CN112934235B - Catalyst for purifying hydrogen of new energy fuel cell - Google Patents
Catalyst for purifying hydrogen of new energy fuel cell Download PDFInfo
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- CN112934235B CN112934235B CN202110247093.8A CN202110247093A CN112934235B CN 112934235 B CN112934235 B CN 112934235B CN 202110247093 A CN202110247093 A CN 202110247093A CN 112934235 B CN112934235 B CN 112934235B
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- 239000003054 catalyst Substances 0.000 title claims abstract description 67
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 48
- 239000001257 hydrogen Substances 0.000 title claims abstract description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000000446 fuel Substances 0.000 title claims abstract description 32
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 32
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 11
- 239000000956 alloy Substances 0.000 claims abstract description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 48
- 238000003756 stirring Methods 0.000 claims description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 238000010438 heat treatment Methods 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 20
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 19
- 229910002845 Pt–Ni Inorganic materials 0.000 claims description 17
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 17
- 238000012360 testing method Methods 0.000 claims description 17
- 229910001868 water Inorganic materials 0.000 claims description 16
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 14
- 229910017604 nitric acid Inorganic materials 0.000 claims description 14
- 239000011148 porous material Substances 0.000 claims description 14
- 239000012018 catalyst precursor Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 238000004108 freeze drying Methods 0.000 claims description 10
- 238000000746 purification Methods 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 8
- 239000012295 chemical reaction liquid Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 5
- 238000003760 magnetic stirring Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 11
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 239000012286 potassium permanganate Substances 0.000 description 6
- 235000010344 sodium nitrate Nutrition 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- -1 twice that Chemical compound 0.000 description 1
Classifications
-
- B01J35/393—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- B01J35/30—
-
- B01J35/615—
-
- B01J35/638—
-
- B01J35/647—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
- C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
Abstract
The invention discloses a catalyst for purifying hydrogen of a new energy fuel cell, which is a cylindrical zirconia-graphene carrier with macroporous and mesoporous structures, wherein the catalyst carrier has high surface area, active components are distributed on the surface of the catalyst in an alloy form, and the catalyst can catalyze and purify reformed gas, so that CO in the reformed gas can be purified to be lower than 1 ppm.
Description
Technical Field
The invention relates to a catalyst for purifying hydrogen of a new energy fuel cell, belongs to the field of new energy fuel cells, and particularly relates to the field of raw material hydrogen purified in the new energy fuel cell by using the catalyst.
Technical Field
The hydrogen energy is used as an efficient, clean and renewable secondary energy source, and is applied to various fields of social life, and the demand for the hydrogen energy is increasing in recent years. At present, the main technical fields of hydrogen production include fossil fuel hydrogen production (methanol, ethanol and natural gas), biological hydrogen production, water electrolysis hydrogen production and the like.
The main way of the fuel cell hydrogen production technology is that hydrocarbon (methanol, ethanol, natural gas, etc.) is reformed or partially oxidized and then subjected to water gas shift reaction, and the obtained reformed gas contains 45% -75% of H2, 15% -25% of CO2, 0.5% -2% of CO and a small amount of H2O and N2. The fuel cell electrode material is Pt, and the presence of CO in the hydrogen-rich gas not only can poison the Pt electrode, but also can be easily adsorbed on the surface of a catalyst to prevent the catalytic oxidation of fuel, so that the content of CO in the hydrogen-rich gas must be controlled below 100 ppm.
The purification method of CO in the hydrogen-rich gas comprises a physical method and a chemical method, wherein the physical method comprises a pressure swing adsorption method, a membrane separation method and the like; chemical methods include CO methanation and CO preferential oxidation. The pressure swing adsorption method has the problems of complex system, high manufacturing cost of the membrane separation method and the like, and is not suitable for a vehicle-mounted fuel cell system. The CO methanation process consumes a large amount of hydrogen while purifying CO and occurs with the water gas shift reaction, and is therefore also not suitable. CO preferential oxidation is the most effective method for purifying CO in hydrogen-rich atmosphere, and is suitable for being applied to vehicle-mounted fuel cells or small portable fuel cells.
