CN112892563A - F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof - Google Patents
F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof Download PDFInfo
- Publication number
- CN112892563A CN112892563A CN202110119182.4A CN202110119182A CN112892563A CN 112892563 A CN112892563 A CN 112892563A CN 202110119182 A CN202110119182 A CN 202110119182A CN 112892563 A CN112892563 A CN 112892563A
- Authority
- CN
- China
- Prior art keywords
- zncds
- doped
- solid solution
- photocatalytic material
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000006104 solid solution Substances 0.000 title claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 12
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 6
- AUIZLSZEDUYGDE-UHFFFAOYSA-L cadmium(2+);diacetate;dihydrate Chemical compound O.O.[Cd+2].CC([O-])=O.CC([O-])=O AUIZLSZEDUYGDE-UHFFFAOYSA-L 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000004246 zinc acetate Substances 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- 238000007146 photocatalysis Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 12
- 238000000354 decomposition reaction Methods 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000031700 light absorption Effects 0.000 abstract description 3
- 238000006303 photolysis reaction Methods 0.000 abstract description 3
- 230000015843 photosynthesis, light reaction Effects 0.000 abstract description 3
- 239000004065 semiconductor Substances 0.000 abstract description 3
- UQMZPFKLYHOJDL-UHFFFAOYSA-N zinc;cadmium(2+);disulfide Chemical compound [S-2].[S-2].[Zn+2].[Cd+2] UQMZPFKLYHOJDL-UHFFFAOYSA-N 0.000 abstract description 3
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 239000011941 photocatalyst Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000004298 light response Effects 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 150000004690 nonahydrates Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
The invention relates to the technical field of preparation of photocatalytic materials and hydrogen production by photolysis, in particular to a F-doped Zn CdS solid solution photocatalytic material, and a preparation method and application thereof. According to the invention, firstly, the nano flower-shaped ZnCdS is obtained by a hydrothermal synthesis method, and then the F-doped ZnCdS is obtained by a second hydrothermal method. On one hand, the F element doping can regulate and control the energy band structure of ZnCdS and enhance the light absorption capacity of the ZnCdS, so that the photocatalytic hydrogen production performance of the ZnCdS is improved, and on the other hand, the F element doping can also improve the specific surface of the zinc cadmium sulfide, so that more active sites are provided. The absorption capacity and the energy band structure of ZnCdS to light are regulated and controlled by doping of F element, so that the performance of catalyzing water decomposition to prepare hydrogen of a semiconductor under the irradiation of visible light is promoted.
Description
Technical Field
The invention relates to the technical field of preparation of photocatalytic materials and hydrogen production through photolysis, in particular to a F-doped ZnCdS solid solution photocatalytic material, and a preparation method and application thereof.
Background
Over the past few decades, the high dependence and overuse of fossil fuels has led to very serious energy crisis and environmental problems, and therefore energy production and environmental remediation are currently of paramount importance. Hydrogen energy is considered an ideal alternative energy source to fossil fuels because of its high specific enthalpy and lack of environmental pollution. In recent years, the decomposition of water by means of semiconductor photocatalysts is considered to be one of the most promising green technologies for obtaining hydrogen, which can directly utilize inexhaustible solar energy as a driving force to catalyze the decomposition of water by means of photocatalysts to obtain hydrogen. However, the known photocatalysts have great problems in light absorption capacity, catalytic efficiency and cost, and thus the development of photocatalytic water splitting technology is limited. In response to these problems, studies are currently being made to improve photocatalysts mainly by element doping.
Metal sulfide photocatalysts with high activity and visible light response are widely used in the field of photocatalysis and have been shown to be effective in driving water decomposition in the presence of sacrificial reagents. Particularly, the photocatalyst based on the bimetallic zinc cadmium sulfide shows very high photocatalytic hydrogen production activity, but the fast carrier recombination efficiency and unstable factors caused by photo-corrosion greatly limit the application of the photocatalyst.
