CN112746202A - Aluminum alloy sheet for automobile body and production method thereof - Google Patents

Aluminum alloy sheet for automobile body and production method thereof Download PDF

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Publication number
CN112746202A
CN112746202A CN202011602402.0A CN202011602402A CN112746202A CN 112746202 A CN112746202 A CN 112746202A CN 202011602402 A CN202011602402 A CN 202011602402A CN 112746202 A CN112746202 A CN 112746202A
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CN
China
Prior art keywords
aluminum alloy
room temperature
sheet
alloy sheet
rolled plate
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Pending
Application number
CN202011602402.0A
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Chinese (zh)
Inventor
李少飞
张超
崔清磊
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Henan Zhongduo Aluminum Magnesium New Material Co ltd
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Henan Zhongduo Aluminum Magnesium New Material Co ltd
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Application filed by Henan Zhongduo Aluminum Magnesium New Material Co ltd filed Critical Henan Zhongduo Aluminum Magnesium New Material Co ltd
Priority to CN202011602402.0A priority Critical patent/CN112746202A/en
Publication of CN112746202A publication Critical patent/CN112746202A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent

Abstract

The aluminum alloy sheet for the automobile body comprises the following chemical components in percentage by weight: 1.4-1.5% of Si, 0.1-0.4% of Fe, 0-0.2% of Cu, 0.03-0.17% of Mn, 0.63-0.68% of Mg, 0.1-0.15% of Cr, 0.01-0.02% of Ti, 0-0.10% of Zn and the balance of Al; a production method of an aluminum alloy sheet for an automobile body comprises the following steps: the method comprises the steps of ingot preparation, hot rolling, intermediate annealing, cold rolling, solution treatment, room temperature placement, pre-aging treatment and room temperature placement. The aluminum alloy sheet for the automobile body is produced by the technical scheme of the invention, a homogenization treatment process is omitted on the basis of the traditional processing method, hot rolling is directly carried out, so that the deep drawing performance and the baking hardenability of the alloy sheet are improved, the production flow is obviously shortened, the energy is saved, the production cost is greatly reduced, and the stamping formability and the baking hardenability of the alloy sheet are improved.

