CN112898704A - High-performance modified polyvinyl chloride - Google Patents
High-performance modified polyvinyl chloride Download PDFInfo
- Publication number
- CN112898704A CN112898704A CN202110390457.8A CN202110390457A CN112898704A CN 112898704 A CN112898704 A CN 112898704A CN 202110390457 A CN202110390457 A CN 202110390457A CN 112898704 A CN112898704 A CN 112898704A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyvinyl chloride
- calcium polyphosphate
- nitrile rubber
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 55
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 55
- 239000004132 Calcium polyphosphate Substances 0.000 claims abstract description 34
- 235000019827 calcium polyphosphate Nutrition 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- 239000000945 filler Substances 0.000 claims abstract description 30
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 26
- 150000001669 calcium Chemical class 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 239000000314 lubricant Substances 0.000 claims abstract description 18
- 239000004014 plasticizer Substances 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 9
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 238000013329 compounding Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- 230000000052 comparative effect Effects 0.000 description 9
- 239000012510 hollow fiber Substances 0.000 description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- BKUSIKGSPSFQAC-RRKCRQDMSA-N 2'-deoxyinosine-5'-diphosphate Chemical compound O1[C@H](CO[P@@](O)(=O)OP(O)(O)=O)[C@@H](O)C[C@@H]1N1C(NC=NC2=O)=C2N=C1 BKUSIKGSPSFQAC-RRKCRQDMSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses high-performance modified polyvinyl chloride, which comprises the following raw materials: PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant. According to the high-performance modified polyvinyl chloride, the high-performance modified polyvinyl chloride is added with the partially crosslinked nitrile rubber, and the compound filler and the modified calcium polyphosphate are added, so that various mechanical properties of the polyvinyl chloride are further improved in a balanced manner.
Description
[ technical field ] A method for producing a semiconductor device
The invention belongs to the technical field of polymers, and particularly relates to high-performance modified polyvinyl chloride.
[ background of the invention ]
Polyvinyl chloride is one of the earliest plastic varieties for realizing industrialization in the world, is a general resin with excellent performance and low price, has the advantages of excellent flame retardant property, corrosion resistance, wear resistance, small friction coefficient, low thermal conductivity, good sealing property, dust prevention, sound insulation, shock resistance, weather resistance and the like, and is widely applied to the fields of buildings, light industry, agriculture, packaging, daily use and the like. However, the polyvinyl chloride molecules contain a large amount of C-Cl bonds, and a large acting force exists among the molecules, so the polyvinyl chloride molecules are relatively hard, show a certain brittleness to the outside, and have poor impact strength.
Therefore, a high-performance modified polyvinyl chloride and a preparation method thereof are urgently needed.
[ summary of the invention ]
The invention provides high-performance modified polyvinyl chloride and a preparation method thereof, and the prepared product has a polyvinyl chloride material with excellent mechanical property by optimizing components and dosage.
In order to solve the technical problems, the invention adopts the following technical scheme:
the high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant; the gel mass percentage content of the partially crosslinked nitrile rubber is 40-60%; the compound filler is formed by mixing hollow structure fibers and hydroxyl silicone oil, and the modified calcium polyphosphate is calcium polyphosphate subjected to surface modification by a silane coupling agent; the mass ratio of the PVC to the partially crosslinked nitrile rubber is 100: 15-25.
Further, the high-performance modified polyvinyl chloride comprises the following raw materials in parts by mass: 100 parts of PVC, 15-25 parts of partially crosslinked nitrile rubber, 5-10 parts of compound filler, 5-10 parts of modified calcium polyphosphate, 4-6 parts of plasticizer, 1-3 parts of antioxidant and 2-4 parts of lubricant.
Further, the compound filling agent is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 5-15min, and filtering.
Further, the hollow structural fiber is nylon 66 chopped fiber with the hollowness of 10-20%.
Further, the plasticizer is DOP, DOS, DIDP, liquid polyester type.
Further, the compounding mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 5-10.
Further, the antioxidant is antioxidant 1010 or antioxidant DLTP.
Further, the lubricant is at least one of calcium stearate, paraffin wax and polyethylene wax.
