CN112795324A - Antistatic flame-retardant double-transparent PET label material and preparation method thereof - Google Patents

Antistatic flame-retardant double-transparent PET label material and preparation method thereof Download PDF

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Publication number
CN112795324A
CN112795324A CN202011635884.XA CN202011635884A CN112795324A CN 112795324 A CN112795324 A CN 112795324A CN 202011635884 A CN202011635884 A CN 202011635884A CN 112795324 A CN112795324 A CN 112795324A
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flame
retardant
pet
label material
phosphorus
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Inventor
刘致远
唐贤坤
司徒灼铝
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Shenzhen Changmao Mucilage Glue New Material Co ltd
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Shenzhen Changmao Mucilage Glue New Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02Electrically-conducting adhesives
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/33Applications of adhesives in processes or use of adhesives in the form of films or foils for batteries or fuel cells
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/334Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/28Presence of paper
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention belongs to the technical field of label materials, and particularly relates to an antistatic flame-retardant double-transparent PET label material and a preparation method thereof. The preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET. The label material is mainly applied to labels in the field of new energy automobiles and the like, is used as an automobile battery label, and helps to solve the safety problem of automobile batteries. The label material has insulating property, can resist static electricity, has high viscosity, enables the label to have better fitting property, enables the label to be more firmly fitted, has flame retardance, achieves the flame retardance verification of UL-VO, and can effectively resist secondary damage caused by battery burning and splashing.

Description

Antistatic flame-retardant double-transparent PET label material and preparation method thereof
Technical Field
The invention belongs to the technical field of label materials, and particularly relates to an antistatic flame-retardant double-transparent PET label material and a preparation method thereof.
Background
In addition, in recent years, the concept of environmental protection is gradually deepened, and new energy automobiles gradually start to replace certain fuel automobiles. Under the great trend, the performance and quality of the new energy battery become social hotspots, so that an antistatic flame-retardant automobile label becomes a standard for new energy automobiles. And the improvement of the flame retardant property is undoubtedly the first choice for increasing the safety of new energy automobiles.
Disclosure of Invention
The invention provides an antistatic flame-retardant double-transparent PET label material and a preparation method thereof. The label material is mainly applied to labels in the field of new energy automobiles and the like, is used as an automobile battery label, and helps to solve the safety problem of automobile batteries. The label material has insulating property, can resist static electricity, has high viscosity, enables the label to have better fitting property, enables the label to be more firmly fitted, has flame retardance, achieves the flame retardance verification of UL-VO, and can effectively resist secondary damage caused by battery burning and splashing.
The invention is realized by the following technical scheme:
the antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
Further, the mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 4-5.
Further, the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20-30:5: 5.
Further, the corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4-5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Further, the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min.
In the invention, the used equipment such as scraper type coating equipment is common equipment in the field of film materials and can be obtained commercially.
The antistatic flame-retardant double-transparent PET label material is mainly applied to labels in the field of new energy automobiles and the like. The safety problem of car battery is solved in help, uses as car battery label.
The invention has the beneficial effects that:
(1) the antistatic flame-retardant double-transparent PET label material has insulativity (the resistance between 10MM is more than 1000M omega), can avoid short circuit, protects an automobile battery and is antistatic.
(2) The antistatic flame-retardant double-transmission PET label material has high viscosity which is more than 1.2Kgf/25mm, meets the standard of national standard GB/T2792-. The battery can be wrapped and protected more safely and more firmly.
(3) The antistatic flame-retardant double-transparent PET label material has flame retardance, achieves the flame-retardant verification of UL-VO, can effectively resist secondary damage caused by battery combustion and splashing, and cannot cause dripping.
(4) The antistatic flame-retardant double-transparent PET label material can be printed on the surface and can replace an automobile battery label.
Detailed Description
The present invention will be further described with reference to specific examples so that those skilled in the art may better understand the present invention, but the present invention is not limited thereto.
The polyurethane resin is
Figure BDA0002878473560000021
PUR-MATT 300, the mesh number of the mica powder is 800 meshes.
Example 1
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 4.5.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:25:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4.5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Example 2
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100:4.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:30:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Example 3
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 5.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Comparative example 1
Same as example 1 except that no urethane resin was added.
Comparative example 2
Same as example 1 except that no mica powder was added.
The antistatic flame-retardant double-transparent PET label material prepared by the embodiments of the invention is tested, and the specific test is as follows:
the adhesive force is tested according to the national standard GB/T2792-2014 (20min), the flame retardance is tested according to the UL94 standard, and the resistance between 10MM is tested by using a resistance meter. The results are shown in Table 1.
TABLE 1
Viscous force Kgf/25mm Flame retardancy Resistance M omega
Example 1 1.39 V0 1200
Example 2 1.55 V0 1300
Example 3 1.46 V0 1100
Comparative example 1 1.08 V1 800
Comparative example 2 1.15 V1 700

Claims (6)

1. The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
2. The antistatic flame-retardant double-transparent PET label material as claimed in claim 1, wherein the mass ratio of the phosphorus-nitrogen flame-retardant acrylic glue to the corresponding hardener is 100: 4-5.
3. The antistatic flame-retardant double-transparent PET label material as claimed in claim 1, wherein the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20-30:5: 5.
4. The antistatic flame retardant two-through PET label material according to claim 1, characterized in that the corresponding hardener is isocyanate.
5. The preparation method of the antistatic flame-retardant double-transparent PET label material is characterized by comprising the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4-5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
6. The preparation method of the antistatic flame-retardant two-way PET label material according to claim 5, wherein the high-temperature drying temperature in the step (3) is 110 ℃ and the drying time is 3 min.
CN202011635884.XA 2020-12-31 2020-12-31 Antistatic flame-retardant double-transparent PET label material and preparation method thereof Pending CN112795324A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102911636A (en) * 2012-09-26 2013-02-06 贵阳时代沃顿科技有限公司 Double-component polyurethane adhesive, preparation method and application thereof
CN103131341A (en) * 2011-11-30 2013-06-05 琳得科株式会社 Flame retardant adhering sheet
CN110317547A (en) * 2019-06-21 2019-10-11 深圳昌茂粘胶新材料有限公司 A kind of PET battery label material and preparation method thereof with flame resistant drippage
CN111518494A (en) * 2020-05-07 2020-08-11 扬中市锋利研磨材料有限公司 Super-strong bonding material for abrasive cloth and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103131341A (en) * 2011-11-30 2013-06-05 琳得科株式会社 Flame retardant adhering sheet
CN102911636A (en) * 2012-09-26 2013-02-06 贵阳时代沃顿科技有限公司 Double-component polyurethane adhesive, preparation method and application thereof
CN110317547A (en) * 2019-06-21 2019-10-11 深圳昌茂粘胶新材料有限公司 A kind of PET battery label material and preparation method thereof with flame resistant drippage
CN111518494A (en) * 2020-05-07 2020-08-11 扬中市锋利研磨材料有限公司 Super-strong bonding material for abrasive cloth and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
欧育湘 等: "《稀土改性导电陶瓷材料》", 30 September 2009, 国防工业出版社 *

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