CN112794672A - Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof - Google Patents
Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof Download PDFInfo
- Publication number
- CN112794672A CN112794672A CN202110041791.2A CN202110041791A CN112794672A CN 112794672 A CN112794672 A CN 112794672A CN 202110041791 A CN202110041791 A CN 202110041791A CN 112794672 A CN112794672 A CN 112794672A
- Authority
- CN
- China
- Prior art keywords
- parts
- baking
- excitant
- sodium
- free brick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention belongs to the technical field of baking-free brick additives, and particularly relates to an excitant for gold tailing overflow mud baking-free bricks and a preparation method thereof. The excitant is prepared from the following raw materials in parts by weight: 0.02-0.2 part of water reducing agent, 0.5-2 parts of triethanolamine, 0.1-1.5 parts of glycerol, 1-7 parts of sodium sulfate, 1-5 parts of potassium sulfate, 1-3 parts of magnesium chloride, 0.2-0.8 part of sodium hydroxide, 1-5 parts of sodium silicate, 0.1-0.5 part of sodium abietate and 80-100 parts of deionized water. The excitant for the gold tailing overflow mud baking-free brick can excite SiO in raw materials after being added into a gold tailing overflow mud baking-free brick system2And Al2O3The components are used for reducing the production cost of the baking-free brick by reducing the consumption of cement and improving the strength and freeze-thaw resistance of the baking-free brick.
Description
Technical Field
The invention belongs to the technical field of baking-free brick additives, and particularly relates to an excitant for gold tailing overflow mud baking-free bricks and a preparation method thereof.
Background
The gold tailings overflow mud is a byproduct discharged by precipitation, pressure filtration and discharge of fine mud generated in the process of producing potassium-sodalite and cleaning construction sand by comprehensively utilizing gold tailings, and the particle fineness is below minus 325 meshes. At present, the annual gold production in China is about 400 tons, and the annual removal of gold tailings is estimated to be 20000 million tons (calculated according to 2 g gold contained in 1 ton ore). The annual gold production in the tobacco field is about 55 tons, the tailings production is about 2250 ten thousand tons, the underground filling is calculated according to 60%, and 650 ten thousand tons are processed. At present, about 0.3 ton of overflow mud is discharged after 1 ton of gold tailings are used for producing potash albite and building sand, and 195 ten thousand tons of overflow mud is produced after 650 ten thousand tons of gold tailings are discharged one year. The appearance of the overflow mud is close to the soil color, and the chemical components of the overflow mud are as follows:
| name (R) | SiO2 | Al2O3 | K2O | Na2O | CaO | MgO | Fe2O3 | TiO2 |
| Content/% | 68.11 | 17.71 | 4.70 | 2.64 | 1.19 | 0.25 | 1.33 | 0.16 |
Because the iron sesquioxide has fine fineness and is easy to agglomerate after dehydration, and the color of the iron sesquioxide is dark brown after the iron sesquioxide is burnt to 1200 ℃, a good outlet is not provided for the prior large-scale utilization. A large amount of overflow mud can not be fully and effectively utilized, and can only be stacked by a large-area storage yard, thereby occupying a large amount of land and causing serious pollution to the environment. The generation of a large amount of overflow mud restricts the development of gold enterprises and causes direct and indirect influences on various aspects of production and life of local residents, so that how to recycle, reduce and harmlessly utilize the gold tailings overflow mud becomes a great problem in the front of people at present.
At present, in order to protect land resources and ecological environment, clay red bricks which are originally used as building wall materials are gradually forbidden to be used in China, and are replaced by various baking-free bricks, baking-free building blocks and other novel building materials. If the overflow mud can be used for preparing the baking-free brick, on one hand, the overflow mud can be reused, and on the other hand, the preparation cost of the baking-free brick can be reduced. However, in the process of preparing the overflow mud baking-free brick, due to the characteristics of the overflow mud, the pressed baking-free brick has the defect of low strength, in order to improve the strength, a mode of increasing the cement dosage is mostly adopted, and the increase of the cement dosage greatly improves the production cost of the overflow mud baking-free brick.
Therefore, there is a need to develop an activator for baking-free bricks made of gold tailings overflow mud, so as to improve the strength and frost resistance of the bricks.
Disclosure of Invention
The purpose of the invention is: provides an excitant for gold tailing overflowing mud baking-free bricks. The excitant can reduce the consumption of cement, improve the strength of the baking-free brick and reduce the production cost of the baking-free brick; the invention also provides a preparation method thereof.
The excitant for the gold tailing overflow mud baking-free brick is prepared from the following raw materials in parts by weight: 0.02-0.2 part of water reducing agent, 0.5-2 parts of triethanolamine, 0.1-1.5 parts of glycerol, 1-7 parts of sodium sulfate, 1-5 parts of potassium sulfate, 1-3 parts of magnesium chloride, 0.2-0.8 part of sodium hydroxide, 1-5 parts of sodium silicate, 0.1-0.5 part of sodium abietate and 80-100 parts of deionized water.
Preferably, the excitant for the gold tailings overflow mud baking-free brick is prepared from the following raw materials in parts by weight: 0.1-0.2 part of water reducing agent, 1.2-1.5 parts of triethanolamine, 0.5-1.5 parts of glycerol, 5-5.5 parts of sodium sulfate, 3-3.5 parts of potassium sulfate, 1-2 parts of magnesium chloride, 0.2-0.3 part of sodium hydroxide, 3-5 parts of sodium silicate, 0.2-0.4 part of sodium abietate and 80-100 parts of deionized water.
More preferably, the excitant for the gold tailings overflow mud baking-free brick is prepared from the following raw materials in parts by weight: 0.15 part of water reducing agent, 1.3 parts of triethanolamine, 1 part of glycerol, 5 parts of sodium sulfate, 3 parts of potassium sulfate, 1.5 parts of magnesium chloride, 0.3 part of sodium hydroxide, 4 parts of sodium silicate, 0.3 part of sodium abietate and 90 parts of deionized water.
Wherein:
the water reducing agent is one of polycarboxylate high-efficiency water reducing agents or lignosulfonate water reducing agents; the polycarboxylate high-efficiency water reducing agent is DH-4005 type polycarboxylate high-efficiency water reducing agent; the lignosulfonate water reducing agent is sodium lignosulfonate water reducing agent.
The excitant for the baking-free brick is added into a gold tailing overflow mud baking-free brick system, and SiO in the raw materials can be excited2And Al2O3Ingredients, the production cost of the baking-free brick is reduced by reducing the consumption of cementAnd the strength and the freeze-thaw resistance of the brick are improved, and the method has the advantages of convenience in production, high strength, better durability, environmental friendliness and energy conservation in the actual production process of the gold tailing overflowing mud baking-free brick.
The preparation method of the excitant for the gold tailing overflow mud baking-free brick comprises the following steps:
(1) adding sodium silicate into deionized water at the temperature of 80-90 ℃, and stirring and dissolving to obtain a sodium silicate aqueous solution;
(2) and (2) adding a water reducing agent, triethanolamine, glycerol, sodium sulfate, potassium sulfate, magnesium chloride, sodium hydroxide and sodium abietate into the sodium silicate aqueous solution prepared in the step (1), and stirring and dissolving to obtain the excitant for the baking-free brick of the gold tailings overflow mud.
The application of the excitant for the gold tailing overflow mud baking-free brick is that the excitant is added into a gold tailing overflow mud baking-free brick system; the usage amount of the excitant is 0.01-0.05% of the mass of the raw material of the baking-free brick made of gold tailings overflowing mud.
Compared with the prior art, the invention has the following beneficial effects:
(1) the excitant for the gold tailing overflow mud baking-free brick can excite SiO in raw materials after being added into a gold tailing overflow mud baking-free brick system2And Al2O3The production cost of the baking-free brick is reduced by reducing the consumption of cement, and the strength and the frost resistance of the baking-free brick are improved.
(2) The preparation method of the excitant for the gold tailing overflow mud baking-free brick is scientific, reasonable, simple and feasible, and is suitable for industrial production.
(3) The application of the excitant for the gold tailing overflow mud baking-free brick directly adds the excitant into a raw material system of the gold tailing overflow mud baking-free brick according to a certain proportion, has the advantages of convenient use, high strength of a finished brick, strong frost resistance, better durability, environmental protection and energy saving, realizes the comprehensive utilization of the gold tailing overflow mud, and reduces the pollution of the gold tailing overflow mud to the environment.
Detailed Description
The present invention is further described below with reference to examples.
Example 1
The excitant for the gold tailings overflow mud baking-free brick in the embodiment 1 is prepared from the following raw materials by weight: 0.1Kg of water reducing agent, 1.2Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.5Kg of potassium sulfate, 1Kg of magnesium chloride, 0.25Kg of sodium hydroxide, 4Kg of sodium silicate, 0.2Kg of sodium abietate and 90Kg of deionized water.
Wherein the water reducing agent is a DH-4005 type polycarboxylate high-efficiency water reducing agent.
The preparation method of the excitant for the gold tailings overflow mud baking-free brick in the embodiment 1 comprises the following steps:
(1) weighing 4kg of sodium silicate, adding the sodium silicate into 90kg of deionized water at 85 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.1Kg of DH-4005 type polycarboxylate superplasticizer, 1.2Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.5Kg of potassium sulfate, 1Kg of magnesium chloride, 0.25Kg of sodium hydroxide and 0.2Kg of sodium abietate, and adding the weighed materials into the sodium silicate solution to be fully stirred and dissolved to prepare the excitant for the gold tailings overflow mud baking-free brick.
In the application of the excitant for the baking-free brick made of the gold tailings overflow mud in the embodiment 1, 50kg of gold tailings overflow mud and 37kg of waste incineration slag are weighed; weighing 13kg of 425# cement and 0.02kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Example 2
The excitant for the gold tailings overflow mud baking-free brick in the embodiment 2 is prepared from the following raw materials by weight: 0.1Kg of water reducing agent, 1.2Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.5Kg of potassium sulfate, 1Kg of magnesium chloride, 0.25Kg of sodium hydroxide, 4Kg of sodium silicate, 0.2Kg of sodium abietate and 90Kg of deionized water.
Wherein the water reducing agent is a DH-4005 type polycarboxylate high-efficiency water reducing agent.
The preparation method of the excitant for the gold tailings overflow mud baking-free brick in the embodiment 2 comprises the following steps:
(1) weighing 4kg of sodium silicate, adding the sodium silicate into 90kg of deionized water at 85 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.1Kg of DH-4005 type polycarboxylate superplasticizer, 1.2Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.5Kg of potassium sulfate, 1Kg of magnesium chloride, 0.25Kg of sodium hydroxide and 0.2Kg of sodium abietate, and adding the weighed materials into the sodium silicate solution to be fully stirred and dissolved to prepare the excitant for the gold tailings overflow mud baking-free brick.
In the application of the excitant for the baking-free brick made of the gold tailings overflow mud in the embodiment 2, 50kg of gold tailings overflow mud and 37kg of waste incineration slag are weighed; weighing 13kg of 425# cement and 0.04kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Example 3
The excitant for the gold tailing overflowing mud baking-free brick in the embodiment 3 is prepared from the following raw materials in parts by weight: 0.15Kg of water reducing agent, 1.3Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.0Kg of potassium sulfate, 1.5Kg of magnesium chloride, 0.3Kg of sodium hydroxide, 4Kg of sodium silicate, 0.3Kg of sodium abietate and 90Kg of deionized water.
Wherein the water reducing agent is sodium lignosulfonate water reducing agent.
The preparation method of the excitant for the gold tailings overflow mud baking-free brick in the embodiment 3 comprises the following steps:
(1) weighing 4kg of sodium silicate, adding the sodium silicate into 90kg of deionized water at 85 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.15Kg of sodium lignosulfonate water reducing agent, 1.3Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.0Kg of potassium sulfate, 1.5Kg of magnesium chloride, 0.3Kg of sodium hydroxide and 0.3Kg of sodium abietate, adding the sodium lignosulfonate water reducing agent, the sodium hydroxide and the sodium abietate into the sodium silicate solution, and fully stirring and dissolving to obtain the excitant for the gold tailing overflow mud baking-free brick.
In the application of the excitant for the gold tailing overflow sludge baking-free brick in the embodiment 3, 50kg of gold tailing overflow sludge and 37kg of waste incineration residue are weighed; weighing 13kg of 425# cement and 0.02kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Example 4
The excitant for the gold tailings overflow mud baking-free brick in the embodiment 4 is prepared from the following raw materials by weight: 0.15Kg of water reducing agent, 1.3Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.0Kg of potassium sulfate, 1.5Kg of magnesium chloride, 0.3Kg of sodium hydroxide, 4Kg of sodium silicate, 0.3Kg of sodium abietate and 90Kg of deionized water.
Wherein the water reducing agent is sodium lignosulfonate water reducing agent.
The preparation method of the excitant for the gold tailings overflow mud baking-free brick in the embodiment 4 comprises the following steps:
(1) weighing 4kg of sodium silicate, adding the sodium silicate into 90kg of deionized water at 85 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.15Kg of sodium lignosulfonate water reducing agent, 1.3Kg of triethanolamine, 1Kg of glycerol, 5Kg of sodium sulfate, 3.0Kg of potassium sulfate, 1.5Kg of magnesium chloride, 0.3Kg of sodium hydroxide and 0.3Kg of sodium abietate, adding the sodium lignosulfonate water reducing agent, the sodium hydroxide and the sodium abietate into the sodium silicate solution, and fully stirring and dissolving to obtain the excitant for the gold tailing overflow mud baking-free brick.
Wherein the water reducing agent is sodium lignosulfonate water reducing agent.
In the application of the excitant for the baking-free brick made of gold tailings overflow mud in the embodiment 4, 50kg of gold tailings overflow mud and 37kg of waste incineration slag are weighed; weighing 13kg of 425# cement and 0.04kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Example 5
The excitant for the gold tailings overflow mud baking-free brick in the embodiment 5 is prepared from the following raw materials by weight: 0.2Kg of water reducing agent, 1.5Kg of triethanolamine, 1.5Kg of glycerol, 7Kg of sodium sulfate, 1Kg of potassium sulfate, 3Kg of magnesium chloride, 0.8Kg of sodium hydroxide, 5Kg of sodium silicate, 0.5Kg of sodium abietate and 100Kg of deionized water.
Wherein the water reducing agent is sodium lignosulfonate water reducing agent.
The preparation method of the excitant for the gold tailings overflow mud baking-free brick in the embodiment 5 comprises the following steps:
(1) weighing 5kg of sodium silicate, adding the sodium silicate into 100kg of deionized water at 90 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.2Kg of sodium lignosulfonate water reducing agent, 1.5Kg of triethanolamine, 1.5Kg of glycerol, 7Kg of sodium sulfate, 1Kg of potassium sulfate, 3Kg of magnesium chloride, 0.8Kg of sodium hydroxide and 0.5Kg of sodium abietate, adding the sodium silicate solution, and fully stirring and dissolving to obtain the excitant for the gold tailings overflow mud baking-free brick.
In the application of the excitant for the baking-free brick made of gold tailings overflow mud in the embodiment 5, 50kg of gold tailings overflow mud and 37kg of waste incineration slag are weighed; weighing 13kg of 425# cement and 0.05kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Comparative example 1
The excitant for the gold tailing overflow mud baking-free brick in the comparative example 1 is prepared from the following raw materials in parts by weight: 0.2kg of water reducing agent, 1.5kg of triethanolamine, 1.5kg of glycerol, 7kg of sodium sulfate, 1kg of potassium sulfate, 3kg of magnesium chloride, 0.8kg of sodium hydroxide, 5kg of sodium silicate and 100kg of deionized water.