The preferential oxidation reaction (CO-PROX) of carbon monoxide in the hydrogen-rich atmosphere refers to the preferential catalytic oxidation of CO by adding a small amount of oxygen or air into the hydrogen-rich atmosphere. The reactions involved in the reaction are as follows:
/> （1-1）
/> （1-2）
/> （1-3）
/> （1-4）
/> （1-5）
wherein (1-1) is the target reaction; (1-2) is H 2 Is a side reaction mainly occurring in the reaction process; at higher reaction temperatures (150-300 o C) Methanation such as (1-3) (1-4) and reverse water gas shift reaction of (1-5) also occur. The methanation consumes a large amount of fuel hydrogen, and the CO generated by the reverse water gas shift reaction reduces the effect of purifying CO, which is avoided in the reaction process.
Disclosure of Invention
Based on the above, the invention provides a catalyst for purifying hydrogen of a new energy fuel cell, which takes ZrO2-GE with macropore mesoporous pores as a carrier, and Pt-Ni nano alloy active components are adhered on the surface, wherein the pore diameter is 2-7 mu m, the pore diameter of the mesoporous pores is 15-17nm, and the pore volume is 3.1-3.8cm 3 Per gram, the specific surface area of the catalyst is 400-500m 2 And/g, wherein the compressive strength of the catalyst is 7-8Mpa, and the heat conductivity coefficient is 36-39W/m/K.
Further, the alloy particles are concentrated in size distribution of 20-30nm.
Further, the catalyst is prepared by the following method:
(1) Preparing graphene oxide: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3wt% HCl solution, and then washing with deionized water for multiple times to neutrality to obtain 5-15wt.% graphene oxide suspension;
(2) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the graphene oxide solution, and magnetically stirring to obtain a sol, wherein the mole ratio of the citric acid to the nitric acid to the tetrabutyl zirconate is (2-3): (0.2-0.3): 1, a step of;
(3) Introducing the above sol into a test tube, sealing, and standing at 80-90 o C, in a vacuum drying oven, reacting for 24-36h to obtain a shaped gel;
(4) Introducing the gel in a plurality of test tubes into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, removing air by using nitrogen, and performing hydrothermal reaction to obtain a catalyst precursor;
(5) Filtering and washing the catalyst precursor, and performing reduction treatment under a reducing atmosphere by freeze drying to obtain the Pt-Ni/ZrO2-GE catalyst.
Further, the new energy fuel cell is a proton exchange membrane fuel cell.
Further, the magnetic stirring speed in the step (2) is 100rpm-200rpm, and the temperature is 18-24 o C, stirring for 60-90min, and standing for 30-40min.
Further, (12-18) mm of the test tube is (100-180) mm.
Further, the heating of the hydrothermal reaction is gradient heating: heating to 120 ℃ at a heating rate of 2-4 ℃/min, maintaining for 1 hour, then heating to 290-310 ℃ at a heating rate of 2-4 ℃/min, maintaining for 24-36 hours, stopping heating, and naturally cooling.
Further, the mass concentration of the chloroplatinic acid and the nickel nitrate in the aqueous solution is the same and is 3-5 wt%.
Further, in the step (5), a reducing atmosphere3-5vol.% H 2 /N 2 The reduction temperature is 320-350 o C。
Further, the freeze-drying time is 24-30h.
The process for preparing the Pt-Ni/ZrO2-GE catalyst of the invention is as follows:
first, graphene was prepared by hummer: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3wt% HCl solution, and then washing with deionized water for multiple times to neutrality to obtain 5-15wt.% graphene oxide suspension; the graphene is theoretically obtained, but by XRD, raman and the like, the graphene is found to be a material mainly comprising graphene oxide and secondarily comprising graphene obtained by the following method for preparing the graphene.
Secondly, tetrabutyl zirconate has a chemical formula of Zr (-O-X) 4, wherein x=ch2-CH 2-CH3 undergoes hydrolysis reaction under acidic condition, i.e., hydroxyl-OH in water undergoes substitution reaction with tetrabutyl zirconate-OX to form alcohol, then zirconium Zr- (OH) which is hydroxyl group and zirconium Zr- (OH) undergo dehydration condensation reaction with tetrabutyl zirconate to form Zr-O-Zr, which is also a hydrolysis and condensation process of ordinary tetrabutyl zirconate, and then zirconium oxide is formed by subsequent heat treatment, as in comparative example 1.
In the invention, citric acid HA is added into tetrabutyl zirconate, and in the hydrolysis process,
the citric acid chelates with Zr, and under the condition of excess citric acid, such as twice that, zr (-O-X) 4 forms at least Zr (-O-X) with citric acid 2 (A) 2 ，Zr(-O-X) 2 (A) 2 Condensing with tetrabutyl zirconate to form Zr-O-A, repeatedly condensing to obtain zirconium oxide with controllable rate and three-dimensional skeleton structure, adding graphene oxide in the hydrolysis process, wherein the graphene has strong hydrophilicity and the surface is provided withThe abundant hydroxyl groups can be further shared to reduce hydrolysis, and finally the abundant three-dimensional pore channel structure is obtained, as shown in the accompanying figures 3 and 4.
The longer the hydrolysis-condensation process is, the more favorable the formation of a three-dimensional embryo structure is.
The obtained three-dimensional block structure is placed in a hydrothermal reaction kettle, the condensation process is enhanced under the addition of extreme high temperature and high pressure, oxygen-containing groups on the surface of graphene are further reduced, the three-dimensional blank structure is reduced, the three-dimensional staggered structure is more tightly connected, a high-strength three-dimensional catalyst carrier skeleton is obtained, in the hydrothermal process, macropore or micropore structure is easy to interweave, mesopores are kept to have a mesoporous structure and cannot collapse under hydrothermal conditions, as shown in BET-BJH shown in figure 9, the pore diameter of the mesopores is 15-17nm, and the pore volume is 3.1-3.8cm 3 Per gram, the specific surface area of the catalyst is 400-500m 2 /g。
And adding an active component precursor in a hydrothermal process, wherein a Pt-Ni alloy structure is easy to form under the hydrothermal condition, and the particles have energy peaks of Pt and Ni at the same time through the energy spectrum characterization of TEM (transverse electric field) as shown in figure 6, so that the alloy structure is formed.
And then the excessive water is removed through subsequent freeze drying, heat treatment is not promoted, thermal stress is easy to occur, and the mechanical strength of the catalyst is not easy to maintain.
Then the catalyst is placed in a reducing atmosphere for reduction, so that the catalytic activity of the catalyst is improved, as shown in a figure 10, the pT-Ni alloy of the invention has a reduction peak between 300 ℃ and 350 ℃, generally, the lower the reduction peak is, the more beneficial to the improvement of the catalytic activity, the higher the reasonable dispersity of the alloy is, as shown in a figure 5, the lamellar graphene and the highly dispersed pT-Ni alloy particles can be obviously seen on the surface of the catalyst, and the sizes of the alloy particles are intensively distributed at 20 nm to 30nm.
The cylindrical structure of the catalyst obtained by the preparation method is shown in figure 1, and the preparation method can be used for mass production in a reaction kettle by firstly forming a three-dimensional blank structure and then performing hot water heat treatment, as shown in figure 2.
The compressive strength of the sample was tested by performing it on an electronic universal tester of the DSS-25T model manufactured by shimadzu corporation, japan, as shown in fig. 8.
The thermal conductivity was measured on a thermal conductivity meter (XIATECH TC 3010) using the transient hot wire method as shown in fig. 7.
The finally obtained catalyst takes ZrO2-GE with macropore mesoporous as a carrier, and a Pt-Ni nano alloy active component with the diameter of 20-30nm is attached on the surface, wherein the pore diameter is 2-7 mu m, the pore diameter of the mesoporous is 15-17nm, and the pore volume is 3.1-3.8cm 3 Per gram, the specific surface area of the catalyst is 400-500m 2 And/g, wherein the compressive strength of the catalyst is 7-8Mpa, and the heat conductivity coefficient is 36-39W/m/K.
Drawings
FIG. 1 is an optical view of a hydrogen purging catalyst of the present invention.
FIG. 2 is an optical view of a mass-produced hydrogen purification catalyst of the present invention.
Fig. 3 is an SEM image of the catalyst of the present invention.
Fig. 4 is a TEM image of the catalyst of the present invention.
Fig. 5 is a TEM image of the active component of the catalyst of the present invention.
FIG. 6 is an SEM-Mapping diagram of an alloy of Pt-Ni active components of the catalyst of the present invention.
Fig. 7 is a graph of thermal conductivity measurements for the catalyst of the present invention.
FIG. 8 is a graph showing the compressive strength test of the catalyst of the present invention.
FIG. 9 is a BET-BJH plot of the catalyst of the present invention.
FIG. 10 is a TPR graph for the catalyst of the present invention.
Detailed Description
Example 1
A catalyst for purifying hydrogen of a new energy fuel cell is prepared by the following method:
(1) Preparing graphene oxide: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3 wt% HCl solution, and then washing with deionized water to neutrality for several times to obtain graphene oxide suspension with 5-15 wt%.
(2) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the graphene oxide solution, and magnetically stirring at 100rpm to obtain a sol, wherein the temperature is 18 o C, stirring for 60min, and standing for 30min, wherein the molar ratio of the citric acid to the nitric acid to the tetrabutyl zirconate is (2): (0.2): 1.
(3) Introducing the above sol into a test tube, sealing, and standing at 80 o And C, reacting for 24 hours in a vacuum drying box to obtain the shaped gel.
(4) The gel in a plurality of test tubes is led into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, and after the nitrogen is used for removing air, hydrothermal reaction is carried out, thus obtaining the catalyst precursor.
Heating to 120 ℃ at a heating rate of 2 ℃/min, maintaining for 1 hour, then heating to 290 ℃ at 2 ℃/min, maintaining for 24 hours, stopping heating, and naturally cooling.
The mass concentration of chloroplatinic acid and nickel nitrate in the aqueous solution is the same and is 1wt.%.
(5) Filtering and washing the catalyst precursor, and freeze-drying for 24H under a reducing atmosphere of 3vol.% H 2 /N 2 Reduction temperature 320 o C, obtaining the Pt-Ni/ZrO2-GE catalyst.
The Pt-Ni/ZrO2-GE catalyst is stored under vacuum or other oxygen-free conditions.
Example 2
A catalyst for purifying hydrogen of a new energy fuel cell is prepared by the following method:
(1) Preparing graphene oxide: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3 wt% HCl solution, and then washing with deionized water to neutrality for several times to obtain graphene oxide suspension with 5-15 wt%.
(2) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the graphene oxide solution, and magnetically stirring at 150rpm to obtain a sol with a temperature of 21 DEG C o C, stirring for 75min, and standing for 35min, wherein the molar ratio of the citric acid to the nitric acid to the tetrabutyl zirconate is 2.5:0.25:1.
(3) Introducing the above sol into a test tube, sealing, and standing at 85 o And C, reacting for 30 hours in a vacuum drying box to obtain the shaped gel.
(4) The gel in a plurality of test tubes is led into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, and after the nitrogen is used for removing air, hydrothermal reaction is carried out, thus obtaining the catalyst precursor.
Heating to 120 ℃ at a heating rate of 3 ℃/min, maintaining for 1 hour, then heating to 300 ℃ at 3 ℃/min, maintaining for 30 hours, stopping heating, and naturally cooling.
The mass concentrations of chloroplatinic acid and nickel nitrate in the aqueous solution are the same and are 2wt.%.
(5) Filtering and washing the catalyst precursor, and freeze-drying for 24-30H under a reducing atmosphere of 4vol.% H 2 /N 2 Reduction temperature 335 o C, obtaining the Pt-Ni/ZrO2-GE catalyst.
The Pt-Ni/ZrO2-GE catalyst was kept under vacuum or other oxygen-free conditions and was designated S-2.
Example 3
A catalyst for purifying hydrogen of a new energy fuel cell is prepared by the following method:
(1) Preparing graphene oxide: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3 wt% HCl solution, and then washing with deionized water to neutrality for several times to obtain graphene oxide suspension with 5-15 wt%.
(2) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the graphene oxide solution, and magnetically stirring at 200rpm to obtain a sol with the temperature of 24 o C, stirring for 90min, and standing for 40min, wherein the mole ratio of the citric acid to the nitric acid to the tetrabutyl zirconate is (3): (0.3): 1.
(3) Introducing the above sol into a test tube, sealing, and standing at 90 deg.F o And C, reacting for 36 hours in a vacuum drying box to obtain the shaped gel.
(4) The gel in a plurality of test tubes is led into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, and after the nitrogen is used for removing air, hydrothermal reaction is carried out, thus obtaining the catalyst precursor.
Heating to 120 ℃ at a heating rate of 4 ℃/min, maintaining for 1 hour, then heating to 310 ℃ at the temperature of 4 ℃/min, maintaining for 36 hours, stopping heating, and naturally cooling.
The mass concentrations of chloroplatinic acid and nickel nitrate in the aqueous solution are the same and are 3wt.%.
(5) Filtering and washing the catalyst precursor, and freeze-drying for 30H under a reducing atmosphere of 5vol.% H 2 /N 2 Reduction temperature 350 o C, obtaining the Pt-Ni/ZrO2-GE catalyst.
The Pt-Ni/ZrO2-GE catalyst is stored under vacuum or other oxygen-free conditions.
Comparative example 1
A catalyst for purifying hydrogen of a new energy fuel cell is prepared by the following method:
(1) Preparing graphene oxide: adding 25ml of concentrated sulfuric acid into a flask, cooling to 0-2 ℃, adding 0.5g of natural crystalline flake graphite and 0.5g of NaNO3 into the flask while stirring, adding 3g of KMnO4 particles, and uniformly stirring; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; adding 46ml of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140ml of deionized water and 3ml of 30wt.% H2O2 for reaction for 40min after high-temperature reaction; washing with 1-3 wt% HCl solution, and then washing with deionized water to neutrality for several times to obtain graphene oxide suspension with 5-15 wt%.
(2) Adding concentrated nitric acid and tetrabutyl zirconate into the graphene oxide solution, and magnetically stirring at 150rpm to obtain a sol with the temperature of 21 o C, stirring for 75min, and standing for 35min, wherein the molar ratio of the nitric acid to the tetrabutyl zirconate is 0.25:1.
(3) Introducing the above sol into a test tube, sealing, and standing at 85 o And C, reacting for 30 hours in a vacuum drying box to obtain the shaped gel.
(2) Filtering and washing the catalyst precursor, and freeze-drying for 24-30H, loading 2wt.% Pt2wt.% Ni by isovolumetric impregnation, and performing reduction treatment in a reducing atmosphere of 4vol.% H 2 /N 2 Reduction temperature 335 o C, pt-Ni/ZrO2 catalyst, named D-1, was obtained.
Comparative example 2
A catalyst for purifying hydrogen of a new energy fuel cell is prepared by the following method:
(1) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the deionized water, and magnetically stirring at 150rpm to obtain sol with a temperature of 21 o C, stirring for 75min, and standing for 35min, wherein the molar ratio of the citric acid to the nitric acid to the tetrabutyl zirconate is 2.5:0.25:1.
(3) Introducing the above sol into a test tube, sealing, and standing at 85 o And C, reacting for 30 hours in a vacuum drying box to obtain the shaped gel.
(4) The gel in a plurality of test tubes is led into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, and after the nitrogen is used for removing air, hydrothermal reaction is carried out, thus obtaining the catalyst precursor.
Heating to 120 ℃ at a heating rate of 3 ℃/min, maintaining for 1 hour, then heating to 300 ℃ at 3 ℃/min, maintaining for 30 hours, stopping heating, and naturally cooling.
The mass concentrations of chloroplatinic acid and nickel nitrate in the aqueous solution are the same and are 2wt.%.
(5) Filtering and washing the catalyst precursor, and freeze-drying for 24-30H under a reducing atmosphere of 4vol.% H 2 /N 2 Reduction temperature 335 o C, obtaining the Pt-Ni/ZrO2 catalyst.
The Pt-Ni/ZrO2 catalyst was kept under vacuum or other oxygen-free conditions and was designated as D-2.
Purified hydrogen activity test:
reformer components: 1 vol.% CO, 1 vol.% O 2 、50 vol.% H 2 And 33 vol.% N 2 ，10 vol.% CO 2 And 5vol.% H 2 O, the conversion of CO was tested.
CO conversion:
| 110 o C | 120 o C | 140 o C | 160 o C | |
| S-2 | 100% | 100% | 97% | 89% |
| D-1 | 65% | 67% | 42% | 45% |
| D-2 | 77% | 69% | 53% | 59% |
as can be seen from the above table, the Pt-Ni/ZrO2-GE catalyst of the present invention was in the range of 110 to 120 o C has extremely high CO purifying activity, can purify CO to ppm, so that the poison of hydrogen raw material to proton exchange membrane fuel electrode is zero, D-1 has no graphene, and the obtained ZrO is subjected to anhydrous heat setting 2 The powder structure is obtained after drying, the shaping is impossible, and the specific surface area is low actively. The catalyst in D-2 can be shaped, but has no graphene, namely the whole catalyst carrier has no mesoporous input, so that the specific surface area of the carrier is reduced, the active components are obviously agglomerated on the surface of the catalyst, and in addition, the gas-solid mass transfer of reformed gas is obviously inhibited.
The above examples are preferred embodiments of the present invention, but the embodiments of the present invention are not limited to the above examples, and any other changes, modifications, substitutions, combinations, and simplifications that do not depart from the spirit and principle of the present invention should be made in the equivalent manner, and the embodiments are included in the protection scope of the present invention.
Claims (8)
1. A catalyst for purifying hydrogen of new energy fuel cell is characterized in that ZrO with macropores and mesopores is used as the catalyst 2 The GE is taken as a carrier, the surface is attached with Pt-Ni nano alloy active components, wherein the pore diameter is 2-7 mu m, the pore diameter of the mesoporous is 15-17nm, and the pore volume is 3.1-3.8cm 3 Per gram, the specific surface area of the catalyst is 400-500m 2 The compressive strength of the catalyst is 7-8Mpa, the heat conductivity coefficient is 36-39W/m/K, the size of the alloy particles is concentrated and distributed at 20-30nm, and the catalyst is of a three-dimensional block structure;
the catalyst is prepared by the following method:
(1) Preparing graphene oxide: 25mL of concentrated sulfuric acid is added into a flask, cooled to 0-2 ℃, and 0.5g of natural crystalline flake graphite and 0.5g of NaNO are added into the flask while stirring 3 And adding 3g KMnO 4 Particles, stirring uniformly; then placing the flask in a constant-temperature water bath at 35+/-2 ℃, and continuously stirring when the temperature of the reaction liquid is raised to 35+/-2 ℃; then adding 46mL of deionized water into the solution, stirring for 15min at 98+/-2 ℃, adding 140mL of deionized water and 3mL of 30wt.% H after high-temperature reaction 2 O 2 Reacting for 40min; washing with 1-3wt% HCl solution, and then washing with deionized water for multiple times to neutrality to obtain 5-15wt.% graphene oxide suspension;
(2) Adding a certain amount of citric acid, concentrated nitric acid and tetrabutyl zirconate into the graphene oxide suspension, and magnetically stirring to obtain a sol, wherein the mole ratio of the citric acid to the concentrated nitric acid to the tetrabutyl zirconate is (2-3): (0.2-0.3): 1, a step of;
(3) Introducing the sol into a test tube, sealing, placing in a vacuum drying oven at 80-90 ℃ for reaction for 24-36h to obtain a shaped gel;
(4) Introducing the gel in the test tube into a hydrothermal reaction kettle containing aqueous solution of chloroplatinic acid and nickel nitrate, removing air by using nitrogen, and performing hydrothermal reaction to obtain a catalyst precursor;
(5) The catalyst precursor is filtered and washed,and freeze drying, and performing reduction treatment under reducing atmosphere to obtain Pt-Ni/ZrO 2 -GE catalyst.
2. The catalyst for hydrogen purification of a new energy fuel cell as claimed in claim 1, wherein said new energy fuel cell is a proton exchange membrane fuel cell.
3. The catalyst for hydrogen purification for a new energy fuel cell as claimed in claim 1, wherein the magnetic stirring rotation speed in the step (2) is 100rpm-200rpm, the temperature is 18-24 ℃, the stirring time is 60-90min, and the standing time is 30-40min.
4. A catalyst for hydrogen purification of a new energy fuel cell according to claim 1, wherein (12-18) mm of said test tube is (100-180) mm.
5. The catalyst for hydrogen purification of a new energy fuel cell according to claim 1, wherein the heating of the hydrothermal reaction is a gradient temperature increase: heating to 120 ℃ at a heating rate of 2-4 ℃/min, maintaining for 1 hour, then heating to 290-310 ℃ at a heating rate of 2-4 ℃/min, maintaining for 24-36 hours, stopping heating, and naturally cooling.
6. The catalyst for hydrogen purification of a new energy fuel cell according to claim 1, wherein the mass concentrations of chloroplatinic acid and nickel nitrate in the aqueous solution are the same and are 3 to 5wt.%.
7. The catalyst for hydrogen purification for a new energy fuel cell as claimed in claim 1, wherein the reducing atmosphere in the step (5) is 3 to 5vol.% H 2 /N 2 The reduction temperature is 320-350 ℃.
8. The catalyst for hydrogen purification for a new energy fuel cell as claimed in claim 1, wherein the freeze-drying time is 24 to 30 hours.
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