The preparation method of the high-performance modified polyvinyl chloride is characterized by comprising the following steps:
(1) weighing PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant according to the formula, and putting the materials into a mixer to be stirred for 1-3 minutes to obtain a mixed raw material;
(2) putting the mixed raw materials in the step 1 into a double-screw extruder for reaction, allowing the materials to stay in a machine barrel for 1-2min to obtain a reaction product,
(3) and cutting the reaction product into particles and drying to obtain a finished product.
Further, the temperatures of the zones of the twin-screw extruder are as follows: the first zone is 180-class at 200 ℃, the second zone is 200-class at 220 ℃, the third zone is 200-class at 220 ℃, the fourth zone is 200-class at 220 ℃, the fifth zone is 200-class at 220 ℃, the sixth zone is 200-class at 220 ℃, the seventh zone is 200-class at 220 ℃, the eighth zone is 200-class at 220 ℃, the ninth zone is 200-class at 220 ℃, and the head is 200-class at 210 ℃.
The invention has the following beneficial effects:
1) the invention takes PVC as a substrate, and adds the partially crosslinked nitrile rubber with certain gel content, thereby effectively improving the impact resistance of the polyvinyl chloride and balancing and improving other properties, wherein the impact resistance is reduced due to excessive gel content, and other mechanical properties are reduced due to excessive gel content.
2) The invention prepares the compound filling agent, and takes the modified calcium polyphosphate as the filling main body. The compound filler is a compound of hollow fibers and hydroxyl silicone oil, the impact resistance and other mechanical properties of the resin are greatly improved by adding the hollow fibers, and the hollowness of the hollow fibers is 10-20%. Too high hollowness will result in mechanical properties decreasing and easy to bubble, and too low hollowness will result in failure to achieve a large improvement in impact resistance. Through the pre-compounding of the hollow fiber and the hydroxyl silicone oil, the air reserved in the hollow fiber can be effectively removed, the bubbling phenomenon is prevented, and the dispersion can be promoted. Compared with other inorganic fillers, the modified calcium polyphosphate has the advantage that the overall rigidity of the polyvinyl chloride is greatly improved by adding the inorganic polymer with long chain. The compound filling agent and the modified calcium polyphosphate are added simultaneously, so that the polyvinyl chloride composite material has the characteristics of improving the mechanical properties of all polyvinyl chloride in a balanced manner and overcoming the characteristic that the traditional filling agent brings partial performance deterioration.
According to the high-performance modified polyvinyl chloride, the high-performance modified polyvinyl chloride is added with the partially crosslinked nitrile rubber, and the compound filler and the modified calcium polyphosphate are added, so that various mechanical properties of the polyvinyl chloride are further improved in a balanced manner.
[ detailed description ] embodiments
In order to facilitate a better understanding of the invention, the following examples are given to illustrate, but not to limit the scope of the invention.
The following is a more specific example.
The high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: 100 parts of PVC, 15-25 parts of partially crosslinked nitrile rubber, 5-10 parts of compound filler, 5-10 parts of modified calcium polyphosphate, 4-6 parts of plasticizer, 1-3 parts of antioxidant and 2-4 parts of lubricant.
The gel mass percentage content of the partially crosslinked nitrile rubber is 40-60%. The compound filler is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 5-15min and filtering. The hollow structure fiber is nylon 66 chopped fiber with the hollowness of 10-20%. The plasticizer is DOP. The compound mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 5-10. The antioxidant is antioxidant 1010. The lubricant is polyethylene wax.
The preparation method of the high-performance modified polyvinyl chloride is characterized by comprising the following steps:
(1) weighing PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant according to the formula, and putting the materials into a mixer to be stirred for 1-3 minutes to obtain a mixed raw material;
(2) putting the mixed raw materials obtained in the step 1 into a double-screw extruder for reaction, wherein the materials stay in a machine barrel for 1-2min to obtain a reaction product, and the temperature of each zone of the double-screw extruder is as follows: the first zone is 180-class at 200 ℃, the second zone is 200-class at 220 ℃, the third zone is 200-class at 220 ℃, the fourth zone is 200-class at 220 ℃, the fifth zone is 200-class at 220 ℃, the sixth zone is 200-class at 220 ℃, the seventh zone is 200-class at 220 ℃, the eighth zone is 200-class at 220 ℃, the ninth zone is 200-class at 220 ℃, and the head is 200-class at 210 ℃.
