CN112920863A - Low-carbon clean power component of motor gasoline and preparation method thereof - Google Patents

Low-carbon clean power component of motor gasoline and preparation method thereof Download PDF

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CN112920863A
CN112920863A CN202110144009.XA CN202110144009A CN112920863A CN 112920863 A CN112920863 A CN 112920863A CN 202110144009 A CN202110144009 A CN 202110144009A CN 112920863 A CN112920863 A CN 112920863A
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parts
power component
low
clean power
solvent oil
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李裕民
李翰超
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Shenzhen Lannuo Clean Energy Technology Co ltd
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Shenzhen Lannuo Clean Energy Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
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    • C10L10/00Use of additives to fuels or fires for particular purposes
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
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    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Detergent Compositions (AREA)
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Abstract

The invention discloses a low-carbon clean power component of motor gasoline and a preparation method thereof, wherein the low-carbon clean power component of the motor gasoline is prepared from the following raw materials: 1-5 parts of methanol, 1-3 parts of methyl tert-butyl ether, 1-2 parts of methylal, 1-10 parts of ethanol, 1 part of corrosion inhibitor, 1 part of heat booster, 1-3 parts of solvent oil, 1 part of deodorant and 3-8 parts of additive; the preparation method is used for preparing the low-carbon clean power component of the vehicle gasoline; its advantages are low harmful pollutant discharge, and high stability of methanol, alcohol and solvent oil.

Description

Low-carbon clean power component of motor gasoline and preparation method thereof
Technical Field
The invention relates to the technical field of fuel manufacturing, in particular to a low-carbon clean power component of automotive gasoline and a preparation method thereof.
Background
Automobile exhaust emission of air pollution sources in large and medium cities in China accounts for more than 40%. The treatment of urban air pollution becomes a major problem which is urgently and urgently needed to be solved by China. Therefore, the inventor invents a vehicle solvent oil clean power component and a preparation method thereof, the vehicle solvent oil clean power component can reduce the emission of harmful pollutants of solvent oil vehicles and improve the urban environment quality; the fuel oil partially replaces petroleum-based fuel, reduces petroleum import, and plays an important role in ensuring national energy safety.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a low-carbon clean power component of automotive gasoline and a preparation method thereof.
The invention has a technical scheme that:
the low-carbon clean power component of the motor gasoline is prepared from the following raw materials in parts by weight: 1-5 parts of methanol, 1-3 parts of methyl tert-butyl ether, 1-2 parts of methylal, 1-10 parts of ethanol, 1 part of corrosion inhibitor, 1 part of heat enhancer, 1-3 parts of solvent oil, 1 part of deodorant and 3-8 parts of additive, wherein the additive is prepared from the following raw materials in parts by weight: 5-10 parts of dimethyl carbonate, 2-5 parts of neopentyl glycol, 1-2 parts of n-butylamine, 1-3 parts of n-butyl methacrylate, 3-5 parts of isobutyl alcohol, 1-2 parts of dimethyl sulfoxide, 1-3 parts of methyl cyclopentadiene, 1-2 parts of isobutylamine, 1 part of corrosion inhibitor, 1 part of heating agent, 1-2 parts of diethylhydroxylamine, 1-2 parts of triethylamine and 1-2 parts of 6-di-tert-butyl-p-cresol.
One preferred scheme is that the solvent is methanol 5 parts, methyl tert-butyl ether 1 part, methylal 1 part, ethanol 1 part, corrosion inhibitor 1 part, heating agent 1 part, solvent oil 1 part and deodorant 1 part.
One preferable scheme is that the heat-insulating material comprises 5 parts of dimethyl carbonate, 2 parts of neopentyl glycol, 1 part of n-butylamine, 1 part of n-butyl methacrylate, 5 parts of isobutyl alcohol, 1 part of dimethyl sulfoxide, 2 parts of methyl cyclopentadiene, 1 part of isobutylamine, 1 part of corrosion inhibitor, 1 part of heat-increasing agent, 1 part of diethyl hydroxylamine, 1 part of triethylamine and 1 part of 6-di-tert-butyl-p-cresol.
A preparation method of a low-carbon clean power component of motor gasoline comprises the following steps:
s1, respectively injecting the solvent oil, the methyl tert-butyl ether and the methylal into a first container according to the proportion, and uniformly mixing for later use;
s2, respectively injecting the methanol, the ethanol, the additive, the corrosion inhibitor, the heat enhancer and the deodorant into a second container according to the proportion, and mixing at normal temperature for T1, wherein the mixing is uniform for later use;
s3, respectively injecting the raw materials in the first container and the second container into a third container, mixing at normal temperature for T2 and standing for T3, and uniformly mixing to obtain the vehicle solvent oil low-carbon clean power component.
In a preferred embodiment, the T1 is 40 minutes, the T2 is 40 minutes, and the T3 is 60 minutes.
By combining the technical scheme, the invention has the beneficial effects that: methanol and ethanol are internationally recognized clean fuels with oxygen contents of 50% and 34.7%, respectively. Because of high oxygen content, the solvent oil can be promoted to be fully combusted when being mixed with the solvent oil, thereby greatly reducing the emission of harmful pollutants of automobiles and being beneficial to urban environment protection; meanwhile, the consumption of petroleum-based fuel can be saved, and the national energy safety is maintained; the additive enhances the stability of mixing and burning the methanol and the ethanol with the solvent oil; the invention has the advantages of convenient process operation, fuel cost reduction, convenient vehicle use, power increase, energy consumption saving, good social benefit and contribution to popularization and application; the low-carbon clean power component of the motor gasoline also has the following advantages: 1. the vapor pressure is reduced, and the problem of air resistance of oil products in application is reduced; 2. the intersolubility and stability of the solvent oil with different qualities are enhanced; 2. the water-melting performance is good, and the water-melting rate of oil products is increased; 3. the blending combustion proportion with oil products is improved; 4. the oil way and the engine of the automobile are effectively cleaned, and the working condition of the automobile is improved; 5. good economy and flexible and convenient operability.
The foregoing description is only an overview of the technical solutions of the present invention, and in order to make the technical means of the present invention more clearly understood, the present invention may be implemented in accordance with the content of the description, and in order to make the above and other objects, features, and advantages of the present invention more clearly understandable, the following specific preferred embodiments are described in detail.
Detailed Description
The present invention will be further described with reference to specific examples for the purpose of illustrating the spirit and objects of the present invention.
The first embodiment is a low-carbon clean power component of motor gasoline, which is prepared from the following raw materials in parts by weight: 1-5 parts of methanol, 1-3 parts of methyl tert-butyl ether, 1-2 parts of methylal, 1-10 parts of ethanol, 1 part of corrosion inhibitor, 1 part of heat enhancer, 1-3 parts of solvent oil, 1 part of deodorant and 3-8 parts of additive, wherein the additive is prepared from the following raw materials in parts by weight: 5-10 parts of dimethyl carbonate, 2-5 parts of neopentyl glycol, 1-2 parts of n-butylamine, 1-3 parts of n-butyl methacrylate, 3-5 parts of isobutyl alcohol, 1-2 parts of dimethyl sulfoxide, 1-3 parts of methyl cyclopentadiene, 1-2 parts of isobutylamine, 1 part of corrosion inhibitor, 1 part of heating agent, 1-2 parts of diethylhydroxylamine, 1-2 parts of triethylamine and 1-2 parts of 6-di-tert-butyl-p-cresol.
Methanol and ethanol are internationally recognized clean fuels with oxygen contents of 50% and 34.7%, respectively. Because of high oxygen content, the solvent oil can be promoted to be fully combusted when being mixed with the solvent oil, thereby greatly reducing the emission of harmful pollutants of automobiles and being beneficial to urban environment protection; meanwhile, the consumption of petroleum-based fuel can be saved, and the national energy safety is maintained; the additive enhances the stability of mixing and burning the methanol and the ethanol with the solvent oil; the low-carbon clean power component of the motor gasoline also has the following advantages: 1. the vapor pressure is reduced, and the problem of air resistance of oil products in application is reduced; 2. the intersolubility and stability of the solvent oil with different qualities are enhanced; 2. the water-melting performance is good, and the water-melting rate of oil products is increased; 3. the blending combustion proportion with oil products is improved; 4. the oil way and the engine of the automobile are effectively cleaned, and the working condition of the automobile is improved; 5. good economy and flexible and convenient operability.
In the second example, 5 parts of methanol, 1 part of methyl tert-butyl ether, 1 part of methylal, 1 part of ethanol, 1 part of corrosion inhibitor, 1 part of heating agent, 1 part of solvent oil and 1 part of odor remover.
In the third example, 1 part of methanol, 3 parts of methyl tert-butyl ether, 2 parts of methylal, 10 parts of ethanol and 1 part of corrosion inhibitor are used.
In the fourth embodiment, 5 parts of dimethyl carbonate, 2 parts of neopentyl glycol, 1 part of n-butylamine, 1 part of n-butyl methacrylate, 5 parts of isobutyl alcohol, 1 part of dimethyl sulfoxide, 2 parts of methylcyclopentadiene, 1 part of isobutylamine, 1 part of a corrosion inhibitor, 1 part of a heat booster, 1 part of diethylhydroxylamine, 1 part of triethylamine and 1 part of 6-di-tert-butyl-p-cresol are used.
In the fifth embodiment, the catalyst comprises 10 parts of dimethyl carbonate, 5 parts of neopentyl glycol, 2 parts of n-butylamine, 3 parts of n-butyl methacrylate, 3 parts of isobutyl alcohol, 2 parts of dimethyl sulfoxide, 3 parts of methylcyclopentadiene, 2 parts of isobutylamine, 1 part of a corrosion inhibitor, 1 part of a heat booster, 2 parts of diethylhydroxylamine, 2 parts of triethylamine and 2 parts of 6-di-tert-butyl-p-cresol.
Table 1 shows the results of comparative pollutant emissions tests in the first to fifth examples.
Figure RE-GDA0002993142880000041
In a sixth embodiment, a method for preparing a low-carbon clean power component of motor gasoline comprises the following steps:
s1, respectively injecting the solvent oil, the methyl tert-butyl ether and the methylal into a first container according to the proportion, and uniformly mixing for later use; 1-3 parts of solvent oil, 1-3 parts of methyl tert-butyl ether and 1-2 parts of methylal are respectively injected into a first container and are uniformly mixed for later use.
S2, respectively injecting the methanol, the ethanol, the additive, the corrosion inhibitor, the heat enhancer and the deodorant into a second container according to the proportion, and mixing at normal temperature for T1, wherein the mixing is uniform for later use; respectively injecting 1-5 parts of methanol, 1-10 parts of ethanol, 3-8 parts of additive, 1 part of corrosion inhibitor, 1 part of heat enhancer and 1 part of deodorant into a second container, and mixing at normal temperature for T1;
s3, respectively injecting the raw materials in the first container and the second container into a third container, mixing at normal temperature for T2 and standing for T3, and uniformly mixing to obtain the vehicle solvent oil low-carbon clean power component.
Preferably, the T1 is 40 minutes, the T2 is 40 minutes, and the T3 is 60 minutes.
The invention has the advantages of convenient process operation, fuel cost reduction, convenient vehicle use, power increase, energy consumption saving, good social benefit and favorable popularization and application.
In a seventh embodiment, a method for preparing a low-carbon clean power component of motor gasoline comprises:
s1, respectively injecting 1 part of solvent oil, 1 part of methyl tert-butyl ether and 1 part of methylal into a first container, and uniformly mixing for later use.
S2, respectively injecting 5 parts of methanol, 1 part of ethanol, 3 parts of additive, 1 part of corrosion inhibitor, 1 part of heat enhancer and 1 part of deodorant into a second container, and mixing at normal temperature for T1;
s3, respectively injecting the raw materials in the first container and the second container into a third container, mixing at normal temperature for T2 and standing for T3, and uniformly mixing to obtain the vehicle solvent oil low-carbon clean power component.
In an eighth embodiment, a method for preparing a vehicle solvent oil clean low carbon power component includes:
s1, respectively injecting 1 part of solvent oil, 1 part of methyl tert-butyl ether and 1 part of methylal into a first container, and uniformly mixing for later use.
S2, respectively injecting 5 parts of methanol, 1 part of ethanol, 8 parts of additive, 1 part of corrosion inhibitor, 1 part of heat enhancer and 1 part of deodorant into a second container, and mixing at normal temperature for T1;
s3, respectively injecting the raw materials in the first container and the second container into a third container, mixing at normal temperature for T2 and standing for T3, and uniformly mixing to obtain the clean power component of the solvent oil for the vehicle.
The foregoing is a detailed description of the invention, and it should be noted that modifications and adaptations can be made by those skilled in the art without departing from the principle of the invention, and are intended to be within the scope of the invention.

Claims (5)

1. The low-carbon clean power component of the motor gasoline is characterized by being prepared from the following raw materials in parts by weight: 1-5 parts of methanol, 1-3 parts of methyl tert-butyl ether, 1-2 parts of methylal, 1-10 parts of ethanol, 1 part of corrosion inhibitor, 1 part of heat enhancer, 1-3 parts of solvent oil, 1 part of deodorant and 3-8 parts of additive, wherein the additive is prepared from the following raw materials in parts by weight: 5-10 parts of dimethyl carbonate, 2-5 parts of neopentyl glycol, 1-2 parts of n-butylamine, 1-3 parts of n-butyl methacrylate, 3-5 parts of isobutyl alcohol, 1-2 parts of dimethyl sulfoxide, 1-3 parts of methyl cyclopentadiene, 1-2 parts of isobutylamine, 1 part of corrosion inhibitor, 1 part of heating agent, 1-2 parts of diethylhydroxylamine, 1-2 parts of triethylamine and 1-2 parts of 6-di-tert-butyl-p-cresol.
2. The low-carbon clean power component of the motor gasoline as defined in claim 1, wherein the low-carbon clean power component comprises 5 parts of methanol, 1 part of methyl tert-butyl ether, 1 part of methylal, 1 part of ethanol, 1 part of corrosion inhibitor, 1 part of heat enhancer, 1 part of solvent oil and 1 part of odor remover.
3. The low-carbon clean power component of the motor gasoline as defined in claim 1 or 2, wherein the component comprises 5 parts of dimethyl carbonate, 2 parts of neopentyl glycol, 1 part of n-butylamine, 1 part of n-butyl methacrylate, 5 parts of isobutyl alcohol, 1 part of dimethyl sulfoxide, 2 parts of methyl cyclopentadiene, 1 part of isobutylamine, 1 part of corrosion inhibitor, 1 part of heat booster, 1 part of diethylhydroxylamine, 1 part of triethylamine and 1 part of 6-di-tert-butyl-p-cresol.
4. A method for preparing the low-carbon clean power component of the motor gasoline according to any one of claims 1 to 3, which is characterized by comprising the following steps:
s1, respectively injecting the solvent oil, the methyl tert-butyl ether and the methylal into a first container according to the proportion, and uniformly mixing for later use;
s2, respectively injecting the methanol, the ethanol, the additive, the corrosion inhibitor, the heat enhancer and the deodorant into a second container according to the proportion, and mixing at normal temperature for T1, wherein the mixing is uniform for later use;
s3, respectively injecting the raw materials in the first container and the second container into a third container, mixing at normal temperature for T2 and standing for T3, and uniformly mixing to obtain the clean power component of the solvent oil for the vehicle.
5. The method for preparing the low-carbon clean power component of the motor gasoline as claimed in claim 4, wherein the T1 is 40 minutes, the T2 is 40 minutes, and the T3 is 60 minutes.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060174538A1 (en) * 2005-02-07 2006-08-10 Mao-Sheng Lee Vehicle fuel composition
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