CN113061371A - Anti-corrosion powder coating and preparation method thereof - Google Patents
Anti-corrosion powder coating and preparation method thereof Download PDFInfo
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- CN113061371A CN113061371A CN202110220985.9A CN202110220985A CN113061371A CN 113061371 A CN113061371 A CN 113061371A CN 202110220985 A CN202110220985 A CN 202110220985A CN 113061371 A CN113061371 A CN 113061371A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anticorrosive powder coating which is prepared from the following raw materials in parts by weight: 5-7 parts of polyvinyl chloride paste resin, 2-3 parts of triglycidyl isocyanurate, 0.4-1 part of di-n-octyl tin isooctyl bis-thioglycolate, 10-14 parts of triethanolamine borate, 110-130 parts of high-density polyethylene and 30-40 parts of polyester modified solution.
Description
Technical Field
The invention belongs to the field of coatings, and particularly relates to an anti-corrosion powder coating and a preparation method thereof.
Background
The powder coating is a solid powder synthetic resin coating composed of solid resin, pigment, filler, auxiliary agent and the like. Unlike conventional solvent-based coatings and water-based coatings, the dispersion medium is not a solvent and water, but air. It has the characteristics of no solvent pollution, 100 percent film forming and low energy consumption. Powder coatings fall into two broad categories, thermoplastic and thermosetting. The appearance (luster and leveling property) of a coating film of the thermoplastic powder coating is poor, and the adhesion between the thermoplastic powder coating and metal is also poor, so the thermoplastic powder coating is rarely applied in the field of automobile coating. The appearance, various mechanical properties and corrosion resistance of a paint film formed by the paint can meet the requirements of automobile coating. The polyethylene powder coating has excellent corrosion resistance, chemical resistance, electrical insulation and ultraviolet radiation resistance. The disadvantages are low mechanical strength and poor adhesion to the substrate. Can be used for chemical tank, impeller, pump, inner wall of pipeline, meter shell, metal plate, screen plate in refrigerator, automobile parts, etc.
Disclosure of Invention
The invention aims to provide an anti-corrosion powder coating and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
an anti-corrosion powder coating is composed of the following raw materials in parts by weight:
5-7 parts of polyvinyl chloride paste resin, 2-3 parts of triglycidyl isocyanurate, 0.4-1 part of isooctyl bis (n-octyl) tin bis (thioglycolate), 10-14 parts of triethanolamine borate, 110-130 parts of high-density polyethylene and 30-40 parts of polyester modified solution.
The polyester modified solution is prepared from the following raw materials in parts by weight:
3-5 parts of aminopropyltriethoxysilane, 1-hydroxyethyl-2-oleyl imidazoline, 30-40 parts of methyl methacrylate, 4-7 parts of fumed silica, 1-2 parts of dicumyl peroxide, 1-2 parts of a dispersant and 2-3 parts of diethylenetriamine.
The dispersant is one of glyceryl monostearate and sp-80.
The preparation method of the polyester modified solution comprises the following steps:
(1) adding dicumyl peroxide into acetone with the weight 10-17 times that of the dicumyl peroxide, and uniformly stirring to obtain an acetone dispersion liquid;
(2) mixing gas-phase silicon dioxide and aminopropyltriethoxysilane, adding into deionized water with the weight of 20-30 times of that of the mixture, and performing ultrasonic treatment for 10-20 minutes to obtain a silicon dioxide dispersion liquid;
(3) mixing diethylenetriamine and methyl methacrylate, adding the mixture into the silicon dioxide dispersion liquid, stirring the mixture evenly, feeding the mixture into a reaction kettle, introducing nitrogen, adjusting the temperature of the reaction kettle to be 70-75 ℃, adding the acetone dispersion liquid, keeping the temperature and stirring the mixture for 3-5 hours, discharging the mixture, adding 1-hydroxyethyl-2-oil-based imidazoline and a dispersing agent, and stirring the mixture evenly to obtain the silicon dioxide dispersion liquid.
