CN112935620A - Metal composition for welding - Google Patents

Metal composition for welding Download PDF

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Publication number
CN112935620A
CN112935620A CN202110045694.0A CN202110045694A CN112935620A CN 112935620 A CN112935620 A CN 112935620A CN 202110045694 A CN202110045694 A CN 202110045694A CN 112935620 A CN112935620 A CN 112935620A
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percent
equal
welding
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metal composition
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CN202110045694.0A
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CN112935620B (en
Inventor
王圣棻
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Pleiades Shanghai New Materials Co ltd
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Shanghai Xingang Trading Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/34Laser welding for purposes other than joining
    • B23K26/342Build-up welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Abstract

The invention provides a metal composition for welding, which comprises the following components in percentage by weight: c: 0.05 to 0.1 percent; si: 0.2 to 0.6 percent; mn: 0.2 to 0.7 percent; s: 0.01 to 0.02 percent; cr: 8 to 15 percent; ni: 0.1 to 0.15 percent; mo: 0.01 to 0.02 percent; co: 0.01-0.025%; nb: less than or equal to 0.005 percent but not 0 percent; ti: less than or equal to 0.005 percent but not 0 percent; v: 0.01 to 0.02 percent; w: less than or equal to 0.005 percent but not 0 percent; b: less than or equal to 0.005 percent but not 0 percent; the balance of Fe and inevitable impurities. The metal composition for welding provided by the invention has higher hardness, can be used for welding iron base materials, and is particularly used as a 3D printing metal consumable.

