Electrochemical electrolysis equipment and electrolysis method
Technical Field
The invention belongs to the technical field of electrochemistry, and particularly relates to electrochemical electrolysis equipment.
Background
Electrochemistry, one of the branches of chemistry, is the science of studying the changes in charging and electron transfer that occur at the interface formed by two types of conductors (electronic conductors, such as metals or semiconductors, and ionic conductors, such as electrolyte solutions, electrolyte solutions). Conventional wisdom holds that electrochemistry is primarily concerned with the interconversion of electrical energy and chemical energy-chemical energy, such as electrolysis and galvanic cells. However, electrochemistry is not limited to chemical reactions in which electric energy is generated, but also includes other physicochemical processes such as electrochemical corrosion and electrochemical corrosion of metals, and metal displacement reaction and displacement reaction in an electrolyte solution, electrolysis is a process of passing a current through an electrolyte solution or a molten state electrolyte (also referred to as an electrolyte solution) to cause redox reactions at a cathode and an anode, an electrochemical cell can perform an electrolysis process upon application of a direct current voltage, electrolysis is a process of synthesizing a high-purity substance of a chemical and treating a surface of a material by using an electrochemical reaction occurring at an interface of an electrode as an electron conductor and an electrolyte as an ion conductor. When the power is on, cations in the electrolyte move to the cathode to absorb electrons, and reduction is carried out to generate new substances; the anions in the electrolyte move to the anode, releasing electrons, and oxidation occurs, and new species are also generated. For example, molten sodium chloride is electrolyzed, ions in the electrolyte are always in disorder motion, and the ions move directionally after direct current is applied. The positive ions move to the cathode, and electrons are obtained at the cathode and are reduced; the anions move to the anode, lose electrons at the anode, and are oxidized. In the water electrolysis process of water electrolysis, OH loses electrons at the anode and is oxidized into oxygen to be discharged; h gets electrons at the cathode and is reduced into hydrogen to be discharged. The obtained oxygen and hydrogen are the products of the water electrolysis process. During electrolysis, a battery is formed between a product separated out from the electrode and an electrolyte solution, the electromotive force of the battery is equal to the theoretical electrolytic voltage of the electrolyte in value, and the electrolysis of the aqueous solution mainly electrolyzes water to prepare hydrogen and oxygen; electrolyzing the sodium (potassium) chloride aqueous solution to prepare sodium (potassium) oxide, chlorine and hydrogen; preparing various oxidants, such as hydrogen peroxide, chlorate, perchlorate, permanganate, persulfate and the like, by an electrolytic oxidation method; electrolytic reduction methods such as the electrolysis of acrylonitrile to adiponitrile or adiponitrile; wet electrolysis to produce metals such as zinc, cadmium, chromium, manganese, nickel, cobalt, etc., and wet electrolysis to refine metals such as copper, silver, gold, platinum, etc.
However, in the use process of the conventional electrochemical electrolysis equipment, the stirring and mixing treatment effect of the electrolyte solution in the electrolytic tank body is poor, so that the electrolyte solution in the electrolytic tank body is difficult to perform rapid and sufficient reaction, and the temperature of the electrolyte solution is easy to be abnormal, so that the electrolytic reaction effect is influenced.
Disclosure of Invention
The invention aims to provide electrochemical electrolysis equipment, which is provided with a tank body assembly, an end cover assembly, a stirring assembly and a base assembly, and solves the problems that in the use process of the traditional electrochemical electrolysis equipment, the electrolyte solution in an electrolysis tank is difficult to perform rapid and sufficient reaction and is easy to influence the electrolytic reaction effect due to poor stirring and mixing treatment effects on the electrolyte solution in the electrolysis tank in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: an electrochemical electrolysis device comprises a tank assembly, wherein an end cover assembly is arranged at the upper end of the tank assembly, stirring assemblies are arranged at intervals on the inner side of the tank assembly, and a base assembly is arranged at the bottom end of the tank assembly;
the tank assembly comprises an electrolytic tank body, a transmission toothed ring is fixedly mounted at the upper end inside the electrolytic tank body, two assembling through holes are symmetrically formed in the surface of the transmission toothed ring, a sealing ring is fixedly mounted at the upper end of the transmission toothed ring, a sealing groove is formed in the surface of the sealing ring, an electric heating sheet is fixedly mounted on the inner side of the electrolytic tank body, a temperature sensor is fixedly mounted on one side, close to the electric heating sheet, of the inner side of the electrolytic tank body, a mounting block is fixedly mounted at one end of the electrolytic tank body, a positioning bottom block is fixedly mounted at the other end of the electrolytic tank body, a control panel is fixedly mounted on the side face of the electrolytic tank body, a controller is fixedly mounted on the side face of the control panel, a rotating disc is arranged at the bottom side inside the electrolytic tank body, connecting frames are fixedly mounted at intervals on, the electrolytic cell comprises an electrolytic cell body, a micro motor is fixedly mounted in the middle of the bottom end of the electrolytic cell body, an output shaft of the micro motor is fixedly connected with a rotating disc, a connecting ring is fixedly mounted on the outer side of the bottom end of the electrolytic cell body, two supporting rods are symmetrically and fixedly mounted at the bottom end of the connecting ring, a limiting block is fixedly mounted at the bottom end of each supporting rod, a positioning magnetic block is fixedly mounted at the bottom end of each limiting block, an end cover assembly comprises an assembly end cover, an anode electrode penetrates through the surface of the assembly end cover, an anode connector is fixedly mounted at the upper end of the anode electrode, a cathode electrode penetrates through the surface of the assembly end cover, the surface of the assembly end cover is far away from the anode electrode, a cathode connector is fixedly mounted at the upper end of the cathode electrode, the bottom ends of the anode, the connecting block is in threaded connection with a locking screw rod, the other end of the assembling end cover is fixedly provided with an assembling block, the bottom end of the assembling block is fixedly provided with a positioning top block, and the bottom end of the assembling end cover is fixedly provided with a sealing ring pad;
the stirring assembly comprises an assembly rotating rod, stirring pieces are fixedly installed on the peripheral side face of the assembly rotating rod at intervals, liquid through ports are formed in the surfaces of the stirring pieces at intervals, a rotating shaft is fixedly installed at the bottom end of the assembly rotating rod, the bottom end of the rotating shaft is rotatably connected with a connecting seat, a connecting shaft is fixedly installed at the upper end of the assembly rotating rod, a transmission gear is fixedly installed at the upper end of the connecting shaft and is meshed with a transmission gear ring, the base assembly comprises an assembly base, a sound-proof cover is fixedly installed in the middle of the upper end of the assembly base and movably sleeved on the outer side of a micro motor, two limiting grooves are symmetrically formed in the surface of the upper end of the assembly base, adsorption magnetic blocks are fixedly installed on the inner sides of the limiting grooves, four supporting blocks are symmetrically arranged on the bottom side of the assembly base, and two orientation rods are, the directional rod movably penetrates through the assembly base, a spring is fixedly connected between the supporting block and the assembly base, and a positioning stop block is fixedly mounted at the upper end of the directional rod.
In a preferred embodiment, a liquid outlet pipe is fixedly communicated with the bottom end of the electrolytic tank body, and a sealing valve is fixedly arranged on the side surface of the liquid outlet pipe.
As a preferred embodiment, the positioning groove is formed in the surface of the positioning bottom block, the cross-sectional shapes of the positioning top block and the positioning groove are both rectangular, and the size of the positioning top block is matched with the size of the positioning groove.
As a preferred embodiment, an installation screw groove is formed in the surface of the installation block, the locking screw is matched with the installation screw groove, and a rotating handle is fixedly installed at one end of the locking screw.
As a preferred embodiment, the output end of the temperature sensor is electrically connected to the input end of the controller, and the output end of the controller is electrically connected to the input end of the electric heating plate.
As a preferred embodiment, the cross-sectional shapes of the limiting block and the limiting groove are both circular, the size of the limiting block is matched with that of the limiting groove, and the magnetic poles at the end, close to the positioning magnetic block, of the positioning magnetic block and the adsorption magnetic block are opposite.
As a preferred embodiment, the upper end of the assembling end cover is fixedly communicated with a liquid inlet pipe, and the upper end of the liquid inlet pipe is in threaded connection with a sealing cover.
In a preferred embodiment, the surface of the electrolytic tank body is provided with an observation port, and a sealing plate is fixedly mounted inside the observation port, wherein the sealing plate is a PE transparent plate member.
In a preferred embodiment, the surface of the sound-proof housing is provided with heat dissipation openings at intervals, and a dust screen is fixedly mounted on the inner sides of the heat dissipation openings.
In a preferred embodiment, a non-slip mat is fixedly mounted at the bottom end of the supporting block, and the non-slip mat is a member made of rubber.
Compared with the prior art, the electrochemical electrolysis equipment provided by the invention at least comprises the following beneficial effects:
according to the invention, the micro motor is used for driving the rotating disc to rotate, and the rotating disc can drive the stirring sheet to rotate along the connecting seat, so that the stirring sheet can efficiently stir and mix the electrolyte solution in the electrolytic tank, the stirring and mixing treatment effect of the electrolyte solution in the electrolytic tank is improved, the electrolyte solution in the electrolytic tank can be rapidly and fully reacted, the electrolytic reaction working efficiency is favorably improved, the temperature of the electrolyte solution in the electrolytic tank can be monitored in real time through the temperature sensor, the controller can control the electric heating sheet to operate according to temperature information, the temperature of the electrolyte solution in the electrolytic tank can be in a proper range, the electrolytic reaction can be ensured to be normally carried out, and the electrolytic reaction effect can be prevented from being influenced by abnormal temperature of the electrolyte solution.
According to the invention, the limiting block is matched and inserted in the limiting groove, the positioning magnetic block is contacted and adsorbed on the adsorption magnetic block, so that the electrolytic tank body can be arranged on the assembly base, the electrolytic tank body is convenient and simple to assemble and disassemble on the assembly base, the electrolytic tank body is convenient to clean and maintain, the sound-proof cover is sleeved on the micro motor, the noise generated when the micro motor works can be blocked, the assembly base can be buffered by the spring, and the electrolytic tank body is prevented from being easily damaged due to hard contact when the electrolytic tank body is arranged on the assembly base.
Drawings
FIG. 1 is a schematic view of an electrochemical electrolysis apparatus;
FIG. 2 is a schematic view of a can assembly from a first perspective;
FIG. 3 is a schematic view of a can assembly from a second perspective;
FIG. 4 is a schematic structural view of an end cap assembly;
FIG. 5 is a schematic view of the construction of the agitation assembly;
FIG. 6 is a first perspective structural view of the base assembly;
FIG. 7 is a second perspective view of the base assembly;
in the figure: 1. a canister assembly; 101. an electrolytic tank body; 1011. a control panel; 1012. a controller; 1013. an electrical heating sheet; 1014. a temperature sensor; 1015. positioning the bottom block; 1016. positioning a groove; 1017. mounting blocks; 1018. installing a screw groove; 102. a transmission gear ring; 1021. assembling the through hole; 1022. a seal ring; 1023. sealing the groove; 103. rotating the disc; 1031. a connecting frame; 1032. a connecting seat; 104. a viewing port; 1041. a sealing plate; 105. a connecting ring; 1051. a support bar; 1052. a limiting block; 1053. a positioning magnetic block; 106. a liquid outlet pipe; 1061. a sealing valve; 107. a micro motor; 2. an end cap assembly; 201. assembling an end cover; 2011. assembling the block; 2012. positioning a top block; 2013. connecting blocks; 2014. locking the screw rod; 2015. a seal ring pad; 202. an anode electrode; 2021. an anode tap; 203. a cathode electrode; 2031. a cathode terminal; 204. a liquid inlet pipe; 2041. a sealing cover; 3. an agitation assembly; 301. assembling a rotary rod; 3011. a rotating shaft; 3012. a connecting shaft; 3013. a transmission gear; 302. a stirring sheet; 3021. a liquid through port; 4. a base assembly; 401. assembling a base; 4011. a limiting groove; 4012. an adsorption magnetic block; 402. a sound-proof housing; 4021. a heat dissipation port; 4022. a dust screen; 403. a support block; 4031. a non-slip mat; 4032. an orientation bar; 4033. positioning a stop block; 404. a spring.
Detailed Description
The present invention will be further described with reference to the following examples.
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention. The conditions in the embodiments can be further adjusted according to specific conditions, and simple modifications of the method of the present invention based on the concept of the present invention are within the scope of the claimed invention.
Referring to fig. 1-7, the present invention provides an electrochemical electrolysis apparatus, which includes a tank assembly 1, an end cap assembly 2 disposed at an upper end of the tank assembly 1, a stirring assembly 3 disposed at an interval inside the tank assembly 1, and a base assembly 4 disposed at a bottom end of the tank assembly 1;
the tank assembly 1 comprises an electrolytic tank body 101, a transmission toothed ring 102 is fixedly installed at the upper end inside the electrolytic tank body 101, two assembling through holes 1021 are symmetrically formed in the surface of the transmission toothed ring 102, a sealing ring 1022 is fixedly installed at the upper end of the transmission toothed ring 102, a sealing groove 1023 is formed in the surface of the sealing ring 1022, an electric heating sheet 1013 is fixedly installed on the inner side of the electrolytic tank body 101, a temperature sensor 1014 is fixedly installed on one side, close to the electric heating sheet 1013, of the inner side of the electrolytic tank body 101, an installation block 1017 is fixedly installed at one end of the electrolytic tank body 101, a positioning bottom block 1015 is fixedly installed at the other end of the electrolytic tank body 101, a control panel 1011 is fixedly installed on the side surface of the electrolytic tank body 101, a controller 1012 is fixedly installed on the side surface of the control panel 1011, a rotating disc 103 is arranged at the bottom side inside the electrolytic tank body 101, the middle of the bottom end of the electrolytic tank body 101 is fixedly provided with the micro motor 107, the output shaft of the micro motor 107 is fixedly connected with the rotating disc 103, the outer side of the bottom end of the electrolytic tank body 101 is fixedly provided with the connecting ring 105, the bottom end of the connecting ring 105 is symmetrically and fixedly provided with two supporting rods 1051, the bottom end of each supporting rod 1051 is fixedly provided with a limiting block 1052, the bottom end of each limiting block 1052 is fixedly provided with a positioning magnetic block 1053, the end cover assembly 2 comprises an assembling end cover 201, the surface of the assembling end cover 201 is fixedly provided with an anode electrode 202 in a penetrating manner, the upper end of the anode electrode 202 is fixedly provided with an anode connector 2021, one side of the surface of the assembling end cover 201 far away from the anode electrode 202 is fixedly provided with a cathode electrode 203 in a penetrating manner, the upper end of the cathode electrode 203 is fixedly provided with a cathode connector 2031, the bottom ends, the connecting block 2013 is in threaded connection with a locking screw 2014, the other end of the assembling end cover 201 is fixedly provided with an assembling block 2011, the bottom end of the assembling block 2011 is fixedly provided with a positioning top block 2012, the bottom end of the assembling end cover 201 is fixedly provided with a sealing ring gasket 2015, and the sealing ring gasket 2015 is matched and embedded into the sealing groove 1023 of the sealing ring 1022, so that the aim of improving the sealing performance between the assembling end cover 201 and the electrolytic tank body 101 is fulfilled;
the stirring component 3 comprises an assembly rotating rod 301, stirring sheets 302 are fixedly installed on the peripheral side surface of the assembly rotating rod 301 at intervals, liquid through ports 3021 are formed in the surface of the stirring sheets 302 at intervals, a rotating shaft 3011 is fixedly installed at the bottom end of the assembly rotating rod 301, the bottom end of the rotating shaft 3011 is rotatably connected with a connecting seat 1032, a connecting shaft 3012 is fixedly installed at the upper end of the assembly rotating rod 301, a transmission gear 3013 is fixedly installed at the upper end of the connecting shaft 3012, the transmission gear 3013 is meshed with the transmission toothed ring 102, the rotating disc 103 rotates and can drive the stirring sheets 302 to rotate along the connecting seat 1032, the base component 4 comprises an assembly base 401, a sound insulation cover 402 is fixedly installed in the middle of the upper end of the assembly base 401, the sound insulation cover 402 is movably sleeved on the outer side of the micro motor 107, two limiting grooves 4011 are symmetrically formed in the upper end surface of the assembly base 401, adsorption magnet blocks 4012 are fixedly, two orientation bars 4032 are symmetrically and fixedly mounted at the upper end of the supporting block 403, the orientation bars 4032 penetrate through the assembly base 401 movably, a spring 404 is fixedly connected between the supporting block 403 and the assembly base 401, the spring 404 can play a role in buffering the assembly base 401, the problem that when the electrolytic tank body 101 is mounted on the assembly base 401, hard contact easily causes damage to the electrolytic tank body 101 is avoided, and a positioning stop 4033 is fixedly mounted at the upper end of the orientation bar 4032.
As shown in fig. 3, the bottom end of the electrolytic tank 101 is fixedly communicated with the liquid outlet pipe 106, so that the waste electrolyte solution in the electrolytic tank 101 can be discharged through the liquid outlet pipe 106, and the sealing valve 1061 is fixedly arranged on the side surface of the liquid outlet pipe 106, thereby achieving the purpose of conveniently sealing the liquid outlet pipe 106.
As shown in fig. 2 and 4, the positioning groove 1016 is formed in the surface of the positioning bottom block 1015, the cross-sectional shapes of the positioning top block 2012 and the positioning groove 1016 are rectangular, the size of the positioning top block 2012 is matched with the size of the positioning groove 1016, so that the positioning top block 2012 can be matched and inserted into the positioning groove 1016, the surface of the mounting block 1017 is provided with a mounting screw groove 1018, the locking screw 2014 is matched with the mounting screw groove 1018, the purpose of enabling the locking screw 2014 to be matched and screwed with the mounting screw groove 1018 is achieved, and a rotating handle is fixedly mounted at one end of the locking screw 2014.
As shown in fig. 2, the output end of the temperature sensor 1014 is electrically connected to the input end of the controller 1012, the temperature sensor 1014 can monitor the temperature of the electrolyte solution in the electrolytic tank 101 in real time, the temperature sensor 1014 can transmit temperature information to the controller 1012, the output end of the controller 1012 is electrically connected to the input end of the electric heating sheet 1013, and the controller 1012 can control the electric heating sheet 1013 to operate according to the temperature information, so as to achieve the purpose of enabling the temperature of the electrolyte solution in the electrolytic tank 101 to be within a proper range.
As shown in fig. 3 and 6, the cross-sectional shapes of the limiting block 1052 and the limiting groove 4011 are circular, the size of the limiting block 1052 is matched with the size of the limiting groove 4011, so that the limiting block 1052 can be inserted into the limiting groove 4011 in a matching manner, the magnetic poles at one end of the positioning magnetic block 1053 close to the adsorbing magnetic block 4012 are opposite, and the positioning magnetic block 1053 and the adsorbing magnetic block 4012 can generate an adsorption acting force mutually.
As shown in fig. 4, the upper end of the assembling end cover 201 is fixedly communicated with a liquid inlet pipe 204, and the upper end of the liquid inlet pipe 204 is in threaded connection with a sealing cover 2041, so as to facilitate the purpose of opening or sealing the sealing cover 2041 on the liquid inlet pipe 204.
As shown in fig. 2, the surface of the electrolytic tank 101 is provided with the viewing port 104, a sealing plate 1041 is fixedly mounted on the inner side of the viewing port 104, the sealing plate 1041 is a PE transparent plate member, and the purpose of checking the electrolysis status in the electrolytic tank 101 through the sealing plate 1041 is achieved.
As shown in fig. 6, heat dissipation ports 4021 are spaced apart from the surface of the soundproof cover 402 to improve the heat dissipation performance of the soundproof cover 402, and a dustproof mesh 4022 is fixedly mounted on the inner side of the heat dissipation ports 4021 to prevent external dust and impurities from entering the soundproof cover 402 through the heat dissipation ports 4021.
As shown in fig. 7, a non-slip pad 4031 is fixedly mounted at the bottom end of the supporting block 403, and the non-slip pad 4031 is a member made of rubber, so as to achieve the purpose of improving the non-slip performance of the supporting block 403.
In the process of using the electrochemical electrolysis equipment, the sealing cover 2041 is opened, the electrolyte solution is added into the electrolytic tank body 101 through the liquid inlet pipe 204, the sealing cover 2041 is sealed on the liquid inlet pipe 204, the micro motor 107 is used for driving the rotating disc 103 to rotate, so that the stirring sheet 302 can stir and mix the electrolyte solution in the electrolytic tank body 101, the upper end of the assembling rotating rod 301 is fixedly provided with the connecting shaft 3012, the upper end of the connecting shaft 3012 is fixedly provided with the transmission gear 3013, the transmission gear 3013 is meshed and connected with the transmission toothed ring 102, the rotating disc 103 rotates and can drive the stirring sheet 302 to rotate along the connecting seat 1032, the electrolyte solution in the electrolytic tank body 101 can be stirred and mixed sufficiently and quickly, the temperature of the electrolyte solution in the electrolytic tank body 101 can be monitored in real time through the temperature sensor 1014, the output end of the controller 1012 is electrically connected with the input end of the electric heating sheet, the controller 1012 can control the operation of the electric heating sheet 1013 according to the temperature information, so that the temperature of the electrolyte solution in the electrolytic tank 101 can be within a proper range, the upper end of the anode electrode 202 is fixedly provided with the anode connector 2021, the upper end of the cathode electrode 203 is fixedly provided with the cathode connector 2031, the anode connector 2021 is connected with the anode of the external power supply, so that the oxidation reaction can occur, the cathode connector 2031 is connected with the cathode of the external power supply, so that the reduction reaction can occur, and finally the electrolyte is obtained, when the electrolytic tank body 101 needs to be disassembled on the assembly base 401, the electrolytic tank body 101 is drawn out from the assembly base 401 for disassembly, when the electrolytic tank body 101 needs to be installed on the assembling base 401, the limiting block 1052 is matched and inserted into the limiting groove 4011, and the positioning magnetic block 1053 is contacted and adsorbed on the adsorbing magnetic block 4012, so that the electrolytic tank body 101 is convenient to install and detach on the assembling base 401.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.