A method for preparing an anti-corrosive powder coating, comprising the steps of:
(1) adding polyvinyl chloride paste resin into the polyester modified solution, raising the temperature to 60-70 ℃, keeping the temperature and stirring for 1-2 hours, performing rotary evaporation, and removing the solvent to obtain modified resin;
(2) mixing high-density polyethylene, triglycidyl isocyanurate and modified resin, preserving heat at the temperature of 130-140 ℃ for 100-130 minutes, adding isooctyl bis (n-octyl) tin bis (thioglycollate) and triethanolamine borate, stirring uniformly, feeding into an extruder, melting and extruding, cooling, granulating and sieving to obtain the polyethylene glycol/ethylene glycol/propylene glycol composite material.
The sieving in the step (2) is to sieve the mixture by a sieve of 80 to 200 meshes.
The invention has the advantages that:
the polyester modified solution has the beneficial effects that the methyl methacrylate is used as a monomer, the polymerization is carried out under the action of an initiator, and the fumed silica is doped to obtain the polyester modified solution, so that the comprehensive mechanical property of a finished product can be improved, the dispersion property among raw materials can be improved, and the mechanical stability and the strength of a finished product coating can be improved.
Detailed Description
Example 1
An anti-corrosion powder coating is composed of the following raw materials in parts by weight:
polyvinyl chloride paste resin 5, triglycidyl isocyanurate 2, isooctyl bis (mercaptoacetate) di-n-octyl tin 0.4, triethanolamine borate 10, high-density polyethylene 110 and polyester modified solution 30.
The polyester modified solution is prepared from the following raw materials in parts by weight:
aminopropyl triethoxysilane 3, 1-hydroxyethyl-2-oleyl imidazoline 1, methyl methacrylate 30, fumed silica 4, dicumyl peroxide 1, a dispersant 1 and diethylenetriamine 2.
The dispersant is glyceryl monostearate.
The preparation method of the polyester modified solution comprises the following steps:
(1) adding dicumyl peroxide into acetone with the weight being 10 times of that of the dicumyl peroxide, and uniformly stirring to obtain an acetone dispersion liquid;
(2) mixing gas-phase silicon dioxide and aminopropyltriethoxysilane, adding the mixture into deionized water with the weight being 20 times that of the mixture, and performing ultrasonic treatment for 10 minutes to obtain silicon dioxide dispersion liquid;
(3) mixing diethylenetriamine and methyl methacrylate, adding the mixture into the silicon dioxide dispersion liquid, stirring the mixture evenly, feeding the mixture into a reaction kettle, introducing nitrogen, adjusting the temperature of the reaction kettle to 70 ℃, adding the acetone dispersion liquid, keeping the temperature and stirring the mixture for 3 hours, discharging the mixture, adding 1-hydroxyethyl-2-oil-based imidazoline and a dispersing agent, and stirring the mixture evenly to obtain the silicon dioxide dispersion liquid.
A method for preparing an anti-corrosive powder coating, comprising the steps of:
(1) adding polyvinyl chloride paste resin into a polyester modified solution, raising the temperature to 60 ℃, keeping the temperature and stirring for 1 hour, performing rotary evaporation, and removing the solvent to obtain modified resin;
(2) mixing high-density polyethylene, triglycidyl isocyanurate and modified resin, keeping the temperature at 130 ℃ for 100 minutes, adding isooctyl dimercaptoacetate and triethanolamine borate, stirring uniformly, feeding into an extruder, carrying out melt extrusion, cooling, granulating and sieving to obtain the high-density polyethylene-modified polyurethane adhesive.
The sieving in the step (2) is to sieve the mixture by a sieve of 80 to 200 meshes.
Example 2
An anti-corrosion powder coating is composed of the following raw materials in parts by weight:
polyvinyl chloride paste resin 7, triglycidyl isocyanurate 3, isooctyl bis (mercaptoacetate) di-n-octyl tin 1, triethanolamine borate 14, high-density polyethylene 130 and polyester modified solution 40.
The polyester modified solution is prepared from the following raw materials in parts by weight:
aminopropyl triethoxysilane 3, 1-hydroxyethyl-2-oleyl imidazoline 2, methyl methacrylate 40, fumed silica 4, dicumyl peroxide 2, a dispersant 2 and diethylenetriamine 3.
The dispersing agent is sp-80.
