CN112795324A - Antistatic flame-retardant double-transparent PET label material and preparation method thereof - Google Patents
Antistatic flame-retardant double-transparent PET label material and preparation method thereof Download PDFInfo
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- CN112795324A CN112795324A CN202011635884.XA CN202011635884A CN112795324A CN 112795324 A CN112795324 A CN 112795324A CN 202011635884 A CN202011635884 A CN 202011635884A CN 112795324 A CN112795324 A CN 112795324A
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 85
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000003292 glue Substances 0.000 claims abstract description 41
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000010409 thin film Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 10
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000004848 polyfunctional curative Substances 0.000 claims description 6
- 229920005749 polyurethane resin Polymers 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000011247 coating layer Substances 0.000 claims description 5
- 238000004049 embossing Methods 0.000 claims description 5
- 239000012948 isocyanate Substances 0.000 claims description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000012795 verification Methods 0.000 abstract description 3
- 230000005611 electricity Effects 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/33—Applications of adhesives in processes or use of adhesives in the form of films or foils for batteries or fuel cells
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/28—Presence of paper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Battery Mounting, Suspending (AREA)
Abstract
The invention belongs to the technical field of label materials, and particularly relates to an antistatic flame-retardant double-transparent PET label material and a preparation method thereof. The preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET. The label material is mainly applied to labels in the field of new energy automobiles and the like, is used as an automobile battery label, and helps to solve the safety problem of automobile batteries. The label material has insulating property, can resist static electricity, has high viscosity, enables the label to have better fitting property, enables the label to be more firmly fitted, has flame retardance, achieves the flame retardance verification of UL-VO, and can effectively resist secondary damage caused by battery burning and splashing.
Description
Technical Field
The invention belongs to the technical field of label materials, and particularly relates to an antistatic flame-retardant double-transparent PET label material and a preparation method thereof.
Background
In addition, in recent years, the concept of environmental protection is gradually deepened, and new energy automobiles gradually start to replace certain fuel automobiles. Under the great trend, the performance and quality of the new energy battery become social hotspots, so that an antistatic flame-retardant automobile label becomes a standard for new energy automobiles. And the improvement of the flame retardant property is undoubtedly the first choice for increasing the safety of new energy automobiles.
Disclosure of Invention
The invention provides an antistatic flame-retardant double-transparent PET label material and a preparation method thereof. The label material is mainly applied to labels in the field of new energy automobiles and the like, is used as an automobile battery label, and helps to solve the safety problem of automobile batteries. The label material has insulating property, can resist static electricity, has high viscosity, enables the label to have better fitting property, enables the label to be more firmly fitted, has flame retardance, achieves the flame retardance verification of UL-VO, and can effectively resist secondary damage caused by battery burning and splashing.
The invention is realized by the following technical scheme:
the antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
Further, the mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 4-5.
Further, the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20-30:5: 5.
Further, the corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4-5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Further, the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min.
In the invention, the used equipment such as scraper type coating equipment is common equipment in the field of film materials and can be obtained commercially.
The antistatic flame-retardant double-transparent PET label material is mainly applied to labels in the field of new energy automobiles and the like. The safety problem of car battery is solved in help, uses as car battery label.
The invention has the beneficial effects that:
(1) the antistatic flame-retardant double-transparent PET label material has insulativity (the resistance between 10MM is more than 1000M omega), can avoid short circuit, protects an automobile battery and is antistatic.
(2) The antistatic flame-retardant double-transmission PET label material has high viscosity which is more than 1.2Kgf/25mm, meets the standard of national standard GB/T2792-. The battery can be wrapped and protected more safely and more firmly.
(3) The antistatic flame-retardant double-transparent PET label material has flame retardance, achieves the flame-retardant verification of UL-VO, can effectively resist secondary damage caused by battery combustion and splashing, and cannot cause dripping.
(4) The antistatic flame-retardant double-transparent PET label material can be printed on the surface and can replace an automobile battery label.
Detailed Description
The present invention will be further described with reference to specific examples so that those skilled in the art may better understand the present invention, but the present invention is not limited thereto.
Example 1
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 4.5.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:25:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4.5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Example 2
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100:4.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:30:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Example 3
The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
The mass ratio of the phosphorus-nitrogen-bonded flame-retardant acrylic glue to the corresponding hardening agent is 100: 5.
The high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20:5: 5. The corresponding hardener is isocyanate.
A preparation method of an antistatic flame-retardant double-transparent PET label material comprises the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying; the high-temperature drying temperature in the step (3) is 110 ℃, and the drying time is 3 min;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
Comparative example 1
Same as example 1 except that no urethane resin was added.
Comparative example 2
Same as example 1 except that no mica powder was added.
The antistatic flame-retardant double-transparent PET label material prepared by the embodiments of the invention is tested, and the specific test is as follows:
the adhesive force is tested according to the national standard GB/T2792-2014 (20min), the flame retardance is tested according to the UL94 standard, and the resistance between 10MM is tested by using a resistance meter. The results are shown in Table 1.
TABLE 1
Viscous force Kgf/25mm | Flame retardancy | Resistance M omega | |
Example 1 | 1.39 | V0 | 1200 |
Example 2 | 1.55 | V0 | 1300 |
Example 3 | 1.46 | V0 | 1100 |
Comparative example 1 | 1.08 | V1 | 800 |
Comparative example 2 | 1.15 | V1 | 700 |
Claims (6)
1. The antistatic flame-retardant double-transmission PET label material is characterized in that the preparation raw materials of the PETPET label material comprise the following materials: 36 transparent flame-retardant PET thin films, high-viscosity phosphorus nitrogen flame-retardant acrylic glue, a corresponding hardening agent, embossed base paper with a release function and 25 black PET.
2. The antistatic flame-retardant double-transparent PET label material as claimed in claim 1, wherein the mass ratio of the phosphorus-nitrogen flame-retardant acrylic glue to the corresponding hardener is 100: 4-5.
3. The antistatic flame-retardant double-transparent PET label material as claimed in claim 1, wherein the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue comprises: acrylic acid glue, polyurethane resin, mica powder and a nitrogen-phosphorus flame retardant in a weight ratio of 100:20-30:5: 5.
4. The antistatic flame retardant two-through PET label material according to claim 1, characterized in that the corresponding hardener is isocyanate.
5. The preparation method of the antistatic flame-retardant double-transparent PET label material is characterized by comprising the following steps:
(1) uniformly coating the 36 transparent flame-retardant PET thin films with 18U of phosphorus-nitrogen flame-retardant glue by using professional scraper type coating equipment;
(2) blending the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue and the corresponding hardening agent according to the proportion of 100:4-5, placing the mixture in a stirrer, and stirring the mixture for 15min at the speed of 1200R/S to ensure that the mixture is uniformly stirred;
(3) uniformly coating the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue uniformly stirred in the step 2 on the release surface of the embossed base paper with the release function by using professional scraper type coating equipment, wherein the coating thickness is 30 mu m, and completely curing the high-viscosity phosphorus-nitrogen flame-retardant acrylic glue through high-temperature drying;
(4) the release surface of the release base paper with separable embossing is adhered to the surface of 25 black PET coating layers, and the prepared product is rolled to form the matte black fireproof flame-retardant PET automobile battery label with anti-flaming and anti-dripping functions.
6. The preparation method of the antistatic flame-retardant two-way PET label material according to claim 5, wherein the high-temperature drying temperature in the step (3) is 110 ℃ and the drying time is 3 min.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102911636A (en) * | 2012-09-26 | 2013-02-06 | 贵阳时代沃顿科技有限公司 | Double-component polyurethane adhesive, preparation method and application thereof |
CN103131341A (en) * | 2011-11-30 | 2013-06-05 | 琳得科株式会社 | Flame retardant adhering sheet |
CN110317547A (en) * | 2019-06-21 | 2019-10-11 | 深圳昌茂粘胶新材料有限公司 | A kind of PET battery label material and preparation method thereof with flame resistant drippage |
CN111518494A (en) * | 2020-05-07 | 2020-08-11 | 扬中市锋利研磨材料有限公司 | Super-strong bonding material for abrasive cloth and preparation method thereof |
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2020
- 2020-12-31 CN CN202011635884.XA patent/CN112795324A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103131341A (en) * | 2011-11-30 | 2013-06-05 | 琳得科株式会社 | Flame retardant adhering sheet |
CN102911636A (en) * | 2012-09-26 | 2013-02-06 | 贵阳时代沃顿科技有限公司 | Double-component polyurethane adhesive, preparation method and application thereof |
CN110317547A (en) * | 2019-06-21 | 2019-10-11 | 深圳昌茂粘胶新材料有限公司 | A kind of PET battery label material and preparation method thereof with flame resistant drippage |
CN111518494A (en) * | 2020-05-07 | 2020-08-11 | 扬中市锋利研磨材料有限公司 | Super-strong bonding material for abrasive cloth and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
欧育湘 等: "《稀土改性导电陶瓷材料》", 30 September 2009, 国防工业出版社 * |
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