CN112724791A - Anticorrosive paint for steel bar mesh cage arranged in aerated plate and preparation method thereof - Google Patents

Anticorrosive paint for steel bar mesh cage arranged in aerated plate and preparation method thereof Download PDF

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Publication number
CN112724791A
CN112724791A CN202110085023.7A CN202110085023A CN112724791A CN 112724791 A CN112724791 A CN 112724791A CN 202110085023 A CN202110085023 A CN 202110085023A CN 112724791 A CN112724791 A CN 112724791A
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parts
weight
stirring
aerated
agent
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何俊廷
胡荣建
刘会军
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Taiyuan Iron and Steel Group Co Ltd
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Taiyuan Iron and Steel Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D113/00Coating compositions based on rubbers containing carboxyl groups
    • C09D113/02Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Paints Or Removers (AREA)

Abstract

An anticorrosive coating for an aerated plate built-in reinforcement cage and a preparation method thereof belong to the technical field of coating preparation processes, and mainly solve the technical problems of easy corrosion of an internal reinforcement structure, low structural durability, poor reliability and the like of the existing aerated concrete plate. The technical scheme of the invention is as follows: an anticorrosive paint for a steel bar mesh cage arranged in an aerated plate is prepared from the following raw materials: modified waterborne epoxy resin, carboxylic styrene-butadiene latex, industrial soda ash, polyanionic cellulose, purified water, multi-level composite quartz sand powder, ground aerated concrete waste, slaked quicklime, a silane coupling agent XH-10 adhesion promoter, a 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, an amidoamine carboxylate solution anti-sagging agent, a triethanolamine organic carboxylic acid composite waterborne antirust agent and an epoxy iron oxide red pigment. The invention has the advantages of reasonable process proportion, good shearing resistance, tensile strength and crack resistance, good fusion of the reinforcement cage and the aerated concrete matrix and the like.

