CN112965311A - Electrochromic film and preparation method thereof - Google Patents
Electrochromic film and preparation method thereof Download PDFInfo
- Publication number
- CN112965311A CN112965311A CN202110147632.0A CN202110147632A CN112965311A CN 112965311 A CN112965311 A CN 112965311A CN 202110147632 A CN202110147632 A CN 202110147632A CN 112965311 A CN112965311 A CN 112965311A
- Authority
- CN
- China
- Prior art keywords
- electrochromic
- film
- thermosetting resin
- molecules
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 36
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 26
- 239000003792 electrolyte Substances 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 238000002834 transmittance Methods 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims description 35
- -1 1-ethyl-3-methylimidazolium tetrafluoroborate Chemical compound 0.000 claims description 17
- 229920002799 BoPET Polymers 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 239000002608 ionic liquid Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000013007 heat curing Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 238000001029 thermal curing Methods 0.000 claims description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 4
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- MJSWUFPARNWKRE-UHFFFAOYSA-N B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC Chemical compound B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC.C[N+]1=CN(C=C1)CC MJSWUFPARNWKRE-UHFFFAOYSA-N 0.000 claims description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 claims description 3
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 claims description 2
- LRESCJAINPKJTO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F LRESCJAINPKJTO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims 2
- 230000008023 solidification Effects 0.000 claims 2
- 239000010408 film Substances 0.000 abstract description 44
- 239000000463 material Substances 0.000 abstract description 20
- 230000008859 change Effects 0.000 abstract description 7
- 239000012788 optical film Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 17
- 239000000203 mixture Substances 0.000 description 8
- 239000004925 Acrylic resin Substances 0.000 description 7
- 229920000178 Acrylic resin Polymers 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- FQERWQCDIIMLHB-UHFFFAOYSA-N 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium;chloride Chemical compound [Cl-].CC[NH+]1CN(C)C=C1 FQERWQCDIIMLHB-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
- G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
- G02F1/15165—Polymers
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
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CN202110147632.0A CN112965311B (en) | 2021-02-03 | 2021-02-03 | Electrochromic film and preparation method thereof |
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CN202110147632.0A CN112965311B (en) | 2021-02-03 | 2021-02-03 | Electrochromic film and preparation method thereof |
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CN112965311A true CN112965311A (en) | 2021-06-15 |
CN112965311B CN112965311B (en) | 2022-07-19 |
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CN202110147632.0A Active CN112965311B (en) | 2021-02-03 | 2021-02-03 | Electrochromic film and preparation method thereof |
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CN (1) | CN112965311B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113583526A (en) * | 2021-07-26 | 2021-11-02 | 畅的新材料科技(上海)有限公司 | Stain-resistant self-repairing coating and preparation method thereof |
CN115480419A (en) * | 2022-08-23 | 2022-12-16 | 杭州兵智科技有限公司 | Ionic liquid doped polymer dispersed liquid crystal color-changing device and preparation method thereof |
CN115572515A (en) * | 2022-10-07 | 2023-01-06 | 江苏中新瑞光学材料有限公司 | Electrochromic coating and electrochromic film based on same |
Citations (12)
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---|---|---|---|---|
US6203154B1 (en) * | 1997-12-19 | 2001-03-20 | Nippon Mitsubishi Oil Corporation | Electrochromic element |
US6285486B1 (en) * | 1997-07-15 | 2001-09-04 | Nippon Oil Co., Ltd. | Electrochromic mirror and electrochromic devices |
US20020181068A1 (en) * | 1996-03-15 | 2002-12-05 | Pierre Bonhote | Electrochromic or photoelectrochromic device |
US20060258870A1 (en) * | 2004-04-02 | 2006-11-16 | Masatomi Sen | Process for producing bipyridinium compound |
CN101852960A (en) * | 2010-05-14 | 2010-10-06 | 马鞍山市盛宁高分子材料科技有限公司 | Full-solid state macromolecule controllable electrochromism flexible film device and manufacturing method thereof |
US20110235150A1 (en) * | 2010-03-26 | 2011-09-29 | Samsung Electronics Co., Ltd. | Electrochromic material and electrochromic device including the same |
CN104610132A (en) * | 2014-11-26 | 2015-05-13 | 北京服装学院 | Viologen compound, and preparation method and application thereof |
CN105579549A (en) * | 2013-09-17 | 2016-05-11 | 埃西勒国际通用光学公司 | Electrochromic composition |
CN106371258A (en) * | 2016-10-21 | 2017-02-01 | 北京华逸高科科技有限公司 | Method for preparing electrochromic film and an electrochromic device |
US9810962B1 (en) * | 2016-08-24 | 2017-11-07 | E-Chem Enterprise Corp. | Electrochromic material and anti-dazzle mirror having the same |
CN108779113A (en) * | 2016-03-10 | 2018-11-09 | 佳能株式会社 | Organic compound, electrochromic device, electrochromic device, optical filter, image pick-up device, lens unit and window member |
CN109557740A (en) * | 2018-12-21 | 2019-04-02 | 东华大学 | A kind of preparation method of purple Luo Jingji flexible color changing piece |
-
2021
- 2021-02-03 CN CN202110147632.0A patent/CN112965311B/en active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020181068A1 (en) * | 1996-03-15 | 2002-12-05 | Pierre Bonhote | Electrochromic or photoelectrochromic device |
US6285486B1 (en) * | 1997-07-15 | 2001-09-04 | Nippon Oil Co., Ltd. | Electrochromic mirror and electrochromic devices |
US6203154B1 (en) * | 1997-12-19 | 2001-03-20 | Nippon Mitsubishi Oil Corporation | Electrochromic element |
US20060258870A1 (en) * | 2004-04-02 | 2006-11-16 | Masatomi Sen | Process for producing bipyridinium compound |
US20110235150A1 (en) * | 2010-03-26 | 2011-09-29 | Samsung Electronics Co., Ltd. | Electrochromic material and electrochromic device including the same |
CN101852960A (en) * | 2010-05-14 | 2010-10-06 | 马鞍山市盛宁高分子材料科技有限公司 | Full-solid state macromolecule controllable electrochromism flexible film device and manufacturing method thereof |
CN105579549A (en) * | 2013-09-17 | 2016-05-11 | 埃西勒国际通用光学公司 | Electrochromic composition |
CN104610132A (en) * | 2014-11-26 | 2015-05-13 | 北京服装学院 | Viologen compound, and preparation method and application thereof |
CN108779113A (en) * | 2016-03-10 | 2018-11-09 | 佳能株式会社 | Organic compound, electrochromic device, electrochromic device, optical filter, image pick-up device, lens unit and window member |
US9810962B1 (en) * | 2016-08-24 | 2017-11-07 | E-Chem Enterprise Corp. | Electrochromic material and anti-dazzle mirror having the same |
CN106371258A (en) * | 2016-10-21 | 2017-02-01 | 北京华逸高科科技有限公司 | Method for preparing electrochromic film and an electrochromic device |
CN109557740A (en) * | 2018-12-21 | 2019-04-02 | 东华大学 | A kind of preparation method of purple Luo Jingji flexible color changing piece |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113583526A (en) * | 2021-07-26 | 2021-11-02 | 畅的新材料科技(上海)有限公司 | Stain-resistant self-repairing coating and preparation method thereof |
CN115480419A (en) * | 2022-08-23 | 2022-12-16 | 杭州兵智科技有限公司 | Ionic liquid doped polymer dispersed liquid crystal color-changing device and preparation method thereof |
CN115572515A (en) * | 2022-10-07 | 2023-01-06 | 江苏中新瑞光学材料有限公司 | Electrochromic coating and electrochromic film based on same |
CN115572515B (en) * | 2022-10-07 | 2024-02-06 | 江苏中新瑞光学材料有限公司 | Electrochromic coating and electrochromic film based on same |
Also Published As
Publication number | Publication date |
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CN112965311B (en) | 2022-07-19 |
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SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An electrochromic film and its preparation method Effective date of registration: 20230129 Granted publication date: 20220719 Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd. Pledgor: CHANGDI NEW MATERIAL TECHNOLOGY (SHANGHAI) CO.,LTD. Registration number: Y2023310000012 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20220719 Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd. Pledgor: CHANGDI NEW MATERIAL TECHNOLOGY (SHANGHAI) CO.,LTD. Registration number: Y2023310000012 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A electrochromic thin film and its preparation method Granted publication date: 20220719 Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd. Pledgor: CHANGDI NEW MATERIAL TECHNOLOGY (SHANGHAI) CO.,LTD. Registration number: Y2024980007123 |