CN112979214B - Polyether water-retaining agent, preparation method thereof and cement-based building material - Google Patents
Polyether water-retaining agent, preparation method thereof and cement-based building material Download PDFInfo
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- CN112979214B CN112979214B CN202110200256.7A CN202110200256A CN112979214B CN 112979214 B CN112979214 B CN 112979214B CN 202110200256 A CN202110200256 A CN 202110200256A CN 112979214 B CN112979214 B CN 112979214B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/46—Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
- C04B2103/465—Water-sorbing agents, hygroscopic or hydrophilic agents
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Abstract
The invention belongs to the field of building materials, and relates to a polyether water-retaining agent, a preparation method thereof and a cement-based building material containing the polyether water-retaining agent. The polymer contained in the polyether type water-retaining agent comprises unsaturated polyether structural units, unsaturated amide structural units, polyfunctional unsaturated carboxylic acid structural units, organic silicon structural units and unsaturated sulfonate structural units with specific content; in the synthesis process of the polyether water-retaining agent, gluconate and/or citrate are/is added to stabilize the pH value of a polymerization system, and the buffer is gluconate and/or citrate. According to the invention, in a system which takes unsaturated polyether and unsaturated amide as main polymerization monomers and takes organosilicon and unsaturated sulfonate as auxiliary polymerization monomers, a polycarboxylic acid monomer is introduced, and meanwhile, gluconate and/or citrate is added into the polymerization system as a buffering agent, so that the water retention and segregation resistance of concrete is improved.
Description
Technical Field
The invention belongs to the field of building materials, and particularly relates to a polyether water-retaining agent, a preparation method thereof and a cement-based building material containing the polyether water-retaining agent.
Background
With the development of building science, commercial concrete increasingly requires high slump and high fluidity in order to improve the construction performance and efficiency, and is particularly significant in underwater pile concrete, self-compacting concrete, high-rise pumping concrete and the like. However, the fluidity and cohesiveness of concrete are often incompatible, i.e., it is difficult to maintain high cohesiveness in concrete in a large flow regime. Thus, the concrete with high fluidity is easy to generate bleeding and segregation phenomena. In addition, with the gradual exhaustion of river sand resources and mineral resources in China, the large fluctuation of the grading, fineness and the like of river sand, the large-scale use of common machine-made sand with poor grain type, the fluctuation of the water retention property of cement, and the continuous popularization of the polycarboxylic acid type water reducing agent with high water reduction but higher sensitivity, the quality control of the ready-mixed concrete faces increasingly serious challenges.
In order to solve the problem of concrete workability, biological additives such as xanthan gum, cellulose ether, dextrin and the like are generally added to adjust the workability of the concrete. However, the above-mentioned bio-additives have problems of solubility and storage stability, etc., so that their use is greatly restricted.
In addition, some polymer concrete segregation resisting agents have been developed in the year. For example, CN103539889A discloses a concrete segregation reducing agent, which is prepared by copolymerizing a monomer a and a monomer B, wherein the monomer a is at least one selected from acrylamide, N-methylolacrylamide, acrylic acid and methacrylic acid, and the monomer B is at least one selected from hydroxyethyl acrylate, hydroxyethyl methacrylate, maleic anhydride, fumaric acid, polyethylene glycol maleate, citraconic acid, antacid, itaconic acid, sodium methallylate, sodium acrylate sulfonate and 2-acrylamide-2 methylpropanesulfonic acid. Although the anti-segregation agent can obtain an obvious anti-segregation effect when the dosage of the anti-segregation agent accounts for 0.01-0.01% of the concrete gel material, the anti-segregation agent needs to be synthesized under the conditions of high temperature and air isolation, the acting force of the anti-segregation agent with materials such as cement, sand and stone is poor, the bleeding segregation phenomenon can be effectively improved only by using a higher dosage, the acting time is shorter, and the effect of improving the bleeding segregation of concrete still needs to be improved.
Disclosure of Invention
The invention aims to overcome the problem that the existing high-fluidity concrete is easy to generate bleeding segregation phenomenon, and provides a novel polyether water-retaining agent, a preparation method thereof and a cement-based building material containing the polyether water-retaining agent.
