CN113161439B - Battery interconnection structure, assembly and preparation method - Google Patents

Battery interconnection structure, assembly and preparation method Download PDF

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Publication number
CN113161439B
CN113161439B CN202110131145.5A CN202110131145A CN113161439B CN 113161439 B CN113161439 B CN 113161439B CN 202110131145 A CN202110131145 A CN 202110131145A CN 113161439 B CN113161439 B CN 113161439B
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battery
transparent conductive
main grid
adhesive layer
conductive adhesive
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CN113161439A (en
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姜亚帅
黄国平
庄浩
史振侠
白玲玲
龚琴赟
李菁楠
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CECEP Solar Energy Technology Zhenjiang Co Ltd
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CECEP Solar Energy Technology Zhenjiang Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • H01L31/0508Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module the interconnection means having a particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • H01L31/0512Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module made of a particular material or composition of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a battery interconnection structure, a battery assembly and a preparation method, wherein the battery interconnection structure comprises a battery, a main grid, a transparent conductive adhesive layer and a welding strip, wherein the transparent conductive adhesive layer covers the main grid, and the width of the transparent conductive adhesive layer is larger than that of the main grid; the welding strip is pressed on the main grid, and the height of the transparent conductive adhesive layer is larger than the heights of the main grid and the welding strip. In the invention, the welding strip and the main grid are adhered and fixed by adopting the transparent conductive adhesive layer, so that the process reliability of the whole assembly is greatly improved. Due to the presence of the double-layer parallel conductors, the total resistance will be greatly reduced according to 1/r=1/r1+1/R2 even with lower diameter solder strips. The design of the battery screen plate can cancel the bonding pad and the anti-breaking grid structure due to the transparent conductive bonding layer, so that the positive silver consumption is saved; the structure of eliminating the bonding pad and reducing the diameter of the bonding tape can increase the light receiving surface of the battery and improve the power output generated in unit area.

Description

Battery interconnection structure, assembly and preparation method
Technical Field
The invention relates to the technical field of photovoltaic cells, in particular to a battery interconnection structure, a battery assembly and a preparation method.
Background
In the past, the large-scale use of traditional petrochemical industry promotes the industry level to continuously advance, the living level of people is continuously improved, but the use is improper, the management is lack to cause the environmental pollution to be serious, and the households on which people depend to live are seriously threatened, each government agency also continuously adopts powerful measures to suppress pollution, one of the powerful measures is to develop green energy, the photovoltaic module can directly convert sunlight into electric energy, and the photovoltaic module has no pollution, can be continued, has high efficiency and is easy to realize, so that the photovoltaic module is rapidly developed in recent years, and the accumulated installed quantity of China breaks through 130.25GW at present.
In recent years, photovoltaic power station project investors pay more and more attention to electricity cost, and the application of high-power components can further reduce electricity cost, and photovoltaic component manufacturers continuously upgrade and improve component output power through technology. The output power of the component can be improved by improving the efficiency of the battery, optimizing the material collocation, innovating the circuit design and the like, such as half-sheet, tile overlapping, double-sided, multi-main grid technology and the like. The multi-main-grid assembly can reduce the positive silver consumption, the power of the lifting assembly is widely welcomed, the market share is rapidly improved, and the market share in 2020 reaches more than 40%.
At present, the realization mode of the multi-main-grid assembly is that a circular welding strip with tin-lead alloy plated on the surface is welded with a battery through thermal infrared, and a battery screen plate is provided with a plurality of welding pads, but at present, the following problems still exist (as disclosed in patent document CN208767313U, namely, a multi-main-grid solar photovoltaic assembly):
the circular welding strip is only welded with the battery through a plurality of welding pads, the bottom of the circular welding strip is only welded with the battery, the contact area is small, the problem of false welding is easy to occur, in order to reduce the influence of the false welding, a plurality of welding pads are required to be arranged on a single main grid, the grid breakage is prevented from being gradually changed, the consumption of silver paste is greatly increased, and the cost is also greatly increased; secondly, the solder reacts with silver in the bonding pad to form alloy under the condition of thermal heating of tin-lead alloy on the surface of the circular solder strip, the tin-lead protective layer on the surface of the circular solder strip is adsorbed on the battery bonding pad under the action of surface tension and the like in a molten state, the copper body at the upper part of the solder strip is exposed to air and rapidly oxidized at high temperature, the conductivity is poor, and even acetic acid, water oxygen and the like in EVA after encapsulation further corrode the copper body, the conductivity of the solder strip is reduced, and the long-term reliability is influenced; thirdly, the resistance of the circular welding strip is inversely proportional to the sectional area under the condition of the same length, and the larger the area is, the lower the resistance is, so that the diameter of the circular welding strip is generally 0.35-0.4mm based on the consideration of circuit loss, the shading area of the welding strip reaches 2% based on a nine-main-grid 158.75 battery, and the power of the assembly is difficult to further improve; fourthly, the diameter of the conventional welding strip is 0.35-0.4mm, the spacing between the component pieces is required to be set to be 2mm or more, so that series welding and lamination cracking can be reduced, the component efficiency is lower, and the BOM cost is increased.
Disclosure of Invention
The invention aims to solve the defects in the prior art, and provides a battery interconnection structure which comprises a battery, a main grid, a transparent conductive adhesive layer and a welding strip, wherein the transparent conductive adhesive layer covers the main grid, and the width of the transparent conductive adhesive layer is larger than that of the main grid; the welding strip is pressed on the main grid, and the transparent conductive adhesive layer is higher than the main grid and the welding strip.
Further, the transparent conductive adhesive layer is one of an organosilicon system, an acrylic acid system, an epoxy resin system and a hybridization system thereof.
Further, the conductive medium in the transparent conductive bonding layer is one or more of conductive oxide, a hybridization system, a carbon nanotube, graphene, a conductive polymer, a metal nanowire and a metal nanodot.
Further, the conductive medium in the transparent conductive adhesive layer is SnO 2 、In 2 O 3 、 Cd 2 In 4 、SnO 2 :Sb、SnO 2 :F、In 2 O 3 :Sn、ZnO:Al、TiO 2 : nb, polyimide, (3, 4-ethylenedioxythiophene): one or more of polystyrene sulfonate, silver and silver-coated copper.
Further, the section of the welding strip is circular, the diameter of the welding strip is 0.05-0.3 mm, and the thickness of the tin-lead layer on the surface of the welding strip is 3-10 mu m.
Compared with the traditional welding strip with the diameter of 0.3-0.5 mm, the welding strip with the diameter of 0.05-0.3 mm can enlarge the light receiving surface of the battery, so that the battery component with unit area can generate more power output.
Further, both left and right sides of the transparent conductive adhesive layer extend to the surface of the battery, respectively.
A battery interconnection assembly comprises a frame and a battery interconnection structure, wherein a cover plate, a lower adhesive film, the battery interconnection structure, an upper adhesive film and glass are sequentially arranged in the frame from inside to outside.
Preferably, the upper adhesive film is a transparent adhesive film, and the lower adhesive film is a transparent or ceramic white adhesive film.
Preferably, the cover plate is a back plate or inorganic glass
A method for manufacturing an interconnection structure of a battery, the method comprising the steps of:
step one: coating a transparent conductive adhesive layer on the main grid side of the battery;
step two: the welding strip is arranged on the transparent conductive adhesive layer at the position of the main grid through the positioning device, and is connected with the main grid in a crimping manner;
step three: preheating for 10-30 s at the temperature of 80-110 ℃ by using thermal infrared rays to realize the primary solidification of the adhesive layer;
step four: and after the lamination is completed, the adhesive film is laminated in a laminating machine to realize complete curing.
The beneficial effects are that: (1) According to the invention, the transparent conductive bonding layer is adopted to bond and fix the welding strip and the main grid, so that the problems of easy occurrence of cold joint, tin beads and exposed copper in the inner layer of the welding strip during high-temperature heating can be effectively avoided, the defective rate of series joint, repair and lamination caused by cold joint and tin beads is further avoided, the influence of the reduction of long-term reliability of the component caused by exposed copper is avoided, and the process reliability of the whole component is greatly improved.
(2) Due to the presence of the double-layer parallel conductors, the total resistance will be greatly reduced according to 1/r=1/r1+1/R2 even with lower diameter solder strips.
(3) In the invention, due to the transparent conductive adhesive layer, the design of the battery screen plate can cancel the bonding pad and the anti-breaking grid structure, thereby saving the positive silver consumption.
(4) In the invention, the structure of eliminating the bonding pad and reducing the diameter of the bonding tape can increase the light receiving surface of the battery and improve the power output generated in unit area.
Drawings
FIG. 1 is a schematic diagram of a front screen of a conventional battery in the background art;
FIG. 2 is a schematic view of a front screen of a battery in the present invention;
fig. 3 is a schematic view of a battery interconnect structure in the present invention;
fig. 4 is a partial enlarged view of a battery interconnection structure in the present invention;
fig. 5 is a schematic cross-sectional view of a battery interconnect structure in accordance with the present invention;
fig. 6 is an enlarged partial schematic view of a cross section of a battery interconnect structure in accordance with the present invention;
FIG. 7 is a schematic cross-sectional view of a battery interconnect assembly in accordance with the present invention;
in the figure: 1. glass, 2, upper adhesive film, 3, battery interconnection structure, 4, lower adhesive film, 5, cover plate, 6, bonding pad, 7, gradual change design, 8, main grid, 9, transparent conductive adhesive layer, 10, welding strip, 11, battery, 12, frame.
Detailed Description
The present invention will be further described in detail with reference to the following examples and drawings for the purpose of enhancing the understanding of the present invention, which examples are provided for the purpose of illustrating the present invention only and are not to be construed as limiting the scope of the present invention.
As shown in fig. 2-6, a battery interconnection structure comprises a battery 11, a main grid 8, a transparent conductive adhesive layer 9 and a welding strip 10, wherein the transparent conductive adhesive layer 9 covers the main grid 8, and the width of the transparent conductive adhesive layer 9 is larger than that of the main grid 8; the welding strip 10 is pressed on the main grid 8, and the height of the transparent conductive bonding layer 9 is larger than the heights of the main grid 8 and the welding strip 10.
In this embodiment, the transparent conductive adhesive layer is one of an organosilicon system, an acrylic system, an epoxy system, and a hybrid system thereof.
In this embodiment, the conductive medium in the transparent conductive adhesive layer is one or more of conductive oxide and hybrid system, carbon nanotube, graphene, conductive polymer, metal nanowire, and metal nanodot.
In this embodiment, the conductive medium in the transparent conductive adhesive layer is specifically SnO 2 、In 2 O 3 、Cd 2 In 4 、SnO 2 :Sb、SnO 2 :F、In 2 O 3 :Sn、ZnO:Al、TiO 2 : nb, polyimide, (3, 4-ethylenedioxythiophene): one or more of polystyrene sulfonate, silver and silver-coated copper.
In this embodiment, the cross section of the solder strip is circular, the diameter of the solder strip is 0.05-0.3 mm, and the thickness of the tin-lead layer on the surface of the solder strip is 3-10 μm.
In this embodiment, the left and right sides of the transparent conductive adhesive layer extend to the surface of the battery, respectively.
As shown in FIG. 7, a battery interconnection assembly, the assembly comprises a frame and a battery interconnection structure, wherein a cover plate, a lower adhesive film, a battery interconnection structure, an upper adhesive film and glass are sequentially arranged in the frame from inside to outside.
In this embodiment, the upper adhesive film is a transparent adhesive film, and the lower adhesive film is transparent or porcelain Bai Jiaomo; the cover plate is a back plate or inorganic glass
A method for manufacturing an interconnection structure of a battery, the method comprising the steps of:
step one: coating a transparent conductive adhesive layer on the main grid side of the battery;
step two: the welding strip is arranged on the transparent conductive adhesive layer at the position of the main grid through the positioning device, and is connected with the main grid in a crimping manner;
step three: preheating for 10-30 s at the temperature of 80-110 ℃ by using thermal infrared rays to realize the primary solidification of the adhesive layer;
step four: and after the lamination is completed, the adhesive film is laminated in a laminating machine to realize complete curing.
The foregoing description of the preferred embodiments of the invention is not intended to limit the invention to the precise form disclosed, and any such modifications, equivalents, and alternatives falling within the spirit and scope of the invention are intended to be included within the scope of the invention.

Claims (7)

1. The battery interconnection structure is characterized by comprising a battery, a main grid, a transparent conductive adhesive layer and a welding strip, wherein the transparent conductive adhesive layer covers the main grid, and the width of the transparent conductive adhesive layer is larger than that of the main grid; the welding strip is pressed on the main grid, and the height of the transparent conductive adhesive layer is greater than the heights of the main grid and the welding strip;
the transparent conductive bonding layer is one of an organic silicon system, an acrylic acid system, an epoxy resin system and a hybridization system thereof, and the conductive medium in the transparent conductive bonding layer is one or more of a conductive oxide and hybridization system, a carbon nano tube, graphene, a conductive polymer, a metal nano wire and a metal nano dot.
2. The battery interconnection structure according to claim 1, wherein the solder strip has a circular cross section, the solder strip has a diameter of 0.05-0.3 mm, and the solder strip has a surface tin-lead layer thickness of 3-10 μm.
3. The structure of claim 1, wherein the transparent conductive adhesive layer extends to the surface of the battery on both sides.
4. A battery interconnection assembly, characterized in that the assembly comprises a frame and a battery interconnection structure, wherein the battery interconnection structure is as claimed in any one of claims 1-3, and a cover plate, a lower adhesive film, a battery interconnection structure, an upper adhesive film and glass are sequentially arranged in the frame from inside to outside.
5. The battery interconnect assembly of claim 4, wherein the upper adhesive film is a transparent adhesive film and the lower adhesive film is a transparent or ceramic white adhesive film.
6. The battery interconnect assembly of claim 5 wherein the cover plate is a back plate or inorganic glass.
7. A method of manufacturing a battery interconnect assembly according to any one of claims 4-6, comprising the steps of:
step one: coating a transparent conductive adhesive layer on the main grid side of the battery;
step two: the welding strip is arranged on the transparent conductive adhesive layer at the position of the main grid through the positioning device, and is connected with the main grid in a crimping manner;
step three: preheating for 10-30 s at the temperature of 80-110 ℃ by using thermal infrared rays to realize the primary solidification of the adhesive layer;
step four: and after the lamination is completed, the adhesive film is laminated in a laminating machine to realize complete curing.
CN202110131145.5A 2021-01-30 2021-01-30 Battery interconnection structure, assembly and preparation method Active CN113161439B (en)

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Publication number Priority date Publication date Assignee Title
CN113871496A (en) * 2021-09-17 2021-12-31 常州大学 Electrode structure of photovoltaic cell and preparation method
CN116093167A (en) * 2022-12-19 2023-05-09 无锡荷雨新能源科技有限公司 Battery assembly, photovoltaic assembly and preparation method of photovoltaic assembly

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CN103283034A (en) * 2010-10-29 2013-09-04 夏普株式会社 Method for manufacturing solar cell with wiring sheet, method for manufacturing solar cell module, solar cell with wiring sheet, and solar cell module
JP3198443U (en) * 2015-03-23 2015-07-02 ▲ゆ▼晶能源科技股▲分▼有限公司Gintech Energy Corporation Solar cell module
CN206401339U (en) * 2016-12-14 2017-08-11 3M中国有限公司 Crystal silicon solar energy battery
CN107393994A (en) * 2017-06-29 2017-11-24 中节能太阳能科技(镇江)有限公司 A kind of high-performance high reliability photovoltaic module
CN208256682U (en) * 2018-05-30 2018-12-18 苏州阿特斯阳光电力科技有限公司 Photovoltaic module

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102376791A (en) * 2010-08-11 2012-03-14 Lg电子株式会社 Solar cell panel
CN103283034A (en) * 2010-10-29 2013-09-04 夏普株式会社 Method for manufacturing solar cell with wiring sheet, method for manufacturing solar cell module, solar cell with wiring sheet, and solar cell module
JP3198443U (en) * 2015-03-23 2015-07-02 ▲ゆ▼晶能源科技股▲分▼有限公司Gintech Energy Corporation Solar cell module
CN206401339U (en) * 2016-12-14 2017-08-11 3M中国有限公司 Crystal silicon solar energy battery
CN107393994A (en) * 2017-06-29 2017-11-24 中节能太阳能科技(镇江)有限公司 A kind of high-performance high reliability photovoltaic module
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