CN113213759A - Matte gold grain glaze and method for preparing matte gold grain glaze ceramic product by using same - Google Patents
Matte gold grain glaze and method for preparing matte gold grain glaze ceramic product by using same Download PDFInfo
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- CN113213759A CN113213759A CN202110554060.8A CN202110554060A CN113213759A CN 113213759 A CN113213759 A CN 113213759A CN 202110554060 A CN202110554060 A CN 202110554060A CN 113213759 A CN113213759 A CN 113213759A
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- matt gold
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 118
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 91
- 239000010931 gold Substances 0.000 title claims abstract description 91
- 239000000919 ceramic Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 14
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000292 calcium oxide Substances 0.000 claims abstract description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 13
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium peroxide Inorganic materials [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 claims abstract description 7
- CLSKHAYBTFRDOV-UHFFFAOYSA-N potassium;molecular oxygen Chemical compound [K+].O=O CLSKHAYBTFRDOV-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 64
- 238000000227 grinding Methods 0.000 claims description 51
- 239000000463 material Substances 0.000 claims description 51
- 238000010304 firing Methods 0.000 claims description 31
- 238000007598 dipping method Methods 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 24
- 238000007873 sieving Methods 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 235000015895 biscuits Nutrition 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 12
- 239000002023 wood Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 10
- 238000000498 ball milling Methods 0.000 claims description 9
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 7
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 6
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 claims description 6
- 229940107698 malachite green Drugs 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 230000000007 visual effect Effects 0.000 abstract description 6
- 241001622925 Acacia coriacea Species 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 12
- 238000001514 detection method Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2209/00—Compositions specially applicable for the manufacture of vitreous glazes
- C03C2209/02—Compositions specially applicable for the manufacture of vitreous glazes to produce non-uniformly coloured glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a matt gold grain glaze and a method for preparing a matt gold grain glaze ceramic product by using the matt gold grain glaze, and belongs to the technical field of ceramics. The glazed matt gold wire wood grain glaze disclosed by the invention consists of a hand-painted glaze and a matt gold wire glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.42-0.65 part of potassium dioxide, 4.45-6.02 parts of sodium oxide, 9.5-10.8 parts of calcium oxide, 2-3 parts of magnesium oxide, 6.8-7.9 parts of calcium carbonate, 55-65 parts of silicon dioxide and 11-12.5 parts of aluminum oxide. The matt gold grain glaze ceramic product prepared by the invention is environment-friendly and energy-saving, and has strong visual effect of matt gold grain.
Description
Technical Field
The invention belongs to the technical field of ceramics, and particularly relates to a matt gold grain glaze and a method for preparing a matt gold grain glaze ceramic product by using the matt gold grain glaze.
Background
China occupies a great position as a large country for ceramic production, but is sold internally or externally, and ceramic products are often given to friends as gifts. Since ancient times, glaze of ceramic products is strange, some glaze is controllable, some glaze changes randomly along with different firing conditions, and visual effects are various.
The chinese patent application No. 202010411676.5 discloses a wood grain glaze, a wood grain glaze ceramic and a preparation method thereof, and it can be seen from the drawings of the specification that the visual effect of the wood grain is not good and is easily misled to be only the grain of a line.
Therefore, it is necessary to provide an environment-friendly, energy-saving and matte golden silk grain glaze ceramic product with strong wood grain visual effect.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide an environment-friendly energy-saving matt gold grain glaze ceramic product with strong wood grain visual effect.
The invention adopts the following technical scheme:
the matt gold wood grain glaze consists of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.42-0.65 part of potassium dioxide, 4.45-6.02 parts of sodium oxide, 9.5-10.8 parts of calcium oxide, 2-3 parts of magnesium oxide, 6.8-7.9 parts of calcium carbonate, 55-65 parts of silicon dioxide and 11-12.5 parts of aluminum oxide.
Further, the matt gold wire glaze comprises the following components in parts by weight: 5.5-6.5 parts of potassium oxide, 4-5 parts of sodium oxide, 4.6-5.5 parts of calcium oxide, 4.2-5.6 parts of magnesium oxide, 12-18 parts of barium carbonate, 7-8 parts of zinc oxide, 39-42 parts of silicon oxide, 9.5-12 parts of aluminum oxide, 10-13 parts of titanium oxide, 4-6 parts of malachite green and 2.5-4 parts of manganese oxide.
The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze comprises the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
step two, sieving:
sieving the hand-painted glaze grinding material and the matt golden silk glaze grinding material separately to obtain a hand-painted glaze screen material and a matt golden silk glaze screen material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water; moreover, the applicant can add ceramic pigments with different colors according to the requirements of different colors;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product. .
Further, during grinding in the first step, 77-85% of water in parts by weight of the hand-drawing glaze is added and mixed, 77-85% of water in parts by weight of the matt gold glaze is added and mixed, and then ball milling is carried out for 48-50 hours separately.
And furthermore, 150-200 mesh screens are adopted during sieving in the second step.
Further, the release agent is 10-12% by mass of the hand-painted glaze.
And further, in the drawing process of the fourth step, the biscuit is fired at the temperature of 600-650 ℃, and dust is removed before drawing.
Further, in the glaze dipping process in the fifth step, the baume degree of the matt golden wire glaze water is 45-55, the glaze dipping time is 2-3 s, and the matt golden wire glaze water is taken out, wiped at the bottom and naturally dried for 2-3 h.
Further, in the sixth firing step, the firing is carried out in an oxidizing atmosphere, the temperature is raised to 400-500 ℃ at a speed of 2.5-3.0 ℃/min, the temperature is kept for 30min, then the temperature is raised to 800-850 ℃ at a constant speed of 2.0-2.5 ℃/min, the temperature is kept for 30min, finally the temperature is raised to 1250-1270 ℃ at a speed of 2.0-3.0 ℃/min, the constant temperature firing is carried out for 2-2.5 h, and then the obtained product is naturally cooled.
Compared with the prior art, the invention has the following beneficial effects:
firstly, the hand-painted glaze and the matt gold glaze which are independently researched and developed by the applicant are firstly coated on the outer surface of a blank body in a hand-painted mode, and then the matt gold glaze is applied, so that a unique glaze effect with the grain texture of the matt gold is formed after firing, and a very strong visual impact feeling is brought to people;
in the matt gold wire glaze, potassium oxide, sodium oxide and silicon dioxide are mixed for use, so that the transparency of the glaze surface is effectively improved, the thermal stability of the ceramic product is improved, and the fullness of the grain of the matt gold wire is increased;
thirdly, the prepared matt gold grain glaze ceramic product has strong thermal shock resistance and high wear resistance.
Detailed Description
The raw materials used in the present invention are all commercially available products.
Wherein the separant is purchased from ceramic colored glaze water-blocking agent of the Ministry of chemical industry of Haicheng of the city of carinly.
Example 1
The matt gold wood grain glaze consists of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.42 part of potassium dioxide, 4.45 parts of sodium oxide, 9.5 parts of calcium oxide, 2 parts of magnesium oxide, 6.8 parts of calcium carbonate, 55 parts of silicon dioxide and 11 parts of aluminum oxide.
The matt gold wire glaze comprises the following components in parts by weight: 5.5 parts of potassium oxide, 4 parts of sodium oxide, 4.6 parts of calcium oxide, 4.2 parts of magnesium oxide, 12 parts of barium carbonate, 7 parts of zinc oxide, 39 parts of silicon oxide, 9.5 parts of aluminum oxide, 10 parts of titanium oxide, 4 parts of malachite green and 2.5 parts of manganese oxide.
