CN113004740A - Water-resistant printing ink and preparation method thereof - Google Patents
Water-resistant printing ink and preparation method thereof Download PDFInfo
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- CN113004740A CN113004740A CN202110225251.XA CN202110225251A CN113004740A CN 113004740 A CN113004740 A CN 113004740A CN 202110225251 A CN202110225251 A CN 202110225251A CN 113004740 A CN113004740 A CN 113004740A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 alkoxy acrylate Chemical compound 0.000 claims abstract description 21
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 18
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003381 stabilizer Substances 0.000 claims abstract description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims abstract description 14
- LNUDKRYFAFELDF-UHFFFAOYSA-N carbonic acid;prop-2-enoic acid Chemical compound OC(O)=O.OC(=O)C=C LNUDKRYFAFELDF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 229960000892 attapulgite Drugs 0.000 claims abstract description 13
- 238000000227 grinding Methods 0.000 claims abstract description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical class O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 13
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 239000010703 silicon Substances 0.000 claims abstract description 12
- 150000002009 diols Chemical class 0.000 claims abstract description 11
- 239000012860 organic pigment Substances 0.000 claims abstract description 11
- 229920000728 polyester Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000009775 high-speed stirring Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 43
- 238000003756 stirring Methods 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000004135 Bone phosphate Substances 0.000 claims description 5
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 4
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 claims description 2
- 125000005520 diaryliodonium group Chemical group 0.000 claims description 2
- IRCSIGNHSFZBRR-UHFFFAOYSA-N dioctyltin 6-methylheptyl 2,2-bis(sulfanyl)acetate Chemical compound C(CCCCCCC)[Sn]CCCCCCCC.SC(C(=O)OCCCCCC(C)C)S IRCSIGNHSFZBRR-UHFFFAOYSA-N 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 37
- PIRIAZVDIOKRIR-UHFFFAOYSA-N dioctyltin;6-methylheptyl 2-hydroxyethanedithioate Chemical compound CC(C)CCCCCSC(=S)CO.CCCCCCCC[Sn]CCCCCCCC PIRIAZVDIOKRIR-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UIKROCXWUNQSPJ-VIFPVBQESA-N (-)-cotinine Chemical compound C1CC(=O)N(C)[C@@H]1C1=CC=CN=C1 UIKROCXWUNQSPJ-VIFPVBQESA-N 0.000 description 1
- UIKROCXWUNQSPJ-UHFFFAOYSA-N Cotinine Natural products C1CC(=O)N(C)C1C1=CC=CN=C1 UIKROCXWUNQSPJ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229950006073 cotinine Drugs 0.000 description 1
- 125000002592 cumenyl group Chemical group C1(=C(C=CC=C1)*)C(C)C 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention provides water-resistant printing ink and a preparation method thereof, and relates to the technical field of ink processing. The water-resistant printing ink is prepared from the following raw materials: epoxy acrylate, polyether acrylic acid, organic silicon, organic pigment, tetrabutyl titanate, alkoxy acrylate, carbonic acid monoacrylate, fluorocarbon wax, a stabilizer, modified kaolin, attapulgite, polyester diol, a photoinitiator and an anti-aging agent, wherein the preparation method mainly comprises the following steps: high-temperature high-pressure modification, high-speed stirring, grinding and mixing, grinding and dispersing and the like. The UV printing ink overcomes the defects of the prior art, and can effectively improve the waterproof performance of the UV printing ink, enhance the printing effect and improve the quality of the printing ink.
Description
Technical Field
The invention relates to the technical field of ink processing, in particular to water-resistant printing ink and a preparation method thereof.
Background
UV ink refers to ink that is formed into a film and dried by polymerizing monomers in an ink vehicle into polymers using ultraviolet light of different wavelengths and energies under ultraviolet irradiation. UV inks also belong to the group of inks, as they must possess brilliant color (except in special cases), good printability, and suitable curing drying rates. Meanwhile, the paint has good adhesive force and has the characteristics of wear resistance, corrosion resistance, weather resistance and the like.
With the development of science and technology, various performances of the UV ink are greatly improved; however, the general ink has poor waterproof effect, and the ink fades after being stored in water or a humid environment for a long time, which is not beneficial to printing of some special packages by the UV ink.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the water-resistant printing ink and the preparation method thereof, which can effectively improve the water resistance of the UV printing ink, enhance the printing effect and improve the quality of the printing ink.
In order to achieve the above purpose, the technical scheme of the invention is realized by the following technical scheme:
a water-resistant printing ink is prepared from the following raw materials in parts by weight: 36-40 parts of epoxy acrylate, 7-10 parts of polyether acrylic acid, 1-4 parts of organic silicon, 2-4 parts of organic pigment, 1-4 parts of tetrabutyl titanate, 4-6 parts of alkoxy acrylate, 2-4 parts of carbonic acid monoacrylate, 2-3 parts of fluorocarbon wax, 1-3 parts of stabilizer, 2-6 parts of modified kaolin, 1-3 parts of attapulgite, 1-3 parts of polyester diol, 5-8 parts of photoinitiator and 1-3 parts of anti-aging agent.
Preferably, the stabilizing agent is a mixture of zinc stearate, isooctyl dimercaptoacetate di-n-octyl tin and tribasic lead maleate with the mass ratio of 2: 1.
Preferably, the photoinitiator is any one or a mixture of more of diaryl iodonium salt, triaryl iodonium salt, alkyl iodonium salt and cumeneferrocene hexafluorophosphate.
Preferably, the anti-aging agent is one or a mixture of more of anti-aging agent IPPD, anti-aging agent CPPD and anti-aging agent 264.
The preparation method of the water-resistant printing ink comprises the following steps:
(1) placing epoxy acrylate mixed polyether acrylic acid and organic silicon in a high-pressure reaction kettle, mixing and stirring uniformly, then boosting the pressure to 10-12MPa, heating to 100 ℃ and standing for 2-3h, then taking out, and continuing stirring to obtain a mixed base material;
(2) mixing tetrabutyl titanate, alkoxy acrylate and carbonic acid monoacrylate, heating to 60-65 ℃, and stirring at a high speed to obtain a mixture A for later use;
(3) mixing the modified kaolin, the attapulgite and the fluorocarbon wax, grinding and crushing the mixture in a grinder, adding the polyester diol, and uniformly stirring the mixture to obtain a mixture B for later use;
(4) and adding the mixed base material into the mixture A, the mixture B, the organic pigment, the stabilizer, the photoinitiator and the anti-aging agent, uniformly stirring in a stirrer, and continuously dispersing in a grinding dispersion machine to obtain the water-resistant printing ink.
Preferably, the rotation speed of mixing and stirring in the step (1) is 180-.
Preferably, the rotation speed of the high-speed stirring in the step (2) is 400-600r/min, and the stirring time is 15-30 min.
Preferably, the modified kaolin, the attapulgite and the fluorocarbon wax in the step (3) are sieved by a 200-mesh sieve after being ground.
Preferably, the particle size of the material after grinding and dispersing in the step (4) is less than 5 μm.
The invention provides water-resistant printing ink and a preparation method thereof, and compared with the prior art, the water-resistant printing ink has the advantages that:
(1) according to the invention, epoxy acrylate and polyether acrylic acid are used as main base materials, and organic silicon is used for modifying the base materials at high temperature and high pressure, so that the viscosity and the later waterproof performance of the ink are effectively improved, and the using effect of the ink is enhanced;
(2) according to the invention, the water resistance of the ink is further improved by adding tetrabutyl titanate, alkoxy acrylate, carbonic acid monoacrylate and fluorocarbon wax, so that the printed and dried ink can keep the flexibility for a long time in a humid environment and is not easy to fall off.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention are clearly and completely described below in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
a water-resistant printing ink is prepared from the following raw materials in parts by weight: 36 parts of epoxy acrylate, 7 parts of polyether acrylic acid, 1 part of organic silicon, 2 parts of organic pigment, 1 part of tetrabutyl titanate, 4 parts of alkoxy acrylate, 2 parts of carbonic acid monoacrylate, 2 parts of fluorocarbon wax, 1 part of stabilizer, 2 parts of modified kaolin, 1 part of attapulgite, 1 part of polyester diol, 5 parts of cumenyl cyclopentadienyl iron hexafluorophosphate and 1 part of anti-aging agent IPPD.
Wherein the stabilizer is a mixture of zinc stearate, isooctyl dithioglycolate di-n-octyl tin and tribasic lead maleate with the mass ratio of 2: 1.
The preparation method of the water-resistant printing ink comprises the following steps:
(1) placing epoxy acrylate mixed polyether acrylic acid and organic silicon in a high-pressure reaction kettle, mixing and stirring at the rotating speed of 180r/min for 10min, then boosting the pressure to 10MPa, heating to 100 ℃, preserving heat and standing for 2h, then taking out, and continuously stirring at the rotating speed of 800r/min for 20min to obtain a mixed base material;
(2) mixing tetrabutyl titanate, alkoxy acrylate and carbonic acid monoacrylate, heating to 60 ℃, and then stirring at a high speed of 400r/min for 15min to obtain a mixture A for later use;
(3) mixing the modified kaolin, the attapulgite and the fluorocarbon wax, grinding and crushing the mixture in a grinder, sieving the ground mixture with a 200-mesh sieve, adding the polyester diol, and uniformly stirring the mixture to obtain a mixture B for later use;
(4) and adding the mixed base material into the mixture A, the mixture B, the organic pigment, the stabilizer, the photoinitiator and the anti-aging agent, uniformly stirring in a stirrer, and continuously dispersing in a grinding dispersion machine until the particle size is less than 5 mu m to obtain the water-resistant printing ink.
Example 2:
a water-resistant printing ink is prepared from the following raw materials in parts by weight: 40 parts of epoxy acrylate, 10 parts of polyether acrylic acid, 4 parts of organic silicon, 4 parts of organic pigment, 4 parts of tetrabutyl titanate, 6 parts of alkoxy acrylate, 4 parts of carbonic acid monoacrylate, 3 parts of fluorocarbon wax, 3 parts of stabilizer, 6 parts of modified kaolin, 3 parts of attapulgite, 3 parts of polyester diol, 8 parts of cumenyl cyclopentadienyl iron hexafluorophosphate and 3 parts of anti-aging agent IPPD.
Wherein the stabilizer is a mixture of zinc stearate, isooctyl dithioglycolate di-n-octyl tin and tribasic lead maleate with the mass ratio of 2: 1.
The preparation method of the water-resistant printing ink comprises the following steps:
(1) placing epoxy acrylate mixed polyether acrylic acid and organic silicon in a high-pressure reaction kettle, mixing and stirring at the rotating speed of 200r/min for 20min, then boosting the pressure to 12MPa, heating to 110 ℃, preserving heat, standing for 3h, then taking out, and continuously stirring at the rotating speed of 1000r/min for 30min to obtain a mixed base material;
(2) mixing tetrabutyl titanate, alkoxy acrylate and carbonic acid monoacrylate, heating to 65 ℃, and then stirring at a high speed of 600r/min for 30min to obtain a mixture A for later use;
(3) mixing the modified kaolin, the attapulgite and the fluorocarbon wax, grinding and crushing the mixture in a grinder, sieving the ground mixture with a 200-mesh sieve, adding the polyester diol, and uniformly stirring the mixture to obtain a mixture B for later use;
(4) and adding the mixed base material into the mixture A, the mixture B, the organic pigment, the stabilizer, the photoinitiator and the anti-aging agent, uniformly stirring in a stirrer, and continuously dispersing in a grinding dispersion machine until the particle size is less than 5 mu m to obtain the water-resistant printing ink.
Example 3:
a water-resistant printing ink is prepared from the following raw materials in parts by weight: 38 parts of epoxy acrylate, 8.5 parts of polyether acrylic acid, 3 parts of organic silicon, 3 parts of organic pigment, 2.5 parts of tetrabutyl titanate, 5 parts of alkoxy acrylate, 5 parts of carbonic acid monoacrylate, 2.5 parts of fluorocarbon wax, 2 parts of stabilizer, 4 parts of modified kaolin, 2 parts of attapulgite, 2 parts of polyester diol, 6.5 parts of cumenyl ferrocenyl hexafluorophosphate and 2 parts of anti-aging agent IPPD.
Wherein the stabilizer is a mixture of zinc stearate, isooctyl dithioglycolate di-n-octyl tin and tribasic lead maleate with the mass ratio of 2: 1.
The preparation method of the water-resistant printing ink comprises the following steps:
(1) placing epoxy acrylate mixed polyether acrylic acid and organic silicon in a high-pressure reaction kettle, mixing and stirring at the rotating speed of 180r/min for 20min, then boosting the pressure to 10MPa, heating to 100 ℃, preserving heat, standing for 3h, then taking out, and continuously stirring at the rotating speed of 1000r/min for 20min to obtain a mixed base material;
(2) mixing tetrabutyl titanate, alkoxy acrylate and carbonic acid monoacrylate, heating to 60 ℃, and then stirring at a high speed of 400r/min for 30min to obtain a mixture A for later use;
(3) mixing the modified kaolin, the attapulgite and the fluorocarbon wax, grinding and crushing the mixture in a grinder, sieving the ground mixture with a 200-mesh sieve, adding the polyester diol, and uniformly stirring the mixture to obtain a mixture B for later use;
(4) and adding the mixed base material into the mixture A, the mixture B, the organic pigment, the stabilizer, the photoinitiator and the anti-aging agent, uniformly stirring in a stirrer, and continuously dispersing in a grinding dispersion machine until the particle size is less than 5 mu m to obtain the water-resistant printing ink.