Description

Anticorrosive paint for steel bar mesh cage arranged in aerated plate and preparation method thereof
Technical Field
The invention belongs to the technical field of paint preparation processes, and particularly relates to an anticorrosive paint for an aerated plate built-in steel bar net cage and a preparation method thereof.
Background
The aerated concrete is a material with a porous structure, a plurality of micro air holes with the diameter of 1-3mm are formed in the aerated concrete, a hole solution is alkaline, the corrosion of the steel bar is easily caused in the processes of autoclaved maintenance and use, the corrosion on the surface of the steel bar is divided into chemical corrosion and electrochemical corrosion, the chemical corrosion is the corrosion caused by the contact of the surface of the steel bar and gas or a gas medium solution, and the corrosion does not have the flow of electrons and is only a small part of the corrosion phenomenon; the electrochemical corrosion is corrosion caused by electrochemical reaction between the surface of the steel bar and a corrosion medium, and most of the corrosion belongs to the electrochemical corrosion, so that the influence of the electrochemical corrosion on the aerated concrete slab is mainly considered.
The condition of electrochemical corrosion on the surface of the steel bar is that when moisture exists on the surface of the steel bar, an anode reaction of iron ionization and a cathode reaction of solution state oxygen reduction occur and are carried out at equal speed, and the reaction equation is as follows:
anode Fe → Fe2+ +2e-Cathode 0.5O2 + H2O+2e-→ 2OH-
Fe2++2OH- →Fe(OH)2 Fe(OH)2+0.5H2O+0.25O2→ Fe(OH)3
Resulting Fe (OH)3Further oxidized to form red rust Fe2O3Partial incomplete oxidation to form black rust Fe3O4. The volume of the corroded steel bar is 2-6 times of that of the corroded steel bar, and the aerated concrete slab can crack due to volume expansion, and the aerated concrete protective layer falls off in severe cases. The protective action on the steel bars is further degraded after the aerated concrete slab cracks, and a corrosive medium is easier to contact the steel bars, so that the corrosion is further aggravated, the structural damage of the aerated concrete slab is accelerated, and the structural durability is reduced. Meanwhile, the bonding force between the corroded steel bar and the aerated concrete is reduced, the foundation of cooperative work of the steel bar and the aerated concrete is damaged, and the reliability of the structure is reduced. Thus being developed and adapted for aerated mixesThe special anticorrosive coatings for the application systems of the panels have become the key to solving the above problems. However, the corrosion-resistant coating is limited by the influence of system environment and use environment factors, so that the influence factors of steel bar corrosion are more, and the problems of effective fusion of the corrosion-resistant coating, the steel bars and the aerated concrete matrix material and the like become the difficulty of the development of the corrosion-resistant coating.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, provides an anticorrosive coating for a steel reinforcement mesh cage arranged in an aerated concrete slab and a preparation method thereof, and solves the technical problems of easy corrosion of an internal steel reinforcement structure, low structural durability, poor reliability and the like of the conventional aerated concrete slab.
In order to solve the problems, the technical scheme of the invention is as follows: an anticorrosive paint for a steel bar mesh cage arranged in an aerated plate is prepared from the following raw materials in parts by weight: 20-30 parts of modified waterborne epoxy resin, 20-30 parts of carboxylic styrene-butadiene latex, 1-5 parts of industrial soda ash, 2-3 parts of polyanionic cellulose, 17-26 parts of purified water, 5-9 parts of multi-stage composite quartz sand powder, 5-7 parts of ground aerated concrete waste, 2-5 parts of slaked quicklime, 1-3 parts of silane coupling agent XH-10 adhesion promoter, 5-7 parts of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, 2-8 parts of amidoamine carboxylate solution hanging agent, 2-6 parts of triethanolamine organic carboxylic acid composite waterborne antirust agent and 7-15 parts of epoxy iron red pigment.
A preparation method of anticorrosive paint for a steel bar mesh cage arranged in an aerated plate comprises the following process steps:
1) preparing an anticorrosive base liquid: adding 20-30 parts by weight of modified waterborne epoxy resin and 20-30 parts by weight of carboxylic styrene-butadiene latex into a stirring device, stirring for 5-10 min to prepare an anticorrosion base liquid in a suspension emulsion state, and storing for later use;
2) preparing a consistency regulator: adding 1-5 parts by weight of industrial soda and 2-3 parts by weight of polyanionic cellulose into 5 parts by weight of purified water, soaking for 30min, stirring for 3-5 min to prepare a consistency regulator, and storing for later use;
3) preparing an inorganic admixture mixed solution: adding 5-9 parts by weight of multistage composite quartz sand powder, 5-7 parts by weight of ground aerated concrete waste and 2-5 parts by weight of slaked quicklime into 12-21 parts by weight of purified water, uniformly stirring to prepare an inorganic admixture mixed solution, and storing for later use;
4) adding an anticorrosive additive and a surface modifier: adding 1-3 parts by weight of a silane coupling agent XH-10 adhesion promoter into the prepared anticorrosive base liquid for later use in the step 1), and stirring for 3-5 min; after uniformly stirring, adding 5-7 parts by weight of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, and stirring for 3-5 min; after the mixture is uniformly stirred, adding 2-8 parts by weight of an anti-sagging agent of the amidoamine carboxylate solution and 2-6 parts by weight of a triethanolamine organic carboxylic acid composite water-based antirust agent, and stirring for 3-5 min;
