CN112808322A - Cleaning and regeneration synergist for water treatment ion exchange resin - Google Patents

Cleaning and regeneration synergist for water treatment ion exchange resin Download PDF

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Publication number
CN112808322A
CN112808322A CN202011574893.2A CN202011574893A CN112808322A CN 112808322 A CN112808322 A CN 112808322A CN 202011574893 A CN202011574893 A CN 202011574893A CN 112808322 A CN112808322 A CN 112808322A
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China
Prior art keywords
ion exchange
exchange resin
synergist
cleaning
regeneration
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CN202011574893.2A
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Chinese (zh)
Inventor
刘金彪
蔡小华
包孝林
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Jiangsu Suqing Water Treatment Engineering Group Co ltd
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Jiangsu Suqing Water Treatment Engineering Group Co ltd
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Priority to CN202011574893.2A priority Critical patent/CN112808322A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3245Aminoacids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/18Glass; Plastics

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The invention discloses a cleaning and regeneration synergist for water treatment ion exchange resin, relates to the technical field of cleaning and regeneration synergists, and consists of water, active substances and a supplement. The cleaning and regeneration synergist is prepared from sodium polyacrylate, diammonium ethylenediamine tetraacetate, ammonium methacrylate, a sodium chloride aqueous solution, styrene and acrylic ester serving as raw materials according to a certain mass concentration, wherein the styrene and the acrylic ester can supplement main components diluted during cleaning to ion exchange resin, and after the ion exchange resin is repeatedly cleaned, the sewage treatment capacity of the ion exchange resin can be greatly improved, so that the water treatment effect of the ion exchange resin is remarkably improved.

Description

Cleaning and regeneration synergist for water treatment ion exchange resin
Technical Field
The invention relates to the technical field of cleaning and regenerating synergists, in particular to a cleaning and regenerating synergist for water treatment ion exchange resin.
Background
The ion exchange resin is a high molecular compound with functional groups (active groups for exchanging ions), a reticular structure and insolubility, and is usually spherical particles, the full name of the ion exchange resin consists of a classification name, a framework name and a basic name, the pore structure is divided into a gel type and a macroporous type, the macroporous type resin with a physical pore structure is added with a macroporous part before the full name, the acidic part is added with a positive part before the name, the basic part is added with a negative part before the name, and the following steps are carried out: the macroporous strong-acid styrene cation exchange resin and synergist are generally substances which do not have a certain specific activity or have low activity, but can greatly improve the performance of active substances when being mixed with the substances with the activity.
In the prior art, ion exchange resin is used for removing various anions and cations in water in the water treatment industry, when the ion exchange resin is used for treating water, the ion exchange resin needs to be cleaned, but in the cleaning process, main components in the ion exchange resin are very easy to dilute, and the water treatment effect is reduced after the ion exchange resin is regenerated.
Disclosure of Invention
The invention aims to: in order to solve the problem that the main components in the ion exchange resin are diluted when the ion exchange resin is cleaned in the prior art, so that the water treatment effect is reduced after the ion exchange resin is regenerated, a cleaning and regeneration synergist for the ion exchange resin for water treatment is provided.
In order to achieve the purpose, the invention provides the following technical scheme: a cleaning and regeneration synergist for water treatment ion exchange resin, which consists of water, active substances and a supplement, wherein the mass concentrations of the active substances are respectively as follows: 200-400 mg/L of polyacrylate sodium, 200-500 mg/L of ethylenediamine tetraacetic acid diammonium, 30-150 mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution, wherein the mass concentrations of the supplements are respectively as follows: styrene 100 mg/L-200 mg/L, acrylate 200 mg/L-300 mg/L.
In order to achieve the purpose, the invention provides the following technical scheme: a cleaning and regeneration synergist for water treatment ion exchange resin is prepared by the following specific steps:
the method comprises the following steps: weighing 300mg/L of polyacrylate sodium, 350mg/L of ethylenediamine tetraacetic acid diammonium, 80mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution according to the mass concentration ratio;
step two: putting a plurality of substances in the first step into a stirrer in sequence, adding the rest of aqueous solution, heating to 50-90 ℃, stirring for 20-40 min, reacting the substances for 1-2 h, stopping stirring and taking out for later use to obtain an active substance mixed colloid;
step three: weighing three parts of styrene 100mg/L and acrylate 200mg/L, styrene 200mg/L and acrylate 250mg/L, styrene 300mg/L and acrylate 300mg/L according to the mass concentration ratio, respectively mixing and stirring to prepare three parts of supplements with different dosages;
step four: adding three supplements with different dosages in the three steps into three active substance mixed colloids with the same amount respectively, stirring, and standing for 30-40 min;
step five: then three parts of the cleaning and regeneration synergist with different mass concentration replenisher dosage for the water treatment ion exchange resin are prepared.
Preferably, the internal water content of the synergist is the balance of the synergist, and the temperature of the aqueous solution is kept at room temperature of 20 ℃.
Preferably, the supplement is internally in a colloidal state.
Compared with the prior art, the invention has the beneficial effects that: the cleaning and regeneration synergist is prepared from sodium polyacrylate, diammonium ethylenediamine tetraacetate, ammonium methacrylate, a sodium chloride aqueous solution, styrene and acrylic ester serving as raw materials according to a certain mass concentration, wherein the styrene and the acrylic ester can supplement main components diluted during cleaning to ion exchange resin, and after the ion exchange resin is repeatedly cleaned, the sewage treatment capacity of the ion exchange resin can be greatly improved, so that the water treatment effect of the ion exchange resin is remarkably improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the invention relates to a cleaning and regeneration synergist for water treatment ion exchange resin, which consists of water, active substances, a supplement agent and a sodium chloride aqueous solution, wherein the mass concentrations of the active substances are respectively as follows: 300mg/L of polyacrylate sodium, 350mg/L of ethylenediamine tetraacetic acid diammonium, 80mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution, wherein the mass concentrations of the supplements are respectively as follows: styrene 100mg/L and acrylate 200 mg/L.
Before the cleaning and regeneration synergist of the invention is not used: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, and after the ion exchange resin is cleaned by using a conventional method, the content of the main components in the ion exchange resin is detected to be 50%, so that the content of the main components in the ion exchange resin is reduced by 30% after the ion exchange resin is cleaned, and after the ion exchange resin is subjected to regeneration treatment by using active substances, the secondary treatment effect of the ion treatment resin on water is reduced.
Effect after use of this dose of cleaning and regeneration booster: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, the ion exchange resin is cleaned and regenerated by using the cleaning and regeneration synergist, the main components in the ion exchange resin can be replaced and supplemented by 100mg/L of styrene and 200mg/L of acrylic ester in the cleaning and regeneration synergist, and the content of the main components in the ion exchange resin is 60% by detection, so that the content of the main components in the ion exchange resin is reduced by 20% after the ion exchange resin is cleaned, and the secondary treatment effect of the ion treatment resin on water is obviously improved after the ion exchange resin is subjected to regeneration treatment by using active substances.
Example 2:
the invention relates to a cleaning and regeneration synergist for water treatment ion exchange resin, which consists of water, active substances, a supplement agent and a sodium chloride aqueous solution, wherein the mass concentrations of the active substances are respectively as follows: 300mg/L of polyacrylate sodium, 350mg/L of ethylenediamine tetraacetic acid diammonium, 80mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution, wherein the mass concentrations of the supplements are respectively as follows: 200mg/L of styrene and 250mg/L of acrylic ester.
Before the cleaning and regeneration synergist of the invention is not used: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, and after the ion exchange resin is cleaned by using a conventional method, the content of the main components in the ion exchange resin is detected to be 50%, so that the content of the main components in the ion exchange resin is reduced by 30% after the ion exchange resin is cleaned, and after the ion exchange resin is subjected to regeneration treatment by using active substances, the secondary treatment effect of the ion treatment resin on water is reduced.
Effect after use of this dose of cleaning and regeneration booster: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, the ion exchange resin is cleaned and regenerated by using the cleaning and regeneration synergist, 200mg/L of styrene and 250mg/L of acrylate of the cleaning and regeneration synergist can replace and supplement the main components in the ion exchange resin, and the content of the main components in the ion exchange resin is 70% by detection, so that the content of the main components in the ion exchange resin is reduced by 10% after the ion exchange resin is cleaned, and the secondary treatment effect of the ion treatment resin on water is obviously improved after the ion exchange resin is subjected to regeneration treatment by using active substances.
Example 3:
the invention relates to a cleaning and regeneration synergist for water treatment ion exchange resin, which consists of water, active substances, a supplement agent and a sodium chloride aqueous solution, wherein the mass concentrations of the active substances are respectively as follows: 300mg/L of polyacrylate sodium, 350mg/L of ethylenediamine tetraacetic acid diammonium, 80mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution, wherein the mass concentrations of the supplements are respectively as follows: 300mg/L of styrene and 300mg/L of acrylic ester.
Before the cleaning and regeneration synergist of the invention is not used: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, and after the ion exchange resin is cleaned by using a conventional method, the content of the main components in the ion exchange resin is detected to be 50%, so that the content of the main components in the ion exchange resin is reduced by 30% after the ion exchange resin is cleaned, and after the ion exchange resin is subjected to regeneration treatment by using active substances, the secondary treatment effect of the ion treatment resin on water is reduced.
Effect after use of this dose of cleaning and regeneration booster: after the ion exchange resin is subjected to water treatment, the content of the main components in the ion exchange resin is 80%, the ion exchange resin is cleaned and regenerated by using the cleaning and regeneration synergist, the main components in the ion exchange resin can be replaced and supplemented by 300mg/L of styrene and 300mg/L of acrylic ester of the cleaning and regeneration synergist, and the content of the main components in the ion exchange resin is 76% by detection, so that the content of the main components in the ion exchange resin is reduced by 4% after the ion exchange resin is cleaned, and the secondary treatment effect of the ion treatment resin on water is obviously improved after the ion exchange resin is subjected to regeneration treatment by using active substances.
Table 1: the ion exchange resin uses the cleaning and regeneration synergist of the invention and the content of the main components in the front and the back are changed:
Figure BDA0002863276130000051
as can be seen from Table 1, when the ion exchange resin is regenerated for the first time without using the method provided by the embodiment of the present invention, the content of the main component in the ion exchange resin is remained 50%, when the replenisher with styrene 100mg/L and acrylate 200mg/L is used for the second time, the content of the main component in the ion exchange resin is remained 60%, which is 10% higher than that of the first time, the dosage for the third time is 200mg/L and acrylate 250mg/L, which is 20% higher than that of the first time, and the dosage for the fourth time is 300mg/L and acrylate 300mg/L, which is 26% higher than that of the first time, after the dosages of the substances in the replenisher are increased, the cleaning and regenerating capabilities of the ion exchange resin are significantly improved, and the problem that the water treatment capability of the ion exchange resin is reduced during multiple times of cleaning and regenerating of the ion exchange resin, The water treatment effect is increasingly poor.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (4)

1. A cleaning and regeneration synergist for water treatment ion exchange resin is characterized in that: the synergist consists of water, active substances and a supplement, wherein the mass concentrations of the active substances are respectively as follows: 200-400 mg/L of polyacrylate sodium, 200-500 mg/L of ethylenediamine tetraacetic acid diammonium, 30-150 mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution, wherein the mass concentrations of the supplements are respectively as follows: styrene 100 mg/L-200 mg/L, acrylate 200 mg/L-300 mg/L.
2. The cleaning and regeneration synergist for water treatment ion exchange resin according to claim 1, characterized in that: the preparation method of the cleaning and regeneration synergist for the water treatment ion exchange resin comprises the following steps:
the method comprises the following steps: weighing 300mg/L of polyacrylate sodium, 350mg/L of ethylenediamine tetraacetic acid diammonium, 80mg/L of ammonium methacrylate and 300mg/L of sodium chloride aqueous solution according to the mass concentration ratio;
step two: putting a plurality of substances in the first step into a stirrer in sequence, adding the rest of aqueous solution, heating to 50-90 ℃, stirring for 20-40 min, reacting the substances for 1-2 h, stopping stirring and taking out for later use to obtain an active substance mixed colloid;
step three: weighing three parts of styrene 100mg/L and acrylate 200mg/L, styrene 200mg/L and acrylate 250mg/L, styrene 300mg/L and acrylate 300mg/L according to the mass concentration ratio, respectively mixing and stirring to prepare three parts of supplements with different dosages;
step four: adding three supplements with different dosages in the three steps into three active substance mixed colloids with the same amount respectively, stirring, and standing for 30-40 min;
step five: then three parts of the cleaning and regeneration synergist with different mass concentration replenisher dosage for the water treatment ion exchange resin are prepared.
3. The cleaning and regeneration synergist for water treatment ion exchange resin according to claim 1, characterized in that: the water content in the synergist is the balance of the synergist, and the temperature of the aqueous solution is kept at room temperature of 20 ℃.
4. The cleaning and regeneration synergist for water treatment ion exchange resin according to claim 1, characterized in that: the supplement is in a colloidal state inside.
CN202011574893.2A 2020-12-28 2020-12-28 Cleaning and regeneration synergist for water treatment ion exchange resin Pending CN112808322A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130146086A1 (en) * 2011-12-13 2013-06-13 Ecolab Usa Inc. Acid regeneration of ion exchange resins for industrial applications
CN109536291A (en) * 2018-12-13 2019-03-29 吉林省电力科学研究院有限公司 A kind of cleaning of water process ion exchange resin and regeneration synergist
CN111729515A (en) * 2020-07-29 2020-10-02 青岛沁安化工科技有限公司 Nanofiltration membrane repairing agent for brine refining and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130146086A1 (en) * 2011-12-13 2013-06-13 Ecolab Usa Inc. Acid regeneration of ion exchange resins for industrial applications
CN109536291A (en) * 2018-12-13 2019-03-29 吉林省电力科学研究院有限公司 A kind of cleaning of water process ion exchange resin and regeneration synergist
CN111729515A (en) * 2020-07-29 2020-10-02 青岛沁安化工科技有限公司 Nanofiltration membrane repairing agent for brine refining and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐风广等: "《无机非金属材料化验与检测实训》", 31 July 2018, 北京:中国建材工业出版社 *

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Application publication date: 20210518