Disclosure of Invention
Aiming at the technical problems, the invention provides an F-doped ZnCdS solid solution photocatalytic material and a preparation method and application thereof, wherein the method comprises the steps of firstly obtaining nano flower-shaped ZnCdS (CZS) by a hydrothermal synthesis method, and then obtaining the F-doped ZnCdS (0.1F-CZS) by a second hydrothermal method. The absorption capacity and the energy band structure of ZnCdS (CZS) to light are regulated and controlled by doping of the F element, so that the performance of catalyzing water decomposition of a semiconductor to prepare hydrogen under the irradiation of visible light is promoted; on one hand, the F element doping can regulate and control the energy band structure of ZnCdS (CZS) and enhance the light absorption capacity of the ZnCdS (CZS), so that the photocatalytic hydrogen production performance of the ZnCdS is improved, and on the other hand, the F element doping can also improve the specific surface of the cadmium zinc sulfide, so that more active sites are provided.
The technical scheme for realizing the aim of the invention is as follows:
the preparation method of the F-doped ZnCdS photocatalytic material comprises the following steps:
(1) firstly, putting zinc acetate, cadmium acetate dihydrate and thiourea in deionized water, and magnetically stirring and dissolving at normal temperature to obtain a clear mixed solution;
(2) transferring the obtained mixed solution to a hydrothermal reaction kettle for reaction; standing the obtained reaction product, and then centrifugally separating, washing and drying to obtain flower-shaped ZnCdS;
(3) placing the obtained flower-shaped ZnCdS and ammonium fluoride in deionized water, and magnetically stirring at normal temperature to dissolve the flower-shaped ZnCdS and the ammonium fluoride to obtain a mixed dispersion liquid;
(4) transferring the obtained mixed dispersion liquid to a hydrothermal reaction kettle for reaction; and standing the obtained reaction product, and then centrifugally separating, washing and drying to obtain the F-doped ZnCdS.
In the preparation method, in the step 1, the mass ratio of zinc acetate, cadmium acetate dihydrate, thiourea and deionized water is 0.2-1: 0.3-1.2: 0.2-1: 15-65, and the stirring time is 30-60 min.
In the preparation method, in the step 2, the reaction temperature is 160-180 ℃, and the reaction time is 8-12 h.
In the above preparation method, in the step 3, the mass ratio of the flower-shaped zncds (czs) to the ammonium fluoride is 1: 1.
in the preparation method, in the step 4, the reaction temperature is 180 ℃, and the reaction time is 12-24 h.
Compared with the prior art, the invention has the following remarkable advantages: by doping the F element, the hydrogen production efficiency of photolysis of ZnCdS (CZS) with a flower-shaped structure can be effectively promoted. The synthesis method disclosed by the invention is simple, high in controllability, low in cost and excellent in industrial application prospect.
Drawings
FIG. 1 is an XRD plot of F-doped ZnCdS (0.1F-CZS) prepared according to the present invention;
FIG. 2 is an SEM image of F-doped ZnCdS (0.1F-CZS) prepared by the present invention;
FIG. 3 is a solid UV diffuse reflectance plot of F-doped ZnCdS (0.1F-CZS) prepared according to the present invention;
FIG. 4 shows N of F-doped ZnCdS (0.1F-CZS) prepared according to the present invention2Isothermal adsorption-desorption curve diagram;
FIG. 5 is a photo-current plot of F-doped ZnCdS (0.1F-CZS) prepared according to the present invention;
FIG. 6 is a graph showing hydrogen production by photocatalytic decomposition of F-doped ZnCdS (0.1F-CZS) prepared by the present invention under visible light irradiation time.
Detailed Description
The invention is explained in further detail below with reference to the drawing.