The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze comprises the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
during grinding, 77% of water in parts by mass of the hand-painted glaze is added and mixed, and then ball milling is carried out for 48 hours;
step two, sieving:
sieving the hand-painted glaze grinding material and the matt golden silk glaze grinding material separately, and adopting a 150-mesh sieve to obtain a hand-painted glaze sieve material and a matt golden silk glaze sieve material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water, wherein the separant accounts for 10% of the mass of the hand-painted glaze;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
wherein the biscuit is fired at 600 ℃;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
during the glaze dipping process, the baume degree of the matt gold glaze water is 45, the glaze dipping time is 2s, and the matt gold glaze water is taken out, wiped at the bottom and naturally dried for 2 h;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product. The firing process is as follows: firing in an oxidizing atmosphere, namely heating to 400 ℃ at the speed of 2.5 ℃/min, keeping the temperature constant for 30min, heating to 800 ℃ at the constant temperature of 2.0 ℃/min, keeping the temperature constant for 30min, heating to 1250 ℃ at the speed of 2.0 ℃/min, firing for 2.5h at the constant temperature, and then naturally cooling.
Example 2
The matt gold wood grain glaze consists of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 00.65 parts of potassium dioxide, 6.02 parts of sodium oxide, 10.8 parts of calcium oxide, 3 parts of magnesium oxide, 7.9 parts of calcium carbonate, 65 parts of silicon dioxide and 12.5 parts of aluminum oxide.
The matt gold wire glaze comprises the following components in parts by weight: 6.5 parts of potassium oxide, 5 parts of sodium oxide, 5.5 parts of calcium oxide, 5.6 parts of magnesium oxide, 18 parts of barium carbonate, 8 parts of zinc oxide, 42 parts of silicon oxide, 12 parts of aluminum oxide, 13 parts of titanium oxide, 6 parts of malachite green and 4 parts of manganese oxide.
The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze comprises the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
during grinding, adding 80% of water in parts by mass of the hand-painted glaze, mixing, and then carrying out ball milling for 50 h;
adding 80% of water in parts by mass of the matt gold glaze grinding material, mixing, and then carrying out ball milling for 50 h.
Step two, sieving:
sieving the hand-painted glaze grinding material and the matt gold glaze grinding material separately, and adopting a 200-mesh sieve to obtain a hand-painted glaze sieve material and a matt gold glaze sieve material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water, wherein the separant accounts for 10% of the mass of the hand-painted glaze;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
wherein the biscuit is fired at 650 ℃;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
during the glaze dipping process, the baume degree of the matt gold glaze water is 55, the glaze dipping time is 3s, and the matt gold glaze water is taken out, wiped at the bottom and naturally dried for 3 h;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product. The firing process is as follows: firing in an oxidizing atmosphere, namely heating to 500 ℃ at a speed of 3.0 ℃/min, keeping the temperature constant for 30min, heating to 850 ℃ at a constant temperature of 2.5 ℃/min, keeping the temperature constant for 30min, heating to 1270 ℃ at a speed of 3.0 ℃/min, firing for 2h at a constant temperature, and then naturally cooling.
Example 3
The matt gold wood grain glaze consists of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.50 part of potassium dioxide, 5.3 parts of sodium oxide, 10.1 parts of calcium oxide, 2.5 parts of magnesium oxide, 7.2 parts of calcium carbonate, 59 parts of silicon dioxide and 11.5 parts of aluminum oxide.
The matt gold wire glaze comprises the following components in parts by weight: 6.3 parts of potassium oxide, 5 parts of sodium oxide, 5.2 parts of calcium oxide, 5.1 parts of magnesium oxide, 15 parts of barium carbonate, 8 parts of zinc oxide, 41 parts of silicon oxide, 11 parts of aluminum oxide, 12 parts of titanium oxide, 5 parts of malachite green and 3.2 parts of manganese oxide.
The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze comprises the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
during grinding, 83% of water in parts by mass of the hand-painted glaze is added and mixed, and then ball milling is carried out for 50 hours;
adding 83% of water in parts by mass of the matt gold glaze grinding material, mixing, and then carrying out ball milling for 50 h.
Step two, sieving:
sieving the hand-painted glaze grinding material and the matt gold glaze grinding material separately, and adopting a 200-mesh sieve to obtain a hand-painted glaze sieve material and a matt gold glaze sieve material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water, wherein the separant accounts for 10% of the mass of the hand-painted glaze;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
wherein the biscuit is fired at 600 ℃;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
during the glaze dipping process, the baume degree of the matt gold glaze water is 50, the glaze dipping time is 3s, and the matt gold glaze water is taken out, wiped at the bottom and naturally dried for 3 h;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product. The firing process is as follows: firing in an oxidizing atmosphere, namely heating to 450 ℃ at the speed of 2.6 ℃/min, keeping the temperature constant for 30min, heating to 800 ℃ at the constant temperature of 2.2 ℃/min, keeping the temperature constant for 30min, heating to 1260 ℃ at the speed of 2.5 ℃/min, keeping the temperature constant, firing for 2.2h, and then naturally cooling.
Example 4
The matt gold wood grain glaze consists of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.64 part of potassium dioxide, 6.00 parts of sodium oxide, 10.6 parts of calcium oxide, 3 parts of magnesium oxide, 7.6 parts of calcium carbonate, 63 parts of silicon dioxide and 12.2 parts of aluminum oxide.
The matt gold wire glaze comprises the following components in parts by weight: 6.3 parts of potassium oxide, 5 parts of sodium oxide, 5.2 parts of calcium oxide, 5.3 parts of magnesium oxide, 17 parts of barium carbonate, 7 parts of zinc oxide, 41 parts of silicon oxide, 11 parts of aluminum oxide, 12 parts of titanium oxide, 5 parts of malachite green and 3.8 parts of manganese oxide.
The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze comprises the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
during grinding, adding 84% of water in parts by mass of the hand-painted glaze, mixing, and then carrying out ball milling for 50 h;
step two, sieving:
sieving the hand-painted glaze grinding material and the matt golden silk glaze grinding material separately, and adopting a 150-mesh sieve to obtain a hand-painted glaze sieve material and a matt golden silk glaze sieve material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water, wherein the separant accounts for 10% of the mass of the hand-painted glaze;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
wherein the biscuit is fired at 600 ℃;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
during the glaze dipping process, the baume degree of the matt gold glaze water is 54, the glaze dipping time is 3s, and the matt gold glaze water is taken out, wiped at the bottom and naturally dried for 2 h;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product. The firing process is as follows: and (3) firing in an oxidizing atmosphere, namely heating to 450 ℃ at the speed of 2.9 ℃/min, keeping the temperature for 25min, heating to 800 ℃ at the constant temperature of 2.1 ℃/min, keeping the temperature for 25min, heating to 1260 ℃ at the speed of 2.6 ℃/min, keeping the temperature for firing for 2.1h, and then naturally cooling.
The crack resistance detection of the matt gold grain glaze ceramic product is detected by adopting a GB/T34252 and 2017 daily ceramic ware crack resistance test method;
detecting the matt gold grain glaze ceramic product by using GB/T3532-containing 2009 daily porcelain;
carrying out performance detection on the matt gold grain glaze ceramic product obtained in the embodiment 1-4;
the abrasion resistance is tested by adopting the GB/T3710.7-2016 glazed brick surface abrasion resistance measurement.
The detection results are shown in the following table 1:
table 1: detection results of matte gold grain glaze ceramic products obtained in examples 1 to 4
As can be seen from Table 1, the matt gold grain glaze ceramic products prepared in examples 1 to 4 do not crack once exchanged at 180 ℃ to 20 ℃, have strong thermal shock resistance, are beneficial to prolonging the service life, have low lead and chromium dissolution, reduce the harm to human bodies, and have strong appreciation.
It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The matt gold wood grain glaze is characterized by consisting of a hand-painted glaze and a matt gold glaze, wherein the hand-painted glaze comprises the following components in parts by mass: 0.42-0.65 part of potassium dioxide, 4.45-6.02 parts of sodium oxide, 9.5-10.8 parts of calcium oxide, 2-3 parts of magnesium oxide, 6.8-7.9 parts of calcium carbonate, 55-65 parts of silicon dioxide and 11-12.5 parts of aluminum oxide.
2. The matt gold grain glaze according to claim 1, wherein the matt gold grain glaze comprises the following components in parts by mass: 5.5-6.5 parts of potassium oxide, 4-5 parts of sodium oxide, 4.6-5.5 parts of calcium oxide, 4.2-5.6 parts of magnesium oxide, 12-18 parts of barium carbonate, 7-8 parts of zinc oxide, 39-42 parts of silicon oxide, 9.5-12 parts of aluminum oxide, 10-13 parts of titanium oxide, 4-6 parts of malachite green and 2.5-4 parts of manganese oxide.
3. The method for preparing the matt gold grain glaze ceramic product by using the matt gold grain glaze as claimed in claim 2, which is characterized by comprising the following steps:
step one, grinding:
uniformly mixing the components of the hand-painted glaze according to the mass parts, and then grinding to obtain a hand-painted glaze grinding material;
uniformly mixing all components of the matt gold glaze, and then grinding to obtain a matt gold glaze grinding material;
step two, sieving:
sieving the hand-painted glaze grinding material and the matt golden silk glaze grinding material separately to obtain a hand-painted glaze screen material and a matt golden silk glaze screen material;
step three, preparing hand-painted glaze water:
adding water and a separant into the hand-painted glaze screen mesh material obtained in the second step, and mixing to obtain hand-painted glaze water;
step four, colored drawing:
drawing the biscuit by using the hand-drawing glaze water obtained in the step three, and drying to obtain a drawing blank body;
step five, dipping glaze:
adding water to prepare a matt gold wire glaze screen material into matt gold wire glaze water, dipping the drawn blank obtained in the fourth step into the matt gold wire glaze water, and drying to obtain a glazed blank;
step six, firing:
firing the glaze-dipped blank obtained in the fifth step, and naturally cooling to obtain the matt gold grain glaze ceramic product.
4. The method for preparing the matt gold grain glaze ceramic product as claimed in claim 3, wherein in the step one, 77-85% of water in parts by weight of hand-drawn glaze is added for mixing during grinding, and then ball milling is carried out for 48-50 h;
adding 77-85% of water in parts by weight of the matt gold glaze grinding material, mixing, and then carrying out ball milling for 48-50 h.
5. The method for preparing the matt gold grain glaze ceramic product as claimed in claim 3, wherein a 150-200 mesh sieve is adopted during sieving in the second step.
6. The method for preparing the matt gold grain glaze ceramic product as claimed in claim 3, wherein the release agent is 10-12% by weight of the hand-drawn glaze.
7. The method for preparing a matt gold grain glaze ceramic product as claimed in claim 3, wherein in the drawing process of the fourth step, the biscuit is fired at 600-650 ℃, and dust is removed before drawing.
8. The method for preparing the matt gold grain glaze ceramic product according to claim 3, wherein in the glaze dipping process in the fifth step, the baume degree of the matt gold grain glaze water is 45-55, the glaze dipping time is 2-3 s, and the matt gold grain glaze water is taken out, wiped at the bottom and naturally dried for 2-3 h.
9. The method for preparing the matt gold grain glaze ceramic product according to claim 3, wherein in the sixth firing step, the matt gold grain glaze ceramic product is fired in an oxidizing atmosphere, the temperature is raised to 400-500 ℃ at a speed of 2.5-3.0 ℃/min, the constant temperature is maintained for 20-30 min, then the temperature is raised to 800-850 ℃ at a constant temperature of 2.0-2.5 ℃/min, the constant temperature is maintained for 20-30 min, finally the temperature is raised to 1250-1270 ℃ at a speed of 2.0-3.0 ℃/min, the constant temperature firing is performed for 2-2.5 h, and then the product is naturally cooled.
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