Description

Metal composition for welding
Technical Field
The present invention relates to a weld metal material, and more particularly, to a metal composition for welding and an alloy obtained from the metal composition.
Background
In the past half century, the fusion of laser technology, computer technology and new material technology has led to a new era of additive manufacturing (3D printing) technology. The additive manufacturing is a direct near-net forming technology without a mold, and is based on computer aided design/manufacturing, materials are solidified and clad layer by layer or stacked layer by layer and connected into an integral structure by block assembly welding, so that a personalized, customized and miniaturized production mode can be realized.
In terms of the physical concept of machining and manufacturing, welding is a typical example of additive manufacturing, and both a welding rod repair surfacing technology and a numerical control automatic welding technology and additive manufacturing based on a high-energy beam heat source belong to the field of generalized additive manufacturing. The technology basis for the rapid development of the additive manufacturing technology of metal components is the technical progress of taking high-energy beams (electron beams and laser beams) as special welding heat sources, the high-energy beams are very flexible, the energy can be accurately controlled, the high-energy beams are deeply fused with computer-aided design/manufacturing information technology, and metal wires or metal powder is filled into a focusing heating area or paved into the focusing heating area in a vacuum chamber or in an inert gas protection environment, so that the materials are melted and solidified and formed layer by layer.
The additive manufacturing essentially belongs to the field of material processing, commonly used additive manufacturing materials (consumables) comprise engineering plastics, rubber materials, photosensitive resin, metal, ceramic and the like, wherein the 3D printing technology of the metal materials is developed rapidly, and metal powder used in 3D printing generally requires high purity, good sphericity, narrow particle size distribution and low oxygen content. At present, the metal powder materials applied to 3D printing mainly include titanium alloys, cobalt-chromium alloys, stainless steel, aluminum alloy materials, and the like.
At present, the additive manufacturing of China already has some influential enterprises and brands in the fields of equipment, software and the like, but materials mainly depend on import, and the research and development of additive manufacturing materials with independent intellectual property rights have important significance.
Disclosure of Invention
The invention provides a metal material for welding and a composition of the metal material for welding.
In a first aspect of the invention there is provided a metallic composition for welding, in particular an additive manufacturing (3D printing) metallic or alloy consumable composition.
In a preferred embodiment of the present invention, the metal composition for welding comprises, by weight, based on the total weight of the metal composition for welding:
C:0.05-0.1%;
Si:0.2-0.6%;
Mn:0.2-0.7%;
S:0.01-0.02%;
Cr:8-15%;
Ni:0.1-0.15%;
Mo:0.01-0.02%;
Co:0.01-0.025%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.01-0.02%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
The metal composition for welding of the present invention more preferably includes, in terms of weight ratio, based on the total weight of the metal composition for welding:
C:0.07-0.085%;
Si:0.3-0.55%;
Mn:0.3-0.6%;
S:0.01-0.018%;
Cr:10-13%;
Ni:0.11-0.14%;
Mo:0.012-0.017%;
Co:0.014-0.022%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.012-0.017%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
The metal composition for welding of the present invention more preferably includes, in terms of weight ratio, based on the total weight of the metal composition for welding:
C:0.07-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.55%;
S:0.012-0.015%;
Cr:11.5-13%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.016-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.012-0.015%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
The metal composition for welding of the invention more preferably includes, in terms of weight ratio, based on the total weight of the metal composition for welding:
C:0.075-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.5%;
S:0.012-0.014%;
Cr:11.5-12.5%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.017-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.013-0.015%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
In a second aspect, the present invention provides a welding alloy, preferably prepared from the above-described welding metal composition.
The alloy for welding comprises the following components in percentage by weight based on the total weight of the alloy for welding:
C:0.05-0.1%;
Si:0.2-0.6%;
Mn:0.2-0.7%;
S:0.01-0.02%;
Cr:8-15%;
Ni:0.1-0.15%;
Mo:0.01-0.02%;
Co:0.01-0.025%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.01-0.02%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
In the alloy for welding of the present invention, the composition comprises, in terms of weight ratio, more preferably:
C:0.07-0.085%;
Si:0.3-0.55%;
Mn:0.3-0.6%;
S:0.01-0.018%;
Cr:10-13%;
Ni:0.11-0.14%;
Mo:0.012-0.017%;
Co:0.014-0.022%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.012-0.017%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
In the welding alloy of the present invention, the composition, based on the total weight of the welding alloy, more preferably includes, by weight:
C:0.07-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.55%;
S:0.012-0.015%;
Cr:11.5-13%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.016-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.012-0.015%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
In the welding alloy of the present invention, the composition, based on the total weight of the welding alloy, more preferably includes, by weight:
C:0.075-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.5%;
S:0.012-0.014%;
Cr:11.5-12.5%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.017-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
ti: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
V:0.013-0.015%;
w: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
b: less than or equal to 0.005 percent but not 0 percent; preferably more than or equal to 0.00001 percent;
the balance of Fe and inevitable impurities.
The metal composition or alloy for welding of the present invention preferably comprises a powder. Preferably, the powder is entirely elemental powder, or at least comprises elemental powder.
In a preferred embodiment, the particle size of the elemental powder is preferably 50 to 250 mesh, more preferably 60 to 200 mesh.
More preferably, the elemental powder described herein may be present in such a manner that a part of the powder has a particle diameter outside the above mesh number range, but the powder weight ratio outside this range cannot exceed 10%.
In a preferred embodiment, the particle size of any two elemental powders may be the same or different.
In a third aspect, the present invention provides a method for manufacturing a 3D printed product, comprising the steps of laying the welding metal composition of the first aspect on a substrate surface layer by layer, and sintering the welding metal composition during or after laying each layer of the welding metal composition.
Wherein the sintering may preferably be laser sintering.
The metal composition for welding and the alloy prepared from the metal composition for welding have high hardness, can be used for welding forged iron base materials, rolled steel materials and cast iron base materials, and can be particularly used as metal consumables for 3D printing (additive manufacturing).
Drawings
Fig. 1 is a schematic structural view of a metal composition additive manufacturing apparatus for welding.
Illustration of the drawings:
1. a laser beam; 2. a metal composition for welding; 3. a molten pool; 4. and (5) a workpiece.
Detailed Description
The steel alloy for a welding material and the composition of the steel alloy according to the present invention will be described below by way of example with reference to specific examples.
Example 1
In the present example, as shown in fig. 1, the metal composition for welding 2 is in a powder form. The metal composition 2 for powder welding is uniformly converged and fed into the focused laser beam 1, and the powder flow and the laser beam 1 are coaxially coupled and output. The laser beam 1 heats the workpiece 4 into a molten pool 3, the powdery metal composition 2 for welding is sprayed into the molten pool 3, and the metal composition 2 for welding is deposited to form a formed part.
The metal composition for welding 2 includes Fe, C, Si, Mn, S, Cr, Ni, Mo, Co, Ti, V, W, and B, and it is understood that the metal composition for welding 2 may contain inevitable impurities. Specifically, the proportions of the respective components of the metal composition for welding 2 to the total weight of the metal composition for welding 2 are as follows:
C:0.07%;
Si:0.55%;
Mn:0.45%;
S:0.01%;
Cr:10%;
Ni:0.1%
Mo:0.011%;
Co:0.02%;
Nb:0.001%;
Ti:0.001%;
V:0.011%;
W:0.001%;
B:0.001%;
the balance being Fe.
Example 2
In the present example, as shown in fig. 1, the metal composition for welding 2 is in a powder form. The metal composition 2 for powder welding is uniformly converged and fed into the focused laser beam 1, and the powder flow and the laser beam 1 are coaxially coupled and output. The laser beam 1 heats the workpiece 4 into a molten pool 3, the powdery metal composition 2 for welding is sprayed into the molten pool 3, and the metal composition 2 for welding is deposited to form a formed part.
The metal composition for welding 2 includes C, Si, Mn, S, Cr, Ni, Mo, Co, Ti, V, W, and B, and it is understood that the metal composition for welding 2 may contain inevitable impurities. Specifically, the proportions of the respective components of the metal composition for welding 2 to the total weight of the metal composition for welding 2 are as follows:
C:0.08%;
Si:0.5%;
Mn:0.5%;
S:0.013%;
Cr:13%;
Ni:0.12%
Mo:0.014%;
Co:0.015%;
Nb:0.001%;
Ti:0.001%;
V:0.014%;
W:0.001%;
B:0.001%;
the balance being Fe.
Example 3
In the present example, as shown in fig. 1, the metal composition for welding 2 is in a powder form. The metal composition 2 for powder welding is uniformly converged and fed into the focused laser beam 1, and the powder flow and the laser beam 1 are coaxially coupled and output. The laser beam 1 heats the workpiece 4 into a molten pool 3, the powdery metal composition 2 for welding is sprayed into the molten pool 3, and the metal composition 2 for welding is deposited to form a formed part.
The metal composition for welding 2 includes C, Si, Mn, S, Cr, Ni, Mo, Co, Ti, V, W, and B, and it is understood that the metal composition for welding 2 may contain inevitable impurities. Specifically, the proportions of the respective components of the metal composition for welding 2 to the total weight of the metal composition for welding 2 are as follows:
C:0.09%;
Si:0.45%;
Mn:0.55%;
S:0.015%;
Cr:14%;
Ni:0.14%
Mo:0.016%;
Co:0.021%;
Nb:0.001%;
Ti:0.001%;
V:0.016%;
W:0.001%;
B:0.001%;
the balance being Fe.
The steel alloy for the welding material according to the above embodiment of the present invention can be used for welding forged iron base materials, rolled steel materials, and cast iron base materials. The post-welding hardness in the non-tempered and pre-heated condition is shown in table 1, wherein the welding method employs a 3D printing (additive manufacturing) method with a thickness of 0.5mm per layer.
TABLE 1 results of the Performance test of the Steel alloys for welding materials
Figure BDA0002897204630000091
Figure BDA0002897204630000101
The embodiments of the present invention have been described in detail, but the embodiments are merely examples, and the present invention is not limited to the embodiments described above. Any equivalent modifications and substitutions to those skilled in the art are also within the scope of the present invention. Accordingly, equivalent changes and modifications made without departing from the spirit and scope of the present invention should be covered by the present invention.

Claims (10)

1. A metal composition for welding, comprising, in weight proportions based on the total weight of the metal composition for welding:
C:0.05-0.1%;
Si:0.2-0.6%;
Mn:0.2-0.7%;
S:0.01-0.02%;
Cr:8-15%;
Ni:0.1-0.15%;
Mo:0.01-0.02%;
Co:0.01-0.025%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.01-0.02%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
2. The metal composition for welding according to claim 1, comprising, in weight proportions based on the total weight of the metal composition for welding:
C:0.07-0.085%;
Si:0.3-0.55%;
Mn:0.3-0.6%;
S:0.01-0.018%;
Cr:10-13%;
Ni:0.11-0.14%;
Mo:0.012-0.017%;
Co:0.014-0.022%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.012-0.017%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
3. The metal composition for welding according to claim 1 or 2, comprising, in weight proportions based on the total weight of the metal composition for welding:
C:0.075-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.5%;
S:0.012-0.014%;
Cr:11.5-12.5%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.017-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.013-0.015%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
4. The metal composition for welding according to any of claim 1, characterized in that it comprises a powder, all of which are elemental powders, or at least comprises an elemental powder.
5. The welding metal composition as defined in claim 4, wherein the particle diameters of any two elemental powders are the same or different.
6. The metal composition for welding according to claim 5, wherein the elemental powder has a particle diameter of 50 to 250 mesh.
7. A metal alloy for welding, characterized in that, based on the total weight of the metal alloy for welding, the composition comprises, by weight:
C:0.05-0.1%;
Si:0.2-0.6%;
Mn:0.2-0.7%;
S:0.01-0.02%;
Cr:8-15%;
Ni:0.1-0.15%;
Mo:0.01-0.02%;
Co:0.01-0.025%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.01-0.02%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
8. The welding metal alloy of claim 7, wherein the composition comprises, in weight proportions, based on the total weight of the welding metal alloy:
C:0.07-0.085%;
Si:0.3-0.55%;
Mn:0.3-0.6%;
S:0.01-0.018%;
Cr:10-13%;
Ni:0.11-0.14%;
Mo:0.012-0.017%;
Co:0.014-0.022%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.012-0.017%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
9. The welding metal alloy of claim 7, wherein the composition comprises, in weight proportions, based on the total weight of the welding metal alloy:
C:0.075-0.08%;
Si:0.4-0.5%;
Mn:0.4-0.5%;
S:0.012-0.014%;
Cr:11.5-12.5%;
Ni:0.11-0.14%;
Mo:0.013-0.015%;
Co:0.017-0.02%;
nb: less than or equal to 0.005 percent but not 0 percent;
ti: less than or equal to 0.005 percent but not 0 percent;
V:0.013-0.015%;
w: less than or equal to 0.005 percent but not 0 percent;
b: less than or equal to 0.005 percent but not 0 percent;
the balance of Fe and inevitable impurities.
10. A method of manufacturing a 3D printed product, comprising:
laying the solder metal composition of claim 1 on a substrate surface layer by layer, and sintering each layer of the solder metal composition during or after laying.
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JP2004230392A (en) * 2003-01-28 2004-08-19 Jfe Steel Kk Welding material for martensitic stainless steel pipe and welding method therefor
CN1727108A (en) * 2004-05-18 2006-02-01 株式会社神户制钢所 Welding wire for modified 9Cr-1Mo steel, and submerged-arc welding material
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范晓明: "《金属凝固理论与技术》", 31 December 2019, 武汉理工大学出版社 *

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