CN112973426A - Ammonia spraying device and flue gas denitration device - Google Patents

Ammonia spraying device and flue gas denitration device Download PDF

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Publication number
CN112973426A
CN112973426A CN202110300583.XA CN202110300583A CN112973426A CN 112973426 A CN112973426 A CN 112973426A CN 202110300583 A CN202110300583 A CN 202110300583A CN 112973426 A CN112973426 A CN 112973426A
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CN
China
Prior art keywords
ammonia
flue
flue gas
ammonia spraying
ammonia injection
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110300583.XA
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Chinese (zh)
Inventor
夏怀鹏
白永锋
吴冲
王凯亮
汪洋
李伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Huadian Engineering Group Co Ltd
Huadian Environmental Protection Engineering and Technology Co Ltd
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China Huadian Engineering Group Co Ltd
Huadian Environmental Protection Engineering and Technology Co Ltd
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Publication date
Application filed by China Huadian Engineering Group Co Ltd, Huadian Environmental Protection Engineering and Technology Co Ltd filed Critical China Huadian Engineering Group Co Ltd
Priority to CN202110300583.XA priority Critical patent/CN112973426A/en
Publication of CN112973426A publication Critical patent/CN112973426A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to the technical field of environmental protection, in particular to an ammonia spraying device and a flue gas denitration device, wherein the ammonia spraying device comprises: the ammonia spraying pipeline is suitable for being horizontally arranged in the flue, the cross section of the ammonia spraying pipeline is in a diamond shape, the short diagonal line of the diamond shape is perpendicular to the flow direction of flue gas in the flue, and the long diagonal line of the diamond shape is parallel to the flow direction of the flue gas in the flue; and the nozzle is arranged on the ammonia spraying pipeline. Because the short diagonal line is perpendicular to the flowing direction of the flue gas, under the premise that the length of the ammonia spraying pipeline is not changed, the projection area of the ammonia spraying pipeline is the product of the length of the short diagonal line and the length of the ammonia spraying pipeline, the projection area can be greatly reduced, the blocking area of the flue gas is reduced, the deamination efficiency of the system is guaranteed, the system resistance is effectively reduced, the path and the area of mass transfer are increased, and the deamination efficiency is improved. In addition, due to the rhombic shape, the smoke flow guide device can guide the flow of smoke, the smoke flow is smooth, and the abrasion to an ammonia spraying pipeline is small.

Description

Ammonia spraying device and flue gas denitration device
Technical Field
The invention relates to the technical field of environmental protection, in particular to an ammonia spraying device and a flue gas denitration device.
Background
At present, a power plant carries out a new round of ultra-low emission modification project, and relates to modification and replacement of a large number of flue gas denitration devices. The improved or newly-built denitration reactor is provided with a plurality of ammonia spraying devices at the vertical section of the reactor for spraying ammonia gas, and the ammonia gas reacts with nitrogen oxides in flue gas in the reactor to remove the nitrogen oxides. The existing ammonia spraying device is made of a round steel pipe, holes are formed in the round pipe, and nozzles at different angles are welded in a cross mode to achieve ammonia spraying coverage.
The pipelines for spraying ammonia are arranged in parallel in the flue side by side, the projection area of the pipelines almost occupies half of the cross-sectional area of the whole flue, the effective cross section through which flue gas can pass is reduced, and the resistance and the energy consumption of the system are greatly increased.
Disclosure of Invention
Therefore, the technical problem to be solved by the invention is to overcome the defect of large resistance of the denitration ammonia injection device in the prior art, so that the ammonia injection device and the flue gas denitration device capable of reducing the resistance are provided.
In order to solve the above technical problem, the present invention provides an ammonia injection device, comprising:
the ammonia spraying pipeline is suitable for being horizontally arranged in the flue, the cross section of the ammonia spraying pipeline is in a diamond shape, the short diagonal line of the diamond shape is perpendicular to the flow direction of flue gas in the flue, and the long diagonal line of the diamond shape is parallel to the flow direction of the flue gas in the flue;
and the nozzle is arranged on the ammonia spraying pipeline.
Optionally, the length ratio of the long diagonal line to the short diagonal line is a, where a is greater than 1 and less than or equal to 30.
Optionally, the nozzle is disposed at a position near the bottom end of the ammonia injection pipe.
Optionally, the nozzles are uniformly and alternately arranged on two sides of the ammonia spraying pipeline close to the bottom end.
Optionally, the nozzle is arranged obliquely on the ammonia injection pipeline.
Optionally, the included angle between the central line of the nozzle and the vertical plane is B, and B is more than or equal to 15 degrees and less than or equal to 50 degrees.
Optionally, one end of the ammonia injection pipeline, which is located in the flue, is connected with a connecting piece, and the connecting piece is suitable for being connected with a fixed beam in the flue.
Optionally, the connecting piece is an angle steel.
The invention also provides a flue gas denitration device, which comprises the ammonia spraying device and a flue, wherein the ammonia spraying pipeline is horizontally arranged in the flue.
Optionally, the ammonia injection pipeline is provided with a plurality of pipelines, and the pipelines are arranged in the flue side by side.
The technical scheme of the invention has the following advantages:
1. according to the ammonia spraying device provided by the invention, when the ammonia spraying pipeline is installed in the flue, the ammonia spraying pipeline is horizontally arranged in the flue, the short diagonal line of the cross section of the ammonia spraying pipeline is vertical to the flow direction of flue gas in the flue, the long diagonal line of the cross section of the ammonia spraying pipeline is parallel to the flow direction of flue gas in the flue, and under the premise that the diamond-shaped cross section area of the ammonia spraying pipeline is equal to the circular cross section area in the prior art, namely under the condition that the ammonia spraying flow is not changed, the projection area of the ammonia spraying pipeline is the product of the length of the short diagonal line and the length of the ammonia spraying pipeline, so that the ammonia spraying pipeline can be greatly reduced, the blocking area of the flue gas is reduced, the deamination efficiency of a system is ensured, the system resistance is effectively reduced, the path and the area of mass transfer are increased, and the deamination efficiency is improved. The reduction of the system resistance can realize energy conservation; the ammonia removal efficiency is improved, so that the using amount of ammonia water can be saved. Meanwhile, the bending resistance of the rhombic ammonia spraying pipeline is superior to that of a circular pipeline with the same section, and the deformation is smaller. In addition, due to the rhombic shape, the smoke flow guide device can guide the flow of smoke, the smoke flow is smooth, and the abrasion to an ammonia spraying pipeline is small.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and other drawings can be obtained by those skilled in the art without creative efforts.
FIG. 1 is a top view of an ammonia injection device provided in example 1 of the present invention;
fig. 2 is a cross-sectional view taken at a-a shown in fig. 1.
Description of reference numerals:
1. an ammonia spraying pipeline; 2. a short diagonal line; 3. a long diagonal line; 4. and (4) a nozzle.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings, and it should be understood that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
In addition, the technical features involved in the different embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example 1
At present, a power plant carries out a new round of ultra-low emission modification project, and relates to modification and replacement of a large number of flue gas denitration devices. The improved or newly-built denitration reactor is provided with a plurality of ammonia spraying devices at the vertical section of the reactor for spraying ammonia gas, and the ammonia gas reacts with nitrogen oxides in flue gas in the reactor to remove the nitrogen oxides. The existing ammonia spraying device is made of a round steel pipe, holes are formed in the round pipe, and nozzles at different angles are welded in a cross mode to achieve ammonia spraying coverage. The pipelines for spraying ammonia are arranged in parallel in the flue side by side, the projection area of the pipelines almost occupies half of the cross-sectional area of the whole flue, the effective cross section through which flue gas can pass is reduced, and the resistance and the energy consumption of the system are greatly increased.
Therefore, the embodiment provides an ammonia injection device. In one embodiment, the ammonia injection device comprises an ammonia injection pipeline 1 and a nozzle 4.
The ammonia spraying pipeline 1 is suitable for being horizontally arranged in a flue, the cross section of the ammonia spraying pipeline 1 is in a diamond shape, the short diagonal line 2 of the diamond shape is perpendicular to the flow direction of flue gas in the flue, and the long diagonal line 3 of the diamond shape is parallel to the flow direction of the flue gas in the flue; the nozzle 4 is arranged on the ammonia spraying pipeline 1.
In the embodiment, when the ammonia injection pipeline 1 is installed in the flue, the ammonia injection pipeline 1 is horizontally arranged in the flue, with reference to fig. 1 and 2, the direction indicated by the arrow in fig. 2 is the flue gas flowing direction in the flue, the short diagonal 2 of the cross section of the ammonia injection pipeline 1 is perpendicular to the flue gas flowing direction in the flue, and the long diagonal 3 is parallel to the flue gas flowing direction in the flue, under the premise that the rhombic cross section area of the ammonia injection pipeline 1 is equal to the circular cross section area in the prior art, that is, under the condition that the ammonia injection flow is not changed, because the short diagonal 2 is perpendicular to the flue gas flowing direction, under the premise that the length of the ammonia injection pipeline 1 is not changed, the projection area of the ammonia injection pipeline 1 is the product of the length of the short diagonal 2 and the length of the ammonia injection pipeline 1, which can be greatly reduced, the blocking area of the flue gas is reduced, the deamination efficiency of the system is, but also increases the path and area of mass transfer and improves the deamination efficiency. The reduction of the system resistance can realize energy conservation; the ammonia removal efficiency is improved, so that the using amount of ammonia water can be saved. Meanwhile, the bending resistance of the rhombic ammonia spraying pipeline 1 is superior to that of a circular pipeline with the same section, and the deformation is smaller. In addition, due to the rhombic shape, the flue gas flow guide device can guide the flow of the flue gas, the flow of the flue gas is smooth, and the abrasion to the ammonia spraying pipeline 1 is small.
Specifically, the cross-sectional area of the ammonia spraying pipe 1 is calculated according to the process requirements, the lengths of the long diagonal line 3 and the short diagonal line 2 are converted according to the area, the ratio of the long diagonal line 3 to the short diagonal line 2 is determined according to the requirements, and the ammonia spraying pipe 1 can be formed by welding steel plates.
On the basis of the above-described embodiment, in a preferred embodiment, the length ratio of the long diagonal 3 to the short diagonal 2 is a, 1 < a ≦ 30. On the premise of ensuring the bending resistance of the ammonia spraying pipeline 1, the longer the value A is, the longer the long diagonal 3 is, and the shorter the short diagonal 2 is, the longer the value A is, the longer the long diagonal 3 and the short diagonal 2 are preferably adopted.
In a preferred embodiment, the value of a is 30. In an alternative embodiment, the value of a is 20 or 15.
On the basis of the above embodiments, in a preferred embodiment, the nozzle 4 is arranged at a position close to the bottom end of the ammonia injection pipe 1. Specifically, the bottom end of the ammonia injection pipe 1 refers to the position of the sharp point at the bottom. In this embodiment, set up nozzle 4 in the position department that spouts ammonia pipeline 1 and be close to the bottom, can all spout the aqueous ammonia in spouting ammonia pipeline 1, avoid spouting ammonia pipeline 1 and have the waste that remains and cause the aqueous ammonia. In other alternative embodiments, the nozzles 4 may be provided on both sides of the ammonia injection pipe 1 near the top end, or on both sides of the ammonia injection pipe 1 near the top end and both sides near the top end.
On the basis of the above embodiments, in a preferred embodiment, the nozzles 4 are uniformly and alternately arranged on both sides of the ammonia injection pipeline 1 near the bottom end. In this embodiment, with nozzle 4 in spout the even setting in turn of both sides that is close to the bottom of ammonia pipeline 1, can make even the spouting of aqueous ammonia to the flue in, avoid causing the waste of aqueous ammonia. In other alternative embodiments, the nozzles 4 may be arranged symmetrically and uniformly on both sides of the ammonia injection pipe 1 near the bottom end.
In addition to the above embodiments, in a preferred embodiment, the nozzle 4 is provided obliquely to the ammonia injection. In the present embodiment, the ammonia injection pipe 1 is provided with the nozzle 4 inclined, so that the range of ammonia injection is wide, and the efficiency of ammonia removal can be improved. In other alternative embodiments, the nozzles 4 may be horizontally or vertically disposed on both sides of the ammonia spraying pipe 1 near the bottom end, and the ammonia water is sprayed vertically through the nozzles 4 horizontally spraying out of the fire.
On the basis of the above embodiment, in a preferred embodiment, the included angle between the center line of the nozzle 4 and a vertical plane is B, wherein B is more than or equal to 15 degrees and less than or equal to 50 degrees, and specifically, the vertical plane is a plane where the long diagonal 3 is positioned and is perpendicular to the cross section.
On the basis of the above embodiments, in a preferred embodiment, one end of the ammonia injection pipeline 1, which is located in the flue, is connected with a connecting piece, and the connecting piece is suitable for being connected with a fixed beam in the flue. In this embodiment, the connector is provided to facilitate connection with the fixed beam within the flue.
In one embodiment, the connecting member is an angle iron. Specifically, an angle steel is welded at the end of the ammonia spraying pipeline 1, and holes are formed in the angle steel, so that the angle steel is connected with the fixed beam through bolts. In other alternative embodiments, the connectors may take on other shaped configurations.
Example 2
The embodiment provides a flue gas denitration device, which comprises the ammonia injection device and a flue, wherein an ammonia injection pipeline 1 of the ammonia injection device is horizontally arranged in the flue. Because the short diagonal 2 of the cross section of ammonia spraying pipeline 1 is perpendicular to the flue gas flow direction in the flue, the long diagonal 3 parallels to the flue gas flow direction in the flue, under the prerequisite that the rhombus cross sectional area of ammonia spraying pipeline 1 equals with circular cross sectional area among the prior art, also under the unchangeable condition of ammonia spraying flow, because short diagonal 2 is perpendicular to flue gas flow direction, under the unchangeable prerequisite of ammonia spraying pipeline 1 length, the projected area of ammonia spraying pipeline 1 can reduce greatly, the area of blockking to the flue gas reduces, flue gas denitrification facility's deamination efficiency has both been guaranteed, effectively reduce flue gas denitrification facility's resistance, the way and the area of mass transfer have been increased again, deamination efficiency has been improved. The energy conservation can be realized by reducing the resistance of the flue gas denitration device; the ammonia removal efficiency is improved, so that the using amount of ammonia water can be saved.
In a preferred embodiment, a plurality of ammonia injection pipes 1 are arranged in the flue and are arranged side by side in the flue. In the embodiment, the ammonia water is sprayed simultaneously by the plurality of ammonia spraying pipelines 1, so that the deamination efficiency can be ensured, the nitrogen oxides in the flue gas in the flue are obviously reduced, and the pollution to the environment is less.
It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.

Claims (10)

1. An ammonia sparger, comprising:
the ammonia spraying pipeline (1) is suitable for being horizontally arranged in the flue, the cross section of the ammonia spraying pipeline (1) is in a diamond shape, the short diagonal line (2) of the diamond shape is perpendicular to the flow direction of flue gas in the flue, and the long diagonal line (3) of the diamond shape is parallel to the flow direction of the flue gas in the flue;
and the nozzle (4) is arranged on the ammonia spraying pipeline (1).
2. An ammonia injection device according to claim 1, characterized in that the length ratio of the long diagonal (3) to the short diagonal (2) is A, 1 < A ≦ 30.
3. An ammonia injection device according to claim 1, wherein the nozzle (4) is arranged in the ammonia injection pipe (1) near the bottom end.
4. An ammonia injection device according to claim 3, wherein the nozzles (4) are arranged alternately and uniformly on both sides of the ammonia injection pipe (1) near the bottom end.
5. An ammonia injection device according to claim 4, characterized in that the nozzle (4) is arranged obliquely on the ammonia injection pipe (1).
6. An ammonia injection device according to claim 5, characterized in that the angle between the centre line of the nozzle (4) and the vertical plane is B, 15 ° ≦ B ≦ 50 °.
7. An ammonia injection device according to claim 5, characterized in that the end of the ammonia injection pipe (1) inside the flue is connected with a connector, which is adapted to be connected with a fixed beam inside the flue.
8. The ammonia injection unit of claim 7, wherein the connector is an angle iron.
9. A flue gas denitration device, which is characterized by comprising the ammonia injection device and a flue of any one of claims 1 to 8, wherein the ammonia injection pipeline (1) is horizontally arranged in the flue.
10. The flue gas denitration device according to claim 9, wherein the ammonia injection pipeline (1) is provided in plurality and arranged side by side in the flue.
CN202110300583.XA 2021-03-19 2021-03-19 Ammonia spraying device and flue gas denitration device Pending CN112973426A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114788995A (en) * 2022-04-28 2022-07-26 中国华电科工集团有限公司 Low-resistance energy-saving slurry spraying system for wet desulphurization and desulfurizing tower
CN114797409A (en) * 2022-04-28 2022-07-29 中国华电科工集团有限公司 Slurry spraying system for wet desulphurization and integrative tower of wet desulphurization and chimney
CN114849436A (en) * 2022-04-28 2022-08-05 中国华电科工集团有限公司 Low-resistance energy-saving wet desulphurization slurry spraying system and desulphurization, dehumidification and integration tower

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH119956A (en) * 1997-06-26 1999-01-19 Babcock Hitachi Kk Absorption tower of wet flue gas desulfurizer
US6887435B1 (en) * 2000-06-23 2005-05-03 The Babcock & Wilcox Company Integrated air foil and ammonia injection grid for SCR systems
CN203971743U (en) * 2014-08-22 2014-12-03 哈尔滨电气股份有限公司 A kind of flue gas even distribution device of desulfuration spray tower
CN105289182A (en) * 2015-11-11 2016-02-03 华南理工大学 Low-resistance air-cooled elliptical tube-type demister and demisting method
CN110227342A (en) * 2019-06-03 2019-09-13 北京中航泰达环保科技股份有限公司 A kind of novel reverse streaming moving bed desulfuring and denitrifying apparatus and its smoke processing system
CN209791290U (en) * 2019-06-03 2019-12-17 北京中航泰达环保科技股份有限公司 Novel counter-flow moving bed desulfurization and denitrification device and flue gas treatment system thereof
CN214635376U (en) * 2021-03-19 2021-11-09 中国华电科工集团有限公司 Ammonia spraying device and flue gas denitration device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH119956A (en) * 1997-06-26 1999-01-19 Babcock Hitachi Kk Absorption tower of wet flue gas desulfurizer
US6887435B1 (en) * 2000-06-23 2005-05-03 The Babcock & Wilcox Company Integrated air foil and ammonia injection grid for SCR systems
CN203971743U (en) * 2014-08-22 2014-12-03 哈尔滨电气股份有限公司 A kind of flue gas even distribution device of desulfuration spray tower
CN105289182A (en) * 2015-11-11 2016-02-03 华南理工大学 Low-resistance air-cooled elliptical tube-type demister and demisting method
CN110227342A (en) * 2019-06-03 2019-09-13 北京中航泰达环保科技股份有限公司 A kind of novel reverse streaming moving bed desulfuring and denitrifying apparatus and its smoke processing system
CN209791290U (en) * 2019-06-03 2019-12-17 北京中航泰达环保科技股份有限公司 Novel counter-flow moving bed desulfurization and denitrification device and flue gas treatment system thereof
CN214635376U (en) * 2021-03-19 2021-11-09 中国华电科工集团有限公司 Ammonia spraying device and flue gas denitration device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114788995A (en) * 2022-04-28 2022-07-26 中国华电科工集团有限公司 Low-resistance energy-saving slurry spraying system for wet desulphurization and desulfurizing tower
CN114797409A (en) * 2022-04-28 2022-07-29 中国华电科工集团有限公司 Slurry spraying system for wet desulphurization and integrative tower of wet desulphurization and chimney
CN114849436A (en) * 2022-04-28 2022-08-05 中国华电科工集团有限公司 Low-resistance energy-saving wet desulphurization slurry spraying system and desulphurization, dehumidification and integration tower

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