Example 1: the invention relates to a F-doped ZnCdS solid solution photocatalytic material as well as a preparation method and application thereof, and specifically comprises the following steps:
the first step is as follows: putting zinc acetate, cadmium acetate dihydrate and thiourea into deionized water, magnetically stirring and dissolving at normal temperature, putting 0.9g of zinc acetate, 1.2g of cadmium acetate dihydrate and 0.9g of thiourea into a beaker filled with 65mL of deionized water, magnetically stirring and dispersing at normal temperature, and stirring for 30min to obtain a clear mixed solution;
the second step is that: transferring the obtained mixed solution to a 100mL hydrothermal reaction kettle, putting the hydrothermal reaction kettle into a constant-temperature oven for reaction for 8 hours at 160 ℃, then naturally cooling the reaction kettle to room temperature, centrifugally separating, washing with deionized water for 3-5 times, washing with ethanol for 2-3 times, and drying in the constant-temperature oven at 60 ℃ to obtain flower-shaped ZnCdS;
the third step: weighing 0.1g of flower-shaped ZnCdS (CZS) and dispersing in a beaker filled with 30mL of deionized water, adding 0.1g of ammonium fluoride, and magnetically stirring and dispersing at normal temperature for 30min to obtain a mixed dispersion liquid;
the fourth step: and transferring the obtained mixed dispersion liquid to a 50mL hydrothermal reaction kettle, putting the hydrothermal reaction kettle into a constant-temperature oven for reaction for 12h at 180 ℃, naturally cooling the reaction kettle to room temperature, performing centrifugal separation, washing the obtained substance with deionized water for 3-5 times, washing the substance with ethanol for 2-3 times, and drying the substance in the constant-temperature oven at 60 ℃ to obtain F-doped ZnCdS (0.1F-CZS).
FIG. 1 shows the X-ray diffraction pattern of ZnCdS (CZS) and ZnCdS (0.1F-CZS) photocatalytic materials prepared in this example. The crystallinity of the ZnCdS (0.1F-CZS) sample is reduced, and the crystallinity of the ZnCdS (0.1F-CZS) sample is not obviously changed.
FIG. 2 is a scanning electron microscope image of ZnCdS (CZS) and ZnCdS (0.1F-CZS) photocatalytic materials prepared in this example, wherein the prepared sample is a flower-like structure assembled by nanoparticles.
Fig. 3 is a solid ultraviolet diffuse reflection diagram of the ZnCdS (CZS) and ZnCdS (0.1F-CZS) photocatalytic materials prepared in this embodiment, where the absorption capability of ZnCdS (0.1F-CZS) to light in the visible light region is enhanced, which is beneficial to the improvement of the photocatalytic performance.
FIG. 4 shows the N of the photocatalytic materials ZnCdS (CZS) and ZnCdS (0.1F-CZS) prepared in this example2Isothermal adsorption-desorption curve diagram. From the data it can be calculated that the specific surface of ZnCdS (0.1F-CZS) is raised by a factor of 2 (2.1 m)2/g vs 4.2m2/g), and the large specific surface can effectively improve the capacity of photocatalytic hydrogen production.
FIG. 5 is a photo current diagram of ZnCdS (CZS) and ZnCdS (0.1F-CZS) photocatalysts prepared in the example. The F-doped sample shows stronger photocurrent intensity, which indicates that the F-doped sample has better photoelectric carrier separation efficiency, thereby promoting the photocatalytic hydrogen production performance.
FIG. 6 is a graph showing hydrogen production from photocatalytic decomposition of ZnCdS (CZS) and ZnCdS (0.1F-CZS) photocatalytic materials prepared in this example under visible light irradiation time. Under the irradiation of visible light, no cocatalyst is added, the mass of the catalyst is 50mg in the mixed solution of 0.1M of nonahydrate and sodium sulfide and 0.1M of anhydrous sodium sulfite, and the hydrogen production by water decomposition can be effectively realized by 100ML of the mixed solution. It is clear from the figure that the activity of ZnCdS (0.1F-CZS) is significantly enhanced, probably 6.6 times that of ZnCdS (CZS).
Claims (6)
- A preparation method of a F-doped ZnCdS solid solution photocatalytic material is characterized by comprising the following specific steps of:(1) firstly, putting zinc acetate, cadmium acetate dihydrate and thiourea in deionized water, and magnetically stirring and dissolving at normal temperature to obtain a clear mixed solution;(2) transferring the obtained mixed solution to a hydrothermal reaction kettle for reaction; standing the obtained reaction product, and then centrifugally separating, washing and drying to obtain flower-shaped ZnCdS;(3) placing the obtained flower-shaped ZnCdS and ammonium fluoride in deionized water, and magnetically stirring at normal temperature to dissolve the flower-shaped ZnCdS and the ammonium fluoride to obtain a mixed dispersion liquid;(4) transferring the obtained mixed dispersion liquid to a hydrothermal reaction kettle for reaction; and standing the obtained reaction product, and then centrifugally separating, washing and drying to obtain the F-doped ZnCdS.
- 2. The method for preparing a F-doped ZnCdS solid solution photocatalytic material according to claim 1, wherein in the step 1, a mass ratio of zinc acetate, cadmium acetate dihydrate, thiourea and deionized water is 0.2-1: 0.3-1.2: 0.2-1: 15-65, and the stirring time is 30-60 min.
- 3. The method for preparing a F-doped ZnCdS solid solution photocatalytic material as defined in claim 1, wherein in step 2, the reaction temperature is 160-180 ℃, and the reaction time is 8-12 h.
- 4. The method for preparing a F-doped ZnCdS solid solution photocatalytic material according to claim 1, wherein in the step 3, the mass ratio of flower-like ZnCdS to ammonium fluoride is 1: 1.
- 5. the method for preparing a F-doped ZnCdS solid solution photocatalytic material as defined in claim 1, wherein in step 4, the reaction temperature is 180 ℃ and the reaction time is 12-24 h.
- 6. Use of the F-doped ZnCdS solid solution photocatalytic material prepared by any one of the preparation methods of claims 1 to 5, characterized in that water is decomposed to produce hydrogen by photocatalysis under the irradiation time of visible light.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110119182.4A CN112892563B (en) | 2021-01-28 | 2021-01-28 | F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110119182.4A CN112892563B (en) | 2021-01-28 | 2021-01-28 | F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112892563A true CN112892563A (en) | 2021-06-04 |
| CN112892563B CN112892563B (en) | 2022-11-18 |
Family
ID=76119679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110119182.4A Active CN112892563B (en) | 2021-01-28 | 2021-01-28 | F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112892563B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114618534A (en) * | 2022-04-18 | 2022-06-14 | 合肥工业大学 | Visible-light-responsive sulfur-doped bismuth telluride nanowire photocatalytic material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04261075A (en) * | 1991-01-07 | 1992-09-17 | Nippon Telegr & Teleph Corp <Ntt> | P type ii-vi compound semiconductor |
| CN110124692A (en) * | 2019-05-07 | 2019-08-16 | 东莞理工学院 | A kind of preparation method of the zinc-cadmium sulfide solid solution of different-shape |
-
2021
- 2021-01-28 CN CN202110119182.4A patent/CN112892563B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04261075A (en) * | 1991-01-07 | 1992-09-17 | Nippon Telegr & Teleph Corp <Ntt> | P type ii-vi compound semiconductor |
| CN110124692A (en) * | 2019-05-07 | 2019-08-16 | 东莞理工学院 | A kind of preparation method of the zinc-cadmium sulfide solid solution of different-shape |
Non-Patent Citations (2)
| Title |
|---|
| QIAOHONG ZHU ET AL.: ""Prolonged electron lifetime in sulfur vacancy-rich ZnCdS nanocages by interstitial phosphorus doping for photocatalytic water reduction"", 《MATERIALS CHEMISTRY FRONTIERS》 * |
| 宋继梅等: ""F掺杂可见光催化剂Bi2MoO6的制备及其增强的光催化性能"", 《中国钼业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114618534A (en) * | 2022-04-18 | 2022-06-14 | 合肥工业大学 | Visible-light-responsive sulfur-doped bismuth telluride nanowire photocatalytic material and preparation method thereof |
| CN114618534B (en) * | 2022-04-18 | 2024-02-20 | 合肥工业大学 | Visible light responsive sulfur-doped bismuth telluride nanowire photocatalytic material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112892563B (en) | 2022-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110694648B (en) | Photocatalytic water-splitting hydrogen-production molybdenum-doped indium-zinc sulfide hollow hierarchical structure photocatalyst and preparation method thereof | |
| CN109248694B (en) | Preparation method and application of non-noble metal copper indium sulfide/zinc indium sulfide composite photocatalyst | |
| CN109364933A (en) | A kind of copper-bismuth/composite bismuth vanadium photocatalyst preparation and application | |
| CN106925304B (en) | Bi24O31Br10/ZnO composite visible light catalyst and preparation method thereof | |
| CN108043426B (en) | Visible-light hydrogen-producing molybdenum disulfide quantum dot/copper indium sulfide composite photocatalyst and preparation method thereof | |
| CN112844412B (en) | Sulfur indium zinc-MXene quantum dot composite photocatalyst and preparation method and application thereof | |
| CN112427045A (en) | CdS/g-C synthesized by hydrothermal method and having Z-shaped heterojunction3N4Preparation method of composite photocatalyst material | |
| CN105709793A (en) | Cadmium sulfide nanoparticle modified niobium pentoxide nanorod/nitrogen doped graphene composite photocatalyst and preparation method and application thereof | |
| CN110961123A (en) | All-solid-state direct Z-type ZnIn prepared by hydrothermal method2S4-MoSe2High-efficiency photocatalyst | |
| CN109731588B (en) | Preparation method of phosphorus-doped cadmium sulfide-loaded nickel carbide quantum dot nanorod photocatalyst | |
| CN106006720A (en) | Method for preparing SnS/SnS2 heterojunction material and application of SnS/SnS2 heterojunction material | |
| CN107983386B (en) | Ultrathin BiOCl/nitrogen-doped graphene quantum dot composite photocatalyst and preparation method thereof | |
| CN111229205B (en) | WO3/Zn2GeO4Non-noble metal bimetal oxide photocatalyst and preparation method and application thereof | |
| CN112892563B (en) | F-doped ZnCdS solid solution photocatalytic material and preparation method and application thereof | |
| CN113952963B (en) | CuInS based on Co modification 2 Preparation method and application of photocatalyst | |
| CN112023965A (en) | Regulation and control g-C3N4Method for producing crystallinity | |
| CN113680353A (en) | Produce H2O2Preparation method of CdS nano-belt | |
| CN112588324B (en) | Method for preparing composite photocatalyst CdS/ZIF-8 by one-pot method and application thereof | |
| CN112892555A (en) | ZnIn synergistically modified by cavity promoter Ti (IV) and electron promoter MXene QDs2S4Photocatalyst and process for producing the same | |
| CN117680168A (en) | Lignin carbon-based bismuth oxyhalide Z-type heterojunction composite material with regular flower-like morphology, and preparation method and application thereof | |
| CN114644320B (en) | Photocatalytic hydrogen production system and application thereof | |
| CN113559856B (en) | Preparation method of barium titanate/silver iodate heterojunction photocatalyst | |
| CN111617778B (en) | Preparation method of hydrothermally synthesized flower-rod-shaped sulfur indium zinc photocatalyst | |
| CN104549268A (en) | AgBi (WO4)2 photocatalytic material and preparation method thereof | |
| CN114011403A (en) | Preparation method and application of amorphous bismuth tungstate photocatalytic material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |