CN113045337A - Method for repairing and protecting surface of stone cultural relic - Google Patents
Method for repairing and protecting surface of stone cultural relic Download PDFInfo
- Publication number
- CN113045337A CN113045337A CN202110262849.6A CN202110262849A CN113045337A CN 113045337 A CN113045337 A CN 113045337A CN 202110262849 A CN202110262849 A CN 202110262849A CN 113045337 A CN113045337 A CN 113045337A
- Authority
- CN
- China
- Prior art keywords
- stone
- repairing
- protecting
- relics
- stone cultural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004575 stone Substances 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000004922 lacquer Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910001868 water Inorganic materials 0.000 claims abstract description 20
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 230000004224 protection Effects 0.000 claims abstract description 6
- 238000007789 sealing Methods 0.000 claims abstract description 6
- 239000003973 paint Substances 0.000 claims description 37
- 238000003756 stirring Methods 0.000 claims description 24
- 238000004458 analytical method Methods 0.000 claims description 12
- 238000003303 reheating Methods 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 7
- RMTXUPIIESNLPW-UHFFFAOYSA-N 1,2-dihydroxy-3-(pentadeca-8,11-dienyl)benzene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1O RMTXUPIIESNLPW-UHFFFAOYSA-N 0.000 claims description 6
- QARRXYBJLBIVAK-UEMSJJPVSA-N 3-[(8e,11e)-pentadeca-8,11-dienyl]benzene-1,2-diol;3-[(8e,11e)-pentadeca-8,11,14-trienyl]benzene-1,2-diol;3-[(8e,11e,13e)-pentadeca-8,11,13-trienyl]benzene-1,2-diol;3-[(e)-pentadec-8-enyl]benzene-1,2-diol;3-pentadecylbenzene-1,2-diol Chemical compound CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O.CCCCCC\C=C\CCCCCCCC1=CC=CC(O)=C1O.CCC\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.C\C=C\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.OC1=CC=CC(CCCCCCC\C=C\C\C=C\CC=C)=C1O QARRXYBJLBIVAK-UEMSJJPVSA-N 0.000 claims description 6
- IYROWZYPEIMDDN-UHFFFAOYSA-N 3-n-pentadec-8,11,13-trienyl catechol Natural products CC=CC=CCC=CCCCCCCCC1=CC=CC(O)=C1O IYROWZYPEIMDDN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000008213 purified water Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- DQTMTQZSOJMZSF-UHFFFAOYSA-N urushiol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DQTMTQZSOJMZSF-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 102000003886 Glycoproteins Human genes 0.000 claims description 5
- 108090000288 Glycoproteins Proteins 0.000 claims description 5
- 238000003916 acid precipitation Methods 0.000 claims description 5
- 238000003912 environmental pollution Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- 235000014220 Rhus chinensis Nutrition 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 241000598860 Garcinia hanburyi Species 0.000 claims description 3
- 240000001972 Gardenia jasminoides Species 0.000 claims description 3
- 229920001131 Pulp (paper) Polymers 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 230000002308 calcification Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000004455 differential thermal analysis Methods 0.000 claims description 3
- 239000003814 drug Substances 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229940117709 gamboge Drugs 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 230000009545 invasion Effects 0.000 claims description 3
- 238000010297 mechanical methods and process Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000013020 steam cleaning Methods 0.000 claims description 3
- 239000002383 tung oil Substances 0.000 claims description 3
- 240000003152 Rhus chinensis Species 0.000 claims 1
- 238000002050 diffraction method Methods 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000009413 insulation Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 241000208225 Rhus Species 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
- C04B41/5315—Cleaning compositions, e.g. for removing hardened cement from ceramic tiles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Plant Pathology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention provides a method for repairing and protecting the surface of a stone cultural relic, which comprises the following steps of firstly, checking the stone cultural relic to be repaired to determine the damage condition of the stone cultural relic; step two, removing stains on the surface of the stone cultural relics, cleaning, and then removing water of the stone cultural relics for later use; thirdly, selecting stone with the same material as the stone cultural relic to be repaired, crushing the stone, and repairing the stone cultural relic to be repaired by using an adhesive; and step four, performing sealing and protecting protection treatment on the stone cultural relics repaired in the step three. According to the repairing and surface protecting method provided by the invention, the stone cultural relic can be effectively repaired by adopting the method, the space limitation cannot be caused by coating the method on the surface of the stone cultural relic, and the vision cannot be influenced by coating the transparent lacquer. In addition, the transparent lacquer has the advantages of heat resistance, durability, corrosion resistance and the like, and simultaneously has good electric insulation performance and certain radiation protection performance.
