CN113149153A - Building site drinking water treatment facilities - Google Patents
Building site drinking water treatment facilities Download PDFInfo
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- CN113149153A CN113149153A CN202110519978.9A CN202110519978A CN113149153A CN 113149153 A CN113149153 A CN 113149153A CN 202110519978 A CN202110519978 A CN 202110519978A CN 113149153 A CN113149153 A CN 113149153A
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- chamber
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- water treatment
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- 239000003651 drinking water Substances 0.000 title claims abstract description 18
- 235000020188 drinking water Nutrition 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 238000010276 construction Methods 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 27
- 239000010936 titanium Substances 0.000 claims description 26
- 229910052719 titanium Inorganic materials 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 7
- 239000003014 ion exchange membrane Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 239000003011 anion exchange membrane Substances 0.000 claims description 5
- 238000005341 cation exchange Methods 0.000 claims description 5
- 238000000502 dialysis Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 4
- 238000009998 heat setting Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000003618 dip coating Methods 0.000 claims description 2
- 229920006351 engineering plastic Polymers 0.000 claims description 2
- 238000003760 magnetic stirring Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 230000003595 spectral effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000008233 hard water Substances 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 241000588724 Escherichia coli Species 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
The invention discloses a drinking water treatment device for a construction site, which comprises an anode chamber, a cathode chamber and an intermediate chamber, wherein a tubular UV source is inserted in the anode chamber, a sol-gel electrode coating is arranged on the surface of an anode, a water inlet is arranged below the intermediate chamber, a water outlet is arranged below the anode chamber, and the volume ratio of the anode chamber to the intermediate chamber is 3-3.5: 1. the device has the advantages of simple structure, convenient operation, environmental protection, high cost benefit and low energy consumption, and can remove 3.9log of bacteria by using the Escherichia coli (ATCC #15597TM) under the conditions that the inlet water concentration is 7.8x104log and the hydraulic retention time is 1 hour. The removal rate can be further improved by optimizing the configuration of the reactor for disinfection, and the technology adopts the photoelectrochemistry water treatment device to soften hard water and remove microorganisms, so that the removal rate of the hard water can reach 60 percent within 6 hours.
Description
Technical Field
The invention relates to the technical field of photoelectrochemistry water purification, in particular to a drinking water treatment device for a construction site.
Background
The trend in drinking water treatment in recent years has been to use membrane separation to reduce contaminants in water. The advantage of the membrane is that a constant and well-regulated quality of water can be produced. The softener is more and more energy efficient with the increase of the waste liquid treatment amount and the reduction of the power consumption, but the problem of adding salt to the environment still exists. In addition to ion exchange, chemical precipitation is also often used to soften municipal primary water. This softening, commonly referred to as lime softening, involves adding lime to hard water to precipitate calcium ions such as calcium carbonate and magnesium ions such as magnesium hydroxide. However, disadvantages of lime softening include the production of a large lime mud stream and the chemicals required to be used, such as quicklime, coagulants (iron or aluminium based), soda ash and acids for adjusting the pH. Other methods of softening water include nanofiltration, electrodialysis, carbon nanotubes, capacitive deionization, reverse osmosis; although these processes consume large amounts of energy and the equipment is expensive to operate and maintain, primarily due to fouling. Therefore, especially in the case of remote construction sites where there is no direct potable water source, there is a need to develop an environmentally friendly, cost effective, low energy consumption process that would be an ideal complement to the water softening market.
Disclosure of Invention
The invention aims to solve the problems of sterilization and disinfection of softened drinking water and drinking water, and provides a drinking water treatment device for a construction site.
In order to achieve the purpose, the invention adopts the following technical scheme:
a drinking water treatment device for a construction site, comprising an anode chamber, a cathode chamber and an intermediate chamber, wherein the anode chamber, the cathode chamber and the intermediate chamber are separated by a heterogeneous ion exchange membrane; the heterogeneous ion exchange membrane comprises an anion exchange membrane disposed between the anode chamber and the intermediate chamber, and a cation exchange membrane disposed between the cathode chamber and the intermediate chamber; a titanium electrode anode is inserted into the anode chamber, a titanium electrode cathode is arranged in the cathode chamber, the titanium electrode anode and the titanium electrode cathode are connected with a power supply through leads, a tubular UV source is also inserted into the anode chamber, a sol-gel electrode coating is arranged on the surface of the anode, a water inlet is arranged below the middle chamber, and a water outlet is arranged below the anode chamber.
The volume ratio of the anode chamber to the middle chamber is 3-3.5: 1.
the titanium electrode anode and the titanium electrode cathode are both made by adopting titanium meshes with 8-18 meshes, the diameter of a metal wire of 0.01 and the open area of 67.24 percent, spot welding the titanium meshes into cylinders and then carrying out heat setting.
The reactor main body is made of engineering plastics.
The preparation method of the sol-gel electrode coating comprises the following steps:
magnetic stirring 5000mL of 0.1mol/L nitric acid, slowly adding 417mL of titanium isopropoxide, forming turbid suspension immediately after adding,
continuously stirring the suspension for 3-4 hr to gelatinize the suspension to form slightly turbid and bluish sol, dialyzing the sol after gelatinization to obtain high porosity coating,
the dialysis process increases the pH of the sol to a desired value of 8, thereby reducing electrostatic repulsion between colloidal particles in the sol, allowing the particles to slightly agglomerate,
the spectral/Por dialysis tubing had a flat width of 54 mm and a molecular weight cut-off of 3500kD, and prior to use, the tubing was washed in an aqueous solution of 0.001M EDTA and 2% by weight sodium bicarbonate,
after the sol was formed, it was applied to a titanium electrode by dip coating, and after coating, the electrode was heated in a furnace at 350 ℃ for 3 hours to form a xerogel coating.
Compared with the prior art, the invention provides a drinking water treatment device for a construction site, which has the following beneficial effects:
the device has the advantages of simple structure, convenient operation, environmental protection, high cost benefit and low energy consumption, and can remove 3.9log of bacteria by using the Escherichia coli (ATCC #15597TM) under the conditions that the inlet water concentration is 7.8x104log and the hydraulic retention time is 1 hour. The removal rate can be further improved by optimizing the configuration of the reactor for disinfection, and the technology adopts the photoelectrochemistry water treatment device to soften hard water and remove microorganisms, so that the removal rate of the hard water can reach 60 percent within 6 hours.
Drawings
Fig. 1 is a structural schematic diagram of a photoelectrochemical drinking water treatment device.
1. The cathode chamber, 2, the intermediate chamber, 3, the anode chamber, 4, the titanium electrode anode, 5, the titanium electrode cathode, 6, the sol-gel electrode coating, 7, the UV source, 8, the water outlet, 9, the water inlet, 10, the power supply, 11, the lead, 12, the anion exchange membrane, 13 and the cation exchange membrane.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "left", "right", "top", "bottom", "inner", "outer", and the like, indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are merely for convenience in describing the present invention and simplifying the description, and do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
Referring to fig. 1, a drinking water treatment apparatus for a construction site includes an anode chamber, a cathode chamber, and an intermediate chamber, which are separated by a heterogeneous ion exchange membrane; the heterogeneous ion exchange membrane comprises an anion exchange membrane 12 disposed between the anode chamber 3 and the intermediate chamber 2, and a cation exchange membrane 13 between the cathode chamber 1 and the intermediate chamber 3; a titanium electrode anode 4 is inserted into the anode chamber, a titanium electrode cathode 5 is arranged in the cathode chamber, the titanium electrode anode 4 and the titanium electrode cathode 5 are connected with a power supply 10 through a lead 11, a tubular UV source 7 (ultraviolet light) is also inserted into the anode chamber 3, a sol-gel electrode coating 6 is arranged on the surface of the anode 4, a water inlet 9 is arranged below the middle chamber, a water outlet 8 is arranged below the anode chamber, the volumes of the anode chamber 3 and the middle chamber 2 are 675 milliliters and 200 milliliters respectively, the titanium electrode anode 4 and the titanium electrode cathode 5 are made by adopting a titanium mesh with 8x 18 meshes, the diameter of a metal wire is 0.01, and the open area is 67.24 percent and is formed by heat setting after being spot welded into a cylinder.
In the present invention, during the water softening process, calcium and magnesium ions enter the cathode chamber through the cation exchange membrane, chloride ions and other anions enter the anode chamber through the anion exchange membrane, where any pathogenic bacteria are inactivated by ultraviolet light, and photochemical oxidation of any organic matter in water is performed by TiO2And (5) finishing the electrode. Photochemical reactions are intended to oxidize any refractory organics (such as personal care products and/or pharmaceuticals) and to partially supply electrons to remove hardness. To accelerate this process, especially when the organic concentration in the water is low, an external potential can be applied and the electrolysis of the water can produce small amounts of hydrogen and oxygen.
When the uv lamp was turned on, the hardness removal increased to 14% and current was generated. When the UV lamp was turned off, no hardness was removed, and no current was generated. These results indicate that uv light is an important component of softened water in PEWT systems.
The PEWT system was able to remove 3.9 logs of bacteria using E.coli at a feed concentration of 7.8X104log and a hydraulic retention time of 1 hour. This removal rate can be increased by optimizing the reactor configuration for sterilization.
The experimental result shows that the adoption of the photoelectrochemistry water treatment device can ensure that the hard water softening and microorganism removal can reach 60 percent of hard water removal rate within 6 hours, and the pure water can obtain 3.9log of bacteria removal rate within 1 hour.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (5)
1. A drinking water treatment device for construction sites, comprising an anode chamber (3), a cathode chamber (1) and an intermediate chamber (2), characterized in that: the anode chamber (3), the cathode chamber (1) and the intermediate chamber (2) are separated by a heterogeneous ion exchange membrane;
the heterogeneous ion exchange membrane comprises an anion exchange membrane (12) arranged between the anode chamber (3) and the intermediate chamber (2), and a cation exchange membrane (13) arranged between the cathode chamber (1) and the intermediate chamber (3);
a titanium electrode anode (4) is inserted into the anode chamber, a titanium electrode cathode (5) is arranged in the cathode chamber,
the titanium electrode anode (4) and the titanium electrode cathode (5) are connected with a power supply (10) through a lead (11),
a tubular UV source (7) is also inserted in the anode chamber (3),
the surface of the anode (4) is provided with a sol-gel electrode coating (6), a water inlet (9) is arranged below the middle chamber, and a water outlet (8) is arranged below the anode chamber.
2. The drinking water treatment device for the construction site according to claim 1, characterized in that the volume ratio of the anode chamber (3) to the intermediate chamber (2) is 3-3.5: 1.
3. a construction site drinking water treatment apparatus according to claim 1, wherein: the titanium electrode anode (4) and the titanium electrode cathode (5) are both made by adopting titanium meshes with 8x 18 meshes, the diameter of a metal wire is 0.01, and the opening area is 67.24 percent, and the titanium meshes are welded into cylinders and then are subjected to heat setting.
4. A construction site drinking water treatment apparatus according to claim 1, wherein: the reactor main body is made of engineering plastics.
5. The construction site drinking water treatment device according to claim 1, wherein the sol-gel electrode coating is prepared by the following method:
magnetic stirring 5000mL of 0.1mol/L nitric acid, slowly adding 417mL of titanium isopropoxide, forming turbid suspension immediately after adding,
continuously stirring the suspension for 3-4 hr to gelatinize the suspension to form slightly turbid and bluish sol, dialyzing the sol after gelatinization to obtain high porosity coating,
the dialysis process increases the pH of the sol to a desired value of 8, thereby reducing electrostatic repulsion between colloidal particles in the sol, allowing the particles to slightly agglomerate,
the spectral/Por dialysis tubing had a flat width of 54 mm and a molecular weight cut-off of 3500kD, and prior to use, the tubing was washed in an aqueous solution of 0.001M EDTA and 2% by weight sodium bicarbonate,
after the sol was formed, it was applied to a titanium electrode by dip coating, and after coating, the electrode was heated in a furnace at 350 ℃ for 3 hours to form a xerogel coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110519978.9A CN113149153A (en) | 2021-05-13 | 2021-05-13 | Building site drinking water treatment facilities |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110519978.9A CN113149153A (en) | 2021-05-13 | 2021-05-13 | Building site drinking water treatment facilities |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113149153A true CN113149153A (en) | 2021-07-23 |
Family
ID=76875082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110519978.9A Pending CN113149153A (en) | 2021-05-13 | 2021-05-13 | Building site drinking water treatment facilities |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113149153A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102066267A (en) * | 2008-08-07 | 2011-05-18 | 松下电器产业株式会社 | Demineralizer and hot water supply apparatus provided with the same |
| CN105253992A (en) * | 2015-11-11 | 2016-01-20 | 河南工业大学 | Method for removing perchlorate in water through electrodialysis ion exchange membrane bioreactor |
| CN105579402A (en) * | 2013-09-16 | 2016-05-11 | 德诺拉工业有限公司 | Electrolytic cell for the production of oxidising solutions |
| CN206940502U (en) * | 2017-04-21 | 2018-01-30 | 上海丁香环境科技有限公司 | A kind of electrochemical desalting water softening device of efficiently spontaneous crystallization |
| CN109626523A (en) * | 2019-02-01 | 2019-04-16 | 华中师范大学 | Novel photoelectric catalytic reactor based on amberplex and its application in the treatment of waste water |
| CN109626417A (en) * | 2018-12-06 | 2019-04-16 | 东莞理工学院 | A kind of TiO2-XThe batch production preparation method of material |
| CN111170529A (en) * | 2018-11-09 | 2020-05-19 | 王宇 | Circulating water sterilization and scale inhibition method |
| CN111646632A (en) * | 2020-05-11 | 2020-09-11 | 南京岱蒙特科技有限公司 | Green energy-saving photoelectrocatalysis water treatment system and water treatment method thereof |
-
2021
- 2021-05-13 CN CN202110519978.9A patent/CN113149153A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102066267A (en) * | 2008-08-07 | 2011-05-18 | 松下电器产业株式会社 | Demineralizer and hot water supply apparatus provided with the same |
| CN105579402A (en) * | 2013-09-16 | 2016-05-11 | 德诺拉工业有限公司 | Electrolytic cell for the production of oxidising solutions |
| CN105253992A (en) * | 2015-11-11 | 2016-01-20 | 河南工业大学 | Method for removing perchlorate in water through electrodialysis ion exchange membrane bioreactor |
| CN206940502U (en) * | 2017-04-21 | 2018-01-30 | 上海丁香环境科技有限公司 | A kind of electrochemical desalting water softening device of efficiently spontaneous crystallization |
| CN111170529A (en) * | 2018-11-09 | 2020-05-19 | 王宇 | Circulating water sterilization and scale inhibition method |
| CN109626417A (en) * | 2018-12-06 | 2019-04-16 | 东莞理工学院 | A kind of TiO2-XThe batch production preparation method of material |
| CN109626523A (en) * | 2019-02-01 | 2019-04-16 | 华中师范大学 | Novel photoelectric catalytic reactor based on amberplex and its application in the treatment of waste water |
| CN111646632A (en) * | 2020-05-11 | 2020-09-11 | 南京岱蒙特科技有限公司 | Green energy-saving photoelectrocatalysis water treatment system and water treatment method thereof |
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