And (3) detection:
by adopting the mixture ratio and the preparation process of the substances shown in the above example 3, substances such as polyether acrylic acid, silicone, tetrabutyl titanate, alkoxy acrylate, carbonic acid monoacrylate, fluorocarbon wax and the like are selectively added, as shown in the following table 1 (wherein "-" indicates no addition, and "√" indicates addition):
table 1:
the inks obtained in examples 1 to 3 and the above-mentioned control groups 1 to 8 were tested for viscosity at 25 ℃, and each group of inks was printed on white-primed cotinine plain iron, and then irradiated with an ultraviolet lamp until completely dried, and then subjected to a check test, and the inks of each group were printed on a soft plastic part, dried, immersed in clear water at 35 ℃ for 100 hours, 300 hours, and 500 hours, and then folded twice forward and backward, and observed for edge burst, with a force of 1N, with the results shown in table 2 below:
table 2:
from the above table, it can be seen that the addition of the polyether acrylic acid, the silicone, the tetrabutyl titanate, the alkoxy acrylate, the carbonate monoacrylate, the fluorocarbon wax and the like in the present invention can effectively improve the performance and quality of the ink.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (9)
1. The water-resistant printing ink is characterized by being prepared from the following raw materials in parts by weight: 36-40 parts of epoxy acrylate, 7-10 parts of polyether acrylic acid, 1-4 parts of organic silicon, 2-4 parts of organic pigment, 1-4 parts of tetrabutyl titanate, 4-6 parts of alkoxy acrylate, 2-4 parts of carbonic acid monoacrylate, 2-3 parts of fluorocarbon wax, 1-3 parts of stabilizer, 2-6 parts of modified kaolin, 1-3 parts of attapulgite, 1-3 parts of polyester diol, 5-8 parts of photoinitiator and 1-3 parts of anti-aging agent.
2. A water-resistant printing ink as claimed in claim 1, characterized in that: the stabilizer is a mixture of zinc stearate, isooctyl dimercaptoacetate di-n-octyl tin and tribasic lead maleate with the mass ratio of 2: 1.
3. A water-resistant printing ink as claimed in claim 1, characterized in that: the photoinitiator is any one or mixture of diaryl iodonium salt, triaryl iodonium salt, alkyl iodonium salt and cumeneferrocene hexafluorophosphate.
4. A water-resistant printing ink as claimed in claim 1, characterized in that: the anti-aging agent is one or a mixture of more of anti-aging agent IPPD, anti-aging agent CPPD and anti-aging agent 264.
5. A preparation method of water-resistant printing ink is characterized by comprising the following steps: the preparation method of the water-resistant printing ink comprises the following steps:
(1) placing epoxy acrylate mixed polyether acrylic acid and organic silicon in a high-pressure reaction kettle, mixing and stirring uniformly, then boosting the pressure to 10-12MPa, heating to 100 ℃ and standing for 2-3h, then taking out, and continuing stirring to obtain a mixed base material;
(2) mixing tetrabutyl titanate, alkoxy acrylate and carbonic acid monoacrylate, heating to 60-65 ℃, and stirring at a high speed to obtain a mixture A for later use;
(3) mixing the modified kaolin, the attapulgite and the fluorocarbon wax, grinding and crushing the mixture in a grinder, adding the polyester diol, and uniformly stirring the mixture to obtain a mixture B for later use;
(4) and adding the mixed base material into the mixture A, the mixture B, the organic pigment, the stabilizer, the photoinitiator and the anti-aging agent, uniformly stirring in a stirrer, and continuously dispersing in a grinding dispersion machine to obtain the water-resistant printing ink.
6. The method of claim 5, wherein the water-resistant printing ink comprises: the rotation speed of mixing and stirring in the step (1) is 180-200r/min, the stirring time is 10-20min, then the rotation speed of taking out and continuing stirring is 800-1000r/min, and the stirring time is 20-30 min.
7. The method of claim 5, wherein the water-resistant printing ink comprises: the rotating speed of the high-speed stirring in the step (2) is 400-600r/min, and the stirring time is 15-30 min.
8. The method of claim 5, wherein the water-resistant printing ink comprises: and (4) after the modified kaolin, the attapulgite and the fluorocarbon wax are ground in the step (3), sieving by a 200-mesh sieve is needed.
9. The method of claim 5, wherein the water-resistant printing ink comprises: the particle size of the material ground and dispersed in the step (4) is less than 5 microns.
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CN113893942A (en) * | 2021-10-03 | 2022-01-07 | 吴迪 | Preparation process of printing ink |
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