The inventor of the invention finds out after intensive research that aiming at a polyether water retention agent which takes a polyether macromonomer and unsaturated amide as main polymerization monomers, polyfunctional unsaturated carboxylic acid with dicarboxylic acid, tricarboxylic acid or tetracarboxylic acid is introduced into a macromolecular chain of the polyether water retention agent, the acting force of an additive and the surface of cement can be improved through chelating chemical action with metal ions, and further the water retention and segregation resistance of concrete is improved, but the chelating action of the polyfunctional unsaturated carboxylic acid and the metal ions is easily influenced by pH value fluctuation, and the addition of gluconate and/or citrate as a buffering agent in the polymerization reaction process can obviously reduce the change of the pH value in a system, so that the chelating process is smoothly carried out, and the water retention and segregation resistance of the obtained concrete is very excellent. Based on this, the present invention has been completed.
Specifically, the invention provides a polyether water-retaining agent, wherein a polymer contained in the polyether water-retaining agent comprises a structural unit derived from unsaturated polyether, a structural unit derived from unsaturated amide, a structural unit derived from polyfunctional unsaturated carboxylic acid, a structural unit derived from organosilicon and a structural unit derived from unsaturated sulfonate in a weight ratio of 100 (55.5-85.5): 7.4-37): 3.7-5.2: 1.8-3.7; (ii) the structural units derived from a polyfunctional unsaturated carboxylic acid have a carboxylic acid functionality of at least 2; a buffering agent is added to stabilize the pH value of a polymerization system in the synthesis process of the polyether water-retaining agent, wherein the buffering agent is gluconate and/or citrate; the pH value of the polyether water-retaining agent is 5-6.
In the polyether water-retaining agent provided by the invention, the content of the structural unit derived from unsaturated polyether is 100 parts by weight; the content of the structural unit derived from the unsaturated amide is 55.5 to 85.5 parts by weight, specifically 55.5, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 85.5 parts by weight and the like; the content of the structural unit derived from the polyfunctional unsaturated carboxylic acid is 7.4 to 37 parts by weight, specifically 7.5, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37 parts by weight and the like; the structural unit derived from the silicone is contained in an amount of 3.7 to 5.2 parts by weight, and for example, may be 3.7, 3.8, 3.9, 4.0, 4.1, 4.2, 4.3, 4.4, 4.5, 4.6, 4.7, 4.8, 4.9, 5.0, 5.1, 5.2 parts by weight, or the like; the content of the structural unit derived from the unsaturated sulfonate is 1.8 to 3.7 parts by weight, and for example, may be 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7 parts by weight, and the like.
In the present invention, the buffer is gluconate and/or citrate. The gluconate may be, for example, potassium gluconate or sodium gluconate. The citrate may be, for example, potassium citrate, sodium citrate, or the like.
In a preferred embodiment of the present invention, the weight ratio of the structural unit derived from the unsaturated polyether to the buffer is 100 (3-7.4), and for example, may be 100:3, 100:4, 100:5, 100:6, 100:7, 100:7.4, and the like.
In a preferred embodiment of the invention, the solid content of the polyether water retention agent is 8-15%.
In a preferred embodiment of the invention, the unsaturated polyether is TPEG and/or HPEG, TPEG having the formula CH2＝C(CH3)CH2CH2O(CH2CH2O)nH, HPEG molecular formula is CH2＝C(CH3)CH2O(CH2CH2O)nH and n are positive integers. In addition, the number average molecular weight of the unsaturated polyether is preferably 2300 to 2500.
In a preferred embodiment of the present invention, the polyfunctional unsaturated carboxylic acid is at least one selected from the group consisting of maleic anhydride, fumaric acid and trans-aconitic acid.
In a preferred embodiment of the invention, the unsaturated amide is acrylamide and/or methacrylamide.
In a preferred embodiment of the invention, the silicone is vinyltrimethylsilane and/or gamma-methacryloxypropyltrimethoxysilane.
In a preferred embodiment of the invention, the unsaturated sulfonate is sodium allyl sulfonate and/or sodium vinyl sulfonate.