(3) And cutting the reaction product into particles and drying to obtain a finished product.
Example 1
The high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: 100 parts of PVC, 20 parts of partially crosslinked nitrile rubber, 7.5 parts of compound filler, 7.5 parts of modified calcium polyphosphate, 5 parts of plasticizer, 2 parts of antioxidant and 3 parts of lubricant.
The gel mass percentage content of the partially crosslinked nitrile rubber is 50%. The compound filler is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 10min and filtering. The hollow structure fiber is nylon 66 chopped fiber with the hollowness of 15%. The plasticizer is DOP. The compounding mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 7.5. The antioxidant is antioxidant 1010. The lubricant is polyethylene wax.
The preparation method of the high-performance modified polyvinyl chloride is characterized by comprising the following steps:
(1) weighing PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant according to the formula, and putting the materials into a mixer to be stirred for 2 minutes to obtain a mixed raw material;
(2) putting the mixed raw materials obtained in the step 1 into a double-screw extruder for reaction, wherein the materials stay in a machine barrel for 1-2min to obtain a reaction product, and the temperature of each zone of the double-screw extruder is as follows: the first zone is 180-class at 200 ℃, the second zone is 200-class at 220 ℃, the third zone is 200-class at 220 ℃, the fourth zone is 200-class at 220 ℃, the fifth zone is 200-class at 220 ℃, the sixth zone is 200-class at 220 ℃, the seventh zone is 200-class at 220 ℃, the eighth zone is 200-class at 220 ℃, the ninth zone is 200-class at 220 ℃, and the head is 200-class at 210 ℃.
(3) And cutting the reaction product into particles and drying to obtain a finished product.
Example 2
The high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: 100 parts of PVC, 25 parts of partially crosslinked nitrile rubber, 5 parts of compound filler, 10 parts of modified calcium polyphosphate, 4 parts of plasticizer, 3 parts of antioxidant and 2 parts of lubricant.
The gel mass percentage content of the partially crosslinked nitrile rubber is 60%. The compound filler is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 5min and filtering. The hollow structure fiber is nylon 66 chopped fiber with the hollowness of 20%. The plasticizer is DOP. The compounding mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 5. The antioxidant is antioxidant 1010. The lubricant is polyethylene wax.
The preparation method is the same as that of example 1.
Example 3
The high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: 100 parts of PVC, 15 parts of partially crosslinked nitrile rubber, 10 parts of compound filler, 5 parts of modified calcium polyphosphate, 6 parts of plasticizer, 1 part of antioxidant and 4 parts of lubricant.
The gel mass percentage content of the partially crosslinked nitrile rubber is 40%. The compound filler is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 15min and filtering. The hollow structure fiber is nylon 66 chopped fiber with the hollowness of 10%. The plasticizer is DOP. The compounding mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 10. The antioxidant is antioxidant 1010. The lubricant is polyethylene wax.
The preparation method is the same as that of example 1.
Comparative example 1
The procedure was essentially the same as in example 1, except that the partially crosslinked nitrile rubber was absent from the raw materials used to prepare the high performance modified polyvinyl chloride.
Comparative example 2
The procedure was essentially the same as in example 1, except that the gel content of the partially crosslinked nitrile rubber in the starting material for the preparation of the high-performance modified polyvinyl chloride was 20%.
Comparative example 3
The procedure was essentially the same as in example 1, except that the gel content of the partially crosslinked nitrile rubber in the starting material for the preparation of the high-performance modified polyvinyl chloride was 80%.
Comparative example 4
The preparation process is basically the same as that of example 1, except that sulfur in the raw materials for preparing the high-performance modified polyvinyl chloride lacks compound filler, modified calcium polyphosphate.
Comparative example 5
The process was essentially the same as that used in example 1, except that the raw materials used to prepare the high performance modified polyvinyl chloride lacked the built-in filler.
