy metal collection device, adsorbs and collects heavy metal.
The disinfection tank is internally provided with an ultraviolet disinfector which generates ultraviolet UV-C light with high efficiency, high intensity and long service life to kill bacteria and viruses in the fourth sewage.
The invention has the following beneficial effects: the novel system for treating the coal washing wastewater provided by the invention can combine heavy metal and a chelating agent to form a heavy metal chelate, and then carry out mud-water separation, so that the heavy metal is further extracted for utilization. Therefore, compared with the prior art, the invention can carry out deep purification treatment on the coal washing wastewater, save a large amount of water resources, and can also recover heavy metal ions in the coal washing wastewater, effectively utilize the heavy metal ions and realize the aim of sustainable development.
Drawings
FIG. 1 is a schematic structural diagram of a novel system for treating coal washing wastewater.
The system comprises a water collecting area 1, a coagulating sedimentation tank 2, a first automatic dosing device 21, a heavy metal sedimentation device 3, a heavy metal sedimentation device 31, a second automatic dosing device 4, a neutralization tank 5, a UASB reactor 6, a disinfection tank 61, an ultraviolet sterilizer 7, a clean water tank 71, a reflux pump 8, a sludge caching device 9, a chelating agent spraying device 91, an automatic spraying device 92, a stirrer 10, a sludge filter press 101, a sludge pump 11, a heavy metal collecting device 111 and an electrode plate.
Detailed Description
In the description of the present invention, it should be noted that the terms "upper", "lower", "left", "right", "inner", "outer", etc. indicate orientations or positional relationships based on positional relationships shown in the drawings or positional relationships that are usually arranged when the system of the present invention is used, and are only used for convenience of description and simplification of description, but do not indicate that the device or the element to be referred to must have a specific position, and thus, should not be construed as limiting the present invention.
Furthermore, the terms "first," "second," "third," and the like are used merely to distinguish one description from another, and are not to be construed as indicating relative importance.
In the description of the present invention, it is also to be noted that the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly unless otherwise specifically stated or limited. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
As shown in fig. 1, a novel system for treating coal washing wastewater comprises: the water collecting area 1 is mainly used for collecting coal washing wastewater discharged by the coal washing device, and before the coal washing wastewater enters the main treatment device, the coal washing wastewater is collected to the water collecting area 1, so that the water quality and the water quantity are kept relatively stable, and a stable and optimized operation condition is provided for a subsequent treatment system.
A coagulating sedimentation tank 2 connected with the water collecting area 1 through a pipeline; the coal washing wastewater enters the coagulating sedimentation tank 2, and because the coal washing wastewater has high concentration of suspended matters, fine particles and stronger negative charges on the surface, two kinds of flocculating agents are used as composite agents. The composite agent can continuously strengthen the actual strength of the flocs, thereby improving the separation work efficiency of the flocculant.
The first automatic medicine adding device 21 detects that the content of suspended matters in the sewage exceeds the standard, namely, the compound medicine is automatically added: PAM and PAC, carry out coagulation reaction after, the coagulating sedimentation effect is better, can form the flocculating constituent, and the water turbidity of separating out is lower moreover, obtains first sewage, and the flocculating constituent of production will deposit to the bottom of the pool because of the action of gravity, carries out periodic cleaning to the flocculating constituent that its bottom was precipitated.
Heavy metal precipitation device 3 that links to each other through the pipeline with coagulating sedimentation tank 2, first sewage get into heavy metal precipitation device 3, and second automatic reagent feeding device 31 detects out heavy metal in the sewage after, and the liquid caustic soda preparation is added automatically, utilizes the heavy metal ion realization degree of depth desorption in the liquid caustic soda preparation with waste water, makes the heavy metal deposit to mud in, obtains second sewage and first mud.
And a neutralization tank 4 connected with the heavy metal precipitation device 3 through a pipeline, wherein the second sewage enters the neutralization tank 4, and excess liquid caustic soda preparation in the second sewage is neutralized to enable the pH value in the water to be neutral, so that third sewage is obtained.
The UASB reactor 5 is connected with the neutralization tank 4 through a pipeline, the UASB reactor 5 runs at high temperature and medium temperature and stably runs at low temperature, the third sewage does not contain heavy metal ions, the UASB reactor 5 does not need oxygen supply, stirring or heating, the consumed energy is less, a large amount of bioenergy biogas can be provided, the concentration of organic matters in the treated sewage basically reaches the discharge standard, and the fourth sewage is obtained.
And after the fourth sewage enters the disinfection tank 6, the ultraviolet disinfector 61 generates ultraviolet UV-C light with high efficiency, high intensity and long service life, kills bacteria and viruses in the fourth sewage, and obtains first treatment clean water.
And the clean water tank 7 is connected with the disinfection tank 6 through a pipeline, the first treatment clean water enters the clean water tank 7, a return pump 71 is arranged in the clean water tank 7, and the return pump 71 can return the water in the clean water tank 7 to the coal washing device for reuse.
And the sludge caching device 8 is connected with the heavy metal precipitation device 3 through a pipeline, and in order to improve the sludge treatment efficiency, the first sludge enters the sludge caching device 8 to perform stable treatment on the sludge.
The chelating agent spraying device 9 is connected with the sludge caching device 8 through a pipeline, the first sludge enters the chelating agent spraying device 9, and the automatic spraying device 91 is arranged at the upper part of the chelating agent spraying device 9 and used for automatically detecting heavy metals and adding an IDS chelating agent to generate a heavy metal chelate; the stirrer 92 is arranged at the lower part of the chelating agent spraying device 9, sludge is stirred and broken up, heavy metal ions in the sediment are better contacted with the IDS chelating agent sprayed by the automatic spraying device 91, and after the heavy metal ions stay for a relatively long time, the heavy metal ions are completely chelated with the chelating agent to form a heavy metal chelate, so that second sludge is obtained;
and the sludge filter press 10 is connected with the chelating agent spraying device 9 through a pipeline, the second sludge enters the sludge filter press 10 through a sludge pump 101, then the sludge is uniformly distributed in the gravity dehydration zone, the free water in the sludge is quickly discharged along with the movement of the filter belt, and the maximum gravity dehydration is realized in the medium-force dehydration zone. The upper and lower positions of the two filter belts are sequentially alternated, so that shearing force is generated on the mud cakes, the residual water in the mud cakes is fully filtered, the mud cakes are promoted to be dehydrated again, finally, the dry mud cakes are scraped off by a scraper and are transported to a mud storage place, the mud is recycled to be made into coal-containing mud cakes, and fifth sewage is obtained;
and the heavy metal collecting device 11 is connected with the sludge filter press 10 through a pipeline, fifth sewage enters the heavy metal collecting device 11, an electrode plate 111 is arranged in the heavy metal collecting device 11, heavy metals can be adsorbed and collected, the heavy metals on the electrode plate 111 are scraped off at regular intervals, and the heavy metals can be recycled.
What has been described above is merely a preferred embodiment of the invention. It should be noted that variations and modifications can be made by those skilled in the art without departing from the principle of the present invention, and they should also be considered as falling within the scope of the present invention.

Claims (10)

1. The utility model provides a novel handle coal washing wastewater system which characterized in that: the system comprises a water collecting area (1), wherein the water collecting area (1) is used for collecting coal washing wastewater discharged by a coal washing device, collecting the coal washing wastewater to the water collecting area (1), and a coagulating sedimentation tank (2) connected with the water collecting area (1) through a pipeline; coal washing wastewater gets into coagulating sedimentation tank (2), is equipped with first automatic reagent feeding device (21) in coagulating sedimentation tank (2), and heavy metal precipitation device (3) link to each other through the pipeline with coagulating sedimentation tank (2), and first sewage gets into heavy metal precipitation device (3), is equipped with second automatic reagent feeding device (31) in heavy metal precipitation device (3), obtains second sewage and first mud, and clear water processing system and sludge processing system are connected respectively through two branches to heavy metal precipitation device (3).
2. The novel system for treating coal washing wastewater as claimed in claim 1, wherein: the clear water processing system comprises: and a neutralization tank (4) connected with the heavy metal precipitation device (3) through a pipeline, wherein the second sewage enters the neutralization tank (4), and excess liquid caustic soda preparation in the second sewage is neutralized to make the pH value of the water neutral, so that third sewage is obtained.
3. The novel system for treating coal washing wastewater as set forth in claim 2, characterized in that: and the neutralization tank (4) is connected with a UASB reactor (5) through a pipeline, and the UASB reactor (5) operates to obtain fourth sewage.
4. The novel system for treating coal washing wastewater as set forth in claim 3, characterized in that: the UASB reactor (5) have disinfection pond (6) through the pipe connection, fourth sewage gets into disinfection pond (6), obtains first processing clear water.
5. The novel system for treating coal washing wastewater as set forth in claim 4, characterized in that: the coal washing device is characterized in that the disinfection tank (6) is connected with a clean water tank (7) through a pipeline, first treated clean water enters the clean water tank (7), a reflux pump (71) is arranged in the clean water tank (7), and water in the clean water tank (7) is refluxed to the coal washing device by the reflux pump (71) to be reused.
6. The novel system for treating coal washing wastewater as claimed in claim 1, wherein: the sludge treatment system comprises: and the sludge caching device (8) is connected with the heavy metal precipitation device (3) through a pipeline, and the first sludge enters the sludge caching device (8).
7. The novel system for treating coal washing wastewater as set forth in claim 6, characterized in that: the sludge caching device (8) is connected with a chelating agent spraying device (9) through a pipeline, the first sludge enters the chelating agent spraying device (9), and an automatic spraying device (91) is arranged at the upper part of the chelating agent spraying device (9) and used for automatically detecting heavy metals and adding an IDS chelating agent to generate a heavy metal chelate; the stirrer (92) is arranged at the lower part of the chelating agent spraying device (9) and is used for stirring and scattering the sludge, so that heavy metal ions in the precipitate can be better contacted with the IDS chelating agent sprayed by the automatic spraying device (91), and the heavy metal ions are completely chelated with the chelating agent to form heavy metal chelate, thereby obtaining second sludge.
8. The novel system for treating coal washing wastewater as set forth in claim 7, characterized in that: the chelating agent spraying device (9) is connected with a sludge filter press (10) through a pipeline, a second sludge pump (101) is arranged in the sludge filter press (10), the second sludge pump (101) enables the sludge to be uniformly distributed in a gravity dehydration zone, free water in the sludge is rapidly discharged along with the movement of a filter belt, the maximum gravity dehydration is realized in the medium-force dehydration zone, and fifth sewage is obtained.
9. The novel system for treating coal washing wastewater as set forth in claim 7, characterized in that: the sludge filter press (10) is connected with a heavy metal collecting device (11) through a pipeline, fifth sewage enters the heavy metal collecting device (11), and an electrode plate (111) is arranged in the heavy metal collecting device (11) and adsorbs and collects heavy metals.
10. The novel system for treating coal washing wastewater as set forth in claim 4, characterized in that: an ultraviolet sterilizer (61) is arranged in the disinfection tank (6) to generate ultraviolet UV-C light with high efficiency, high intensity and long service life, and bacteria and viruses in the fourth sewage are killed.
CN202110637388.6A 2021-06-08 2021-06-08 Novel system for treating coal washing wastewater Pending CN113307452A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115159743A (en) * 2022-07-15 2022-10-11 张彧 Control method of cleaning equipment and related device
CN115477437A (en) * 2022-09-21 2022-12-16 泸州市威鑫煤业有限责任公司 Coal washery sewage treatment system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115159743A (en) * 2022-07-15 2022-10-11 张彧 Control method of cleaning equipment and related device
CN115477437A (en) * 2022-09-21 2022-12-16 泸州市威鑫煤业有限责任公司 Coal washery sewage treatment system

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Application publication date: 20210827