Wherein the water reducing agent is sodium lignosulfonate water reducing agent.
The preparation method of the excitant for the gold tailing overflow mud baking-free brick in the comparative example 1 comprises the following steps:
(1) weighing 5kg of sodium silicate, adding the sodium silicate into 100kg of deionized water at 90 ℃, and fully stirring and dissolving to prepare a sodium silicate solution;
(2) weighing 0.2kg of sodium lignosulfonate water reducing agent, 1.5kg of triethanolamine, 1.5kg of glycerol, 7kg of sodium sulfate, 1kg of potassium sulfate, 3kg of magnesium chloride and 0.8kg of sodium hydroxide, and adding the sodium silicate solution into the sodium silicate solution to be fully stirred and dissolved to obtain the excitant for the gold tailings overflow mud baking-free brick.
The application of the excitant for the gold tailing overflow sludge baking-free brick in the comparative example 1 is that 50kg of gold tailing overflow sludge and 37kg of waste incineration slag are weighed; weighing 13kg of 425# cement and 0.05kg of excitant, mixing, carrying out rolling type stirring for 20min, and adding water to adjust the humidity of the mixture in the stirring process to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished gold tailings overflow mud baking-free bricks.
Comparative example 2
The baking-free brick of gold tailings overflow mud of the comparative example 2: weighing 50kg of gold tailing overflow mud, 37kg of waste incineration slag and 13kg of No. 425 cement, mixing, performing rolling type stirring for 20min, and adding water to adjust the humidity of the mixture during stirring to obtain a raw material mixture; slowly pouring the stirred raw material mixture into a die, slightly shaking to enable the raw material mixture to be leveled in a punching brick making machine, and pressing for 200 seconds at the pressure of 8MPa for forming; and naturally curing the green bricks for 15 days, and drying to obtain the finished product.
The compression strength and frost resistance of the finished products prepared in the examples 1-5 and the comparative examples 1-2 are tested according to the national baking-free brick test standard (GB/T2542 baking-free brick test standard); specific data are shown in table 1.
TABLE 1 compression strength and freeze-thaw resistance of the finished products obtained in examples 1-5 and comparative examples 1-2
| Serial number | Compressive strength (MPa) | Freeze resistance test (-30 ℃ C.) |
| Example 1 | 26.1 | Good integrity of appearance after 30 cycles |
| Example 2 | 26.8 | Good integrity of appearance after 30 cycles |
| Example 3 | 27.3 | Good integrity of appearance after 30 cycles |
| Example 4 | 27.7 | Good integrity of appearance after 30 cycles |
| Example 5 | 27.2 | Good integrity of appearance after 30 cycles |
| Comparative example 1 | 21.7 | The mass loss is 5 percent after 7 times of circulation |
| Comparative example 2 | 15.2 | The mass loss exceeds 5 percent after 4 times of circulation |
As can be seen from Table 1, the addition of the excitant prepared by the invention into a preparation system of the gold tailings overflow mud brick can greatly improve the compressive strength of a finished brick, but when the usage amount of the excitant is more than 0.04%, the compressive strength effect is not obvious, and the influence of freeze thawing resistance is not great; when sodium abietate is removed from the formula of the excitant, the strength is reduced to some extent, and the freezing resistance is obviously reduced. The excitant has the advantages of convenient use, high strength of finished bricks, environmental protection and energy saving, realizes the comprehensive utilization of the gold tailings overflowing mud, and reduces the pollution of the gold tailings overflowing mud to the environment.
The cost before and after the use of the exciting agent is compared with the table:
when the strength effect of adding the exciting agent is achieved without adding the exciting agent, the adding amount of the cement is obviously increased, and the manufacturing cost per square baking-free brick is increased. The preparation cost of the exciting agent is 17.45 yuan/m2The preparation cost without adding the excitant is 22.22 yuan/m2The difference of the cost per square is 4.77 yuan/m2。
The cost of the gold tailings overflow mud baking-free brick without the addition of the excitant is as follows:
the cost of the gold tailings overflow mud baking-free brick added with the excitant is as follows:
Claims (7)
1. an excitant for gold tailing overflow mud baking-free bricks is characterized in that: the feed is prepared from the following raw materials in parts by weight: 0.02-0.2 part of water reducing agent, 0.5-2 parts of triethanolamine, 0.1-1.5 parts of glycerol, 1-7 parts of sodium sulfate, 1-5 parts of potassium sulfate, 1-3 parts of magnesium chloride, 0.2-0.8 part of sodium hydroxide, 1-5 parts of sodium silicate, 0.1-0.5 part of sodium abietate and 80-100 parts of deionized water.
2. The excitant for the gold tailings overflow mud baking-free brick as claimed in claim 1, wherein: the feed is prepared from the following raw materials in parts by weight: 0.1-0.2 part of water reducing agent, 1.2-1.5 parts of triethanolamine, 0.5-1.5 parts of glycerol, 5-5.5 parts of sodium sulfate, 3-3.5 parts of potassium sulfate, 1-2 parts of magnesium chloride, 0.2-0.3 part of sodium hydroxide, 3-5 parts of sodium silicate, 0.2-0.4 part of sodium abietate and 80-100 parts of deionized water.
3. The excitant for the gold tailings overflow mud baking-free brick as claimed in claim 1, wherein: the feed is prepared from the following raw materials in parts by weight: 0.15 part of water reducing agent, 1.3 parts of triethanolamine, 1 part of glycerol, 5 parts of sodium sulfate, 3 parts of potassium sulfate, 1.5 parts of magnesium chloride, 0.3 part of sodium hydroxide, 4 parts of sodium silicate, 0.3 part of sodium abietate and 90 parts of deionized water.
4. The excitant for the baking-free bricks of the gold tailings overflow mud as claimed in any one of claims 1 to 3, which is characterized in that: the water reducing agent is one of polycarboxylate high-efficiency water reducing agents or lignosulfonate water reducing agents.
5. The excitant for the gold tailings overflow mud baking-free brick as claimed in claim 4, wherein: the polycarboxylate high-efficiency water reducing agent is a DH-4005 type polycarboxylate high-efficiency water reducing agent; the lignosulfonate water reducing agent is sodium lignosulfonate water reducing agent.
6. The preparation method of the excitant for the gold tailings overflow mud baking-free brick as claimed in claim 1, is characterized in that: the method comprises the following steps:
(1) adding sodium silicate into deionized water at the temperature of 80-90 ℃, and stirring and dissolving to obtain a sodium silicate aqueous solution;
(2) and (2) adding a water reducing agent, triethanolamine, glycerol, sodium sulfate, potassium sulfate, magnesium chloride, sodium hydroxide and sodium abietate into the sodium silicate aqueous solution prepared in the step (1), and stirring and dissolving to obtain the excitant for the baking-free brick of the gold tailings overflow mud.
7. The application of the excitant for the baking-free bricks of the gold tailings overflow mud as claimed in claim 1, is characterized in that: adding an excitant into a gold tailing overflow mud baking-free brick system; the usage amount of the excitant is 0.01-0.05% of the mass of the raw material of the baking-free brick made of gold tailings overflowing mud.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110041791.2A CN112794672A (en) | 2021-01-13 | 2021-01-13 | Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110041791.2A CN112794672A (en) | 2021-01-13 | 2021-01-13 | Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112794672A true CN112794672A (en) | 2021-05-14 |
Family
ID=75810415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110041791.2A Pending CN112794672A (en) | 2021-01-13 | 2021-01-13 | Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112794672A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105084793A (en) * | 2015-07-02 | 2015-11-25 | 济南大学 | Active excitatory grinding aid for ferronickel slag and preparation method for active excitatory grinding aid |
| CN109485286A (en) * | 2019-01-22 | 2019-03-19 | 山东淄创新材料科技有限公司 | Baking-free brick of red mud promotor and preparation method thereof |
| CN109836066A (en) * | 2019-03-29 | 2019-06-04 | 山东淄创新材料科技有限公司 | The non-burning brick exciting agent and preparation method thereof of dolomite waste residue |
| CN110372249A (en) * | 2019-08-27 | 2019-10-25 | 山东淄创新材料科技有限公司 | The non-burning brick reinforcing agent and preparation method thereof of incineration ash of household rubbish |
-
2021
- 2021-01-13 CN CN202110041791.2A patent/CN112794672A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105084793A (en) * | 2015-07-02 | 2015-11-25 | 济南大学 | Active excitatory grinding aid for ferronickel slag and preparation method for active excitatory grinding aid |
| CN109485286A (en) * | 2019-01-22 | 2019-03-19 | 山东淄创新材料科技有限公司 | Baking-free brick of red mud promotor and preparation method thereof |
| CN109836066A (en) * | 2019-03-29 | 2019-06-04 | 山东淄创新材料科技有限公司 | The non-burning brick exciting agent and preparation method thereof of dolomite waste residue |
| CN110372249A (en) * | 2019-08-27 | 2019-10-25 | 山东淄创新材料科技有限公司 | The non-burning brick reinforcing agent and preparation method thereof of incineration ash of household rubbish |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2020101143A4 (en) | A Method For Preparing The Fast-Hardening Early-Strength High-Performance All-Solid Waste Concrete | |
| CN110041028A (en) | A kind of regeneration concrete and preparation method thereof using building waste | |
| CN109485286B (en) | Accelerant for red mud baking-free brick and preparation method thereof | |
| CN110642585B (en) | Aerated concrete block and preparation process thereof | |
| CN105859229B (en) | A kind of slag make binder materials and fine aggregate without cement green mortar and preparation method thereof | |
| CN103159450B (en) | Production method of foamed concrete block manufactured from steel slag | |
| CN112266201A (en) | Building waste non-fired recycled brick and preparation method thereof | |
| CN112608043B (en) | High-strength nickel slag-based solid waste cementing material and preparation method thereof | |
| CN102329105A (en) | Method for preparing concrete by taking manganese residue-steel residue-limestone powder as admixture | |
| CN104529312A (en) | High-admixing amount high-strength nickel slag brick and preparation method of high-admixing amount high-strength nickel slag brick | |
| CN107056200B (en) | A method of environment friendly pervious brick is prepared using industrial melting waste slag | |
| CN111689742A (en) | Industrial solid waste composite material brick and preparation method thereof | |
| CN102092995A (en) | Concrete material by using tail sand to displace yellow sand and preparation method thereof | |
| CN114988741A (en) | Lithium salt-based composite mineral admixture and preparation method thereof | |
| CN105130492A (en) | Nickel slag aerated concrete and preparation method thereof | |
| CN104803635A (en) | Waste glass-ultrafine tailing sand floor tile and preparation method thereof | |
| CN114230208A (en) | High-strength cement and preparation method thereof | |
| CN114276097A (en) | Nickel slag cementing material for improving activity of nickel slag through split-phase activation and preparation method thereof | |
| CN113149551B (en) | Superfine sulfur-containing tailing concrete | |
| CN110981233B (en) | Ferronickel slag masonry cement and preparation method thereof | |
| CN109836066A (en) | The non-burning brick exciting agent and preparation method thereof of dolomite waste residue | |
| CN115849811B (en) | High-stability self-compaction concrete and preparation method thereof | |
| CN115536358A (en) | Industrial solid waste carbonization and solidification baking-free building block and preparation method thereof | |
| CN112794672A (en) | Excitant for gold tailing overflowing mud baking-free brick and preparation method thereof | |
| CN112521179B (en) | Method for preparing wall thermal insulation material by utilizing industrial solid waste |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210514 |
|
| RJ01 | Rejection of invention patent application after publication |