CN112980550A - Air conditioner accessory processing oil and preparation method thereof - Google Patents

Air conditioner accessory processing oil and preparation method thereof Download PDF

Info

Publication number
CN112980550A
CN112980550A CN202110148867.1A CN202110148867A CN112980550A CN 112980550 A CN112980550 A CN 112980550A CN 202110148867 A CN202110148867 A CN 202110148867A CN 112980550 A CN112980550 A CN 112980550A
Authority
CN
China
Prior art keywords
parts
oil
accessory processing
alpha olefin
linear alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202110148867.1A
Other languages
Chinese (zh)
Other versions
CN112980550B (en
Inventor
郑东方
朱伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU YINUO CHEMICAL MATERIALS CO Ltd
Original Assignee
SUZHOU YINUO CHEMICAL MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU YINUO CHEMICAL MATERIALS CO Ltd filed Critical SUZHOU YINUO CHEMICAL MATERIALS CO Ltd
Priority to CN202110148867.1A priority Critical patent/CN112980550B/en
Publication of CN112980550A publication Critical patent/CN112980550A/en
Application granted granted Critical
Publication of CN112980550B publication Critical patent/CN112980550B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/024Well-defined aliphatic compounds unsaturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to air conditioner accessory processing oil and a preparation method thereof, wherein the processing oil comprises base oil, a lubricant and an antioxidant, wherein the base oil is C8-C16 isoparaffin and coal oil, the lubricant is C14-C20 isomeric alcohol and C10-C20 linear alpha olefin, the antioxidant is 2, 6-di-tert-butyl-4-methylphenol and 2, 6-di-tert-butyl-mixed phenol, the isomeric alkane and the coal oil are used as the base oil, and the lubricant of C14-C20 isomeric alcohol and C10-C20 linear alpha olefin is used for preventing burrs from occurring in the stamping process of aluminum fins, prolonging the service life of machine tool grinding and ensuring certain volatility at normal temperature.

