CN113152096A - Antibacterial and antistatic environment-friendly textile auxiliary and preparation method thereof - Google Patents

Antibacterial and antistatic environment-friendly textile auxiliary and preparation method thereof Download PDF

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Publication number
CN113152096A
CN113152096A CN202110465024.4A CN202110465024A CN113152096A CN 113152096 A CN113152096 A CN 113152096A CN 202110465024 A CN202110465024 A CN 202110465024A CN 113152096 A CN113152096 A CN 113152096A
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parts
antibacterial
agent
volatile oil
textile auxiliary
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王云峰
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Guangdong Kefeng New Material Technology Co ltd
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Guangdong Kefeng New Material Technology Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses an antibacterial and antistatic environment-friendly textile auxiliary and a preparation method thereof, wherein the antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 44-60 parts of fatty alcohol-polyoxyethylene ether, 15-20 parts of sodium polyacrylate, 15-20 parts of butylbenzene transparent impact-resistant resin, 5-8 parts of organic silicon emulsion, 8-10 parts of styrene-acrylic emulsion, 0.8-1.2 parts of tungsten sulfide nano material, 1.2-1.8 parts of zirconium oxide nano powder, 120 parts of ionized water, 1-2 parts of hexabromocyclododecane, 1-2 parts of aluminum hydroxide, 0.5-1.0 part of ethyl dicyclic acid, 1-2 parts of nano silver activated carbon and 1-1.5 parts of nano silver zeolite. The textile auxiliary prepared by the formula and the method has the advantages of good color fastness to washing, excellent antibacterial and antistatic properties, good flame retardant property, environment-friendly formula and simple preparation method under the synergistic effect of the raw materials, and can increase the softness of the textile and meet the use requirement.

Description

Antibacterial and antistatic environment-friendly textile auxiliary and preparation method thereof
Technical Field
The invention relates to the technical field of textile auxiliary agents, in particular to an antibacterial and antistatic environment-friendly textile auxiliary agent and a preparation method thereof.
Background
Textile auxiliaries are chemicals which are necessary in the production and processing of textiles. The textile auxiliary agent has an indispensable important role in improving the product quality and the added value of the textile. Textile auxiliaries are crucial to increasing the overall level of the textile industry and their role in the textile industry chain. The textile auxiliary agents all over the world have nearly 100 categories, nearly 1.6 ten thousand varieties are produced, and the annual output is about 410 ten thousand tons. Wherein the European and American textile auxiliary varieties are 48 categories, and more than 8000 categories; there are 5500 varieties in Japan. It can not only endow the textile with various special functions and styles, such as the treatment of cotton and linen fabrics by animal protein amino acid, but also can make the textile have the excellent characteristics of wrinkle resistance, elasticity, fluffiness, shape memory and the like.
Due to the problem of the development status of the whole industry, the textile auxiliary on the market can realize a plurality of functions, and the textile auxiliary is blank, and the requirements for antibacterial and antistatic auxiliaries in the textile industry are urgent, so that the development of the textile auxiliary with antistatic and antibacterial functions is urgently needed.
Disclosure of Invention
In view of the above, the present invention provides an antibacterial and antistatic environmental-friendly textile auxiliary and a preparation method thereof, which have the characteristics of antibacterial, antistatic and flame retardant properties.
In order to achieve the purpose, the invention adopts the following technical scheme:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 44-60 parts of fatty alcohol-polyoxyethylene ether, 15-20 parts of sodium polyacrylate, 15-20 parts of butylbenzene transparent impact-resistant resin, 5-8 parts of organic silicon emulsion, 8-10 parts of styrene-acrylic emulsion, 0.8-1.2 parts of tungsten sulfide nano material, 1.2-1.8 parts of zirconium oxide nano powder, 120 parts of ionized water, 1-2 parts of hexabromocyclododecane, 1-2 parts of aluminum hydroxide, 0.5-1.0 part of ethyl dicyclic acid, 1-2 parts of nano silver activated carbon, 1-1.5 parts of nano silver zeolite, 0.5-1.0 part of natural antibacterial agent, 10-15 parts of polyethylene glycol monostearate, 5-6 parts of polyacrylic acid, 3-4 parts of hexametaphosphate, 6-8 parts of nonylphenol polyoxyethylene ether, 7-8 parts of organic acid, 6-7 parts of coupling agent, 4-5 parts of color fixing agent, 2-3 parts of a reinforcing agent.
As a preferable scheme, the natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1.
As a preferable scheme, the coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2.
As a preferable scheme, the reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3.
As a preferable scheme, the color fixing agent comprises at least one of polyvinylamine and xanthan gum.
A preparation method of an antibacterial and antistatic environment-friendly textile auxiliary comprises the following steps:
(1) accurately weighing the raw materials in parts by weight;
(2) mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2-3h at the stirring speed of 5000-plus 5500r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl bicyclic phosphoric acid, stirring for 1-2h at the stirring speed of 4000-plus 5000r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, stirring for 1-2h at the stirring speed of 4000-plus 5000r/m to obtain mixed solution;
(3) feeding the stirred mixed solution into a reaction kettle, heating to 70-75 ℃ by adopting a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphoric acid, nonylphenol polyoxyethylene ether and organic acid, emulsifying at a high speed for 50-60 minutes after uniform mixing to obtain an emulsified mixed solution, then adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 15-20 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 10-15 minutes, then carrying out third ultrasonic treatment, then adding a reinforcing agent, carrying out heat preservation for 5-10 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1-2 hours, the second ultrasonic power is 1000w, and the ultrasonic time is 1-2 hours, the third ultrasonic power is 1500w, and the ultrasonic time is 0.5-1 h.
Compared with the prior art, the invention has obvious advantages and beneficial effects, and specifically, the technical scheme includes that:
the textile auxiliary prepared by the formula and the method has the advantages of good color fastness to washing, excellent antibacterial and antistatic properties, good flame retardant property, environment-friendly formula and simple preparation method under the synergistic effect of the raw materials, and can increase the softness of the textile and meet the use requirement.
Detailed Description
The invention discloses an antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following raw materials in parts by weight: 44-60 parts of fatty alcohol-polyoxyethylene ether, 15-20 parts of sodium polyacrylate, 15-20 parts of butylbenzene transparent impact-resistant resin, 5-8 parts of organic silicon emulsion, 8-10 parts of styrene-acrylic emulsion, 0.8-1.2 parts of tungsten sulfide nano material, 1.2-1.8 parts of zirconium oxide nano powder, 120 parts of ionized water, 1-2 parts of hexabromocyclododecane, 1-2 parts of aluminum hydroxide, 0.5-1.0 part of ethyl dicyclic acid, 1-2 parts of nano silver activated carbon, 1-1.5 parts of nano silver zeolite, 0.5-1.0 part of natural antibacterial agent, 10-15 parts of polyethylene glycol monostearate, 5-6 parts of polyacrylic acid, 3-4 parts of hexametaphosphate, 6-8 parts of nonylphenol polyoxyethylene ether, 7-8 parts of organic acid, 6-7 parts of coupling agent, 4-5 parts of color fixing agent, 2-3 parts of a reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2-3h at the stirring speed of 5000-550 r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl bicyclic phosphoric acid, stirring for 1-2h at the stirring speed of 4000-5000r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1-2h at the stirring speed of 4000-5000r/m to obtain a mixed solution.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 70-75 ℃ by adopting a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphoric acid, nonylphenol polyoxyethylene ether and organic acid, emulsifying at a high speed for 50-60 minutes after uniform mixing to obtain an emulsified mixed solution, then adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 15-20 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 10-15 minutes, then carrying out third ultrasonic treatment, then adding a reinforcing agent, carrying out heat preservation for 5-10 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1-2 hours, the second ultrasonic power is 1000w, and the ultrasonic time is 1-2 hours, the third ultrasonic power is 1500w, and the ultrasonic time is 0.5-1 h.
The invention is illustrated in more detail below in the following examples:
example 1:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 44 parts of fatty alcohol-polyoxyethylene ether, 16 parts of sodium polyacrylate, 17 parts of butylbenzene transparent impact-resistant resin, 6 parts of organic silicon emulsion, 8 parts of styrene-acrylic emulsion, 0.9 part of tungsten sulfide nano material, 1.3 parts of zirconium oxide nano powder, 120 parts of ionized water, 1 part of hexabromocyclododecane, 1.5 parts of aluminum hydroxide, 0.6 part of ethyl dicyclic phosphoric acid, 1.2 parts of nano silver activated carbon, 1.2 parts of nano silver zeolite, 0.6 part of natural antibacterial agent, 10 parts of polyethylene glycol monostearate, 5.2 parts of polyacrylic acid, 3 parts of hexametaphosphoric acid, 7 parts of nonylphenol polyoxyethylene ether, 8 parts of organic acid, 6.5 parts of coupling agent, 4 parts of color fixing agent and 2 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2 hours at the stirring speed of 5000r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl dicyclic acid, stirring for 1 hour at the stirring speed of 5000r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 2 hours at the stirring speed of 4500r/m to obtain mixed liquid.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 72 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, uniformly mixing, emulsifying at high speed for 50 minutes to obtain emulsified mixed solution, adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 15 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 12 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, keeping the temperature for 7 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1h, the second ultrasonic power is 1000w, the ultrasonic time is 2h, the third ultrasonic power is 1500w, and the ultrasonic time is 0.5 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Example 2:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 50 parts of fatty alcohol-polyoxyethylene ether, 15 parts of sodium polyacrylate, 15 parts of butylbenzene transparent impact-resistant resin, 5 parts of organic silicon emulsion, 8.5 parts of styrene-acrylic emulsion, 0.8 part of tungsten sulfide nano material, 1.2 parts of zirconia nano powder, 120 parts of ionized water, 1.2 parts of hexabromocyclododecane, 1 part of aluminum hydroxide, 0.7 part of ethyl dicyclic phosphoric acid, 1.5 parts of nano silver activated carbon, 1.1 parts of nano silver zeolite, 0.8 part of natural antibacterial agent, 11 parts of polyethylene glycol monostearate, 5 parts of polyacrylic acid, 4 parts of hexametaphosphoric acid, 6 parts of nonylphenol polyoxyethylene ether, 7 parts of organic acid, 6.2 parts of coupling agent, 5 parts of color fixing agent and 3 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconia nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 3 hours at the stirring speed of 5100r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl dicyclic acid, stirring for 2 hours at the stirring speed of 4000r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1 hour at the stirring speed of 4000r/m to obtain mixed solution.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 75 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, uniformly mixing, emulsifying at high speed for 60 minutes to obtain emulsified mixed solution, adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 20 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 15 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, keeping the temperature for 8 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1.2h, the second ultrasonic power is 1000w, the ultrasonic time is 1h, the third ultrasonic power is 1500w, and the ultrasonic time is 0.8 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Example 3:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 60 parts of fatty alcohol-polyoxyethylene ether, 18 parts of sodium polyacrylate, 20 parts of butylbenzene transparent impact-resistant resin, 7 parts of organic silicon emulsion, 9 parts of styrene-acrylic emulsion, 1 part of tungsten sulfide nano material, 1.6 parts of zirconia nano powder, 120 parts of ionized water, 1.8 parts of hexabromocyclododecane, 1.4 parts of aluminum hydroxide, 0.5 part of ethyl dicyclic phosphoric acid, 1 part of nano silver activated carbon, 1 part of nano silver zeolite, 0.5 part of natural antibacterial agent, 15 parts of polyethylene glycol monostearate, 5.4 parts of polyacrylic acid, 3.2 parts of hexametaphosphoric acid, 8 parts of nonylphenol polyoxyethylene ether, 7.5 parts of organic acid, 6.3 parts of coupling agent, 4.3 parts of color fixing agent and 2.3 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2.3h at a stirring speed of 5500r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl dicyclic acid, stirring for 1.2h at a stirring speed of 4100r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1.2h at a stirring speed of 4200r/m to obtain mixed liquid.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 70 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, uniformly mixing, emulsifying at high speed for 55 minutes to obtain emulsified mixed solution, adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 17 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 10 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, keeping the temperature for 9 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1.3h, the second ultrasonic power is 1000w, the ultrasonic time is 1.3h, the third ultrasonic power is 1500w, and the ultrasonic time is 0.7 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Example 4:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 56 parts of fatty alcohol-polyoxyethylene ether, 20 parts of sodium polyacrylate, 18 parts of butylbenzene transparent impact-resistant resin, 8 parts of organic silicon emulsion, 9.5 parts of styrene-acrylic emulsion, 1.1 parts of tungsten sulfide nano material, 1.7 parts of zirconia nano powder, 120 parts of ionized water, 1.6 parts of hexabromocyclododecane, 1.5 parts of aluminum hydroxide, 0.9 part of ethyl dicyclic phosphoric acid, 2 parts of nano silver activated carbon, 1.5 parts of nano silver zeolite, 1 part of natural antibacterial agent, 14 parts of polyethylene glycol monostearate, 5.8 parts of polyacrylic acid, 3.3 parts of hexametaphosphoric acid, 6.5 parts of nonylphenol polyoxyethylene ether, 7.3 parts of organic acid, 6.8 parts of coupling agent, 4.2 parts of color fixing agent and 2.5 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2.4 hours at the stirring speed of 5300r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl bicyclic phosphoric acid, stirring for 1.5 hours at the stirring speed of 4300r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1.8 hours at the stirring speed of 4800r/m to obtain mixed solution.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 74 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, uniformly mixing, emulsifying at a high speed for 58 minutes to obtain an emulsified mixed solution, adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 18 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 14 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, carrying out heat preservation for 10 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 2h, the second ultrasonic power is 1000w, the ultrasonic time is 1.2h, the third ultrasonic power is 1500w, and the ultrasonic time is 0.6 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Example 5:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 48 parts of fatty alcohol-polyoxyethylene ether, 17 parts of sodium polyacrylate, 19 parts of butylbenzene transparent impact-resistant resin, 6 parts of organic silicon emulsion, 10 parts of styrene-acrylic emulsion, 1.2 parts of tungsten sulfide nano material, 1.8 parts of zirconium oxide nano powder, 120 parts of ionized water, 1.7 parts of hexabromocyclododecane, 1.7 parts of aluminum hydroxide, 1 part of ethyl dicyclic phosphoric acid, 1.4 parts of nano silver activated carbon, 1.4 parts of nano silver zeolite, 0.7 part of natural antibacterial agent, 13 parts of polyethylene glycol monostearate, 6 parts of polyacrylic acid, 3.5 parts of hexametaphosphoric acid, 7.5 parts of nonylphenol polyoxyethylene ether, 7.8 parts of organic acid, 7 parts of coupling agent, 4.6 parts of color fixing agent and 2.8 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2.6h at a stirring speed of 5500r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl dicyclic acid, stirring for 1.6h at a stirring speed of 4600r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1.5h at a stirring speed of 5000r/m to obtain mixed liquid.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 73 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, uniformly mixing, emulsifying at high speed for 57 minutes to obtain emulsified mixed solution, adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 19 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 13 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, keeping the temperature for 5 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1.4h, the second ultrasonic power is 1000w, the ultrasonic time is 1.5h, the third ultrasonic power is 1500w, and the ultrasonic time is 1 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Example 6:
an antibacterial and antistatic environment-friendly textile auxiliary comprises the following raw materials in parts by weight: 53 parts of fatty alcohol-polyoxyethylene ether, 16 parts of sodium polyacrylate, 16 parts of butylbenzene transparent impact-resistant resin, 5 parts of organic silicon emulsion, 9.3 parts of styrene-acrylic emulsion, 0.85 part of tungsten sulfide nano material, 1.5 parts of zirconia nano powder, 120 parts of ionized water, 2 parts of hexabromocyclododecane, 2 parts of aluminum hydroxide, 0.8 part of ethyl dicyclic phosphoric acid, 1.6 parts of nano silver activated carbon, 1.3 parts of nano silver zeolite, 0.9 part of natural antibacterial agent, 12 parts of polyethylene glycol monostearate, 5.3 parts of polyacrylic acid, 3.7 parts of hexametaphosphoric acid, 6.8 parts of nonylphenol polyoxyethylene ether, 7.6 parts of organic acid, 6.9 parts of coupling agent, 4.8 parts of color fixing agent and 2.4 parts of reinforcing agent. The natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1. The coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2. The reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3. The color fixing agent comprises at least one of polyvinylamine and xanthan gum.
The invention also discloses a preparation method of the antibacterial and antistatic environment-friendly textile auxiliary, which comprises the following steps:
(1) accurately weighing the raw materials in parts by weight.
(2) Mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2.5h at the stirring speed of 5400r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl dicyclic acid, stirring for 1.1h at the stirring speed of 4500r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, and stirring for 1.3h at the stirring speed of 4600r/m to obtain mixed liquid.
(3) Feeding the stirred mixed solution into a reaction kettle, heating to 71 ℃ in a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphate, nonylphenol polyoxyethylene ether and organic acid, emulsifying at high speed for 54 minutes after uniform mixing to obtain emulsified mixed solution, then adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 16 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 11 minutes, then, carrying out third ultrasonic treatment, adding a reinforcing agent, keeping the temperature for 6 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1.6h, the second ultrasonic power is 1000w, the ultrasonic time is 1.8h, the third ultrasonic power is 1500w, and the ultrasonic time is 0.9 h.
The textile prepared by the embodiment is subjected to a color fastness to washing experiment according to the detection in the color fastness to washing experiment for textiles of household and commercial in GB/T12490-; the textile prepared by the embodiment is subjected to an antibacterial experiment according to the national standard GB/T20944, and the antibacterial grade can reach 3A grade; the fabric prepared by the embodiment is subjected to an electrostatic performance test according to GB/T12703, and the antistatic performance reaches a good grade.
Comparative example: the textile auxiliary is different from the textile auxiliary in example 1 in that the formula does not contain hexabromocyclododecane, aluminum hydroxide, ethyl dicyclic phosphoric acid, nano silver activated carbon, nano silver zeolite, a natural antibacterial agent, a color fixing agent and a reinforcing agent.
The textile prepared by the comparative example is subjected to a color fastness to washing test according to the detection in the color fastness to washing test of textiles of GB/T12490-; carrying out an antibacterial experiment on the textile prepared by the comparative example according to the national standard GB/T20944, wherein the antibacterial grade is 1A grade; the fabric prepared by the comparative example was subjected to an electrostatic performance test according to GB/T12703, and the antistatic property was of a normal grade.
The design of the invention is characterized in that: the textile auxiliary prepared by the formula and the method has the advantages of good color fastness to washing, excellent antibacterial and antistatic properties, good flame retardant property, environment-friendly formula and simple preparation method under the synergistic effect of the raw materials, and can increase the softness of the textile and meet the use requirement.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the technical scope of the present invention, so that any minor modifications, equivalent changes and modifications made to the above embodiment according to the technical spirit of the present invention are within the technical scope of the present invention.

Claims (6)

1. An antibacterial and antistatic environment-friendly textile auxiliary is characterized in that: comprises the following raw materials in parts by weight: 44-60 parts of fatty alcohol-polyoxyethylene ether, 15-20 parts of sodium polyacrylate, 15-20 parts of butylbenzene transparent impact-resistant resin, 5-8 parts of organic silicon emulsion, 8-10 parts of styrene-acrylic emulsion, 0.8-1.2 parts of tungsten sulfide nano material, 1.2-1.8 parts of zirconium oxide nano powder, 120 parts of ionized water, 1-2 parts of hexabromocyclododecane, 1-2 parts of aluminum hydroxide, 0.5-1.0 part of ethyl dicyclic acid, 1-2 parts of nano silver activated carbon, 1-1.5 parts of nano silver zeolite, 0.5-1.0 part of natural antibacterial agent, 10-15 parts of polyethylene glycol monostearate, 5-6 parts of polyacrylic acid, 3-4 parts of hexametaphosphate, 6-8 parts of nonylphenol polyoxyethylene ether, 7-8 parts of organic acid, 6-7 parts of coupling agent, 4-5 parts of color fixing agent, 2-3 parts of a reinforcing agent.
2. The antibacterial antistatic environment-friendly textile auxiliary according to claim 1, characterized in that: the natural antibacterial agent comprises mint volatile oil, rhubarb volatile oil and cardamom volatile oil, and the mass ratio of the mint volatile oil to the rhubarb volatile oil to the cardamom volatile oil is 1:2: 1.
3. The antibacterial antistatic environment-friendly textile auxiliary according to claim 1, characterized in that: the coupling agent is a mixture of KH-550 and KH-560 according to the mass ratio of 1: 2.
4. The antibacterial antistatic environment-friendly textile auxiliary according to claim 1, characterized in that: the reinforcing agent consists of quartz powder and ceramic micro powder, and the weight part ratio of the quartz powder to the ceramic micro powder in the reinforcing agent is 1: 3.
5. The antibacterial antistatic environment-friendly textile auxiliary according to claim 1, characterized in that: the color fixing agent comprises at least one of polyvinylamine and xanthan gum.
6. A process for preparing the antibacterial, antistatic and environment-friendly textile auxiliary as claimed in any one of claims 1 to 5, characterized in that: the method comprises the following steps:
(1) accurately weighing the raw materials in parts by weight;
(2) mixing fatty alcohol-polyoxyethylene ether, sodium polyacrylate, butylbenzene transparent impact-resistant resin, organic silicon emulsion, styrene-acrylic emulsion, tungsten sulfide nano material and zirconium oxide nano powder, adding ionic water, simultaneously adding 6% NaOH solution to adjust the pH value to 8.0, stirring for 2-3h at the stirring speed of 5000-plus 5500r/m, then continuously adding hexabromocyclododecane, aluminum hydroxide and ethyl bicyclic phosphoric acid, stirring for 1-2h at the stirring speed of 4000-plus 5000r/m, then continuously adding nano silver activated carbon, nano silver zeolite and natural antibacterial agent, stirring for 1-2h at the stirring speed of 4000-plus 5000r/m to obtain mixed solution;
(3) feeding the stirred mixed solution into a reaction kettle, heating to 70-75 ℃ by adopting a microwave mode, adding polyethylene glycol monostearate, polyacrylic acid, hexametaphosphoric acid, nonylphenol polyoxyethylene ether and organic acid, emulsifying at a high speed for 50-60 minutes after uniform mixing to obtain an emulsified mixed solution, then adding 0.6mol/L HCl solution to adjust the pH of the mixed solution to 5.2, heating to 80 ℃, carrying out first ultrasonic treatment in an ultrasonic machine, then adding a coupling agent, carrying out heat preservation for 15-20 minutes, then carrying out second ultrasonic treatment, then adding a color fixing agent, carrying out heat preservation for 10-15 minutes, then carrying out third ultrasonic treatment, then adding a reinforcing agent, carrying out heat preservation for 5-10 minutes to obtain a finished product, wherein the first ultrasonic power is 800w, the ultrasonic time is 1-2 hours, the second ultrasonic power is 1000w, and the ultrasonic time is 1-2 hours, the third ultrasonic power is 1500w, and the ultrasonic time is 0.5-1 h.
CN202110465024.4A 2021-04-28 2021-04-28 Antibacterial and antistatic environment-friendly textile auxiliary and preparation method thereof Pending CN113152096A (en)

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