Comparative example 6
The preparation process was substantially the same as that of example 1, except that modified calcium polyphosphate was absent from the raw materials for preparing the high-performance modified polyvinyl chloride.
Comparative example 7
The preparation process is basically the same as that of example 1, except that the compound filler in the raw materials for preparing the high-performance modified polyvinyl chloride is directly replaced by the hollow fiber.
Comparative example 8
The preparation process is basically the same as that of example 1, except that the compound filler in the raw materials for preparing the high-performance modified polyvinyl chloride is directly replaced by the common fiber.
Tensile strength was measured according to ASTM D-638, and flexural strength was measured according to ASTM D-790. Rockwell hardness was measured according to ISO 2039-2. The impact properties were tested at 25 ℃.
From the above table, it can be seen that: as can be seen from the data of examples 1-3 and comparative examples 1-8, the high-performance modified polyvinyl chloride further improves various mechanical properties of the polyvinyl chloride in a balanced manner by adding part of cross-linked nitrile rubber and adding compound filler to modify calcium polyphosphate.
The above description should not be taken as limiting the invention to the embodiments, but rather, as will be apparent to those skilled in the art to which the invention pertains, numerous simplifications or substitutions may be made without departing from the spirit of the invention, which shall be deemed to fall within the scope of the invention as defined by the claims appended hereto.
Claims (1)
1. The high-performance modified polyvinyl chloride is characterized by comprising the following raw materials in parts by mass: 100 parts of PVC, 20 parts of partially crosslinked nitrile rubber, 7.5 parts of compound filler, 7.5 parts of modified calcium polyphosphate, 5 parts of plasticizer, 2 parts of antioxidant and 3 parts of lubricant;
the gel mass percentage content of the partially crosslinked nitrile rubber is 50%; the compound filler is obtained by immersing the hollow structure fiber into hydroxyl silicone oil, ultrasonically vibrating for 10min and filtering; the hollow structure fiber is nylon 66 chopped fiber with the hollowness of 15 percent; the plasticizer is DOP; the compounding mass ratio of the calcium polyphosphate to the silane coupling agent in the modified calcium polyphosphate is 100: 7.5; the antioxidant is 1010; the lubricant is polyethylene wax;
the preparation method of the high-performance modified polyvinyl chloride comprises the following steps:
(1) weighing PVC, partially crosslinked nitrile rubber, a compound filler, modified calcium polyphosphate, a plasticizer, an antioxidant and a lubricant according to the formula, and putting the materials into a mixer to be stirred for 2 minutes to obtain a mixed raw material;
(2) putting the mixed raw materials obtained in the step 1 into a double-screw extruder for reaction, wherein the materials stay in a machine barrel for 1-2min to obtain a reaction product, and the temperature of each zone of the double-screw extruder is as follows: the first zone is 180-;
(3) and cutting the reaction product into particles and drying to obtain a finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110390457.8A CN112898704A (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810405391.3A CN108546373B (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride and preparation method thereof |
| CN202110390457.8A CN112898704A (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810405391.3A Division CN108546373B (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112898704A true CN112898704A (en) | 2021-06-04 |
Family
ID=63512977
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810405391.3A Active CN108546373B (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride and preparation method thereof |
| CN202110390457.8A Pending CN112898704A (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810405391.3A Active CN108546373B (en) | 2018-04-29 | 2018-04-29 | High-performance modified polyvinyl chloride and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN108546373B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0493233A (en) * | 1990-08-08 | 1992-03-26 | Mitsubishi Kasei Vinyl Co | Improvement of permanent compressive strain of polyvinyl chloride-based resin molded article |
| JPH0531342A (en) * | 1991-07-31 | 1993-02-09 | Nippon Medical Supply Corp | Hollow fiber membrane improved in dispersibility and its production |
| CN103087438A (en) * | 2011-11-02 | 2013-05-08 | 中国石油化工股份有限公司 | Impact-resistant polyvinyl chloride composition and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104045942B (en) * | 2014-07-04 | 2016-09-28 | 芜湖中源赛特管业有限公司 | PVC and preparation method thereof |
| CN104356530A (en) * | 2014-09-26 | 2015-02-18 | 青岛桐晟桐橡塑科技有限公司 | Formula of electric-conduction and abrasion-proof plastics |
| CN104861352A (en) * | 2014-12-30 | 2015-08-26 | 殷培花 | Impact modified polyvinyl chloride cable material |
| KR101721801B1 (en) * | 2016-05-17 | 2017-03-30 | 주식회사 호만테크 | Pvc compound composition and preparing method thereof |
| CN107501795B (en) * | 2017-09-06 | 2019-10-01 | 淄博职业学院 | Low temperature resistant polyvinyl chloride soft goods composition and preparation method thereof |
-
2018
- 2018-04-29 CN CN201810405391.3A patent/CN108546373B/en active Active
- 2018-04-29 CN CN202110390457.8A patent/CN112898704A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0493233A (en) * | 1990-08-08 | 1992-03-26 | Mitsubishi Kasei Vinyl Co | Improvement of permanent compressive strain of polyvinyl chloride-based resin molded article |
| JPH0531342A (en) * | 1991-07-31 | 1993-02-09 | Nippon Medical Supply Corp | Hollow fiber membrane improved in dispersibility and its production |
| CN103087438A (en) * | 2011-11-02 | 2013-05-08 | 中国石油化工股份有限公司 | Impact-resistant polyvinyl chloride composition and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘西文 等: "《塑料挤出工 中、高级 培训教程》", 31 January 2013, 印刷工业出版社 * |
| 沈新元: "《化学纤维手册》", 30 September 2008, 中国纺织出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108546373A (en) | 2018-09-18 |
| CN108546373B (en) | 2021-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110698836B (en) | High-strength polycarbonate composite material for plastic-coated aluminum and preparation method thereof | |
| CN101165093B (en) | High hydrolysis resistance anti-flaming enhanced polybutylene terephthalate composition and preparation method thereof | |
| CN107778853A (en) | A kind of heat oxygen aging resistance hydrolysis continuous glass-fiber reinforced polyamide composite and preparation method thereof | |
| CN102634162A (en) | Heat-conduction polyformaldehyde composite material and preparation method thereof | |
| CN106147263A (en) | A kind of flame-retardant wood-plastic composite material | |
| CN113881222A (en) | Nylon glass fiber reinforced composite material and preparation method thereof | |
| CN110564147B (en) | High-oxygen-index red phosphorus flame-retardant reinforced nylon 66 compound and preparation method thereof | |
| CN108546373B (en) | High-performance modified polyvinyl chloride and preparation method thereof | |
| CN107298837A (en) | Glass fiber-reinforced polycarbonate resin combination | |
| CN112029258A (en) | Environment-friendly reinforced PC (polycarbonate) and ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof | |
| CN114085526B (en) | Polyphenylene sulfide composition and preparation method and application thereof | |
| CN114163746B (en) | Glass fiber reinforced AS composition and application thereof | |
| CN114621526A (en) | Environment-friendly polypropylene composite material and preparation method thereof | |
| CN109517402A (en) | A kind of pre-stress fibre Wood-plastic floor | |
| CN115028983A (en) | Low-cost POK/PP alloy with good chemical resistance and preparation method and application thereof | |
| CN107868340A (en) | A kind of co-blend polypropylene is material modified | |
| CN112143032B (en) | Modified aluminum hydroxide, flame-retardant polyvinyl chloride material and preparation method thereof | |
| CN112724518A (en) | Environment-friendly rubber pipe and preparation method thereof | |
| CN111286182A (en) | Low-cost halogen-free flame-retardant PCABS alloy and preparation method thereof | |
| US4474922A (en) | Filled poly(arylene sulfide) compositions | |
| CN113214543B (en) | Wood-plastic plate prepared by recycling waste clothes, section bar and preparation method | |
| CN112266614B (en) | Polyphenylene sulfide composite material, preparation method thereof and injection molding part | |
| CN112175296B (en) | Recyclable basalt fiber reinforced polypropylene and preparation method thereof | |
| CN113896981B (en) | High-strength environment-friendly flame-retardant polypropylene composite material and preparation method thereof | |
| CN107828179A (en) | A kind of modified engineered plastic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210604 |