Description

Air conditioner accessory processing oil and preparation method thereof
Technical Field
The invention relates to processing oil, in particular to air conditioner accessory processing oil and a preparation method thereof.
Background
The air-conditioning accessories such as aluminum fins, copper pipes and the like need to be punched to form holes in the machining process, punching oil is needed in the punching process, the punching oil used at present is the deeply refined light mineral oil which is used as base oil, and additives such as alcohol, acid, ester and the like are compounded to obtain the volatile punching oil composition, and the volatile punching oil composition can meet the lubricating requirements of the accessory punching and can be volatilized and removed at high temperature or normal temperature. However, the existing punching oil generates a great peculiar smell in the volatilization process, which causes a severe working environment, and the machined accessories are easy to corrode, thereby affecting the service life of the air conditioner.
Disclosure of Invention
In order to overcome the defects, the invention provides the processing oil for the air-conditioning accessories, which uses isoparaffin and coal oil as base oil, and adds a small amount of antioxidant, so that the processing process does not generate unpleasant smell, and the processed accessories are not corroded due to the processing oil.
The technical scheme adopted by the invention for solving the technical problem is as follows:
the air conditioner accessory processing oil comprises the following components in parts by weight: 40-80 parts of base oil, 10-65 parts of lubricant and 0.01-2 parts of antioxidant, wherein the base oil is at least one of C8-C16 isoparaffin and coal-made oil.
Preferably, the base oil is a mixture of C8-C16 isoparaffin and coal-made oil, and the weight parts of the two are 20-50 parts of C8-C16 isoparaffin and 10-40 parts of coal-made oil.
Preferably, the C8-C16 isoparaffin has the following characteristics:
index (I) Results
Density (20 ℃, g/ml) 0.73-0.75
Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5
Volatility (120 ℃, 10min) 100% without residue
Distillation range (. degree.C.) 160-200
Sulfur content (ppm) <0.5
Smell (150 ℃ oven drying) Has no peculiar smell
Preferably, the coal-based oil is characterized by the following table:
index (I) Results
Density (20 ℃, g/ml) 0.73-0.75
Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5
Volatility (120 ℃, 10min) 100% without residue
Distillation range (. degree.C.) 170-220
Sulfur content (ppm) <1
Smell (150 ℃ oven drying) Has slight odor
Preferably, the lubricant is at least one of a C14-C20 isomeric alcohol and a C10-C20 linear alpha olefin.
Preferably, the lubricant comprises the following components in parts by weight: 0.1-10 parts of C14-C20 isomeric alcohol and 5-60 parts of C10-C20 linear alpha olefin.
Preferably, the lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C14 linear alpha olefin, 5-20 parts of C16 linear alpha olefin and 1-10 parts of C20 linear alpha olefin.
Preferably, the lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C12 linear alpha olefin, 1-15 parts of C14 linear alpha olefin and 1-10 parts of C16 linear alpha olefin.
Preferably, the antioxidant is at least one of 2, 6-di-tert-butyl-4-methylphenol and 2, 6-di-tert-butyl-mixed phenol.
The invention also provides a preparation method of the air conditioner accessory processing oil, which comprises the following steps:
the method comprises the following steps: weighing the base oil, the lubricant and the antioxidant according to the formula ratio for later use;
step two: and (3) sequentially adding the materials in the step one into a reaction kettle, and stirring to obtain colorless and transparent liquid, wherein the temperature in the reaction kettle is 20-45 ℃, and the stirring time is 20-60 min.
The invention has the beneficial effects that: the lubricating oil comprises base oil, a lubricant and an antioxidant, wherein the base oil is C8-C16 isoparaffin and coal oil, the lubricant is C14-C20 isomerous alcohol and C10-C20 linear alpha olefin, the antioxidant is 2, 6-di-tert-butyl-4-methylphenol and 2, 6-di-tert-butyl-mixed phenol, the isoparaffin and the coal oil are used as the base oil, and the lubricant of the C14-C20 isomerous alcohol and the C10-C20 linear alpha olefin can prevent burrs from occurring in the stamping process of aluminum fins, prolong the service life of machine tool grinding at normal temperature and ensure certain volatility; the antioxidant can prevent volatile fin processing oil from being oxidized in air and combined with moisture to generate acid radical ions of formic acid and acetic acid, and the acid radical ions can corrode a copper pipe and an aluminum foil to cause leakage of a refrigerant and cause serious quality problems.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The air conditioner accessory processing oil comprises the following components in parts by weight: 40-80 parts of base oil, 10-65 parts of lubricant and 0.01-2 parts of antioxidant, wherein the base oil is at least one of C8-C16 isoparaffin and coal-made oil. Further, 45-60 parts of base oil, 30-60 parts of lubricant and 0.1-2 parts of antioxidant, the isoparaffin has the characteristics of low melting point, low toxicity, good compatibility with other lubricating oil, good stability, safety and environmental protection, and the isoparaffin partially volatilizes under the normal temperature condition; the coal-to-liquid is a hydrocarbon compound which is synthesized by completely gasifying coal and converting the coal into a mixture of carbon monoxide, methane and hydrogen under the action of an iron-based or cobalt-based catalyst by reacting the coal with oxygen and water vapor at high temperature; the isoparaffin and the coal-made oil are used as the base oil, so that burrs can be prevented from occurring in the stamping process of the aluminum fin, the service life of machine tool grinding is prolonged, and certain volatility is ensured at normal temperature.
The base oil is a mixture of C8-C16 isoparaffin and coal-made oil, and the weight parts of the base oil and the coal-made oil are 20-50 parts of C8-C16 isoparaffin and 10-40 parts of coal-made oil. Further, 30-45 parts of C8-C16 isoparaffin and 15-30 parts of coal-made oil.
The C8-C16 isoparaffin has the following characteristics:
index (I) Results
Density (20 ℃, g/ml) 0.73-0.75
Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5
Volatility (120 ℃, 10min) 100% without residue
Distillation range (. degree.C.) 160-200
Sulfur content (ppm) <0.5
Smell (150 ℃ oven drying) Has no peculiar smell
The characteristics of the coal-to-liquids are as follows:
index (I) Results
Density (20 ℃, g/ml) 0.73-0.75
Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5
Volatility (120 ℃, 10min) 100% without residue
Distillation range (. degree.C.) 170-220
Sulfur content (ppm) <1
Smell (150 ℃ oven drying) Has slight odor
The lubricant is at least one of C14-C20 isomeric alcohol and C10-C20 linear alpha olefin. The isomeric alcohol C14-C20 is odorless isomeric alcohol, and the lubricating oil and the base oil are matched to prevent burrs from occurring in the stamping process of the aluminum fin, so that the service life of the machine tool grinding tool is prolonged.
The lubricant comprises the following components in parts by weight: 0.1-10 parts of C14-C20 isomeric alcohol and 5-60 parts of C10-C20 linear alpha olefin.
The lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C14 linear alpha olefin, 5-20 parts of C16 linear alpha olefin and 1-10 parts of C20 linear alpha olefin, and the formula is more suitable for processing aluminum fins.
The lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C12 linear alpha olefin, 1-15 parts of C14 linear alpha olefin and 1-10 parts of C16 linear alpha olefin, and the formula is more suitable for processing bent pipes.
The antioxidant is at least one of 2, 6-di-tert-butyl-4-methylphenol and 2, 6-di-tert-butyl-mixed phenol. The antioxidant can prevent volatile fin processing oil from being oxidized in air and combined with moisture to generate acid radical ions of formic acid and acetic acid, and the acid radical ions can corrode a copper pipe and an aluminum foil to cause leakage of a refrigerant and cause serious quality problems.
Preparation of the first, examples and comparative examples
Examples 1-10 and comparative example 1 were prepared according to the components and parts by weight in tables 1 and 2:
table 1: raw materials and their amounts (unit, parts by weight)
Figure BDA0002931362790000051
Table 2: raw materials and their amounts (unit, parts by weight)
Figure BDA0002931362790000061
Comparative example 2 is aluminum fin oil produced from dearomatization solvent oil of the company, wherein the dearomatization solvent is 96-99% (mass percent), and the acid radical ion content of comparative example 2 is 5 ppm;
the preparation methods of examples 1 to 10 and comparative example 1 were as follows:
the method comprises the following steps: weighing the base oil, the lubricant and the antioxidant according to the formula ratio for later use;
step two: and (3) sequentially adding the materials in the step one into a reaction kettle, and stirring to obtain colorless and transparent liquid, wherein the temperature in the reaction kettle is 20-45 ℃, and the stirring time is 20-60 min.
The acid ions of the examples and comparative examples were measured and the results are shown in tables 1 and 2, and the acid ion detection method was as follows:
the method comprises the following steps: and (3) preparing a standard curve: preparing five curve point solutions of 0.1ppm, 0.5ppm, 2.0ppm, 5.0ppm and 10.0ppm by using 1000ppm of formate and acetate standard solutions, testing the prepared curve solutions by using an ion chromatograph, making a standard curve, and determining that the curve coefficient is more than 99.5 percent to carry out sample test;
step two: mixing the sample oil with water according to the weight ratio of 9: 1 ratio, taking 90mL of sample oil in 200mL or 250mL round bottom or flat bottom flask, adding 10mL deionized water and 1g of analytically pure alumina powder (or copper powder), mixing the solution well and refluxing at 105 ℃ for 48 hours;
step three: 2mL of NaOH solution (about 1 mol/L) is added into the flask, ultrasonic treatment is carried out for 10min, the clear solution is transferred into a separating funnel, a part of aqueous phase (lower layer solution) is separated, a 0.22 micron filter head of the aqueous phase is used, and after filtration, ICS-900 ion chromatography is used for analysis (using a standard curve prepared in the first step) or an equivalent analysis device for testing the content of formate and acetate.
As can be seen from the test results of the acid ion, the acid ions of examples 1 to 10 of the present invention were < 1ppm, whereas the acid ion of comparative example 1 was 2.5ppm, which is significantly higher than the acid ion (0.3ppm) concentration of example 5, and the only difference between comparative example 1 and example 5 is that: comparative example 1 does not contain any antioxidant, so the antioxidant of the present invention can effectively prevent volatile fin processing oil from being oxidized in air and combined with moisture to generate acid ions of formic acid and acetic acid.
Second, press test of examples and comparative examples
The procedure of the press test of examples 1 to 10 and comparative examples 1 to 2 was as follows:
the method comprises the following steps: quantitative spraying: passing an aluminum fin through the stamping coating oil, wherein the thickness of the aluminum fin aluminum foil is 0.1 +/-0.05 mm;
step two: punching: the sprayed aluminum fin is placed on a punching machine to be punched to form a hole, the aperture is phi 5-15mm, and the speed of the punching machine is 150-;
step three: pipe penetration: penetrating the aluminum pipes into the holes punched and formed by the aluminum fins one by one;
step four: drying: and (3) placing the aluminum fin after the tube penetration into a degreasing furnace for drying, wherein the temperature of the degreasing furnace is 120-140 ℃, and the baking time is 5-10 minutes.
In the stamping process, the stamping oils of examples 1 to 10 and comparative example 1 were used, and no unpleasant odor was generated in the entire stamping process; when the punching oil of comparative example 2 is used, a large peculiar smell is generated in the punching process; the lubricating properties of examples 1 to 10 and comparative examples 1 to 2 were good, and the aluminum fins were free from the occurrence of burr during the processing.
The aluminum fins after punching of examples 1 to 10 and comparative examples 1 to 2 were subjected to the hydrophilic angle test, and the test results were: the angle of hydrophilicity is less than 15 deg.
Third, physical and chemical Properties of the examples
The products obtained in examples 1 to 10 have the following physico-chemical properties:
a: the maximum non-seizing load PB is more than or equal to 18 kg;
b: the volatilization rate is as follows: more than or equal to 60 percent;
c, the hydrophilic angle (aluminum foil after stamping) is less than or equal to 15 degrees;
d; coefficient of friction: < 0.133 mm.
E: sample state: a colorless transparent liquid;
f: drying property; completely volatilize for 3min
G: specific gravity: 0.7-0.8g/cm3
H: acid radical ion: formic acid + acetic acid < 1ppm
I: odor: no smell at normal temperature, and no smell after drying at 150 ℃.
It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (10)

1. The air conditioner accessory processing oil is characterized in that: the paint comprises the following components in parts by weight: 40-80 parts of base oil, 10-65 parts of lubricant and 0.01-2 parts of antioxidant, wherein the base oil is at least one of C8-C16 isoparaffin and coal-made oil.
2. An air conditioning accessory processing oil according to claim 1, wherein: the base oil is a mixture of C8-C16 isoparaffin and coal-made oil, and the weight parts of the base oil and the coal-made oil are 20-50 parts of C8-C16 isoparaffin and 10-40 parts of coal-made oil.
3. An air conditioning accessory processing oil according to claim 1, wherein: the C8-C16 isoparaffin has the following characteristics:
index (I) Results Density (20 ℃, g/ml) 0.73-0.75 Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5 Volatility (120 ℃, 10min) 100% without residue Distillation range (. degree.C.) 160-200 Sulfur content (ppm) <0.5 Smell (150 ℃ oven drying) Has no peculiar smell
4. An air conditioning accessory processing oil according to claim 1, wherein: the characteristics of the coal-to-liquids are as follows:
index (I) Results Density (20 ℃, g/ml) 0.73-0.75 Kinematic viscosity (40 ℃, mm)2/s) 1.2-1.5 Volatility (120 ℃, 10min) 100% without residue Distillation range (. degree.C.) 170-220 Sulfur content (ppm) <1 Smell (150 ℃ oven drying) Has slight odor
5. An air conditioning accessory processing oil according to claim 1, wherein: the lubricant is at least one of C14-C20 isomeric alcohol and C10-C20 linear alpha olefin.
6. An air conditioning accessory processing oil according to claim 5, wherein: the lubricant comprises the following components in parts by weight: 0.1-10 parts of C14-C20 isomeric alcohol and 5-60 parts of C10-C20 linear alpha olefin.
7. An air conditioning accessory processing oil according to claim 6, wherein: the lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C14 linear alpha olefin, 5-20 parts of C16 linear alpha olefin and 1-10 parts of C20 linear alpha olefin.
8. An air conditioning accessory processing oil according to claim 6, wherein: the lubricant comprises the following components in parts by weight: 0.5-5 parts of isomeric hexadecanol, 10-30 parts of C12 linear alpha olefin, 1-15 parts of C14 linear alpha olefin and 1-10 parts of C16 linear alpha olefin.
9. An air conditioning accessory processing oil according to claim 1, wherein: the antioxidant is at least one of 2, 6-di-tert-butyl-4-methylphenol and 2, 6-di-tert-butyl-mixed phenol.
10. A method for producing an air conditioning accessory processing oil according to any one of claims 1 to 9, characterized by: the method comprises the following steps:
the method comprises the following steps: weighing the base oil, the lubricant and the antioxidant according to the formula ratio for later use;
step two: and (3) sequentially adding the materials in the step one into a reaction kettle, and stirring to obtain colorless and transparent liquid, wherein the temperature in the reaction kettle is 20-45 ℃, and the stirring time is 20-60 min.
CN202110148867.1A 2021-02-03 2021-02-03 Air conditioner accessory processing oil and preparation method thereof Active CN112980550B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110148867.1A CN112980550B (en) 2021-02-03 2021-02-03 Air conditioner accessory processing oil and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110148867.1A CN112980550B (en) 2021-02-03 2021-02-03 Air conditioner accessory processing oil and preparation method thereof

Publications (2)

Publication Number Publication Date
CN112980550A true CN112980550A (en) 2021-06-18
CN112980550B CN112980550B (en) 2022-09-16

Family

ID=76346402

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110148867.1A Active CN112980550B (en) 2021-02-03 2021-02-03 Air conditioner accessory processing oil and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112980550B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114181761A (en) * 2021-12-10 2022-03-15 安美科技股份有限公司 Cleaning-free copper-aluminum sheet punching oil

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263056A (en) * 2003-02-28 2004-09-24 Sumitomo Light Metal Ind Ltd Lubricant for fin pressing
CN1613982A (en) * 2003-11-04 2005-05-11 N.S润滑油株式会社 Lubricant oil composition
US20090062167A1 (en) * 2006-03-10 2009-03-05 Idemitsu Kosan Co., Ltd. Refrigerating machine oil composition
JP2011515521A (en) * 2008-03-18 2011-05-19 昭和シェル石油株式会社 Lubricating composition
CN102199476A (en) * 2011-04-29 2011-09-28 上海德润宝特种润滑剂有限公司 Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof
CN102719303A (en) * 2012-06-04 2012-10-10 苏州铱诺化学材料有限公司 Volatile aluminum fin punching oil and preparation method thereof
CN103820195A (en) * 2014-03-13 2014-05-28 苏州铱诺化学材料有限公司 Drying-free water-washable fin processing oil and preparation method thereof
CN106398815A (en) * 2016-08-18 2017-02-15 石家庄新泰特种油有限公司 Geometric ratio volatilization aluminum plate rolling technical oil suitable for heavy reduction rate and preparation method thereof
CN109181832A (en) * 2018-10-09 2019-01-11 中国石油化工股份有限公司 Punching press fluid composition and application thereof
CN111662770A (en) * 2020-06-24 2020-09-15 浙江渤威能源科技有限公司 Environment-friendly volatile stamping oil and preparation method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263056A (en) * 2003-02-28 2004-09-24 Sumitomo Light Metal Ind Ltd Lubricant for fin pressing
CN1613982A (en) * 2003-11-04 2005-05-11 N.S润滑油株式会社 Lubricant oil composition
US20090062167A1 (en) * 2006-03-10 2009-03-05 Idemitsu Kosan Co., Ltd. Refrigerating machine oil composition
JP2011515521A (en) * 2008-03-18 2011-05-19 昭和シェル石油株式会社 Lubricating composition
CN102199476A (en) * 2011-04-29 2011-09-28 上海德润宝特种润滑剂有限公司 Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof
CN102719303A (en) * 2012-06-04 2012-10-10 苏州铱诺化学材料有限公司 Volatile aluminum fin punching oil and preparation method thereof
CN103820195A (en) * 2014-03-13 2014-05-28 苏州铱诺化学材料有限公司 Drying-free water-washable fin processing oil and preparation method thereof
CN106398815A (en) * 2016-08-18 2017-02-15 石家庄新泰特种油有限公司 Geometric ratio volatilization aluminum plate rolling technical oil suitable for heavy reduction rate and preparation method thereof
CN109181832A (en) * 2018-10-09 2019-01-11 中国石油化工股份有限公司 Punching press fluid composition and application thereof
CN111662770A (en) * 2020-06-24 2020-09-15 浙江渤威能源科技有限公司 Environment-friendly volatile stamping oil and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
熊云等: "《油品应用及管理》", 31 May 2004, 中国石化出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114181761A (en) * 2021-12-10 2022-03-15 安美科技股份有限公司 Cleaning-free copper-aluminum sheet punching oil

Also Published As

Publication number Publication date
CN112980550B (en) 2022-09-16

Similar Documents

Publication Publication Date Title
EP2602307B1 (en) Lubricant composition with rust inhibiting properties and with an ionic liquid as the base oil
CN112980550B (en) Air conditioner accessory processing oil and preparation method thereof
JPS61213296A (en) Lubricating oil for cold rolling of metallic material
JP2014189555A (en) Ester base oil for lubricating oil
CN115058273B (en) Cutting oil for metal processing and preparation method thereof
CN1082085C (en) Volatile lubricating oil for machining metals
CN114350431A (en) Multifunctional lubricating grease, and preparation method and application thereof
CN113652287A (en) Aluminum foil and copper foil cleaning-free oily cutting fluid and preparation method thereof
JP2001187893A (en) Brake fluid composition for automobile
CN110628493B (en) High-oxidation-resistance trace lubricating cutting oil and preparation method and application thereof
JPS60199893A (en) Bicyclo amidoketal derivative
CN107573987A (en) Turbine oil compositions of additives and application thereof
CN111892976A (en) Anti-corrosion synthetic aviation lubricating oil and production method thereof
CN111471029B (en) Liquid multi-effect lubricating oil oiliness agent and preparation method thereof
KR101906433B1 (en) Non-water-soluble cutting oil
CN114958468A (en) High-performance cooling lubricant
KR100761557B1 (en) Water soluble metal working fluids using soybean oil and metal working fluids thereof
US3507789A (en) Protection of organic materials against oxidation
CN107739652B (en) The elbow preparation method of aqueous lubricating composition, water-based lubricant and Tube Sheet of Heat Exchanger
CN1098346C (en) Universal machine oil composite
JPS6157360B2 (en)
CN117757551B (en) High-temperature anti-coking food-grade chain lubricating oil and preparation method thereof
CN117586823B (en) Ashless antiwear hydraulic oil and preparation method thereof
CN115074170A (en) Preparation method of lubricating grease, lubricating grease and automobile
US2915464A (en) Compounded lubricant compositions and composite addition agents therefor

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant