CN112724816A - Anti-corrosion rail hanging robot coating in heavy salt environment - Google Patents

Anti-corrosion rail hanging robot coating in heavy salt environment Download PDF

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Publication number
CN112724816A
CN112724816A CN202011584548.7A CN202011584548A CN112724816A CN 112724816 A CN112724816 A CN 112724816A CN 202011584548 A CN202011584548 A CN 202011584548A CN 112724816 A CN112724816 A CN 112724816A
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China
Prior art keywords
coating
corrosion
salt environment
heavy salt
rail
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Pending
Application number
CN202011584548.7A
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Chinese (zh)
Inventor
汤鹏
严国斌
刘毅
王辉
张京
王增光
陈国强
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China Three Gorges Corp
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China Three Gorges Corp
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Priority to CN202011584548.7A priority Critical patent/CN112724816A/en
Publication of CN112724816A publication Critical patent/CN112724816A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4027Mixtures of compounds of group C08G18/54 with other macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/54Polycondensates of aldehydes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, and relates to the technical field of engineering structures. The anti-corrosion rail hanging robot coating in the heavy salt environment comprises 30-40% of xylene formaldehyde resin, 4-6% of nano silicon dioxide, 5-8% of nano titanium dioxide, 40-50% of polytetrahydrofuran glycol, 4-5% of plasticizer, 1.0-3.0% of thixotropic agent and 4-8% of toluene diisocyanate. The invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, which can prevent corrosion and prevent internal materials from contacting with air and moisture, so that the possibility of corrosion is fundamentally avoided, meanwhile, the coating is heat-resistant and high in strength, long in service life and difficult to fall off, and the coating is relatively low in cost and convenient to manufacture.

Description

Anti-corrosion rail hanging robot coating in heavy salt environment
Technical Field
The invention relates to the technical field of engineering structures, in particular to an anti-corrosion rail hanging robot coating in a heavy salt environment.
Background
With the development of science and technology, in industrial engineering, more and more industries adopt industrial robots to replace workers to work, particularly in open places, and when the workers work, the labor intensity is high and the efficiency is low. However, industrial robots are often made of metal materials and are prone to rust and corrosion due to environmental factors when operated in open air, especially in heavy salt and alkali areas.
At present, a rail hanging robot needs to work in a heavy salt alkali area, in order to ensure that the rail hanging robot cannot be corroded and can have long service life, an anti-corrosion coating needs to be coated on the surface of the rail hanging robot, materials which do not react with heavy alkali substances are added into the coating through the chemical reaction principle so as to prevent metal from being corroded in most of the existing anti-corrosion coatings, but the coating is generally high in cost and is easy to fall off after being exposed outside for a long time.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, and solves the problems of high cost and easy shedding of the existing anti-corrosion coating.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the anti-corrosion rail hanging robot coating in the heavy salt environment comprises 30-40% of xylene formaldehyde resin, 4-6% of nano silicon dioxide, 5-8% of nano titanium dioxide, 40-50% of polytetrahydrofuran glycol, 4-5% of plasticizer, 1.0-3.0% of thixotropic agent and 4-8% of toluene diisocyanate.
Preferably, the plasticizer is one of dibutyl phthalate and dioctyl phthalate.
Preferably, the thixotropic agent is an aqueous polyamide anti-sagging agent.
Preferably, the preparation steps of the coating are as follows:
s1, preparing raw materials and various auxiliary materials according to a ratio;
s2, adding polytetrahydrofuran glycol into a reaction kettle for dehydration treatment, adding xylene formaldehyde resin, nano silicon dioxide and nano titanium dioxide after dehydration, stirring and mixing for 1-2 hours;
s3, adding the toluene diisocyanate into the stirred and mixed raw materials, reacting for 2-4 hours in an environment of 50-90 ℃, and then cooling to room temperature;
s4, adding the plasticizer and the thixotropic agent into the reacted raw materials, stirring and mixing again, and obtaining the anticorrosive paint after mixing;
and S5, coating the prepared coating on the surface of the rail-mounted robot, and naturally drying the rail-mounted robot until the coating is prepared.
Preferably, the thickness of the coating is 0.5-1 mm.
(III) advantageous effects
The invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment. The method has the following beneficial effects:
the material generated by the reaction of the xylene formaldehyde resin and the toluene diisocyanate in the anti-corrosion coating designed by the invention has the characteristics of good heat resistance, corrosion resistance and low water absorption, and the material generated by the reaction of the polytetrahydrofuran diol and the toluene diisocyanate has the characteristics of high strength, large elongation, good water resistance and the like, so that the coating can prevent corrosion and prevent internal materials from contacting with air and water, thereby fundamentally avoiding the possibility of corrosion.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, which comprises the following preparation steps:
s1, preparing raw materials and various auxiliary materials according to a ratio, wherein the raw materials comprise 30% of xylene formaldehyde resin, 5% of nano silicon dioxide, 5% of nano titanium dioxide, 44% of polytetrahydrofuran glycol, 5% of a plasticizer, 3% of a thixotropic agent and 8% of toluene diisocyanate, the plasticizer is dibutyl phthalate, and the thixotropic agent is a water-based polyamide anti-sagging agent;
s2, adding polytetrahydrofuran glycol into a reaction kettle for dehydration treatment, adding xylene formaldehyde resin, nano silicon dioxide and nano titanium dioxide after dehydration, stirring and mixing for 2 hours;
s3, adding the toluene diisocyanate into the stirred and mixed raw materials, reacting for 3 hours in an environment of 70 ℃, and then cooling to room temperature;
s4, adding the plasticizer and the thixotropic agent into the reacted raw materials, stirring and mixing again, and obtaining the anticorrosive paint after mixing;
and S5, coating the prepared coating on the surface of the rail-mounted robot, and naturally drying the rail-mounted robot until the coating is prepared.
Example two:
the embodiment of the invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, which comprises the following preparation steps:
s1, preparing raw materials and various auxiliary materials according to a ratio, wherein the raw materials comprise 35% of xylene formaldehyde resin, 5% of nano silicon dioxide, 5% of nano titanium dioxide, 40% of polytetrahydrofuran glycol, 5% of a plasticizer, 3% of a thixotropic agent and 7% of toluene diisocyanate, the plasticizer is dibutyl phthalate, and the thixotropic agent is a water-based polyamide anti-sagging agent;
s2, adding polytetrahydrofuran glycol into a reaction kettle for dehydration treatment, adding xylene formaldehyde resin, nano silicon dioxide and nano titanium dioxide after dehydration, stirring and mixing for 2 hours;
s3, adding the toluene diisocyanate into the stirred and mixed raw materials, reacting for 3 hours in an environment of 80 ℃, and then cooling to room temperature;
s4, adding the plasticizer and the thixotropic agent into the reacted raw materials, stirring and mixing again, and obtaining the anticorrosive paint after mixing;
and S5, coating the prepared coating on the surface of the rail-mounted robot, and naturally drying the rail-mounted robot until the coating is prepared.
Example three:
the embodiment of the invention provides an anti-corrosion rail hanging robot coating in a heavy salt environment, which comprises the following preparation steps:
s1, preparing raw materials and various auxiliary materials according to a ratio, wherein the raw materials comprise 40% of xylene formaldehyde resin, 5% of nano silicon dioxide, 5% of nano titanium dioxide, 35% of polytetrahydrofuran glycol, 5% of a plasticizer, 2% of a thixotropic agent and 8% of toluene diisocyanate, the plasticizer is dibutyl phthalate, and the thixotropic agent is a water-based polyamide anti-sagging agent;
s2, adding polytetrahydrofuran glycol into a reaction kettle for dehydration treatment, adding xylene formaldehyde resin, nano silicon dioxide and nano titanium dioxide after dehydration, stirring and mixing for 2 hours;
s3, adding the toluene diisocyanate into the stirred and mixed raw materials, reacting for 4 hours in an environment of 80 ℃, and then cooling to room temperature;
s4, adding the plasticizer and the thixotropic agent into the reacted raw materials, stirring and mixing again, and obtaining the anticorrosive paint after mixing;
and S5, coating the prepared coating on the surface of the rail-mounted robot, and naturally drying the rail-mounted robot until the coating is prepared.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. Anticorrosive rail robot coating of hanging under heavy salt environment, its characterized in that: the main materials of the composite material comprise 30-40% of xylene formaldehyde resin, 4-6% of nano silicon dioxide, 5-8% of nano titanium dioxide, 40-50% of polytetrahydrofuran diol, 4-5% of plasticizer, 1.0-3.0% of thixotropic agent and 4-8% of toluene diisocyanate.
2. The anti-corrosion rail hanging robot coating under the heavy salt environment according to claim 1, characterized in that: the plasticizer is selected from one of dibutyl phthalate and dioctyl phthalate.
3. The anti-corrosion rail hanging robot coating under the heavy salt environment according to claim 1, characterized in that: the thixotropic agent is an aqueous polyamide anti-sagging agent.
4. The anti-corrosion rail hanging robot coating under the heavy salt environment according to claim 1, characterized in that: the preparation steps of the coating are as follows:
s1, preparing raw materials and various auxiliary materials according to a ratio;
s2, adding polytetrahydrofuran glycol into a reaction kettle for dehydration treatment, adding xylene formaldehyde resin, nano silicon dioxide and nano titanium dioxide after dehydration, stirring and mixing for 1-2 hours;
s3, adding the toluene diisocyanate into the stirred and mixed raw materials, reacting for 2-4 hours in an environment of 50-90 ℃, and then cooling to room temperature;
s4, adding the plasticizer and the thixotropic agent into the reacted raw materials, stirring and mixing again, and obtaining the anticorrosive paint after mixing;
and S5, coating the prepared coating on the surface of the rail-mounted robot, and naturally drying the rail-mounted robot until the coating is prepared.
5. The anti-corrosion rail hanging robot coating in the heavy salt environment according to claim 5, wherein: the thickness of the coating is 0.5-1 mm.
CN202011584548.7A 2020-12-28 2020-12-28 Anti-corrosion rail hanging robot coating in heavy salt environment Pending CN112724816A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011584548.7A CN112724816A (en) 2020-12-28 2020-12-28 Anti-corrosion rail hanging robot coating in heavy salt environment

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Application Number Priority Date Filing Date Title
CN202011584548.7A CN112724816A (en) 2020-12-28 2020-12-28 Anti-corrosion rail hanging robot coating in heavy salt environment

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CN112724816A true CN112724816A (en) 2021-04-30

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05345876A (en) * 1991-11-29 1993-12-27 Dainippon Ink & Chem Inc Urethane-based hard floor convering conposition
JP2003268303A (en) * 2002-03-15 2003-09-25 Sanyu Rec Co Ltd Urethane resin composition for protecting concrete structure for water supply and sewerage from corrosion
JP2004051925A (en) * 2002-07-24 2004-02-19 Dainippon Ink & Chem Inc Urethane-based coating resin composition and coating material
CN103627362A (en) * 2013-11-29 2014-03-12 烟台德邦科技有限公司 Reactive polyurethane hot melt adhesive and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05345876A (en) * 1991-11-29 1993-12-27 Dainippon Ink & Chem Inc Urethane-based hard floor convering conposition
JP2003268303A (en) * 2002-03-15 2003-09-25 Sanyu Rec Co Ltd Urethane resin composition for protecting concrete structure for water supply and sewerage from corrosion
JP2004051925A (en) * 2002-07-24 2004-02-19 Dainippon Ink & Chem Inc Urethane-based coating resin composition and coating material
CN103627362A (en) * 2013-11-29 2014-03-12 烟台德邦科技有限公司 Reactive polyurethane hot melt adhesive and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
汪多仁, 科学技术文献出版社 *

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Application publication date: 20210430