CN113174139A - Jade-silver medical conductive electrode rubber and preparation process thereof - Google Patents
Jade-silver medical conductive electrode rubber and preparation process thereof Download PDFInfo
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- CN113174139A CN113174139A CN202110561790.0A CN202110561790A CN113174139A CN 113174139 A CN113174139 A CN 113174139A CN 202110561790 A CN202110561790 A CN 202110561790A CN 113174139 A CN113174139 A CN 113174139A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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Abstract
The invention provides a jade silver medical conductive electrode rubber and a preparation process, the jade silver medical conductive electrode rubber comprises 45-60 parts of polysiloxane, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-7 parts of white carbon black, 1-2 parts of a release agent, 2-3 parts of silicone oil and 1-2 parts of an anti-aging agent, the preparation process comprises mixing, refining, adding the jade powder and the silver powder, mixing, cutting and vulcanizing and forming, the jade powder and the silver powder are added into the prepared jade silver medical conductive electrode rubber, and the synergistic effect of the jade powder, the silver powder and the nano titanium oxide can obviously improve the sterilization effect of the medical conductive electrode rubber, meanwhile, the medical effect and the health care effect of the conductive electrode are improved, and the added silver powder can also improve the conductivity of the conductive electrode rubber.
Description
Technical Field
The invention relates to the technical field of medical health care physiotherapy appliances, in particular to jade and silver medical conductive electrode rubber and a preparation process thereof.
Background
The electrode plate for the ECG monitor and other medical electrode plates are made of common conductive carbon black, and certain defects and deficiencies exist in the conductivity, stability and efficacy.
The electronic acupuncture is different from the traditional acupuncture in that the electronic acupuncture stimulates acupuncture points through audio pulses, is different from the common electric acupuncture in that a silver needle is not used, does not puncture the skin, and has no wound and side effect. The defects of the traditional acupuncture are abandoned, and the advantages of the traditional acupuncture are inherited and developed.
The electronic holographic acupuncture is an electric pulse stimulation; the traditional acupuncture needs to puncture the skin, and the electronic holographic acupuncture does not puncture the skin. It is also different from the electric acupuncture which is used to prick the acupuncture point and apply current to the acupuncture point, and it has not been completely separated from the traditional acupuncture. Electronic holographic acupuncture has two elements: first, the frequency of the pulses. The frequency of the medicine directly influences the treatment effect, researches show that the frequency is suitable for audio pulse, the richer the frequency is, the better the treatment effect is, the easier the medicine resistance is, and the frequency fatigue is easy to overcome; second, it is the treatment pole. The shape and material of the therapeutic electrode directly influence the therapeutic effect, and the therapeutic electrode which is shaped to cover all acupuncture points of hands, ears, feet and Ashi acupuncture points is manufactured by using conductive rubber and high polymer conductive materials which are pollution-free to human bodies according to the holography of the convex parts of human bodies. Therefore, the holographic therapy is carried out on the human body through the hand, the ear, the foot and the Ashi point, and the effect is obvious.
Disclosure of Invention
In view of the above, the technical problems to be solved by the present invention are: how to provide a conductive electrode rubber with jade powder and silver powder to improve the medical health care efficacy and performance of ear membranes, hand membranes, foot membranes, Ashi points and electrocardio monitoring electrode plates.
In order to achieve the above object, in one aspect, the present invention provides a jade silver medical conductive electrode rubber, which comprises polysiloxane, jade powder, silver powder, nano titanium oxide, white carbon black, a mold release agent, silicone oil and an anti-aging agent;
45-60 parts of polysiloxane, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-7 parts of white carbon black, 1-2 parts of a release agent, 2-3 parts of silicone oil and 1-2 parts of an anti-aging agent.
Further, the particle diameter of the jade powder is nano-scale.
Further, the particle diameter of the silver powder is in the nanometer level.
On the other hand, the invention provides jade silver medical conductive electrode rubber which comprises epoxy rubber, jade powder, silver powder, nano titanium oxide, graphene, a release agent, silicone oil and an anti-aging agent;
the anti-aging coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 10-15 parts of graphene, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent.
On the other hand, the invention provides jade silver medical conductive electrode rubber which comprises epoxy rubber, jade powder, silver powder, nano titanium oxide, acetylene black, carbon fiber, a release agent, silicone oil and an anti-aging agent;
the epoxy resin coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-10 parts of acetylene black, 5-10 parts of carbon fiber, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent.
On the other hand, the invention provides a preparation process of the jade-silver medical conductive electrode rubber membrane, and the preparation of the jade-silver medical conductive electrode rubber comprises the steps of mixing materials, mixing rubber, adding jade powder and silver powder, mixing, cutting and vulcanizing molding.
Further, the material mixing comprises the following specific steps: mixing and stirring polysiloxane, white carbon black, a mold release agent, silicone oil and an anti-aging agent.
Further, the rubber mixing comprises the following specific steps: kneading the mixed materials by a rubber mixing mill.
Further, the mixing comprises the following concrete steps: adding the jade powder, the silver powder and the nano titanium oxide after the rubber mixing is finished, and kneading by a rubber mixing mill.
Further, the vulcanization molding comprises the following specific steps: vulcanizing and profiling the materials by a vulcanizer and a profiling machine.
Compared with the related technology, the jade silver medical conductive electrode rubber and the preparation process provided by the invention have the beneficial effects that:
(1) the jade silver medical conductive electrode rubber has the beneficial effects that the jade powder, the silver powder and the nano titanium oxide are synergistic, so that the sterilization effect of the medical conductive electrode rubber can be obviously improved, and the medical effect and the health care effect of the conductive electrode are improved;
(2) the added silver powder can also improve the conductivity of the conductive electrode rubber.
Drawings
FIG. 1 is a schematic flow chart of a preparation process of the jade silver medical conductive electrode rubber in the embodiment of the invention.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
Example one
The invention provides jade silver medical conductive electrode rubber which comprises polysiloxane, jade powder, silver powder, nano titanium oxide, white carbon black, a mold release agent, silicone oil and an anti-aging agent;
45-60 parts of polysiloxane, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-7 parts of white carbon black, 1-2 parts of a release agent, 2-3 parts of silicone oil and 1-2 parts of an anti-aging agent.
Further, the particle diameter of the jade powder is nano-scale, and the particle diameter of the silver powder is nano-scale.
The anti-aging agent is one or more of 9, 9-dimethylacridine, N-cyclohexyl-N' -phenyl-p-phenylenediamine and 2-mercaptobenzimidazole, and the anti-aging effect of the electrode rubber is improved.
Specifically, the jade powder contains more than ten trace elements beneficial to human body, such as gold, silver, silicon, zinc, iron, selenium, magnesium, manganese and the like, and the trace elements can be used for removing diseases, protecting health and prolonging life of people, for example: zinc can activate insulin, regulate energy metabolism, maintain immunity, promote intelligence development of children, and has anticancer, teratocarcinosis preventing, and antiaging effects. The manganese element can resist the damage of free radicals to human bodies, participate in the synthesis of proteins and vitamins, promote blood circulation, accelerate metabolism, resist aging, prevent senile dementia, osteoporosis, angiosclerosis and the like. The selenium element is a component of the osteocystin peroxidase, can catalyze toxic peroxide to be reduced into harmless hydroxyl compounds, thereby protecting biological membranes from being damaged, playing a role in resisting aging, removing the harm of harmful metals such as cadmium, lead and the like to human bodies, enhancing the immunologic function of the human bodies, improving the disease resistance of the organisms and achieving the effects of preventing and treating cancers.
Specifically, the silver powder can improve the conductivity of the conductive electrode rubber, and moreover, the silver powder has good bactericidal effect on common bacteria, stubborn bacteria, drug-resistant bacteria and infection caused by fungi in terms of medical value.
Example two
The invention provides jade-silver medical conductive electrode rubber which comprises epoxy rubber, jade powder, silver powder, nano titanium oxide, graphene, a release agent, silicone oil and an anti-aging agent;
the anti-aging coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 10-15 parts of graphene, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent. The graphene can be used as a conductive filler to effectively improve the conductivity of the graphene.
EXAMPLE III
The invention provides jade silver medical conductive electrode rubber which comprises epoxy rubber, jade powder, silver powder, nano titanium oxide, acetylene black, carbon fiber, a release agent, silicone oil and an anti-aging agent;
the epoxy resin coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-10 parts of acetylene black, 5-10 parts of carbon fiber, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent. The acetylene black and the carbon fiber are used as conductive fillers to effectively improve the conductivity of the conductive filler.
Example four
The invention also provides a preparation process of the jade and silver medical conductive electrode rubber film, which refers to the attached figure 1 and is used for preparing the jade and silver medical conductive electrode rubber, and the preparation process comprises the steps of mixing materials, rubber mixing, adding jade powder and silver powder, mixing, cutting and vulcanization molding.
Further, the material mixing comprises the following specific steps: the polysiloxane, the white carbon black, the release agent, the silicone oil and the anti-aging agent are mixed and stirred, and specifically, the polysiloxane, the white carbon black, the release agent, the silicone oil and the anti-aging agent can be mixed and stirred by mixing equipment, so that the materials are fully mixed and stirred.
Further, the rubber mixing method comprises the following specific steps: kneading the mixed materials by a rubber mixing mill.
Further, the mixing concrete steps are as follows: adding the jade powder, the silver powder and the nano titanium oxide after rubber mixing is finished, and kneading by a rubber mixing mill, wherein the jade powder and the silver powder are sequentially added into the mixed material, and the adding ratio of the jade powder to the silver powder can be 1: 1.
Further, the vulcanization molding comprises the following specific steps: the vulcanizing machine and the molding press are used for vulcanizing and profiling materials, and specifically, before the vulcanizing and molding process, a material cutting machine is used for cutting the mixed materials, so that the material cutting is realized to improve the vulcanizing and molding efficiency.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
1. The jade-silver medical conductive electrode rubber is characterized by comprising polysiloxane, jade powder, silver powder, nano titanium oxide, white carbon black, a mold release agent, silicone oil and an anti-aging agent;
45-60 parts of polysiloxane, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-7 parts of white carbon black, 1-2 parts of a release agent, 2-3 parts of silicone oil and 1-2 parts of an anti-aging agent.
2. The jade silver medical conductive electrode rubber as claimed in claim 1, wherein the particle diameter of the jade powder is in the nanometer level.
3. The jade silver medical conductive electrode rubber as set forth in claim 1, wherein a particle diameter of the silver powder is in a nanometer order.
4. The jade-silver medical conductive electrode rubber is characterized by comprising epoxy rubber, jade powder, silver powder, nano titanium oxide, graphene, a mold release agent, silicone oil and an anti-aging agent;
the anti-aging coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 10-15 parts of graphene, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent.
5. The jade-silver medical conductive electrode rubber is characterized by comprising epoxy rubber, jade powder, silver powder, nano titanium oxide, acetylene black, carbon fiber, a release agent, silicone oil and an anti-aging agent;
the epoxy resin coating comprises, by weight, 30-50 parts of epoxy rubber, 20-25 parts of jade powder, 20-25 parts of silver powder, 20-25 parts of nano titanium oxide, 5-10 parts of acetylene black, 5-10 parts of carbon fiber, 2 parts of a release agent, 2 parts of silicone oil and 2 parts of an anti-aging agent.
6. A preparation process of jade-silver medical conductive electrode rubber is used for preparing the jade-silver medical conductive electrode rubber in any one of claims 1 to 5, and is characterized by comprising the steps of mixing materials, mixing rubber, adding jade powder and silver powder, mixing, cutting and vulcanizing and forming.
7. The preparation process of the jade silver medical conductive electrode rubber as claimed in claim 6, wherein the mixing comprises the following specific steps: mixing and stirring polysiloxane, white carbon black, a mold release agent, silicone oil and an anti-aging agent.
8. The preparation process of the jade silver medical conductive electrode rubber as claimed in claim 6, wherein the rubber mixing comprises the following specific steps: kneading the mixed materials by a rubber mixing mill.
9. The preparation process of the jade silver medical conductive electrode rubber as claimed in claim 6, wherein the mixing concrete steps are as follows: adding the jade powder, the silver powder and the nano titanium oxide after the rubber mixing is finished, and kneading by a rubber mixing mill.
10. The preparation process of the jade silver medical conductive electrode rubber as claimed in claim 6, wherein the vulcanization molding comprises the following specific steps: vulcanizing and profiling the materials by a vulcanizer and a profiling machine.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101678569B1 (en) * | 2016-03-24 | 2016-11-23 | (주) 엠에스 | Silver and Jade is the antimicrobial composition with its shock sewer |
CN112266504A (en) * | 2020-09-18 | 2021-01-26 | 河北橡一医药科技股份有限公司 | Medical rubber and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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KR101678569B1 (en) * | 2016-03-24 | 2016-11-23 | (주) 엠에스 | Silver and Jade is the antimicrobial composition with its shock sewer |
CN112266504A (en) * | 2020-09-18 | 2021-01-26 | 河北橡一医药科技股份有限公司 | Medical rubber and preparation method thereof |
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