The invention also provides a preparation method of the polyether water-retaining agent, which comprises the following steps: under the stirring condition, adding unsaturated polyether, unsaturated amide, polyfunctional unsaturated carboxylic acid, organic silicon, a buffering agent and water into a reaction kettle, uniformly mixing, adding an oxidant once again, dropwise adding a mixed aqueous solution of unsaturated sulfonate and a reducing agent, controlling the dropping within 1-4 h, stirring and reacting at room temperature for 1-5 h after the dropping is finished, and then adjusting the pH value of the obtained reaction product to 5-6; the weight ratio of the unsaturated polyether, the unsaturated amide, the polyfunctional group unsaturated carboxylic acid, the organic silicon and the unsaturated sulfonate is 100 (55.5-85.5): (7.4-37): (3.7-5.2): 1.8-3.7); the buffer is gluconate and/or citrate.
In the preparation process of the polyether water-retaining agent provided by the invention, the using amount of the unsaturated polyether is 100 parts by weight; the amount of the unsaturated amide is 55.5 to 85.5 parts by weight, specifically 55.5, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 85.5 parts by weight, or the like; the polyfunctional unsaturated carboxylic acid is used in an amount of 7.4 to 37 parts by weight, specifically 7.5, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37 parts by weight, and the like; the amount of the silicone is 3.7 to 5.2 parts by weight, for example, 3.7, 3.8, 3.9, 4.0, 4.1, 4.2, 4.3, 4.4, 4.5, 4.6, 4.7, 4.8, 4.9, 5.0, 5.1, 5.2 parts by weight, etc.; the amount of the unsaturated sulfonate to be used is 1.8 to 3.7 parts by weight, and may be, for example, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7 parts by weight or the like.
In a preferred embodiment of the present invention, the weight ratio of the unsaturated polyether to the buffer is 100 (3 to 7.4), and may be, for example, 100:3, 100:4, 100:5, 100:6, 100:7, 100:7.4, or the like.
In a preferred embodiment of the present invention, the weight ratio of the oxidizing agent to the unsaturated polyether is (3 to 5):100, and may be, for example, 3.0:100, 3.1:100, 3.2:100, 3.3:100, 3.4:100, 3.5:100, 3.6:100, 3.7:100, 3.8:100, 3.9:100, 4.0:100, 4.1:100, 4.2:100, 4.3:100, 4.4:100, 4.5:100, 4.6:100, 4.7:100, 4.8:100, 4.9:100, 5.0:100, or the like.
In a preferred embodiment of the present invention, the weight ratio of the reducing agent to the unsaturated polyether is (1.5 to 2.2):100, and may be, for example, 1.5:100, 1.6:100, 1.7:100, 1.8:100, 1.9:100, 2.0:100, 2.1:100, 2.2:100, or the like.
In a preferred embodiment of the invention, the polyether water-retaining agent is prepared from the following raw materials in parts by weight:
and determining the use amount of the sodium hydroxide and/or potassium hydroxide aqueous solution according to the final pH value, and adjusting the final pH value to 5-6.
In a preferred embodiment of the present invention, the oxidizing agent is selected from at least one of hydrogen peroxide, potassium persulfate, and ammonium persulfate.
In a preferred embodiment of the present invention, the reducing agent is selected from at least one of ascorbic acid, sodium formaldehyde sulfoxylate and sodium bisulfite.
In addition, the invention also provides a cement-based building material which contains sand, cement, an admixture, a water reducing agent, a water retaining agent and water, wherein the water retaining agent is the polyether water retaining agent.
According to the invention, unsaturated polyether, unsaturated amide, polyfunctional unsaturated carboxylic acid, organic silicon and unsaturated sulfonate with specific dosage are used in a matching way, in a system taking unsaturated polyether and unsaturated amide as main polymerization monomers and taking organic silicon and unsaturated sulfonate as auxiliary polymerization monomers, polycarboxylic acid monomers are introduced, and gluconate and/or citrate is added into the polymerization system as a buffering agent, so that the obtained polyether water retention agent can stably generate chelation with metal ions, the acting force of an additive and the cement surface is improved, and the water retention and segregation resistance of concrete is improved.
Drawings
FIG. 1 is an infrared spectrum of a polyether water-retaining agent obtained in example 1.
Detailed Description
The present invention will be described in detail below by way of examples. The examples of embodiments are intended to be illustrative of the invention and are not to be construed as limiting the invention. The examples do not specify particular techniques or conditions, and are performed according to the techniques or conditions described in the literature in the art or according to the product specifications. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available.
In the following examples and comparative examples, the parts of the raw materials are parts by weight.
Example 1
100 parts of TPEG (number average molecular weight 2400, the same below), 62.5 parts of acrylamide, 8.4 parts of maleic anhydride, 4.2 parts of gamma-methacryloxypropyltrimethoxysilane, 4.2 parts of sodium gluconate, and 729 parts of deionized water were added to the reaction kettle. After stirring for 10min, 3.6 parts of ammonium persulfate were added in one portion. Then, a mixed aqueous solution containing 1.8 parts of ascorbic acid and 2.1 parts of sodium allylsulfonate was added dropwise under stirring, and the addition was carried out for 4 hours. After the dripping is finished, stirring and reacting are continued for 2 hours. After the reaction is finished, adding the aqueous solution of sodium hydroxide into a reaction kettle, and adjusting the final pH value to 5-6 to obtain the polyether water-retaining agent with the solid content of 15%. The sample was recorded as G1. The infrared spectrum of the polyether water-retaining agent G1 (which IS separated, purified and scanned by adopting ATR accessory of Nigao force IS 5) IS shown in figure 1, and can be seen from figure 1, 3338cm-1And 3198cm-1Shows an absorption peak of N-H bond on the amide, 1778cm-1The absorption peak of carbonyl group of maleic anhydride was 1659cm-1The absorption peak of the amide at carbonyl group was 1098cm-1The peak of contraction vibration of ether bond on TPEG appeared. It can be demonstrated that acrylamide, maleic anhydride and polyether macromonomer undergo radical copolymerization.
Example 2
100 parts of TPEG, 55.5 parts of acrylamide, 7.4 parts of fumaric acid, 3.7 parts of vinyltrimethoxysilane, 3.7 parts of sodium citrate and 1440 parts of deionized water are added into the reaction kettle. After stirring for 10min, 3.0 parts of potassium persulfate was added in one portion. Then, a mixed aqueous solution containing 1.5 parts of ascorbic acid and 1.9 parts of sodium vinylsulfonate was added dropwise under stirring, and the addition was completed within 1 hour. After the dripping is finished, stirring and reacting are continued for 2 hours. After the reaction is finished, adding a sodium hydroxide aqueous solution into the reaction kettle, and adjusting the final pH value to 5-6 to obtain the polyether water-retaining agent with the solid content of 10%. The sample was recorded as G2.
Example 3
100 parts of TPEG, 55.5 parts of acrylamide, 37 parts of maleic anhydride, 3.7 parts of gamma-methacryloxypropyltrimethoxysilane, 7.4 parts of sodium gluconate and 1410 parts of deionized water were added to the reaction kettle. After stirring for 10min, 3.0 parts of ammonium persulfate was added at once. Then, a mixed aqueous solution containing 2.2 parts of ascorbic acid and 3.7 parts of sodium allylsulfonate was added dropwise under stirring, and the addition was carried out for 3 hours. After the dripping is finished, stirring and reacting are continued for 2 hours. And after the reaction is finished, adding a sodium hydroxide aqueous solution into the reaction kettle, and adjusting the final pH value to 5-6 to obtain the polyether water-retaining agent with the solid content of 10%. The sample was recorded as G3.
Example 4
100 parts of HPEG, 82.5 parts of methacrylamide, 18.5 parts of trans-aconitic acid, 5.2 parts of gamma-methacryloxypropyltrimethoxysilane, 3 parts of sodium gluconate and 1800 parts of deionized water are added into a reaction kettle. After stirring for 10min, 5.0 parts of ammonium persulfate was added at once. Then, under the condition of continuous stirring, a mixed aqueous solution containing 2.2 parts of sodium formaldehyde sulfoxylate and 1.8 parts of sodium vinylsulfonate is dropwise added, and the dropping is controlled to be finished within 3 hours. After the dripping is finished, stirring and reacting are continued for 2 hours. And after the reaction is finished, adding a sodium hydroxide aqueous solution into the reaction kettle, and adjusting the final pH value to 5-6 to obtain the polyether water-retaining agent with the solid content of 8%. The sample was recorded as G4.
Comparative example 1
104.8 parts of TPEG, 71.4 parts of acrylamide, 4.8 parts of sodium allylsulfonate, 3.8 parts of gamma-methacryloxypropyltrimethoxysilane and 1440 parts of deionized water were added to the reaction kettle. After stirring for 10min, 2.9 parts of ammonium persulfate was added at once. Then, under the condition of continuous stirring, 1.9 parts of sodium formaldehyde sulfoxylate, 23.8 parts of acrylic acid and 0.5 part of octyl mercaptan solution are dropwise added, and the dropwise addition is controlled to be finished within 4 hours. After the dripping is finished, stirring and reacting are continued for 2 hours. And after the reaction is finished, adding sodium hydroxide into the reaction kettle, and adjusting the final pH value to 5-6 to obtain the reference polyether type water-retaining agent with the solid content of 10%. The sample was recorded as DG 1.
Comparative example 2
A polyether water-retaining agent was prepared by following the procedure of example 3 except that maleic anhydride was replaced with the same parts by weight of acrylic acid and the other conditions were the same as in example 3 to obtain a reference polyether water-retaining agent having a solid content of 10%. The sample was recorded as DG 2.
Comparative example 3
A polyether water-retaining agent was prepared by following the procedure of example 3 except that sodium gluconate was replaced with the same part by weight of water and the remaining conditions were the same as in example 3 to obtain a reference polyether water-retaining agent having a solid content of 10%. The sample was recorded as DG 3.
Comparative example 4
A polyether water-retaining agent was prepared by following the procedure of example 3 except that acrylamide was replaced with the same parts by weight of TPEG, and the remaining conditions were the same as in example 3, to obtain a reference polyether water-retaining agent having a solid content of 10%. The sample was recorded as DG 4.
Test effects
(1) And (3) mortar test:
referring to GB50119-2013 about a rapid test method for concrete admixture compatibility, mortar tests are carried out on polyether water-retaining agents G1-G4 obtained in examples 1-4 and reference polyether water-retaining agents DG 1-DG 4 obtained in comparative examples 1-4. The mixing proportion of the mortar is as follows: P.O42.5 cement, 400 g; 119g of fly ash, grade II; mineral powder, S95, 136 g; sand, ISO, 1350 g; water, 215 g; the water reducing agent is a commercially available high water reducing type polycarboxylate water reducing agent, and the folded solid content is 0.066%; the water-retaining agent has a folding solid content of 0.006%. The results of the experiment are shown in table 1.
TABLE 1 mortar test data
(2) Concrete test:
the workability test and bleeding test of the mixture were carried out according to GB/T50080-2002 Standard test methods for Performance of ordinary concrete mixtures. The strength grade of the test concrete is C30 concrete: c30 concrete, the total amount of cementing material is 340kg/m3The cement is P.O.42.5 cement, the fly ash is II-grade ash, the fineness modulus of sand is 2.7, the coarse aggregate is crushed stone with the thickness of 5-25 mm, the water-cement ratio is 0.51, the sand rate is 45.5%, a commercial retarding polycarboxylic acid high-performance water reducing agent (the folding and fixing mixing amount is 0.16-0.18%) and the folding and fixing mixing amount of a water-retaining agent is 0.006%.
Table 2 concrete test data
As can be seen from the results in tables 1 and 2, the polyether water retention agent provided by the invention not only can effectively control the post-bleeding phenomenon of mortar and concrete, but also can improve the workability of concrete with high fluidity, and achieve the effects of water retention and viscosity increase. In addition, the preparation method of the polyether water-retaining agent provided by the invention is efficient, does not need a heat source, is simple in process and is suitable for a large-scale industrial production method.
Although embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are exemplary and not to be construed as limiting the present invention, and that those skilled in the art may make variations, modifications, substitutions and alterations within the scope of the present invention without departing from the spirit and scope of the present invention.
Claims (10)
1. The polyether water-retaining agent is characterized in that a polymer contained in the polyether water-retaining agent comprises a structural unit derived from unsaturated polyether, a structural unit derived from unsaturated amide, a structural unit derived from polyfunctional unsaturated carboxylic acid, a structural unit derived from organic silicon and a structural unit derived from unsaturated sulfonate in a weight ratio of 100 (55.5-85.5) to (7.4-37) to (3.7-5.2) to (1.8-3.7); (ii) the structural units derived from a polyfunctional unsaturated carboxylic acid have a carboxylic acid functionality of at least 2; a buffering agent is added to stabilize the pH value of a polymerization system in the synthesis process of the polyether water-retaining agent, wherein the buffering agent is gluconate and/or citrate; the pH value of the polyether water-retaining agent is 5-6.
2. The polyether water-retaining agent as claimed in claim 1, wherein the weight ratio of the structural unit derived from unsaturated polyether to the buffer is 100 (3-7.4).
3. The polyether water-retaining agent as claimed in claim 1, wherein the solid content of the polyether water-retaining agent is 8-15%.
4. The polyether water-retaining agent of claim 1, wherein the polyfunctional unsaturated carboxylic acid is at least one selected from the group consisting of maleic anhydride, fumaric acid and trans-aconitic acid.
5. The polyether water-retaining agent as claimed in any one of claims 1 to 4, wherein the unsaturated polyether is TPEG and/or HPEG, and the molecular formula of TPEG is CH2＝C(CH3)CH2CH2O(CH2CH2O)nH, HPEG molecular formula is CH2＝C(CH3)CH2O(CH2CH2O)nH and n are positive integers; the number average molecular weight of the unsaturated polyether is 2300-2500;
the unsaturated amide is acrylamide and/or methacrylamide;
the organic silicon is vinyl trimethylsilane and/or gamma-methacryloxypropyl trimethoxysilane;
the unsaturated sulfonate is sodium allyl sulfonate and/or sodium vinyl sulfonate.
6. A method for preparing the polyether water-retaining agent of any one of claims 1 to 5, wherein the method comprises the following steps: under the stirring condition, adding unsaturated polyether, unsaturated amide, polyfunctional unsaturated carboxylic acid, organic silicon, a buffering agent and water into a reaction kettle, uniformly mixing, adding an oxidant once again, dropwise adding a mixed aqueous solution of unsaturated sulfonate and a reducing agent, controlling the dropping within 1-4 h, stirring and reacting at room temperature for 1-5 h after the dropping is finished, and then adjusting the pH value of the obtained reaction product to 5-6; the weight ratio of the unsaturated polyether, the unsaturated amide, the polyfunctional group unsaturated carboxylic acid, the organic silicon and the unsaturated sulfonate is 100 (55.5-85.5): (7.4-37): (3.7-5.2): 1.8-3.7); the buffer is gluconate and/or citrate.
7. The preparation method of the polyether water-retaining agent as claimed in claim 6, wherein the weight ratio of the unsaturated polyether to the buffer is 100 (3-7.4).
8. The method for preparing polyether water-retaining agent as claimed in claim 6, wherein the weight ratio of the oxidant, the reducing agent and the unsaturated polyether is (3-5): 1.5-2.2): 100.
9. The method for preparing polyether water-retaining agent according to claim 6,
the oxidant is at least one of hydrogen peroxide, potassium persulfate and ammonium persulfate;
the reducing agent is selected from at least one of ascorbic acid, sodium formaldehyde sulfoxylate and sodium bisulfite.
10. A cement-based building material, which contains sand, cement, an admixture, a water reducing agent, a water retaining agent and water, wherein the water retaining agent is the polyether water retaining agent of any one of claims 1 to 5.
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| CN102826784A (en) * | 2012-09-12 | 2012-12-19 | 江苏奥莱特新材料有限公司 | Polycarboxylate water reducer and preparation method thereof |
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| CN112194762A (en) * | 2020-09-30 | 2021-01-08 | 江苏博思通新材料有限公司 | Preparation method of non-crosslinked reticular polycarboxylic acid water reducing agent |
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| CN106103514B (en) * | 2014-03-31 | 2019-10-18 | 陶氏环球技术有限责任公司 | Synthetic polymer rheology modifier and water-retaining agent substitute for cellulose ether in cement composition |
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| CN102826784A (en) * | 2012-09-12 | 2012-12-19 | 江苏奥莱特新材料有限公司 | Polycarboxylate water reducer and preparation method thereof |
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