The preparation method of the polyester modified solution comprises the following steps:
(1) adding dicumyl peroxide into acetone with the weight 17 times that of the dicumyl peroxide, and uniformly stirring to obtain an acetone dispersion liquid;
(2) mixing gas-phase silicon dioxide and aminopropyltriethoxysilane, adding the mixture into deionized water with the weight 30 times that of the mixture, and performing ultrasonic treatment for 20 minutes to obtain silicon dioxide dispersion liquid;
(3) mixing diethylenetriamine and methyl methacrylate, adding the mixture into the silicon dioxide dispersion liquid, stirring the mixture evenly, feeding the mixture into a reaction kettle, introducing nitrogen, adjusting the temperature of the reaction kettle to 75 ℃, adding the acetone dispersion liquid, keeping the temperature and stirring the mixture for 5 hours, discharging the mixture, adding 1-hydroxyethyl-2-oil-based imidazoline and a dispersing agent, and stirring the mixture evenly to obtain the silicon dioxide dispersion liquid.
A method for preparing an anti-corrosive powder coating, comprising the steps of:
(1) adding polyvinyl chloride paste resin into a polyester modified solution, raising the temperature to 70 ℃, keeping the temperature and stirring for 2 hours, performing rotary evaporation, and removing a solvent to obtain modified resin;
(2) mixing high-density polyethylene, triglycidyl isocyanurate and modified resin, keeping the temperature at 140 ℃ for 130 minutes, adding isooctyl dimercaptoacetate and triethanolamine borate, stirring uniformly, feeding into an extruder, carrying out melt extrusion, cooling, granulating and sieving to obtain the high-density polyethylene-modified polyurethane adhesive.
The sieving in the step (2) is 200-mesh sieving.
Comparative example 1
The powder coating is composed of the following raw materials in parts by weight:
polyvinyl chloride paste resin 7, triglycidyl isocyanurate 2, isooctyl bis (mercaptoacetate) di-n-octyl tin 0.4, triethanolamine borate 10 and high-density polyethylene 110.
A method for preparing an anti-corrosive powder coating, comprising the steps of:
mixing high-density polyethylene, triglycidyl isocyanurate and polyvinyl chloride paste resin, preserving heat at 130 ℃ for 100 minutes, adding isooctyl bis (n-octyl) tin bis (thioglycollate) and triethanolamine borate, stirring uniformly, feeding into an extruder, carrying out melt extrusion, cooling, granulating, and sieving with a 80-200-mesh sieve to obtain the high-density polyethylene-vinyl isocyanurate-polyvinyl chloride paste.
And (3) performance testing:
Claims (6)
1. the anticorrosive powder coating is characterized by comprising the following raw materials in parts by weight:
5-7 parts of polyvinyl chloride paste resin, 2-3 parts of triglycidyl isocyanurate, 0.4-1 part of isooctyl bis (n-octyl) tin bis (thioglycolate), 10-14 parts of triethanolamine borate, 110-130 parts of high-density polyethylene and 30-40 parts of polyester modified solution.
2. The anti-corrosion powder coating of claim 1, wherein said polyester modification solution is comprised of the following raw materials in parts by weight:
3-5 parts of aminopropyltriethoxysilane, 1-hydroxyethyl-2-oleyl imidazoline, 30-40 parts of methyl methacrylate, 4-7 parts of fumed silica, 1-2 parts of dicumyl peroxide, 1-2 parts of a dispersant and 2-3 parts of diethylenetriamine.
3. An anti-corrosive powder coating according to claim 2, wherein said dispersant is one of glyceryl monostearate and sp-80.
4. The anti-corrosion powder coating of claim 2, wherein said polyester modification solution is prepared by a process comprising the steps of:
(1) adding dicumyl peroxide into acetone with the weight 10-17 times that of the dicumyl peroxide, and uniformly stirring to obtain an acetone dispersion liquid;
(2) mixing gas-phase silicon dioxide and aminopropyltriethoxysilane, adding into deionized water with the weight of 20-30 times of that of the mixture, and performing ultrasonic treatment for 10-20 minutes to obtain a silicon dioxide dispersion liquid;
(3) mixing diethylenetriamine and methyl methacrylate, adding the mixture into the silicon dioxide dispersion liquid, stirring the mixture evenly, feeding the mixture into a reaction kettle, introducing nitrogen, adjusting the temperature of the reaction kettle to be 70-75 ℃, adding the acetone dispersion liquid, keeping the temperature and stirring the mixture for 3-5 hours, discharging the mixture, adding 1-hydroxyethyl-2-oil-based imidazoline and a dispersing agent, and stirring the mixture evenly to obtain the silicon dioxide dispersion liquid.
5. A method of preparing the anti-corrosion powder coating of claim 1, comprising the steps of:
(1) adding polyvinyl chloride paste resin into the polyester modified solution, raising the temperature to 60-70 ℃, keeping the temperature and stirring for 1-2 hours, performing rotary evaporation, and removing the solvent to obtain modified resin;
(2) mixing high-density polyethylene, triglycidyl isocyanurate and modified resin, preserving heat at the temperature of 130-140 ℃ for 100-130 minutes, adding isooctyl bis (n-octyl) tin bis (thioglycollate) and triethanolamine borate, stirring uniformly, feeding into an extruder, melting and extruding, cooling, granulating and sieving to obtain the polyethylene glycol/ethylene glycol/propylene glycol composite material.
6. The method of claim 5, wherein the sieving in step (2) is through an 80-200 mesh sieve.
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CN202110220985.9A CN113061371A (en) | 2021-02-26 | 2021-02-26 | Anti-corrosion powder coating and preparation method thereof |
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CN202110220985.9A CN113061371A (en) | 2021-02-26 | 2021-02-26 | Anti-corrosion powder coating and preparation method thereof |
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Citations (8)
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CN103756423A (en) * | 2014-01-15 | 2014-04-30 | 芜湖市宝艺游乐科技设备有限公司 | Cobaltiferous heat dissipation coating |
CN104693949A (en) * | 2015-03-18 | 2015-06-10 | 黄山贝诺科技有限公司 | Thermoplastic powder coating and preparation method thereof |
CN105348941A (en) * | 2015-11-18 | 2016-02-24 | 扬州凯尔化工有限公司 | PVC (polyvinyl chloride) electrostatic spraying powder coating |
CN107011780A (en) * | 2017-05-10 | 2017-08-04 | 江西卓照光电股份有限公司 | A kind of preparation method of LED street lamp thermal dispersant coatings |
CN108641493A (en) * | 2018-03-26 | 2018-10-12 | 繁昌县盛民机械制造有限公司 | A kind of intercalation powdery paints and preparation method thereof |
CN109486293A (en) * | 2018-12-16 | 2019-03-19 | 陈绪涛 | A kind of LED lamp graphene powder coating and preparation method thereof |
CN109722101A (en) * | 2018-12-30 | 2019-05-07 | 陈东宁 | A kind of polypropylene graphene heat radiation coating and preparation method thereof |
CN111334132A (en) * | 2020-03-02 | 2020-06-26 | 成都新柯力化工科技有限公司 | High-sphericity superfine thermoplastic powder coating and preparation method thereof |
-
2021
- 2021-02-26 CN CN202110220985.9A patent/CN113061371A/en not_active Withdrawn
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103756423A (en) * | 2014-01-15 | 2014-04-30 | 芜湖市宝艺游乐科技设备有限公司 | Cobaltiferous heat dissipation coating |
CN104693949A (en) * | 2015-03-18 | 2015-06-10 | 黄山贝诺科技有限公司 | Thermoplastic powder coating and preparation method thereof |
CN105348941A (en) * | 2015-11-18 | 2016-02-24 | 扬州凯尔化工有限公司 | PVC (polyvinyl chloride) electrostatic spraying powder coating |
CN107011780A (en) * | 2017-05-10 | 2017-08-04 | 江西卓照光电股份有限公司 | A kind of preparation method of LED street lamp thermal dispersant coatings |
CN108641493A (en) * | 2018-03-26 | 2018-10-12 | 繁昌县盛民机械制造有限公司 | A kind of intercalation powdery paints and preparation method thereof |
CN109486293A (en) * | 2018-12-16 | 2019-03-19 | 陈绪涛 | A kind of LED lamp graphene powder coating and preparation method thereof |
CN109722101A (en) * | 2018-12-30 | 2019-05-07 | 陈东宁 | A kind of polypropylene graphene heat radiation coating and preparation method thereof |
CN111334132A (en) * | 2020-03-02 | 2020-06-26 | 成都新柯力化工科技有限公司 | High-sphericity superfine thermoplastic powder coating and preparation method thereof |
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Application publication date: 20210702 |