CN112758956B - Method for producing ammonium fluoride solution and co-producing white carbon black - Google Patents
Method for producing ammonium fluoride solution and co-producing white carbon black Download PDFInfo
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- CN112758956B CN112758956B CN201911158585.9A CN201911158585A CN112758956B CN 112758956 B CN112758956 B CN 112758956B CN 201911158585 A CN201911158585 A CN 201911158585A CN 112758956 B CN112758956 B CN 112758956B
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/16—Halides of ammonium
- C01C1/162—Ammonium fluoride
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
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Abstract
The invention relates to a method for producing ammonium fluoride solution and co-producing white carbon black, belonging to the technical field of chemical product preparation. The method for producing the ammonium fluoride solution and co-producing the white carbon black comprises the following steps: 1) Adding ammonia water into the mixed liquid in a flowing state in the tubular reactor for a first ammoniation reaction; the pH value of the mixed solution is 6-7 after the first ammoniation reaction reaches the end point; the mixed solution before adding the ammonia water is a mixture of the ammonia water and fluosilicic acid solution, and the pH value is 1-2; 2) Adding ammonia water into the mixed solution with the pH value of 6-7 for secondary ammoniation reaction; the pH value of the mixed solution is 8-9 after the second ammoniation reaction reaches the end point; 3) And (3) carrying out solid-liquid separation on the mixed solution with the pH value of 8-9 to obtain an ammonium fluoride solution and white carbon black respectively. The method adopts the tubular reactor to carry out continuous production, reduces the process flow, improves the automation degree and the reaction efficiency, can stably and continuously produce, and improves the production efficiency.
Description
Technical Field
The invention relates to a method for producing ammonium fluoride solution and co-producing white carbon black, belonging to the technical field of chemical product preparation.
Background
Fluosilicic acid is used as a byproduct in the production process of phosphorus chemical industry, is mainly used for producing sodium fluosilicate at present, has poor economic benefit, and has insufficient utilization of fluorine and silicon resources. Ammonium fluoride and white carbon black with higher economic value can be prepared by ammonifying fluosilicic acid, and the ammonification process mainly involves the following chemical reactions:
H 2 SiF 6 +2NH 4 OH→(NH 4 ) 2 SiF 6 +2H 2 O；
(NH 4 ) 2 SiF 6 +4NH 4 OH+nH 2 O→6NH 4 F+SiO 2 ·nH 2 O+2H 2 O。
and (3) carrying out solid-liquid separation on fluosilicic acid ammoniation products to obtain an ammonium fluoride solution and white carbon black solids respectively. At present, most of ammonium fluoride and white carbon black are produced discontinuously by ammonification of fluosilicic acid, for example, chinese patent application publication No. CN10577567C discloses a method for producing ammonium fluoride and co-producing white carbon black, which takes fluosilicic acid or ammonium fluosilicate and ammonia water as raw materials, and prepares white carbon black seed crystal by rapidly reacting the ammonia water with fluosilicic acid or ammonium fluosilicate, wherein the time is within 20 seconds, and the pH of the reaction end point is between 6.5 and 7.5; adding water, fluosilicic acid or ammonium fluosilicate and ammonia water to react based on the prepared white carbon black and seed crystal, controlling the pH of the reaction end point between 8 and 9, preparing slurry of white carbon black sediment and ammonium fluoride solution, wherein the adding amount of the seed crystal is 20-40% of the total weight of the white carbon black generated by the reaction, filtering and washing the white carbon black slurry, obtaining white carbon black ointment and ammonium fluoride solution, concentrating, crystallizing and drying the ammonium fluoride solution, and preparing the ammonium fluoride product. The method can effectively utilize byproducts in the phosphate fertilizer production process, changes waste into valuable, but has small production scale, low automation degree and low production efficiency.
Disclosure of Invention
The invention aims to provide a method for producing ammonium fluoride solution and co-producing white carbon black, which can improve the production efficiency of producing ammonium fluoride solution and co-producing white carbon black.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
a method for producing ammonium fluoride solution and co-producing white carbon black comprises the following steps:
1) Adding ammonia water into the mixed liquid in a flowing state in the tubular reactor for a first ammoniation reaction; the pH value of the mixed solution is 6-7 after the first ammoniation reaction reaches the end point; the mixed solution before adding the ammonia water is a mixture of the ammonia water and fluosilicic acid solution, and the pH value is 1-2;
2) Adding ammonia water into the mixed solution with the pH value of 6-7 for secondary ammoniation reaction; the pH value of the mixed solution is 8-9 after the second ammoniation reaction reaches the end point;
3) And (3) carrying out solid-liquid separation on the mixed solution with the pH value of 8-9 to obtain an ammonium fluoride solution and white carbon black respectively.
The method for producing the ammonium fluoride solution and co-producing the white carbon black can avoid the occurrence of the next reaction in advance caused by overlarge local ammonia water concentration, ensure the concentration of local seed crystals, avoid the increase of the number of large particles in the finally produced white carbon black, improve the quality of white carbon black products and ensure that the specific surface area of the prepared white carbon black is 237m 2 The oil absorption value is 2.86cm and is higher than/g 3 The purity of the product is higher than 93 percent per gram. In the method of the invention, the mixed solution of ammonia water and silicon fluoride solution with pH of 1-2 is in a clear and transparent state, when the mixed solution with pH of 1-2 is added with ammonia water to react to the end point of reaction with pH of 6-7 in a flowing state, the mixed solution is in a jelly shape, and then the mixed solution with pH of 6-7 in the jelly shape is continuously added with ammonia water to react to the end point of pH of 8-9 in the flowing state, the mixed solution is in a slurry shape. According to the method for producing the ammonium fluoride solution and co-producing the white carbon black, the first ammonification reaction and the second ammonification reaction are carried out in the tubular reactor under the material flowing state, so that continuous production can be realized, the process flow is reduced, the degree of automation is improved, the reaction efficiency is accelerated, stable and continuous production is realized, and the control precision degree and the production efficiency are improved.
In the step 2), ammonia water is added into the mixed solution with the pH value of 6-7 to carry out the second ammoniation reaction, and the mixed solution with the pH value of 6-7 is also in a tubular reactor and is in a flowing state.
A tubular reactor is a continuous production reactor in the form of a tube. Further, the tubular reactor is a plug flow reactor. Ideally, the flow of material in a plug flow reactor has the following characteristics: (1) there is no flow velocity distribution in a cross section perpendicular to the flow direction; (2) there is no back mixing in the direction of the material flow. The invention adopts a plug flow reactor to control the material to reach the reaction end point of pH 6-7 in the flowing direction and generate seed crystals in each reaction micro-element of pH 6-7, then ammonia water is added into the mixed solution of pH 6-7 to continue the reaction to make each reaction micro-element reach the reaction end point of pH 8-9, so as to generate white carbon black.
Preferably, the tubular reactor is provided with a first ammonia water inlet and a second ammonia water inlet; the first ammonia water adding port is used for adding ammonia water into the mixed solution for a first ammoniation reaction; the first ammonia water adding port is used for adding ammonia water into the mixed solution with the pH value of 6-7 for carrying out a second ammoniation reaction. Ammonia water required by the first ammoniation reaction is added through a first ammonia water adding port; ammonia water required by the second ammoniation reaction is added through a second ammonia water inlet. The number of the first ammonia water adding ports is one or more. The number of the second ammonia water adding ports is one or more.
Preferably, in step 1), the method for obtaining the mixed solution with the pH value of 1-2 comprises the following steps: ammonia water and fluosilicic acid solution are mixed and then are introduced into a tubular reactor, and the mixture is reacted in a flowing state until the pH of the mixture reaches a final pH of 1-2 to obtain the aqueous solution; or introducing fluosilicic acid solution into a tubular reactor, and adding ammonia water in a flowing state to react until the final pH value is 1-2. Preferably, in the step 1), the reaction temperature is controlled to be less than or equal to 50 ℃ in the process of obtaining the mixed solution with the pH value of 1-2. When the aqueous ammonia is mixed with the fluorosilicic acid solution to prepare a mixed solution having a pH of 1 to 2, the concentration of the aqueous ammonia to be used is preferably 9 to 10mol/L.
When high-concentration fluosilicic acid is used for reaction with ammonia water, the quality of the obtained white carbon black is poor, and particularly, the problem of low specific surface area exists. In order to increase the specific surface area of the obtained white carbon black while improving the production efficiency, the concentration of the fluorosilicic acid solution is preferably 15 to 22%.
In order to improve the purity of the obtained white carbon black, preferably, the method for producing the ammonium fluoride solution and co-producing the white carbon black further comprises the following steps: washing the obtained white carbon black; the number of washing treatments is at least one. Further, the method for producing the ammonium fluoride solution and co-producing the white carbon black further comprises the step of drying the white carbon black after the washing treatment. The drying treatment is preferably spray drying.
Because the tubular reactor is a continuous reactor, when the white carbon black obtained by solid-liquid separation is washed, the prepared white carbon black can be washed in batches. Washing for m times if each batch of white carbon black ointment; except the m times of washing treatment of the first batch of white carbon black ointment and the m times of washing treatment of the rest white carbon black ointment of each batch, the n times of washing treatment of the white carbon black ointment of each batch is washed by using washing water generated by the n+1th times of washing treatment of the white carbon black ointment of the previous batch; wherein m is more than or equal to 2, n is more than or equal to 1 and less than or equal to m-1, and m and n are natural numbers. If m can be a natural number such as 2, 3, 4 or 5.
Preferably, the fluosilicic acid solution is obtained by diluting a high-concentration fluosilicic acid solution with a diluent. The diluent is primary washing water generated by primary washing treatment of the white carbon black. The concentration of the high-concentration fluosilicic acid solution is 35-45%. The concentration fluosilicic acid is diluted by utilizing primary washing water generated by washing white carbon black, so that the discharge amount of wastewater in the production process is reduced, the concentration of fluorine in the fluosilicic acid solution is improved, the concentration of the obtained ammonium fluoride solution is further improved, the high-concentration fluosilicic acid can be directly utilized, the production efficiency is further improved, and the production cost is reduced.
The concentration of the aqueous ammonia used in the first ammonification reaction and the second ammonification reaction is not particularly limited, and in order to obtain an ammonium fluoride solution having a higher concentration, aqueous ammonia having a higher concentration is preferably used. Preferably, the concentration of ammonia water adopted in the first ammonification reaction and the second ammonification reaction is independently selected to be 9-10 mol/L. Further, the concentration of ammonia water adopted in each step of the method for producing the ammonium fluoride solution and co-producing the white carbon black is the same.
Preferably, the solid-liquid separation is filtration, and the pore size of the filter material used for the filtration is 30-50 μm. The adoption of the filter material with the aperture of 30-50 mu m can realize rapid filtration and prevent filtration leakage.
The reaction temperature of the first ammonification reaction in step 1) affects the crystal growth rate and crystal grain size during the production process. In order to obtain white carbon black with larger specific surface area, preferably, in the step 1), the temperature is controlled to be less than or equal to 50 ℃ in the first ammoniation reaction process.
In order to make the reaction more complete, it is preferable to control the temperature during the second ammoniation reaction in step 2) to be less than or equal to 45 ℃. In step 3), a filter press is used for solid-liquid separation of the mixed liquid having a pH of 8 to 9.
Drawings
Fig. 1 is a process flow diagram of a method for producing an ammonium fluoride solution and co-producing white carbon black in example 1.
Detailed Description
The technical scheme of the invention is further described below in connection with the specific embodiments.
Example 1
The method for producing the ammonium fluoride solution and co-producing the white carbon black in the embodiment is shown in fig. 1, and the process flow chart comprises the following steps:
1) Diluting the high-concentration fluosilicic acid solution with the mass concentration of 42.19% by adopting a diluent to obtain a low-concentration fluosilicic acid solution with the mass concentration of 20.63%;
2) Introducing a low-concentration fluosilicic acid solution and ammonia water into a plug flow reactor, controlling the introducing amount of the low-concentration fluosilicic acid solution to be 0.4kg/min and the introducing amount of the ammonia water to be 0.1L/min, allowing a material to react while flowing in the plug flow reactor, controlling the reaction temperature to be 45 ℃, allowing the material to flow to a certain position A of the plug flow reactor to react to reach an end point, allowing the material to be clear and transparent, allowing the pH value to be 2, introducing the ammonia water from the position A to be 0.1L/min, continuing to react in the plug flow reactor, controlling the reaction temperature to be 48 ℃, allowing the material to flow to a certain position B of the plug flow reactor to react to reach the end point, allowing the material to be jelly-shaped, allowing the pH value to be 6, introducing the ammonia water from the position B to be 0.3L/min, continuing to react in the plug flow to the position A of the plug flow to reach the end point, and obtaining slurry with the pH value of 9.0;
3) Filtering the obtained slurry by a filter press to obtain an ammonium fluoride solution and a white carbon black ointment respectively, washing the white carbon black ointment in batches, and drying to obtain white carbon black powder; the aperture of the filter cloth in the filter press is 38 mu m;
washing and treating each batch of white carbon black ointment for three times; except for the third washing treatment of the first batch of white carbon black ointment and the third washing treatment of the rest white carbon black ointment, the first washing treatment of the white carbon black ointment of each batch adopts the washing water generated by the second washing treatment of the white carbon black ointment of the previous batch to wash, the second washing treatment adopts the washing water generated by the third washing treatment of the white carbon black ointment of the previous batch to wash, and the washing water generated by the first washing treatment of the white carbon black ointment of each batch is collected and recycled as a diluent to the step 1).
In the initial production of the washing water without the first washing of the white carbon black ointment, clear water is used as the diluent in the step 1).
The concentration of ammonia water used in this example was 9.37mol/L, and the volume of ammonia water introduced at position A, and the volume of ammonia water introduced at position B were 9.8L, 8.5L, and 29.3L, respectively, for each 40kg of the low-concentration fluorosilicic acid solution obtained in step 1) was treated.
The concentration of ammonium fluoride in the ammonium fluoride solution obtained in the embodiment reaches 20.5%; the obtained white carbon black powder has the main content of 94 percent and the specific surface area of 237m 2 Per g, oil absorption value 2.86cm 3 And/g, meets HG/T3061-2009 requirements.
In another embodiment of the present invention, the ammonia added from point A in embodiment 1 is added from a point A downstream of a point A 1 Point addition, the aqueous ammonia added from point B in example 1 was added downstream from point BIs 1 of (B) 1 The point addition, not described, is identical to that of example 1, and the concentration of the ammonium fluoride solution obtained, the purity, the specific surface area and the oil absorption value of the white carbon black powder are substantially the same as those of example 1.
In other embodiments of the present invention, when the white carbon black paste in step 3) of embodiment 1 is washed in batches, each batch is washed three times, and each washing uses clear water.
Example 2
The method for producing the ammonium fluoride solution and co-producing the white carbon black comprises the following steps of:
1) Diluting the high-concentration fluosilicic acid solution with the mass concentration of 44.25% by adopting a diluent to obtain a low-concentration fluosilicic acid solution with the mass concentration of 17.47%;
2) Introducing a low-concentration fluosilicic acid solution and ammonia water into a plug flow reactor, controlling the introducing amount of the low-concentration fluosilicic acid solution to be 0.6kg/min and the introducing amount of the ammonia water to be 0.1L/min, allowing a material to react while flowing in the plug flow reactor, controlling the reaction temperature to be 46 ℃, allowing the material to flow to a certain position A of the plug flow reactor for reaction to reach an end point, allowing the material to be clear and transparent, allowing the pH value to be 2, introducing the ammonia water from the position A to be 0.1L/min for continuous reaction in the plug flow reactor, controlling the reaction temperature to be 47 ℃, allowing the material to flow to a certain position B of the plug flow reactor for reaction to reach the end point, allowing the material to be jelly-shaped, allowing the pH value to be 6, introducing the ammonia water from the position B to be 0.3L/min for continuous reaction in the plug flow reactor, controlling the reaction temperature to be 44 ℃, allowing the material to flow to a certain position C of the plug flow to reach the end point, and obtaining slurry with the pH value of 8.5;
3) Filtering the obtained slurry by a filter press to obtain an ammonium fluoride solution and a white carbon black ointment respectively, washing the white carbon black ointment in batches, and drying to obtain white carbon black powder; the aperture of the filter cloth in the filter press is 48 mu m;
washing and treating each batch of white carbon black ointment for three times; except for the third washing treatment of the first batch of white carbon black ointment and the third washing treatment of the rest white carbon black ointment, the first washing treatment of the white carbon black ointment of each batch adopts the washing water generated by the second washing treatment of the white carbon black ointment of the previous batch to wash, the second washing treatment adopts the washing water generated by the third washing treatment of the white carbon black ointment of the previous batch to wash, and the washing water generated by the first washing treatment of the white carbon black ointment of each batch is collected and recycled as a diluent to the step 1).
In the initial production of the washing water without the first washing of the white carbon black ointment, clear water is used as the diluent in the step 1).
The concentration of the ammonia water used in this example was 9.82mol/L, and the volume of the ammonia water introduced at the position A, the volume of the ammonia water introduced at the position B, and the volume of the ammonia water introduced at the position B were 5.9L, 5.2L, and 15.6L, respectively, when 30kg of the low-concentration fluorosilicic acid solution obtained in step 1) was treated.
The concentration of ammonium fluoride in the ammonium fluoride solution obtained in the embodiment reaches 18.5%; the obtained white carbon black powder has 93 percent of white carbon black content and 284m of specific surface area 2 Per g, oil absorption value 3.05cm 3 And/g, meets the requirements of HG/T3061-2009.
In other embodiments of the present invention, a certain amount of 9.82mol/L ammonia water may be added to the fluorosilicic acid solution obtained in step 1) of embodiment 2 to make the pH of the system be 2 after reaching the end point of the reaction, then the system with the pH of 2 is introduced into the plug flow reactor, then the ammonia water with the concentration of 9.82mol/L is introduced into the plug flow reactor from a certain position a of the plug flow reactor in an amount of 0.1L/min for reaction, the reaction temperature is controlled to be 47 ℃, the material flows to a certain position B of the plug flow reactor for reaction to reach the end point, at this time, the material is in a jelly shape, the pH value is 6, then the ammonia water with the concentration of 9.82mol/L is introduced into the plug flow reactor from the position B in an amount of 0.3L/min for continuous reaction, the reaction temperature is controlled to be 44 ℃, and the material flows to a certain position C of the plug flow reactor for reaction to reach the end point, at this time, the slurry with the pH of 8.5 is obtained. The slurry obtained was then further processed according to step 3) of example 2, finally to an ammonium fluoride solution and white carbon black powder. The concentration of the ammonium fluoride solution, the purity, specific surface area and oil absorption of the white carbon black powder were substantially the same as in example 2.
Claims (5)
1. A method for producing ammonium fluoride solution and co-producing white carbon black is characterized by comprising the following steps: the method comprises the following steps:
1) Adding ammonia water into the mixed liquid in a flowing state in the tubular reactor for a first ammoniation reaction; the pH value of the mixed solution is 6-7 after the first ammoniation reaction reaches the end point; the mixed solution before adding the ammonia water is a mixture of the ammonia water and fluosilicic acid solution, and the pH value is 1-2; the concentration of the fluosilicic acid solution is 15-22%;
2) Adding ammonia water into the mixed solution with the pH value of 6-7 for secondary ammoniation reaction; the pH value of the mixed solution is 8-9 after the secondary ammoniation reaction reaches the end point;
3) Carrying out solid-liquid separation on the mixed solution with the pH value of 8-9 to respectively obtain an ammonium fluoride solution and white carbon black;
the tubular reactor is provided with a first ammonia water inlet and a second ammonia water inlet; the first ammonia water adding port is used for adding ammonia water into the mixed solution for a first ammoniation reaction; the second ammonia water adding port is used for adding ammonia water into the mixed solution with the pH value of 6-7 for a second ammoniation reaction;
the concentration of ammonia water adopted in the first ammonification reaction and the second ammonification reaction is independently selected to be 9-10 mol/L; in the step 1), the temperature is controlled to be less than or equal to 50 ℃ in the first ammoniation reaction process; in the step 2), the temperature is controlled to be less than or equal to 45 ℃ in the second ammoniation reaction process.
2. The method for producing the ammonium fluoride solution and co-producing the white carbon black according to claim 1, which is characterized in that: the tubular reactor is a plug flow reactor.
3. The method for producing the ammonium fluoride solution and co-producing the white carbon black according to claim 1, which is characterized in that: in the step 1), the method for obtaining the mixed solution with the pH value of 1-2 comprises the following steps:
mixing ammonia water and fluosilicic acid solution, and then introducing the mixture into a tubular reactor, and reacting the mixture in a flowing state until the pH value of the end point is 1-2 to obtain the aqueous solution;
or introducing the fluosilicic acid solution into a tubular reactor, and adding ammonia water in a flowing state to react until the final pH value is 1-2.
4. The method for producing the ammonium fluoride solution and co-producing the white carbon black according to claim 1, which is characterized in that: the method also comprises the following steps: washing the obtained white carbon black; the number of washing treatments is at least one.
5. The method for producing the ammonium fluoride solution and co-producing the white carbon black according to claim 4, which is characterized in that: the fluosilicic acid solution is obtained by diluting a high-concentration fluosilicic acid solution with a diluent; the diluent is primary washing water generated by primary washing treatment of the white carbon black; the concentration of the high-concentration fluosilicic acid solution is 35-45%.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1182636A (en) * | 1996-11-18 | 1998-05-27 | 卡尔藤巴赫－蒂林有限公司 | Reactor, process and plant for manufacturing ammonium salts |
| CN101028930A (en) * | 2006-03-01 | 2007-09-05 | 多氟多化工股份有限公司 | Method for linked producing ammonium fluoride and white carbon black |
| CN101139094A (en) * | 2007-08-24 | 2008-03-12 | 云南云天化国际化工股份有限公司 | Method for preparing big-compensating forcing white carbon black and high concentration ammonium fluoride through aminating of fluosilicic acid |
| US20150004089A1 (en) * | 2013-06-28 | 2015-01-01 | Air Products And Chemicals, Inc. | Process for making trisilylamine |
-
2019
- 2019-11-22 CN CN201911158585.9A patent/CN112758956B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1182636A (en) * | 1996-11-18 | 1998-05-27 | 卡尔藤巴赫－蒂林有限公司 | Reactor, process and plant for manufacturing ammonium salts |
| CN101028930A (en) * | 2006-03-01 | 2007-09-05 | 多氟多化工股份有限公司 | Method for linked producing ammonium fluoride and white carbon black |
| CN101139094A (en) * | 2007-08-24 | 2008-03-12 | 云南云天化国际化工股份有限公司 | Method for preparing big-compensating forcing white carbon black and high concentration ammonium fluoride through aminating of fluosilicic acid |
| US20150004089A1 (en) * | 2013-06-28 | 2015-01-01 | Air Products And Chemicals, Inc. | Process for making trisilylamine |
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Address after: 454191 Henan Province, Jiaozuo City Station area coke Rd Applicant after: Duofudo New Material Co.,Ltd. Address before: 454191, Feng County, Henan Province, Jiaozuo Feng Feng Chemical Industry Zone Applicant before: DO-FLUORIDE CHEMICALS Co.,Ltd. |
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