Description
Technical Field
The invention relates to the field of stone cultural relic repair, in particular to a method for repairing and protecting the surface of a stone cultural relic.
Background
The stone cultural relics are numerous and are mainly seriously damaged by environmental pollution and acid rain, and the environmental pollution and the erosion speed of sulfuric acid rain on the stone cultural relics in nearly ten years exceed the past hundreds of years no matter whether the stone cultural relics are various stones such as marble, dolomite, limestone and the like. The acid gases such as sulfur dioxide and nitrogen dioxide in the air are dissolved in the rain fog and the wet surface, and the action of factors such as oxygen is added, so that dilute acid is formed, the acid is thickened along with the evaporation of water, when the acid and the stone cultural relic are corroded chemically, how are the harmful substances separated to protect the stone cultural relic? In recent decades, the stone cultural relics are covered by glass covers to reduce the damage degree of the stone cultural relics, but the stone cultural relics are influenced by space and have unsatisfactory visual effect. The paraffin is dissolved in turpentine to repair stone materials, and the effect is not ideal. And later, lime water to protect and strengthen limestone, zinc and aluminum stearate, sulfate or phosphate to form a protective layer, and later silica sol to protect and strengthen sandstone, etc., are not satisfactory. It is then natural to think of surface coatings which isolate the surface of stone relics from sulfur dioxide, nitrogen dioxide and water, and which are usually coated with various surface protection agents.
The method for protecting the stone cultural relics by using the surface coated with the protective agent is the simplest method for slowing down the erosion. However, a satisfactory surface treatment method free from defects has not been provided so far.
Disclosure of Invention
The invention aims to provide a method for repairing and protecting the surface of a stone cultural relic, which is not limited by space and does not influence vision, and can effectively slow down the erosion of the stone cultural relic.
In order to achieve the above object, the embodiments of the present invention provide the following technical solutions:
according to a first aspect of embodiments of the present invention, there is provided a method for repairing and protecting a surface of a stone relic, comprising the steps of:
the method comprises the following steps of firstly, examining the stone cultural relics to be repaired to determine the damage condition of the stone cultural relics;
step two, removing stains on the surface of the stone cultural relics, cleaning, and then removing water of the stone cultural relics for later use;
thirdly, selecting stone with the same material as the stone cultural relic to be repaired, crushing the stone, and repairing the stone cultural relic to be repaired by using an adhesive;
and step four, performing sealing and protecting protection treatment on the stone cultural relics repaired in the step three.
Further, the damage condition of the stone cultural relics in the step one comprises any one or the combination of more than two of environmental pollution, acid rain damage, weathering, calcification and biological invasion.
Further, the method for detecting the damage of the stone cultural relics in the first step comprises any one or the combination of more than two of component analysis, crystal phase analysis, mechanical state analysis, ultrasonic nondestructive inspection, electrical prospecting crack detection, electron microscopy analysis, X-ray diffraction analysis and differential thermal analysis.
Further, the stains in the second step include any one or a combination of two or more of general stains, attached salts and attached organisms; the general stains comprise any one or the combination of more than two of dust, smoke scale and biological garbage.
Further, the method for removing the general stains comprises any one or the combination of more than two of water washing, chemical solvent cleaning, mechanical clearing and thermal clearing; the method for removing the attached salt comprises any one or combination of more than two of water washing method, paper pulp method and mechanical method; the method for removing the attached organisms comprises any one or the combination of more than two of liquid medicine killing and removing, chemical cleaning, steam cleaning, particle spraying cleaning and laser cleaning.
Further, the binder in step three comprises a lacquer.
Further, the third step comprises the steps of grinding the stone into powder of 40 meshes, 60 meshes and 80 meshes, and mixing the powder with the adhesive to repair the stone cultural relic to be repaired.
Further, the fourth step comprises the step of carrying out sealing and protecting treatment on the stone cultural relics repaired in the third step by adopting transparent lacquer.
Further, the raw materials for preparing the transparent lacquer comprise the following components in parts by weight: 60-80 parts of urushiol, 3-6 parts of gum, 0.7-1 part of water-insoluble glycoprotein, 0.1-0.5 part of sumac enzyme and 15-20 parts of water.
Further, the preparation method of the transparent lacquer comprises the following steps:
s1, selecting raw lacquer for later use;
s2, filtering the raw lacquer for multiple times, and collecting screen residue;
s3, placing the screenings collected in the S2 in a container, stirring at normal temperature, and adding purified water during stirring, wherein the adding amount of the purified water is less than or equal to one tenth of the screenings;
s4, sun-curing the screen residue stirred at normal temperature to prepare the semi-transparent paint, wherein the sun-curing temperature is less than or equal to 45 ℃, the sun-curing time is less than or equal to 3 hours, and the water content of the sun-cured semi-transparent paint is 4% -6%;
s5, placing the semi-transparent paint prepared in the S4 into a container, boiling the semi-transparent paint with Chinese fire, continuously stirring, heating the semi-transparent paint to 50 ℃, taking the container out of the fire, continuously stirring until the temperature of the semi-transparent paint is 30 ℃, reheating the semi-transparent paint, repeatedly stirring for three times, adding 20% of cooked pure tung oil, reheating the semi-transparent paint to 60 ℃, continuously stirring, cooling the semi-transparent paint, repeatedly stirring for three times, adding 10% of gardenia oil, reheating the semi-transparent paint to 70 ℃, continuously stirring after the semi-transparent paint is removed from the fire, adding 8% of gamboge solution, and observing that the paint liquid is a drawable Newtonian body to prepare the transparent lacquer, wherein the container.
The embodiment of the invention has the following advantages: the embodiment of the invention provides a method for repairing and protecting the surface of a stone cultural relic. In addition, the transparent lacquer has the advantages of heat resistance, durability, corrosion resistance, strong acid resistance, strong alkali resistance, solvent resistance, moisture resistance, sterilization resistance, good soil resistance and the like, and has good electrical insulation performance and certain radiation protection performance. The transparent lacquer has excellent physical and mechanical properties, a lacquer film is hard (the hardness of the lacquer film reaches 0.65-0.89 lacquer film value/glass value), the wear-resisting strength of the lacquer film is high, the lacquer film is bright, the brightness is elegant, and the adhesive force is strong.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments, and it should be understood that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The embodiment provides a method for repairing and protecting the surface of a stone cultural relic, which comprises the following steps:
the method comprises the following steps of firstly, examining the stone cultural relics to be repaired to determine the damage conditions of the stone cultural relics, wherein the damage conditions include any one or combination of more than two of environmental pollution, acid rain damage, weathering, calcification and biological invasion, but are not limited to the above; the method for detecting the damage of the stone cultural relics comprises any one or the combination of more than two of component analysis, crystalline phase analysis, mechanical state analysis, ultrasonic nondestructive inspection, electrical prospecting crack detection, electron microscopy analysis, X-ray diffraction analysis and differential thermal analysis.
Step two, removing stains on the surface of the stone cultural relics, cleaning, and then removing water of the stone cultural relics for later use; the stains include any one or the combination of more than two of general stains, attached salt and attached organisms; the general stains comprise any one or the combination of more than two of dust, smoke scale and biological garbage; the method for removing the general stains comprises any one or the combination of more than two of water washing, chemical solvent cleaning, mechanical clearing and thermal clearing; the method for removing the attached salt comprises any one or combination of more than two of water washing method, paper pulp method and mechanical method; the method for removing the attached organisms comprises any one or the combination of more than two of liquid medicine killing and removing, chemical cleaning, steam cleaning, particle spraying cleaning and laser cleaning.
Thirdly, selecting stone materials with the same material as the stone cultural relics to be repaired, grinding the stone materials into powder of 40 meshes, 60 meshes and 80 meshes, and repairing the stone cultural relics to be repaired after mixing the powder with the adhesive; the binder includes a lacquer, but is not limited thereto.
And step four, adopting transparent lacquer to carry out sealing and protecting treatment on the stone cultural relics repaired in the step three.
Example 2
On the basis of the technical scheme of the embodiment 1, the transparent lacquer is provided, and raw materials for preparing the transparent lacquer comprise the following components in parts by weight: 60 parts of urushiol, 3 parts of gum, 0.7 part of water-insoluble glycoprotein, 0.1 part of sumac enzyme and 15 parts of water.
Example 3
The embodiment provides a transparent lacquer, and raw materials for preparing the transparent lacquer comprise the following components in parts by weight: 80 parts of urushiol, 6 parts of gum, 1 part of water-insoluble glycoprotein, 0.5 part of urushiol and 20 parts of water.
Example 4
The embodiment provides a transparent lacquer, and raw materials for preparing the transparent lacquer comprise the following components in parts by weight: 70 parts of urushiol, 4.5 parts of gum, 0.85 part of water-insoluble glycoprotein, 0.3 part of sumac enzyme and 17.5 parts of water.
Example 5
On the basis of the technical scheme of the embodiment 2-4, the preparation method of the transparent lacquer comprises the following steps:
s1, selecting raw lacquer for later use;
s2, filtering the raw lacquer for multiple times, and collecting screen residue;
s3, placing the screenings collected in the S2 in a container, stirring at normal temperature, and adding purified water during stirring, wherein the adding amount of the purified water is less than or equal to one tenth of the screenings;
s4, sun-curing the screen residue stirred at normal temperature to prepare the semi-transparent paint, wherein the sun-curing temperature is less than or equal to 45 ℃, the sun-curing time is less than or equal to 3 hours, and the water content of the sun-cured semi-transparent paint is 4% -6%;
s5, placing the semi-transparent paint prepared in the S4 into a container, boiling the semi-transparent paint with Chinese fire, continuously stirring, heating the semi-transparent paint to 50 ℃, taking the container out of the fire, continuously stirring until the temperature of the semi-transparent paint is 30 ℃, reheating the semi-transparent paint, repeatedly stirring for three times, adding 20% of cooked pure tung oil, reheating the semi-transparent paint to 60 ℃, continuously stirring, cooling the semi-transparent paint, repeatedly stirring for three times, adding 10% of gardenia oil, reheating the semi-transparent paint to 70 ℃, continuously stirring after the semi-transparent paint is removed from the fire, adding 8% of gamboge solution, and observing that the paint liquid is a drawable Newtonian body to prepare the transparent lacquer, wherein the container.
Comparative example 1
The performance of the transparent lacquers prepared in examples 2-4 was tested by using the lacquer as the experimental group and the lacquer as the control group, and the test results are shown in the following table:
the above results show that: the paint film has extremely strong ultraviolet resistance.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (10)
1. A method for repairing and protecting the surface of stone cultural relics is characterized by comprising the following steps:
the method comprises the following steps of firstly, examining the stone cultural relics to be repaired to determine the damage condition of the stone cultural relics;
step two, removing stains on the surface of the stone cultural relics, cleaning, and then removing water of the stone cultural relics for later use;
thirdly, selecting stone with the same material as the stone cultural relic to be repaired, crushing the stone, and repairing the stone cultural relic to be repaired by using an adhesive;
and step four, performing sealing and protecting protection treatment on the stone cultural relics repaired in the step three.
2. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: the damage condition of the stone cultural relics in the first step comprises any one or the combination of more than two of environmental pollution, acid rain damage, weathering, calcification and biological invasion.
3. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: the method for detecting the damage of the stone cultural relics in the first step comprises any one or the combination of more than two of component analysis, crystalline phase analysis, mechanical state analysis, ultrasonic nondestructive inspection, electrical prospecting crack detection, electron microscope analysis, X diffraction analysis and differential thermal analysis.
4. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: the stains in the second step include any one or a combination of two or more of general stains, attached salts and attached organisms; the general stains comprise any one or the combination of more than two of dust, smoke scale and biological garbage.
5. The method for repairing and protecting the surface of stone relics, according to the claim 4, characterized in that: the method for removing the general stains comprises any one or the combination of more than two of water washing, chemical solvent cleaning, mechanical clearing and thermal clearing; the method for removing the attached salt comprises any one or combination of more than two of water washing method, paper pulp method and mechanical method; the method for removing the attached organisms comprises any one or the combination of more than two of liquid medicine killing and removing, chemical cleaning, steam cleaning, particle spraying cleaning and laser cleaning.
6. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: the binder in step three comprises a lacquer.
7. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: and the third step comprises the steps of grinding the stone into powder of 40 meshes, 60 meshes and 80 meshes, and repairing the stone cultural relic to be repaired after mixing the powder and the adhesive.
8. The method for repairing and protecting the surface of stone relics of claim 1, which is characterized in that: and the fourth step comprises the step of carrying out sealing and protecting treatment on the stone cultural relics repaired in the third step by adopting transparent lacquer.
9. The method for repairing and protecting the surface of stone relics of claim 8, which is characterized in that: the raw materials for preparing the transparent lacquer comprise the following components in parts by weight: 60-80 parts of urushiol, 3-6 parts of gum, 0.7-1 part of water-insoluble glycoprotein, 0.1-0.5 part of sumac enzyme and 15-20 parts of water.
10. The method for repairing and protecting the surface of the stone relic as claimed in claim 9, wherein the method for preparing the transparent lacquer comprises the following steps:
s1, selecting raw lacquer for later use;
s2, filtering the raw lacquer for multiple times, and collecting screen residue;
s3, placing the screenings collected in the S2 in a container, stirring at normal temperature, and adding purified water during stirring, wherein the adding amount of the purified water is less than or equal to one tenth of the screenings;
s4, sun-curing the screen residue stirred at normal temperature to prepare the semi-transparent paint, wherein the sun-curing temperature is less than or equal to 45 ℃, the sun-curing time is less than or equal to 3 hours, and the water content of the sun-cured semi-transparent paint is 4% -6%;
s5, placing the semi-transparent paint prepared in the S4 into a container, boiling the semi-transparent paint with Chinese fire, continuously stirring, heating the semi-transparent paint to 50 ℃, taking the container out of the fire, continuously stirring until the temperature of the semi-transparent paint is 30 ℃, reheating the semi-transparent paint, repeatedly stirring for three times, adding 20% of cooked pure tung oil, reheating the semi-transparent paint to 60 ℃, continuously stirring, cooling the semi-transparent paint, repeatedly stirring for three times, adding 10% of gardenia oil, reheating the semi-transparent paint to 70 ℃, continuously stirring after the semi-transparent paint is removed from the fire, adding 8% of gamboge solution, and observing that the paint liquid is a drawable Newtonian body to prepare the transparent lacquer, wherein the container.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110262849.6A CN113045337B (en) | 2021-03-11 | Method for repairing stone relics and protecting surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110262849.6A CN113045337B (en) | 2021-03-11 | Method for repairing stone relics and protecting surfaces |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113045337A true CN113045337A (en) | 2021-06-29 |
| CN113045337B CN113045337B (en) | 2024-09-27 |
Family
ID=
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1025175A (en) * | 1996-07-09 | 1998-01-27 | Shoei Kensou Kk | Repair of stone construction |
| CN102115340A (en) * | 2010-01-06 | 2011-07-06 | 北京大学 | Method for protecting surface of stone cultural relic |
| CN106242324A (en) * | 2016-08-26 | 2016-12-21 | 南华大学 | A kind of repairing stone relics agent and using method thereof |
| CN109575698A (en) * | 2018-12-11 | 2019-04-05 | 西安米诺源环保科技有限公司 | Historical relic's protection performed polymer material and preparation method and guard method |
| CN111470840A (en) * | 2020-04-23 | 2020-07-31 | 中国文化遗产研究院 | Stone cultural relic surface crack repairing material and preparation method thereof |
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1025175A (en) * | 1996-07-09 | 1998-01-27 | Shoei Kensou Kk | Repair of stone construction |
| CN102115340A (en) * | 2010-01-06 | 2011-07-06 | 北京大学 | Method for protecting surface of stone cultural relic |
| CN106242324A (en) * | 2016-08-26 | 2016-12-21 | 南华大学 | A kind of repairing stone relics agent and using method thereof |
| CN109575698A (en) * | 2018-12-11 | 2019-04-05 | 西安米诺源环保科技有限公司 | Historical relic's protection performed polymer material and preparation method and guard method |
| CN111470840A (en) * | 2020-04-23 | 2020-07-31 | 中国文化遗产研究院 | Stone cultural relic surface crack repairing material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ahmed et al. | Corrosion studies on tailored Zn· Co aluminate/kaolin core–shell pigments in alkyd based paints | |
| Sriram et al. | Silica and Silane based polymer composite coating on glass slide by dip-Coating Method | |
| CN104213112A (en) | Method for manufacturing metal surface self-cleaning high-protection film | |
| US20100261029A1 (en) | Multi-phase particulates, method of making, and composition containing same | |
| US20180362773A1 (en) | Waterborne heat-insulation coating and composition thereof | |
| WO2007014878A2 (en) | Varnish compositions and their use for the coating of surfaces of substrates | |
| CN113045337A (en) | Method for repairing and protecting surface of stone cultural relic | |
| Tiwari et al. | Use of fly ash in high performance industrial coatings | |
| Sun et al. | A mechanically robust superhydrophobic corrosion resistant coating with self-healing capability | |
| CN107629657B (en) | Attapulgite/aqueous polyurethane coating and its application | |
| Greiner-Wronowa et al. | Influence of environment on surface of the ancient glasses | |
| Yilbas et al. | Environmental mud adhesion on optical glass surface: Effect of mud drying temperature on surface properties | |
| Ahmed et al. | Modified properties of Egyptian kaolin‐phosphate core‐shell pigments in solvent‐based paints for protection of cold‐rolled steel surfaces | |
| Zhang et al. | Effect of sol-gel film on the corrosion resistance of low carbon steel plate | |
| Igwe et al. | Formulation of anti--corrosive alkyd paints based on Umuahia clay extender | |
| Ahmed et al. | The role of silica fume pigments in corrosion protection of steel surfaces | |
| JP6112074B2 (en) | A method for forming a dense rust early on a weather resistant steel material and a weather resistant steel material produced by the method. | |
| Boraeia et al. | Preparation of SiO2/ZrO2 Ceramic Nanocomposite Coating on Aluminum Alloys as Metallic Part of the Photovoltaic Ccells and Study its Corrosion Behavior | |
| Bullett et al. | Paint: a surface modifier | |
| Jung et al. | Functional coating to improve the anti-pollution characteristics for the cover glass of photovoltaic module | |
| CN117866470B (en) | Modified composite coating for railway bridge steel structure and preparation method thereof | |
| Rostron et al. | Atmospheric corrosion issues in Abu Dhabi | |
| Norzita et al. | Development of Hybrid Nano-Sol Gel Coatings for Corrosion Protection of Carbon Steel | |
| Abdollahi Boraei et al. | Preparation of SiO2/ZrO2 ceramic nanocomposite coating on Aluminum alloys as metallic part of the photovoltaic cells and study its corrosion behavior. | |
| JP7488348B2 (en) | Surface protection coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |