CN112960816B - Electric rust prevention method for machining machine tool - Google Patents
Electric rust prevention method for machining machine tool Download PDFInfo
- Publication number
- CN112960816B CN112960816B CN202110229691.2A CN202110229691A CN112960816B CN 112960816 B CN112960816 B CN 112960816B CN 202110229691 A CN202110229691 A CN 202110229691A CN 112960816 B CN112960816 B CN 112960816B
- Authority
- CN
- China
- Prior art keywords
- cutting fluid
- water
- workbench
- rust prevention
- filtering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
- C23F13/005—Anodic protection
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/05—Conductivity or salinity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/11—Turbidity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
An electric rust-proof method for machining machine tool features that a water-base cutting liquid collecting pool is installed around the bench, the workpiece is fixed to the bench, a DC power supply is used to supply power to the workpiece, the cathode is directly connected to bench and cutting liquid collecting pool, the anode is iron block, and the insulating fixture to bench is used to suppress the electrolysis of cathode bench and cutting liquid collecting pool. The environment-friendly water-based cutting fluid filtering and purifying and recycling are realized through the cutting fluid filtering and recycling system, and the inlet and the outlet of the cutting fluid filtering and recycling system are respectively connected with the water outlet and the water inlet of the blood pool. The invention realizes the use of the environment-friendly water-based cutting fluid and has the rust-proof function through an electric rust-proof method, and has important significance for realizing green machining.
Description
Technical Field
The invention relates to the field of machining, in particular to an electric rust prevention method for a machining machine tool.
Background
Development of cutting technology hardware is mainly reflected in improvements in machine tool and cutter technology. With the development of scientific technology, machine tools perform machining under high-efficiency, high-precision and high-quality conditions. The existing machine tool enters the era of numerical control machine tools, the existing high-end machine tool has higher vibration resistance, machining precision and efficiency, the service life and reliability of the machine tool are also improved, and rust prevention of the machine tool is an important ring for influencing the service life of the machine tool.
The cutting fluid is an industrial fluid which is used for cooling and lubricating a cutter and a workpiece in the metal cutting and grinding process and has the characteristics of good cooling performance, lubricating performance, rust resistance, oil removal cleaning function, corrosion prevention function and easy dilution. Among the several common machining modes, the most resources are consumed for cutting and grinding and the most impact on the environment is the greatest, one of the more important factors is the use of cutting fluid. The cutting and grinding are carried out by contacting with the metal blank in a large area, and the metal is processed, so that the service life of the cutter is shortened and the replacement period is shortened due to the fact that the resistance on the surface of the metal ingredients is large and the generated heat is high. The oil-based cutting fluid wastewater contains a large amount of emulsified oil, metal chips, organic matters and the like, and has high COD, total Organic Carbon (TOC) and oil concentration. If the untreated oil-based cutting fluid wastewater is discharged into a natural water body, an oil film can be formed on the water surface, so that the water body is anoxic, and the growth of organisms in water is threatened. In addition, grease in the cutting fluid wastewater has stronger permeability, and can also penetrate soil to enter an underground water layer so as to pollute an underground water source. After the additives and metal scraps in the wastewater enter the water circulation, the additives and metal scraps can enter a human body through a food chain, so that the risk of cancer is caused, and the human health is endangered. The water-based cutting fluid has lighter influence on the environment than the oil-based cutting fluid, but even if the rust-proof component is added into the water-based cutting fluid, the machine tool and the workbench can rust after a period of time.
The traditional oil-based cutting fluid has serious environmental pollution, so that the environment protection of the cutting fluid is improved when the environment-friendly machining is realized, and the water-based cutting fluid can cause rust of a machine tool and a workbench. New rust inhibitive technologies for water-based cutting fluids are sought to avoid and ameliorate this effect.
Disclosure of Invention
In order to achieve green machining using a water-based cutting fluid and to prevent rust, the present invention provides an electrical rust prevention method for a machining tool.
The technical scheme adopted for solving the technical problems is as follows:
an electric rust prevention method for a machining machine tool is characterized in that a cutting fluid collecting tank for collecting water-based cutting fluid is arranged around a workbench, a workpiece is fixed on the workbench, and a grinding wheel is used for machining the workpiece; the cathode is directly connected with the workbench and the cutting fluid collecting tank through direct current power supply, the anode is an iron block and is fixed on the workbench in an insulating way, and electrolysis of the cathode workbench and the cutting fluid collecting tank is restrained through electrolysis of the anode iron block, so that electric rust prevention is realized.
Further, the cutting fluid filtering and circulating system is used for realizing the filtering and purifying and the recycling of the water-based cutting fluid, and the inlet and the outlet of the cutting fluid filtering and circulating system are respectively connected with the water outlet and the water inlet of the cutting fluid collecting tank.
Still further, the cutting fluid in the cutting fluid collecting tank flows into the magnetic separator from the water outlet, metal scraps are roughly removed by the magnetic separator, other liquid enters the chip sedimentation tank for chip sedimentation, meanwhile, the settled chips are subjected to electric rust prevention treatment so as to prevent water quality pollution, then the liquid is pumped out of the sedimentation tank through a water pump, firstly, the impurity with the particle size of more than or equal to 5 mu m in the liquid is removed through a filter, then the liquid is pushed to a reverse osmosis membrane through a high pressure pump, and the impurity with the particle size of more than or equal to 10 mu m is removed 4 And particles and ions with the diameter of mu m, and flowing the refined cutting fluid into a water reservoir, measuring indexes such as conductivity, turbidity and the like of the cutting fluid in the water reservoir by a sensor, and pumping the cutting fluid in the water reservoir to a water inlet by a water pump to be discharged into a cutting fluid collecting tank, so that the cleaning circulation of the cutting fluid is realized.
According to the cutting fluid filtering and circulating system, the electric rust prevention is carried out on the cuttings and sedimentation tank, so that the cuttings and the sedimentation tank are prevented from being corroded by rust, and the water quality is polluted; the performance of the reverse osmosis membrane is improved by using the high-pressure pump, and the purification capacity of the cutting fluid filtering and circulating system and the flow rate of the refined cutting fluid are improved; and measuring the conductivity and turbidity of the cutting fluid in the reservoir by using a sensor, and monitoring whether the cutting fluid meets the required standard or not in real time.
The technical conception of the invention is as follows: typically, iron-containing workpieces develop rust in water due to Fe 2+ Is etched in water. In order to prevent the workpiece and the machine tool from rusting without adding an antirust component in the machining process using the water-based cutting fluid, an electric antirust method is used for rust prevention. Straight lineThe negative electrode of the current power supply is connected with the workpiece in water, the positive electrode is connected with the iron block, and the corrosion reaction formula (1) originally generated by the workpiece and the machine tool is changed into the reaction formula (2), so that the rust prevention effect is achieved.
Fe→Fe 2+ +2e - (1)
(1/2)O 2 +H 2 O+2e - →2OH - (2)
The circulating purification and the deionization of the water-based cutting fluid can be realized through the cutting fluid filtering and circulating system. Wherein, the electric rust prevention of the chip sedimentation tank can prevent chips from rusting and pollute the water quality. The removal of the reverse osmosis membrane is more than or equal to 10- 4 Particles and ions of μm, prevent the particles from scratching the workpiece and prevent contaminants (rust, ions, etc.) from adhering to the workpiece. The performance of the reverse osmosis membrane is improved by using the high-pressure pump, so that the purification capacity of the system and the flow rate of the refined water-based cutting fluid are improved. And measuring the quality (conductivity, turbidity and the like) of the cutting fluid in the reservoir by using a sensor, and monitoring whether the cutting fluid meets the required standard or not in real time.
The beneficial effects of the invention are mainly shown in the following steps: by the electric rust prevention method, the device realizes the use of the water-based cutting fluid and has the rust prevention function. The cutting fluid filtering and circulating system can save the consumption of the cutting fluid, ensure that the quality of the cutting fluid is not reduced, separate chip impurities, ions and the like in the cutting fluid, and realize zero pollution emission. The method has important significance for realizing rust prevention and green machining of the machine tool workpiece.
Drawings
Fig. 1 is a schematic view of an electrical rust inhibiter for a machine tool.
Fig. 2 is an electrical rust prevention schematic diagram of the apparatus of fig. 1.
Detailed Description
The invention is further described below with reference to the accompanying drawings.
Referring to fig. 1 and 2, an electric rust prevention method for a machine tool is provided, in which a cutting fluid collecting tank 4 for collecting a water-based cutting fluid is installed around a table 3, a work 2 is fixed to the table 3, and grinding work 2 is performed by a grinding wheel 1; the cathode is directly connected with the cutting fluid collecting tank 4 through the workbench 3 by supplying power through the direct-current power supply 18, the anode is an iron block 17, the anode is fixed on the workbench 3 in an insulating manner, and the electrolysis of the cathode workpiece 2 and the cutting fluid collecting tank 4 is inhibited by the electrolysis of the anode iron block 17, so that electric rust prevention is realized.
The device for realizing the method comprises a grinding wheel 1, a cutting fluid collecting tank 4, a workbench 3, an electric rust-proof module and a cutting fluid filtering and circulating system, wherein the grinding wheel 1 is connected with a frame, the negative electrode of the electric rust-proof module is connected with the workbench 3, the positive electrode is an iron block 17 fixed on the workbench 3 and is isolated by an insulating material, and the inlet and the outlet of the cutting fluid filtering and circulating system are respectively connected with a water outlet 5 and a water inlet 16 of the cutting fluid collecting tank.
Further, the cutting fluid filtering and circulating system is used for realizing the filtering and purifying and the recycling of the water-based cutting fluid, and the inlet and the outlet of the cutting fluid filtering and circulating system are respectively connected with the water outlet and the water inlet of the cutting fluid collecting tank 4.
The cutting fluid filtering and circulating system comprises a magnetic separator 7, a sedimentation tank 8, a first water pump 6, a first-stage filter 15, a high-pressure pump 14, a reverse osmosis membrane 12, a water reservoir 10, a sensor 11 and a second water pump 13, wherein a water outlet 5 of a cutting fluid collecting tank 4 is communicated with an inlet of the magnetic separator 7, an outlet of the magnetic separator 7 is communicated with the chip sedimentation tank 8, the chip sedimentation tank 8 pumps liquid out through the first water pump 6 and passes through the first-stage filter 15, then pushes the liquid to the reverse osmosis membrane 12 through the high-pressure pump 14 and flows into the water reservoir 10, the water reservoir 10 is internally provided with a sensor for measuring conductivity and turbidity indexes of the cutting fluid in the water reservoir 10, and the water reservoir 10 pumps the liquid out of a water inlet 16 of the cutting fluid collecting tank 4 through the second water pump 13.
The cutting fluid in the cutting fluid collecting tank 4 flows into the magnetic separator 7 from the water outlet 5, metal scraps are roughly removed by the magnetic separator, the rest of the liquid enters the chip sedimentation tank 8 for chip sedimentation, meanwhile, the electric rust prevention treatment is carried out on the settled chips to prevent the water quality from being polluted, the liquid is pumped out of the chip sedimentation tank 8 through the first water pump 6, firstly, the impurities with the size of more than or equal to 5 mu m in the liquid are removed through the first-stage filter 15, and then the liquid is pushed to the reverse osmosis membrane 12 through the high-pressure pump 14, so that the impurities with the size of more than or equal to 5 mu m are removedIn the- 4 The fine particles and ions are fed into the reservoir 10, and the conductivity, turbidity and other indicators of the cutting fluid in the reservoir 10 are measured by the sensor 11, and the cutting fluid in the reservoir 10 is pumped to the water inlet 16 by the second water pump 13 and discharged into the cutting fluid collecting tank 4.
According to the electric rust prevention method for the machining machine tool, the cathode machine tool is protected through the electrolytic anode to realize rust prevention, and the water-based cutting fluid is continuously circulated and updated through the cutting fluid filtering and circulating system.
Claims (2)
1. An electrical rust prevention method for a machining machine tool, characterized by comprising the steps of: a cutting fluid collecting tank for collecting water-based cutting fluid is arranged around the workbench, a workpiece is fixed on the workbench, power is supplied through a direct current power supply, a cathode is directly connected with the workbench and the cutting fluid collecting tank, an anode is an iron block and is fixed on the workbench in an insulating manner, electrolysis of the cathode workbench and the cutting fluid collecting tank is inhibited through electrolysis of the anode iron block, and electric rust prevention is achieved;
immersing the workpiece and the workbench by the water-based cutting fluid;
the cutting fluid filtering and circulating system is used for realizing the filtering, purifying and recycling of the environment-friendly water-based cutting fluid, and an inlet and an outlet of the cutting fluid filtering and circulating system are respectively connected with a water outlet and a water inlet of the chip sedimentation tank; the cutting fluid filtering system comprises a sedimentation tank, the sedimentation tank is used for carrying out chip sedimentation, and meanwhile, the settled chips are subjected to electric rust prevention treatment.
2. An electrical rust inhibitive method for machine tools according to claim 1, wherein: the cutting fluid filtering and circulating system is characterized in that cutting fluid in a cutting fluid collecting tank flows into a magnetic separator from a water outlet, metal scraps are roughly removed by the magnetic separator, other liquid enters a cutting fluid sedimentation tank to carry out cutting fluid sedimentation, meanwhile, electric rust prevention treatment is carried out on the settled cutting fluid so as to prevent water quality from being polluted, then the liquid is pumped out of the sedimentation tank through a water pump, firstly, impurities which are greater than or equal to 5 mu m in the liquid are removed through a primary filter, then the liquid is pushed to a reverse osmosis membrane through a high-pressure pump, particles and ions which are greater than or equal to 10-4 mu m are removed, the refined cutting fluid flows into a reservoir, conductivity and turbidity indexes of the cutting fluid in the reservoir are measured by a sensor, and the cutting fluid in the reservoir is pumped to a water inlet by the water pump and is discharged into the cutting fluid collecting tank, so that the cleaning and circulating of the cutting fluid is realized.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110229691.2A CN112960816B (en) | 2021-03-02 | 2021-03-02 | Electric rust prevention method for machining machine tool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110229691.2A CN112960816B (en) | 2021-03-02 | 2021-03-02 | Electric rust prevention method for machining machine tool |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112960816A CN112960816A (en) | 2021-06-15 |
CN112960816B true CN112960816B (en) | 2023-08-25 |
Family
ID=76276395
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110229691.2A Active CN112960816B (en) | 2021-03-02 | 2021-03-02 | Electric rust prevention method for machining machine tool |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112960816B (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101050538A (en) * | 2007-05-14 | 2007-10-10 | 杭州五源科技实业有限公司 | Electronic anti rust method between metal manufacturing procedures, and electronic anti rust apparatus |
JP2008221396A (en) * | 2007-03-13 | 2008-09-25 | Nagasaki Prefecture | Device and method for underwater endmill cutting work of nickel alloy using electric rust prevention method |
CN102990513A (en) * | 2011-09-09 | 2013-03-27 | 昆山运城压纹制版有限公司 | Filtration device of grinding machine cutting fluid |
WO2016068842A1 (en) * | 2014-10-27 | 2016-05-06 | Advanced Hydrogen Products, LLC | Water electrolysis systems and methods |
GB202004787D0 (en) * | 2020-04-01 | 2020-05-13 | Fluid Maintenance Solutions Ltd | A system and a separation for removing contaminantes from cutting fluid |
CN210731852U (en) * | 2019-10-30 | 2020-06-12 | 南通永熙机械有限公司 | Workpiece cutting device |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5674847B2 (en) * | 2013-03-28 | 2015-02-25 | ファナック株式会社 | Machine tool with cutting fluid filtration device |
-
2021
- 2021-03-02 CN CN202110229691.2A patent/CN112960816B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008221396A (en) * | 2007-03-13 | 2008-09-25 | Nagasaki Prefecture | Device and method for underwater endmill cutting work of nickel alloy using electric rust prevention method |
CN101050538A (en) * | 2007-05-14 | 2007-10-10 | 杭州五源科技实业有限公司 | Electronic anti rust method between metal manufacturing procedures, and electronic anti rust apparatus |
CN102990513A (en) * | 2011-09-09 | 2013-03-27 | 昆山运城压纹制版有限公司 | Filtration device of grinding machine cutting fluid |
WO2016068842A1 (en) * | 2014-10-27 | 2016-05-06 | Advanced Hydrogen Products, LLC | Water electrolysis systems and methods |
CN210731852U (en) * | 2019-10-30 | 2020-06-12 | 南通永熙机械有限公司 | Workpiece cutting device |
GB202004787D0 (en) * | 2020-04-01 | 2020-05-13 | Fluid Maintenance Solutions Ltd | A system and a separation for removing contaminantes from cutting fluid |
Non-Patent Citations (1)
Title |
---|
赵炳桢等.现代刀具设计与应用.《现代刀具设计与应用》.2014, * |
Also Published As
Publication number | Publication date |
---|---|
CN112960816A (en) | 2021-06-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20090242424A1 (en) | Method and apparatus for treating water or wastewater or the like | |
CN102642961A (en) | Reuse treatment method for industrial wastewater from refrigerator compressor factory | |
CN103951108A (en) | Process method for treating electroplating comprehensive wastewater | |
EA029033B1 (en) | Electrode for electrochemical abatement of chemical oxygen demand of industrial wastes | |
JP5598841B2 (en) | Machining system | |
CN214869794U (en) | Electric rust-proof device for machining machine tool | |
CN105417802B (en) | A kind of die casting waste liquid circulation uses system and recycling method | |
CN112960816B (en) | Electric rust prevention method for machining machine tool | |
US5385653A (en) | Method of and device for industrial waste water treatment | |
CN103663793A (en) | High-concentration emulsified liquid wastewater treatment method | |
JP2013132735A (en) | Wire electric discharge machine dissolving inert gas in machining fluid and wire electric discharge machining method | |
CN112936104A (en) | Electric rust-proof device for machining machine tool | |
Dehghani et al. | Treatment of wastewater by a combined technique of adsorption, electrocoagulation followed by membrane separation | |
CN102050536B (en) | Process for treating electroplating wastewater | |
CN111302573A (en) | Tank-making wastewater treatment method | |
Torosyan et al. | Updating of sewage-purification facilities of electroplating enterprises with counterflow ion-exchange filters | |
CN100439024C (en) | Electric spark machining liquid storage case device for treatment fluid containing addition agent | |
CN1286605C (en) | High speed high quality electric spark processing liquid storage tank system | |
KR100696064B1 (en) | Clean Water Supply System for Wire Cutting Machine | |
CN205347060U (en) | Die -casting waste liquid recycles system | |
CN105645632B (en) | A kind of reuse technology of electroplating wastewater | |
CN216337044U (en) | Metallurgical waste water circulation processing apparatus | |
Pardus et al. | Co-precipitation of Heavy Metals with Chromium in Brass Mill Wastewater | |
CN110563215A (en) | Online recovery process for electroplating waste liquid | |
KOLESNIKOV et al. | Development of technical solutions for preventing discharge of liquid technogenic waste at enterprises using survival processing processes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |