CN112777745A - Full-film biological sewage denitrification treatment device and biological sewage denitrification treatment method - Google Patents

Full-film biological sewage denitrification treatment device and biological sewage denitrification treatment method Download PDF

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Publication number
CN112777745A
CN112777745A CN202110117336.6A CN202110117336A CN112777745A CN 112777745 A CN112777745 A CN 112777745A CN 202110117336 A CN202110117336 A CN 202110117336A CN 112777745 A CN112777745 A CN 112777745A
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membrane
anoxic
aerobic
biological
sewage
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CN202110117336.6A
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李祥
黄勇
袁砚
林振峰
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Suzhou University of Science and Technology
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Suzhou University of Science and Technology
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Priority to CN202110117336.6A priority Critical patent/CN112777745A/en
Priority to CN202211027296.7A priority patent/CN115448456A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention relates to the technical field of sewage treatment, in particular to a full-membrane sewage biological denitrification treatment device and a sewage biological denitrification treatment method. The invention takes the biological membrane as a carrier, and enriches and cultures different microorganisms in different environments respectively, thereby realizing the improvement of the abundance of the microorganisms and being beneficial to the improvement of the nitrogen conversion efficiency. Aiming at heterotrophic microorganisms growing faster in an anoxic zone, a suspended mobile filler is used as a carrier, so that the mutual friction probability is increased, and an anoxic aeration system is additionally arranged to strengthen the falling off of an aged biological membrane and ensure the activity of the biological membrane for degrading pollutants; aiming at autotrophic microorganisms with slower growth in an aerobic zone, the fixed fiber filler is adopted as a carrier, which is beneficial to the efficient enrichment of the microorganisms, and the aeration system is arranged at the bottom, which is beneficial to the scouring of gas on an aged biological membrane on the fixed fiber filler, so that the activity of the biological membrane in the aerobic zone is ensured, the concentration of suspended solids in water is reduced, the abrasion of a reflux pump of nitrifying liquid is reduced, the water yield of an MBR membrane is increased, and the service life of the MBR membrane is prolonged.

Description

Full-film biological sewage denitrification treatment device and biological sewage denitrification treatment method
Technical Field
The invention relates to the technical field of sewage treatment, in particular to a full-membrane sewage biological denitrification treatment device and a sewage biological denitrification treatment method.
Background
Biological denitrification has been considered the most economical denitrification pathway for wastewater. In general, activated sludge is generally used as a carrier in the conventional biological denitrification, and nitrification microorganism and denitrification microorganism enrichment are realized by alternately operating in an anoxic environment and an aerobic environment. In an aerobic environment, the activity of denitrifying microorganisms in the sludge is in a suppressed state due to the lack of an aerobic environment and organic matters, while the activity of nitrifying microorganisms in the sludge is recovered, and ammonia nitrogen in the sewage is converted into nitrite or nitrate by using oxygen; then when the sludge and the nitrifying liquid flow back to the anaerobic or anoxic environment, the activity of the nitrifying microorganisms is in a suppressed state due to lack of dissolved oxygen, and at the moment, the activity of the denitrifying microorganisms is recovered and the nitrate is converted into nitrogen by using organic matters in the inlet water to be removed. In order to fully utilize organic matters carried in raw water to carry out denitrification, a preposed anoxic tank is generally followed by an aerobic tank, and a nitrification liquid reflux system is arranged to reflux water treated by the aerobic tank to the front-end anoxic tank. In order to ensure that the anoxic tank and the aerobic tank have enough microorganisms, the sedimentation tank is additionally arranged, and a sludge reflux pump is additionally arranged to reflux the precipitated high-concentration sludge to the anoxic end. The prior denitrification system using the single sludge as the carrier has the following problems because the carrier is single and continuously and alternately operates in aerobic and anoxic environments: firstly, the nitrifying bacteria are autotrophic microorganisms and grow slowly; while the denitrifying microorganism is a heterotrophic microorganism that grows faster. The method is put into a single sludge system to alternately operate, the specific gravity of autotrophic microorganisms is difficult to increase by adopting a single sludge discharge period, and the activity of a nitrification system is difficult to improve. And secondly, in a conventional biological denitrification system using sludge as a carrier, the sludge often causes the breaking of microorganism aggregates due to aeration and stirring, so that the sludge sedimentation tank has large volume and is difficult in sludge-water separation.
In order to solve the problem of low microbial abundance in a single sludge system, fillers are additionally arranged in an aerobic area and an anoxic area in some existing process designs, so that the abundance of nitrifying microbes and denitrifying microbes in a corresponding tank body is increased, and a membrane-sludge dual system or a single membrane system is further formed. The sludge of the membrane-sludge dual system needs to be precipitated, and still has the problems of fragility and the like, and the problem of low abundance of microorganisms still cannot be solved; the single membrane system suffers from the following problems: 1) the generation time of the denitrifying microorganisms is short, the propagation speed is high, and the growth and death of the biological membrane are high, so that the phenomenon that the aged biological membrane is difficult to fall off is caused; 2) the nitrification system has the phenomenon that the growth of microorganisms is slow, and a biological membrane is difficult to form quickly or is difficult to fall off after being formed. Therefore, it is necessary to adopt membrane carriers with different characteristics according to the growth characteristics of different microorganisms and to solve the above problems by means of unique process design.
Disclosure of Invention
The invention aims to provide a full-film biological sewage denitrification treatment device and a biological sewage denitrification treatment method. The device provided by the invention can realize the improvement of the abundance of microorganisms, is beneficial to the improvement of the nitrogen conversion efficiency, and can save a sedimentation tank, increase the water yield of the MBR membrane and prolong the service life of the MBR membrane.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a full-membrane biological sewage denitrification treatment device, which comprises an anoxic membrane tank 1, an aerobic membrane tank 2, an MBR (membrane bioreactor) membrane system 3 and a reflux system 4;
the anoxic membrane tank 1, the aerobic membrane tank 2 and the MBR membrane system 3 are sequentially connected;
two ends of the reflux system 4 are respectively connected with the anoxic membrane tank 1 and the aerobic membrane tank 2;
the anoxic membrane tank 1 comprises a flow impeller 6, a water inlet pipe 7, an anoxic aeration system 8 and a suspended mobile filler 5; the flow pushing direction of the flow pusher 6 is opposite to the air outlet direction of the anoxic aeration system 8;
the aerobic membrane tank 2 comprises a fixed fiber filler 9 and an aerobic aeration system 13 positioned right below the fixed fiber filler 9.
Preferably, the filling degree of the suspended mobile filler 5 in the anoxic membrane tank 1 is 40-60%.
Preferably, the suspended mobile filler 5 is polyethylene mobile film filler, sponge film or a combination of polyethylene mobile film filler and sponge film.
Preferably, the filling degree of the fixed fiber filler 9 in the aerobic membrane pool 2 is 40-60%.
Preferably, the anoxic membrane tank 1 and the aerobic membrane tank 2 are constructed by sharing the wall.
Preferably, the aerobic aeration system 13 and the anoxic aeration system 8 adopt microporous aeration pipelines.
Preferably, the MBR membrane system 3 is an external membrane.
Preferably, the reflux system 4 adopts a gas lift reflux or a reflux pump reflux.
The invention also provides a biological sewage denitrification treatment method, which comprises the following steps:
the method for biological denitrification treatment of sewage is carried out by utilizing the full-film biological denitrification treatment device for sewage in the technical scheme;
closing the anoxic aeration system 8, starting the flow pushing device 6 and the aerobic aeration system 13, sequentially feeding sewage into the anoxic membrane tank 1 from the water inlet pipe 7 for anoxic treatment and the aerobic membrane tank 2 for aerobic treatment, refluxing a part of nitrified liquid obtained after the aerobic treatment to the anoxic membrane tank 1 through the reflux system 4, and treating the rest part through the MBR membrane system 3 to realize sludge-water separation;
after the biological membrane on the suspended moving filler 5 in the anoxic membrane tank 1 is aged, opening an anoxic aeration system 8 to enable the aged biological membrane to fall off;
and when the biological membrane fixed on the fiber filler 9 in the aerobic membrane tank 2 is aged, the aeration quantity of the aerobic aeration system 13 is instantly increased, so that the aged biological membrane falls off.
Preferably, the reflux ratio of the reflux is (2-14): 1.
The invention provides a full-membrane biological sewage denitrification treatment device, which comprises an anoxic membrane tank 1, an aerobic membrane tank 2, an MBR (membrane bioreactor) membrane system 3 and a reflux system 4; the anoxic membrane tank 1, the aerobic membrane tank 2 and the MBR membrane system 3 are sequentially connected; two ends of the reflux system 4 are respectively connected with the anoxic membrane tank 1 and the aerobic membrane tank 2; the anoxic membrane tank 1 comprises a flow impeller 6, a water inlet pipe 7, an anoxic aeration system 8 and a suspended mobile filler 5; the flow pushing direction of the flow pusher 6 is opposite to the air outlet direction of the anoxic aeration system 8; the aerobic membrane tank 2 comprises a fixed fiber filler 9 and an aerobic aeration system 13 positioned right below the fixed fiber filler 9. The invention takes the biological membrane as a carrier, and enriches and cultures different microorganisms in different environments respectively, thereby realizing the improvement of the abundance of the microorganisms and being beneficial to the improvement of the nitrogen conversion efficiency. Meanwhile, aiming at heterotrophic microorganisms which grow fast in an anoxic zone, a movable suspended movable filler is adopted as a carrier, so that the mutual friction probability is increased, and an anoxic aeration system which can generate convection with the flow pushing direction of a flow pusher is additionally arranged to strengthen the falling of an aged biological membrane and ensure the activity of the biological membrane for degrading pollutants; aiming at autotrophic microorganisms with slower growth in an aerobic zone, the fixed fiber filler is adopted as a carrier, which is beneficial to the efficient enrichment of the microorganisms, the aeration system is arranged at the bottom, which is beneficial to the scouring of gas on an aged biological membrane on the fixed fiber filler, the activity of the biological membrane in the aerobic zone is ensured, the concentration of suspended solids in water is reduced, the reflux abrasion of nitrified liquid is reduced, and the water doping amount and the service life of the MBR membrane are increased.
Drawings
FIG. 1 is a diagram of a full-membrane biological sewage denitrification treatment device, wherein the full-membrane biological sewage denitrification treatment device comprises a 1-anoxic membrane tank, a 2-aerobic membrane tank, a 3-MBR membrane system, a 4-reflux system, 5-suspended movable filler, 6-flow impeller, 7-water inlet pipe, 8-anoxic aeration system, 9-fixed fiber filler, 10-air inlet pipe, 11-old biological membrane outlet, 12-water outlet and 13-aerobic aeration system;
FIG. 2 is a physical diagram of the polyethylene moving film suspended moving filler of example 1;
FIG. 3 is a pictorial representation of a fixed fibrous wadding as described in example 1;
fig. 4 is a diagram of a combination of the polyethylene moving film filler and the sponge film according to the present invention.
Detailed Description
The invention provides a full-membrane biological sewage denitrification treatment device, which comprises an anoxic membrane tank 1, an aerobic membrane tank 2, an MBR (membrane bioreactor) membrane system 3 and a reflux system 4;
the anoxic membrane tank 1, the aerobic membrane tank 2 and the MBR membrane system 3 are sequentially connected;
two ends of the reflux system 4 are respectively connected with the anoxic membrane tank 1 and the aerobic membrane tank 2;
the anoxic membrane tank 1 comprises a flow impeller 6, a water inlet pipe 7, an anoxic aeration system 8 and a suspended mobile filler 5; the flow pushing direction of the flow pusher 6 is opposite to the air outlet direction of the anoxic aeration system 8;
the aerobic membrane tank 2 comprises a fixed fiber filler 9 and an aerobic aeration system 13 positioned right below the fixed fiber filler 9.
As an embodiment of the invention, the filling degree of the suspended mobile filler 5 in the anoxic membrane tank 1 is 40-60%.
As an embodiment of the present invention, the suspended mobile filler 5 is a polyethylene mobile film filler, a sponge film or a combination of a polyethylene mobile film filler and a sponge film (as shown in fig. 4).
As an embodiment of the invention, the filling degree of the fixed fiber filler 9 in the aerobic membrane tank 2 is 40-60%.
As an embodiment of the invention, the anoxic membrane tank 1 and the aerobic membrane tank 2 are constructed in a wall-sharing way.
As an embodiment of the invention, the aerobic aeration system 13 and the anoxic aeration system 8 adopt microporous aeration pipelines.
As an embodiment of the invention, the MBR membrane system 3 is an external membrane.
As an embodiment of the present invention, the reflux system 4 employs a gas lift reflux or a reflux pump reflux.
As an embodiment of the invention, the MBR membrane system 3 comprises an old biofilm outlet 11 and a water outlet 12; and an ultrafiltration membrane is arranged in the MBR membrane system 3.
The invention also provides a biological sewage denitrification treatment method, which comprises the following steps:
the method for biological denitrification treatment of sewage is carried out by utilizing the full-film biological denitrification treatment device for sewage in the technical scheme;
closing the anoxic aeration system 8, starting the flow pushing device 6 and the aerobic aeration system 13, sequentially feeding sewage into the anoxic membrane tank 1 from the water inlet pipe 7 for anoxic treatment and the aerobic membrane tank 2 for aerobic treatment, refluxing a part of nitrified liquid obtained after the aerobic treatment to the anoxic membrane tank 1 through the reflux system 4, and treating the rest part through the MBR membrane system 3 to realize sludge-water separation;
after the biological membrane on the suspended moving filler 5 in the anoxic membrane tank 1 is aged, opening an anoxic aeration system 8 to enable the aged biological membrane to fall off;
and when the biological membrane fixed on the fiber filler 9 in the aerobic membrane tank 2 is aged, the aeration quantity of the aerobic aeration system 13 is instantly increased, so that the aged biological membrane falls off.
In the present invention, the reflux ratio of the reflux is preferably (2-14): 1. In an embodiment of the invention, the reflux ratio of the reflux is 4: 1.
In the invention, when the biological membrane on the suspended mobile filler 5 in the anoxic membrane tank 1 is aged and the anoxic aeration system 8 is opened to make the aged biological membrane fall off, the volume ratio of the air inflow of the anoxic aeration system 8 to the water inflow of the anoxic membrane tank 1 is preferably (10-20): 1, more preferably 20: 1; the duration is preferably 1-3 h, and more preferably 2 h. In the examples of the invention, the volume ratio is in particular 20:1 and the duration is in particular 2 h.
In the invention, the dissolved oxygen in the aerobic membrane pool 2 is preferably 0.5-4 mg/L, and more preferably 2 mg/L; in the examples of the present invention, the dissolved oxygen was specifically 2 mg/L. In the invention, the volume ratio of the air inflow to the water inflow in the aerobic membrane pool 2 is preferably (3-10): 1, and more preferably 5: 1.
In the present invention, when the aeration rate of the aerobic aeration system 13 is increased after the biological membrane fixed on the fiber filler 9 in the aerobic membrane tank 2 is aged, and the aged biological membrane is removed, the specific operation of increasing the aeration rate of the aerobic aeration system 13 is preferably to increase the volume ratio of the air intake amount to the water intake amount in the aerobic membrane tank 2, and the volume ratio is preferably (5-20): 1, more preferably 9: 1.
The following will explain in detail the apparatus for total membrane type biological nitrogen removal treatment of wastewater and the method for biological nitrogen removal treatment of wastewater according to the present invention with reference to examples, but they should not be construed as limiting the scope of the present invention.
Example 1
The full-film biological sewage denitrification treatment device as shown in figure 1, wherein the volume of the anoxic membrane tank 1 is 1m3Polyethylene moving film suspended moving filler (as shown in figure 2) is added into the anoxic film pool 1, and the filling degree is 40%; the volume of the aerobic membrane tank 2 is 5m3A fixed fiber filler (as shown in figure 3) is added into the aerobic membrane pool 2, and the filling degree is 60%; an ultrafiltration membrane is arranged in the MBR membrane system 3; the reflux system 4 adopts a reflux pump for reflux, and the reflux ratio is 4: 1;
the sewage treatment process comprises the following steps:
sewage to be treated: the ammonia nitrogen concentration is 100mg/L, and the COD concentration is 500 mg/L;
closing the anoxic aeration system 8, starting the flow pushing device 6 and the aerobic aeration system 13, sequentially feeding sewage to be treated into the anoxic membrane tank 1 from the water inlet pipe 7 for anoxic treatment and aerobic treatment in the aerobic membrane tank 2, refluxing a part of nitrified liquid obtained after the aerobic treatment to the anoxic membrane tank 1 through the reflux system 4, and treating the rest part of nitrified liquid through the MBR membrane system 3 to realize sludge-water separation, wherein the COD concentration in effluent water of the MBR membrane system 3 is 33mg/L, the nitrate concentration is 5mg/L, the total nitrogen concentration is 10mg/L, the total nitrogen removal rate is 90%, and the total nitrogen removal rate reaches 1.5kg/(m & lt/(m & gt) & gt/(m & lt m & gt &3D) (the total nitrogen removal rate is the total nitrogen removal time divided by the residence time);
after the biological membrane on the suspended mobile filler 5 in the anoxic membrane tank 1 is aged, opening the anoxic aeration system 8 to enable the aged biological membrane to fall off, wherein the volume ratio of the air inflow of the anoxic aeration system 8 to the water inflow of the anoxic membrane tank 1 is 20:1, and the duration time is 2 hours;
when the biological membrane on the fixed fiber filler 9 in the aerobic membrane tank 2 is aged, the aeration quantity of the aerobic aeration system 13 is increased to make the aged biological membrane fall off, and the volume ratio of the air inflow to the water inflow in the aerobic membrane tank 2 is 9: 1;
after the treatment process is operated for 360 days, the polyethylene moving film suspended moving filler of the anoxic film tank 1 and the biological film on the fixed fiber filler of the aerobic film tank 2 both have stronger nitrogen conversion activity, and the denitrification capability of the anoxic film tank 1 reaches 5 kg/(m)3D) of the aerobic membrane tank 2The nitration capacity reaches 2 kg/(m)3D); the water production rate of the MBR membrane system was still maintained at 80%.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (10)

1. A full-membrane biological sewage denitrification treatment device is characterized by comprising an anoxic membrane tank (1), an aerobic membrane tank (2), an MBR (membrane bioreactor) system (3) and a reflux system (4);
the anoxic membrane tank (1), the aerobic membrane tank (2) and the MBR membrane system (3) are sequentially connected;
two ends of the reflux system (4) are respectively connected with the anoxic membrane tank (1) and the aerobic membrane tank (2);
the anoxic membrane tank (1) comprises a flow impeller (6), a water inlet pipe (7), an anoxic aeration system (8) and a suspended mobile filler (5); the flow pushing direction of the flow pusher (6) is opposite to the air outlet direction of the anoxic aeration system (8);
the aerobic membrane tank (2) comprises a fixed fiber filler (9) and an aerobic aeration system (13) positioned right below the fixed fiber filler (9).
2. The apparatus for biological denitrification treatment of full membrane sewage according to claim 1, wherein the filling degree of the suspended moving filler (5) in the anoxic membrane tank (1) is 40-60%.
3. The apparatus for biological denitrification treatment of full-film sewage according to claim 2, wherein the suspended mobile filler (5) is a polyethylene mobile film filler, a sponge film or a combination of the polyethylene mobile film filler and the sponge film.
4. The apparatus for biological denitrification treatment of full membrane sewage according to claim 1, wherein the degree of filling of the fixed fiber filler (9) in the aerobic membrane tank (2) is 40% to 60%.
5. The full-membrane sewage biological denitrification treatment device according to any one of claims 1 to 4, wherein the anoxic membrane tank (1) and the aerobic membrane tank (2) are constructed by sharing the wall.
6. The apparatus for biological denitrification treatment of full-membrane sewage according to claim 1, wherein the aerobic aeration system (13) and the anoxic aeration system (8) employ microporous aeration pipelines.
7. The apparatus for biological denitrification treatment of full-membrane sewage according to claim 1, wherein the MBR membrane system (3) is an external membrane.
8. The full-membrane biological sewage denitrification treatment device according to claim 1, wherein the reflux system (4) adopts air lift reflux or reflux pump reflux.
9. A method for biological denitrification treatment of sewage is characterized by comprising the following steps:
the method for biological denitrification treatment of sewage is carried out by using the full-film biological denitrification treatment device for sewage of any one of claims 1 to 8;
closing the anoxic aeration system (8), starting the flow pushing device (6) and the aerobic aeration system (13), sequentially feeding sewage into the anoxic membrane tank (1) from the water inlet pipe (7) for anoxic treatment and the aerobic membrane tank (2) for aerobic treatment, refluxing a part of nitrified liquid obtained after the aerobic treatment to the anoxic membrane tank (1) through the reflux system (4), and treating the rest part through the MBR membrane system (3) to realize sludge-water separation;
after the biological membrane on the suspended mobile filler (5) in the anoxic membrane tank (1) is aged, opening an anoxic aeration system (8) to enable the aged biological membrane to fall off;
and when the biological membrane fixed on the fiber filler (9) in the aerobic membrane tank (2) is aged, the aeration quantity of the aerobic aeration system (13) is instantly increased, so that the aged biological membrane falls off.
10. The method of claim 9, wherein the reflux ratio of the reflux is (2-14): 1.
CN202110117336.6A 2021-01-28 2021-01-28 Full-film biological sewage denitrification treatment device and biological sewage denitrification treatment method Pending CN112777745A (en)

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CN102092841A (en) * 2010-12-09 2011-06-15 扬州大学 Pulse aeration biological contact oxidation water treatment device
CN106315847A (en) * 2016-11-14 2017-01-11 安徽华骐环保科技股份有限公司 Immobilization filler biomembrane activation and updating and sludge resuspension method
CN109485153A (en) * 2018-12-19 2019-03-19 清华-伯克利深圳学院筹备办公室 A kind of biofilm reactor and method of wastewater efficient denitrogenation
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Application publication date: 20210511

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