Description

Aluminum alloy sheet for automobile body and production method thereof
Technical Field
The invention relates to the technical field of aluminum plates for automobiles, in particular to an aluminum alloy sheet for an automobile body and a production method thereof.
Background
Energy conservation, emission reduction and light weight of automobiles have become a global trend. Through research and development of lightweight materials for automobiles for decades, 6016(Al — Mg — Si series) alloy is gradually considered as an optimal aluminum alloy material for automobile body panels. It not only has comprehensive mechanical property and forming property, but also can strengthen the aluminum alloy by heat treatment, and has better Baking Hardening (BH) property than other aluminum alloys. As an automobile outer panel, it is necessary to have dent resistance, formability, aging stability, surface finish and bake hardenability of the alloy material.
The production method of the 6016 aluminum alloy sheet for the CN104561681A automobile body and the production method thereof are described in the patent, and the production method comprises the process steps of smelting, casting, face milling, hot rolling, cold rolling and heat treatment, so that the HB front elongation and HB rear yield strength of the aluminum alloy sheet are improved, the yield in stamping is improved, the automobile wide-family cost is reduced, and the formability and the baking fracture property of the aluminum alloy sheet are improved. However, such panels can only be used as automobile inner panels or low-cost automobile outer panels.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide an aluminum alloy sheet for an automobile body and a production method thereof.
The invention is realized by the following technical scheme:
the aluminum alloy sheet for the automobile body comprises the following chemical components in percentage by weight: 1.4-1.5% of Si, 0.1-0.4% of Fe, 0-0.2% of Cu, 0.03-0.17% of Mn, 0.63-0.68% of Mg, 0.1-0.15% of Cr, 0.01-0.02% of Ti, 0-0.10% of Zn and the balance of Al.
A production method of an aluminum alloy sheet for an automobile body comprises the following steps:
A. preparing an ingot: preparing an aluminum alloy ingot;
B. hot rolling: heating an aluminum alloy ingot to 510-530 ℃, preserving heat for 4-7 h, and then carrying out hot rolling to obtain a hot rolled plate with the thickness of 4-6 mm;
C. intermediate annealing: keeping the temperature of the hot rolled plate at 540-550 ℃ for 4-7 h, and then cooling the hot rolled plate to room temperature to obtain a furnace-cooled rolled plate;
D. cold rolling: cold rolling the annealed rolled sheet to obtain a cold-rolled sheet with the thickness of 0.9-1.2 mm;
E. solution treatment: carrying out solution treatment on the cold-rolled sheet to form a rolled sheet after the solution treatment; the temperature of the solution treatment is 550-570 ℃, the time is 8-10 min, and the cooling mode is water quenching to room temperature;
F. standing at room temperature: standing the rolled plate after the solution treatment at room temperature for 30-50 min;
G. pre-aging treatment: placing the rolled plate at room temperature, and performing pre-aging treatment to form a pre-aged rolled plate; the pre-aging treatment temperature is 150-170 ℃, the time is 10-15 min, and the cooling mode is air cooling to room temperature;
H. standing at room temperature: and (4) placing the pre-aged rolled plate at room temperature for more than 4 weeks to obtain the aluminum alloy sheet for the automobile body.
In order to further implement the present invention, the following technical solutions may be preferably selected:
preferably, the aluminum alloy ingot in the step A is prepared by semi-continuous casting.
Preferably, the aluminum alloy cast ingot is subjected to head cutting and face milling treatment before heating, the hot rolling mode is combination of transverse rolling and longitudinal rolling, and the hot rolling process comprises rolling for 6-8 times along the width direction of the cast ingot and then rolling for 10-15 times along the length direction of the flat ingot to obtain a hot rolled plate.
Preferably, the thickness of the aluminum alloy cast ingot is 190mm, the thickness of the hot rolled plate is 4-6 mm, and the thickness of the cold rolled plate is 0.9-1.2 mm.
Through the technical scheme, the invention has the beneficial effects that:
the invention saves the homogenization treatment process on the basis of the traditional processing method and directly carries out hot rolling; in order to promote the dissolution of soluble alloy phase, the spheroidization of the particles of the excessive fragmentation crystal phase and the smoothness of the boundary, so as to improve the deep drawing performance and the bake hardenability of the alloy plate, a process method of further increasing the intermediate annealing temperature and properly prolonging the intermediate annealing heat preservation time on the basis of the conventional intermediate annealing treatment (420-440 ℃ for 1-2 hours) is adopted; the method can obviously shorten the production flow of the aluminum alloy automobile body plate, save energy, greatly reduce the production cost and simultaneously improve the stamping formability and the baking hardenability of the alloy plate.
Compared with the prior art, the invention has the advantages that: the plate is prepared by adopting non-homogenization treatment, so that the energy is saved, the efficiency is improved, and the production cost is reduced; the method can be implemented on the existing aluminum alloy production line, the existing tool is not required to be changed, the equipment and process investment is not required to be increased, and the operation is simple, convenient and feasible; the intermediate annealing temperature is increased, the annealing heat preservation time is properly prolonged, the soluble crystal phase is dissolved, and the particle boundary of the excessive crystal phase is smooth and spheroidized, so that the stamping formability and the baking finish hardenability of the aluminum alloy sheet are finally improved at the same time. The method realizes that the deep drawing performance and the baking hardening performance of the plate are improved while the cost of the aluminum alloy automobile body plate is reduced, thereby bringing considerable social and economic benefits.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the aluminum alloy sheet for the automobile body comprises the following chemical components in percentage by weight: 1.4-1.5% of Si, 0.1-0.4% of Fe, 0-0.2% of Cu, 0.03-0.17% of Mn, 0.63-0.68% of Mg, 0.1-0.15% of Cr, 0.01-0.02% of Ti, 0-0.10% of Zn and the balance of Al.
2. A method for producing an aluminum alloy sheet for automobile bodies as recited in claim 1, comprising the steps of:
A. preparing an ingot: preparing an aluminum alloy ingot;
B. hot rolling: heating an aluminum alloy ingot to 510-530 ℃, preserving heat for 4-7 h, and then carrying out hot rolling to obtain a hot rolled plate with the thickness of 4-6 mm;
C. intermediate annealing: keeping the temperature of the hot rolled plate at 540-550 ℃ for 4-7 h, and then cooling the hot rolled plate to room temperature to obtain a furnace-cooled rolled plate;
D. cold rolling: cold rolling the annealed rolled sheet to obtain a cold-rolled sheet with the thickness of 0.9-1.2 mm;
E. solution treatment: carrying out solution treatment on the cold-rolled sheet to form a rolled sheet after the solution treatment; the temperature of the solution treatment is 550-570 ℃, the time is 8-10 min, and the cooling mode is water quenching to room temperature;
F. standing at room temperature: standing the rolled plate after the solution treatment at room temperature for 30-50 min;
G. pre-aging treatment: placing the rolled plate at room temperature, and performing pre-aging treatment to form a pre-aged rolled plate; the pre-aging treatment temperature is 150-170 ℃, the time is 10-15 min, and the cooling mode is air cooling to room temperature;
H. standing at room temperature: and (4) placing the pre-aged rolled plate at room temperature for more than 4 weeks to obtain the aluminum alloy sheet for the automobile body.
And C, preparing the aluminum alloy ingot in the step A by adopting semi-continuous casting.
Before heating, the aluminum alloy cast ingot is subjected to head cutting and face milling treatment, the hot rolling mode is combination of transverse rolling and longitudinal rolling, and the hot rolling process is firstly carried out for 6-8 times along the width direction of the cast ingot and then is carried out for 10-15 times along the length direction of the flat ingot, so that a hot rolled plate is obtained.
The thickness of the aluminum alloy cast ingot is 190mm, the thickness of the hot rolled plate is 4-6 mm, and the thickness of the cold rolled plate is 0.9-1.2 mm.
The invention saves the homogenization treatment process on the basis of the traditional processing method and directly carries out hot rolling; in order to promote the dissolution of soluble alloy phase, the spheroidization of the particles of the excessive fragmentation crystal phase and the smoothness of the boundary, so as to improve the deep drawing performance and the bake hardenability of the alloy plate, a process method of further increasing the intermediate annealing temperature and properly prolonging the intermediate annealing heat preservation time on the basis of the conventional intermediate annealing treatment (420-440 ℃ for 1-2 hours) is adopted; the method can obviously shorten the production flow of the aluminum alloy automobile body plate, save energy, greatly reduce the production cost and simultaneously improve the stamping formability and the baking hardenability of the alloy plate.
Compared with the prior art, the invention has the advantages that: the plate is prepared by adopting non-homogenization treatment, so that the energy is saved, the efficiency is improved, and the production cost is reduced; the method can be implemented on the existing aluminum alloy production line, the existing tool is not required to be changed, the equipment and process investment is not required to be increased, and the operation is simple, convenient and feasible; the intermediate annealing temperature is increased, the annealing heat preservation time is properly prolonged, the soluble crystal phase is dissolved, and the particle boundary of the excessive crystal phase is smooth and spheroidized, so that the stamping formability and the baking finish hardenability of the aluminum alloy sheet are finally improved at the same time. The method realizes that the deep drawing performance and the baking hardening performance of the plate are improved while the cost of the aluminum alloy automobile body plate is reduced, thereby bringing considerable social and economic benefits.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.

Claims (5)

1. The aluminum alloy sheet for the automobile body is characterized by comprising the following chemical components in percentage by weight: 1.4-1.5% of Si, 0.1-0.4% of Fe, 0-0.2% of Cu, 0.03-0.17% of Mn, 0.63-0.68% of Mg, 0.1-0.15% of Cr, 0.01-0.02% of Ti, 0-0.10% of Zn and the balance of Al.
2. A method for producing an aluminum alloy sheet for automobile bodies as recited in claim 1, comprising the steps of:
A. preparing an ingot: preparing an aluminum alloy ingot;
B. hot rolling: heating an aluminum alloy ingot to 510-530 ℃, preserving heat for 4-7 h, and then carrying out hot rolling to obtain a hot rolled plate with the thickness of 4-6 mm;
C. intermediate annealing: keeping the temperature of the hot rolled plate at 540-550 ℃ for 4-7 h, and then cooling the hot rolled plate to room temperature to obtain a furnace-cooled rolled plate;
D. cold rolling: cold rolling the annealed rolled sheet to obtain a cold-rolled sheet with the thickness of 0.9-1.2 mm;
E. solution treatment: carrying out solution treatment on the cold-rolled sheet to form a rolled sheet after the solution treatment; the temperature of the solution treatment is 550-570 ℃, the time is 8-10 min, and the cooling mode is water quenching to room temperature;
F. standing at room temperature: standing the rolled plate after the solution treatment at room temperature for 30-50 min;
G. pre-aging treatment: placing the rolled plate at room temperature, and performing pre-aging treatment to form a pre-aged rolled plate; the pre-aging treatment temperature is 150-170 ℃, the time is 10-15 min, and the cooling mode is air cooling to room temperature;
H. standing at room temperature: and (4) placing the pre-aged rolled plate at room temperature for more than 4 weeks to obtain the aluminum alloy sheet for the automobile body.
3. The method for producing aluminum alloy sheet for automobile bodies as recited in claim 2, wherein the aluminum alloy ingot in the step a is produced by semi-continuous casting.
4. The method for producing the aluminum alloy sheet for the automobile body as claimed in claim 2, wherein the aluminum alloy ingot is subjected to head and face cutting before heating, the hot rolling is performed by combining transverse rolling and longitudinal rolling, and the hot rolling is performed for 6-8 times along the width direction of the ingot and then for 10-15 times along the length direction of the slab to obtain a hot rolled plate.
5. The method for producing an aluminum alloy sheet for automobile bodies as recited in claim 2, wherein the aluminum alloy ingot has a thickness of 190mm, the hot-rolled sheet has a thickness of 4 to 6mm, and the cold-rolled sheet has a thickness of 0.9 to 1.2 mm.
CN202011602402.0A 2020-12-29 2020-12-29 Aluminum alloy sheet for automobile body and production method thereof Pending CN112746202A (en)

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CN202011602402.0A CN112746202A (en) 2020-12-29 2020-12-29 Aluminum alloy sheet for automobile body and production method thereof

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113857871A (en) * 2021-09-24 2021-12-31 广西柳州银海铝业股份有限公司 Production method for eliminating ingot casting cracks of 4XXX aluminum alloy wide hot rolled plate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880805A (en) * 2010-07-30 2010-11-10 浙江巨科铝业有限公司 Al-Mg-Si aluminum alloy for automobile body panel and method for producing same
CN106756285A (en) * 2016-11-16 2017-05-31 东北大学 A kind of preparation method of 6022 aluminum alloy plate materials
CN108359920A (en) * 2018-01-25 2018-08-03 北京科技大学 A kind of short route prepares the deformation heat treatment method of the anti-corrosion Al-Mg-Zn aluminium alloys of high-strength height
CN108385043A (en) * 2018-03-06 2018-08-10 东北大学 A kind of preparation method of 6016 aluminum alloy plate materials of body of a motor car

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880805A (en) * 2010-07-30 2010-11-10 浙江巨科铝业有限公司 Al-Mg-Si aluminum alloy for automobile body panel and method for producing same
CN106756285A (en) * 2016-11-16 2017-05-31 东北大学 A kind of preparation method of 6022 aluminum alloy plate materials
CN108359920A (en) * 2018-01-25 2018-08-03 北京科技大学 A kind of short route prepares the deformation heat treatment method of the anti-corrosion Al-Mg-Zn aluminium alloys of high-strength height
CN108385043A (en) * 2018-03-06 2018-08-10 东北大学 A kind of preparation method of 6016 aluminum alloy plate materials of body of a motor car

Non-Patent Citations (1)

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Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113857871A (en) * 2021-09-24 2021-12-31 广西柳州银海铝业股份有限公司 Production method for eliminating ingot casting cracks of 4XXX aluminum alloy wide hot rolled plate

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