5) uniformly mixing: and (3) testing the viscosity and coating thickness of the suspension emulsion added with the anticorrosion auxiliary agent and the surface modifier and prepared in the step 4), adding the consistency regulator prepared in the step 2) into the suspension emulsion until the viscosity is adjusted to be more than 450mpa.s, stirring for 3min, adding the inorganic admixture mixed solution prepared in the step 3), adding 7-15 parts by weight of epoxy iron oxide red pigment, and stirring for 30min to prepare the anticorrosion paint for the reinforcing mesh cage built in the air-entraining plate.
According to the technical scheme, aiming at the problems of poor corrosion prevention quality and low efficiency of the built-in net cage of the aerated concrete plate, a large number of experiments take modified water-based epoxy resin and carboxylic styrene-butadiene latex as base materials, and take raw materials such as 12-14 carbon primary alcohol polyoxyethylene ether, a silane coupling agent XH-10 adhesion promoter, an amidoamine carboxylate solution anti-sagging agent, a triethanolamine organic carboxylic acid composite water-based antirust agent, industrial soda, a polyanionic cellulose composite thickener and the like as modification aids; the anti-corrosion coating for the steel bar net cage built in the aerated concrete slab is prepared by compounding the multi-level composite quartz sand powder, the finely ground aerated concrete waste material and the digested quicklime as inorganic admixture and the epoxy iron oxide red as dyeing and anti-rust material, and the engineering technical problem is effectively solved.
The invention improves the thixotropy, the suspension property and the stability of the anticorrosive paint, improves the spreadability and the storage stability, increases the thickness of a paint film coating, prevents sagging, sinking and precipitation, ensures that each part, gap and the like of the reinforcing mesh can be uniformly and completely coated, and has no obvious sagging and cracking phenomena in the mesh drying process. The integration of the anticorrosive coating with the steel bars and the aerated concrete matrix is greatly improved, and the production and application process problems of cracking, structural damage and the like caused by corrosion of the steel bars arranged in the aerated concrete slab are effectively solved; the bonding force of the anticorrosive material for the aerated concrete slab and the steel bar is more than 1.0Mp, the bonding force with the aerated concrete matrix material reaches more than 0.8Mp, the corrosion area after the test is less than or equal to 5 percent, the corrosion resistance efficiency is improved by 12-24 times before the improvement, and the shearing resistance, the tensile resistance and the crack resistance of the aerated concrete slab product are obviously improved.
The invention has the advantages of reasonable process proportion, good shearing resistance, tensile strength and crack resistance, good fusion of the reinforcement cage and the aerated concrete matrix and the like.
Detailed Description
The present invention will be described in further detail with reference to examples.
An anticorrosive paint for a steel bar mesh cage arranged in an aerated plate is prepared from the following raw materials in parts by weight: 20-30 parts of modified waterborne epoxy resin, 20-30 parts of carboxylic styrene-butadiene latex, 1-5 parts of industrial soda ash, 2-3 parts of polyanionic cellulose, 17-26 parts of purified water, 5-9 parts of multi-stage composite quartz sand powder, 5-7 parts of ground aerated concrete waste, 2-5 parts of slaked quicklime, 1-3 parts of silane coupling agent XH-10 adhesion promoter, 5-7 parts of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, 2-8 parts of amidoamine carboxylate solution hanging agent, 2-6 parts of triethanolamine organic carboxylic acid composite waterborne antirust agent and 7-15 parts of epoxy iron red pigment.
A preparation method of anticorrosive paint for a steel bar mesh cage arranged in an aerated plate comprises the following process steps:
1) preparing an anticorrosive base liquid: adding 20-30 parts by weight of modified waterborne epoxy resin and 20-30 parts by weight of carboxylic styrene-butadiene latex into a stirring device, stirring for 5-10 min to prepare an anticorrosion base liquid in a suspension emulsion state, and storing for later use;
2) preparing a consistency regulator: adding 1-5 parts by weight of industrial soda and 2-3 parts by weight of polyanionic cellulose into 5 parts by weight of purified water, soaking for 30min, stirring for 3-5 min to prepare a consistency regulator, and storing for later use;
3) preparing an inorganic admixture mixed solution: adding 5-9 parts by weight of multistage composite quartz sand powder, 5-7 parts by weight of ground aerated concrete waste and 2-5 parts by weight of slaked quicklime into 12-21 parts by weight of purified water, uniformly stirring to prepare an inorganic admixture mixed solution, and storing for later use;
4) adding an anticorrosive additive and a surface modifier: adding 1-3 parts by weight of a silane coupling agent XH-10 adhesion promoter into the prepared anticorrosive base liquid for later use in the step 1), and stirring for 3-5 min; after uniformly stirring, adding 5-7 parts by weight of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, and stirring for 3-5 min; after the mixture is uniformly stirred, adding 2-8 parts by weight of an anti-sagging agent of the amidoamine carboxylate solution and 2-6 parts by weight of a triethanolamine organic carboxylic acid composite water-based antirust agent, and stirring for 3-5 min;
5) uniformly mixing: and (3) testing the viscosity and coating thickness of the suspension emulsion added with the anticorrosion auxiliary agent and the surface modifier and prepared in the step 4), adding the consistency regulator prepared in the step 2) into the suspension emulsion until the viscosity is adjusted to be more than 450mpa.s, stirring for 3min, adding the inorganic admixture mixed solution prepared in the step 3), adding 7-15 parts by weight of epoxy iron oxide red pigment, and stirring for 30min to prepare the anticorrosion paint for the reinforcing mesh cage built in the air-entraining plate.

Claims (2)

1. An anticorrosive paint for a steel bar mesh cage arranged in an aerated plate is characterized in that: the anticorrosive paint is prepared from the following raw materials in parts by weight: 20-30 parts of modified waterborne epoxy resin, 20-30 parts of carboxylic styrene-butadiene latex, 1-5 parts of industrial soda ash, 2-3 parts of polyanionic cellulose, 17-26 parts of purified water, 5-9 parts of multi-stage composite quartz sand powder, 5-7 parts of ground aerated concrete waste, 2-5 parts of slaked quicklime, 1-3 parts of silane coupling agent XH-10 adhesion promoter, 5-7 parts of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, 2-8 parts of amidoamine carboxylate solution hanging agent, 2-6 parts of triethanolamine organic carboxylic acid composite waterborne antirust agent and 7-15 parts of epoxy iron red pigment.
2. A preparation method of the anticorrosive paint for the steel reinforcement mesh cage arranged in the aerated slab according to claim 1 is characterized by comprising the following steps: the method comprises the following process steps:
1) preparing an anticorrosive base solution: adding 20-30 parts by weight of modified waterborne epoxy resin and 20-30 parts by weight of carboxylic styrene-butadiene latex into a stirring device, stirring for 5-10 min to prepare an anticorrosion base liquid in a suspension emulsion state, and storing for later use;
2) and preparing a consistency regulator: adding 1-5 parts by weight of industrial soda and 2-3 parts by weight of polyanionic cellulose into 5 parts by weight of purified water, soaking for 30min, stirring for 3-5 min to prepare a consistency regulator, and storing for later use;
3) preparing an inorganic admixture mixed solution: adding 5-9 parts by weight of multistage composite quartz sand powder, 5-7 parts by weight of ground aerated concrete waste and 2-5 parts by weight of slaked quicklime into 12-21 parts by weight of purified water, uniformly stirring to prepare an inorganic admixture mixed solution, and storing for later use;
4) adding an anticorrosive additive and a surface modifier: adding 1-3 parts by weight of a silane coupling agent XH-10 adhesion promoter into the prepared anticorrosive base liquid for later use in the step 1), and stirring for 3-5 min; after uniformly stirring, adding 5-7 parts by weight of 12-14 carbon primary alcohol polyoxyethylene ether nonionic surfactant, and stirring for 3-5 min; after the mixture is uniformly stirred, adding 2-8 parts by weight of an anti-sagging agent of the amidoamine carboxylate solution and 2-6 parts by weight of a triethanolamine organic carboxylic acid composite water-based antirust agent, and stirring for 3-5 min;
5) and uniformly mixing: and (3) testing the viscosity and coating thickness of the suspension emulsion added with the anticorrosion auxiliary agent and the surface modifier and prepared in the step 4), adding the consistency regulator prepared in the step 2) into the suspension emulsion until the viscosity is adjusted to be more than 450mpa.s, stirring for 3min, adding the inorganic admixture mixed solution prepared in the step 3), adding 7-15 parts by weight of epoxy iron oxide red pigment, and stirring for 30min to prepare the anticorrosion paint for the reinforcing mesh cage built in the air-entraining plate.
CN202110085023.7A 2021-01-22 2021-01-22 Anticorrosive paint for steel bar mesh cage arranged in aerated plate and preparation method thereof Pending CN112724791A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103508709A (en) * 2012-06-15 2014-01-15 北京金隅加气混凝土有限责任公司 Method for preparing steel bar antirust paint for autoclaved aerated concrete slabs
CN104231857A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Composite epoxy anticorrosive paint and preparation method thereof
CN104530902A (en) * 2014-12-11 2015-04-22 青岛佰众化工技术有限公司 Water-based anticorrosive paint and preparation method thereof
CN106833250A (en) * 2017-02-23 2017-06-13 广州梵竹水性涂料有限公司 A kind of waterborne metal anti-corrosive paint and preparation method thereof
CN108003708A (en) * 2017-12-26 2018-05-08 陕西凝远新材料科技股份有限公司 A kind of antirust agent and preparation method for steam pressure sand aerated concrete plate reinforcing bar
CN108585739A (en) * 2018-08-02 2018-09-28 遵义市旭辉新型节能建材有限公司 A kind of New Type Aerated Concrete mortar and preparation method thereof
CN109626932A (en) * 2019-01-14 2019-04-16 青岛天利兴达新型建材有限公司 A kind of steam-aerated concrete plate and preparation method thereof
CN111533501A (en) * 2020-05-20 2020-08-14 江苏中昌绝热技术工程有限公司 Composite novel building anticorrosive material and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103508709A (en) * 2012-06-15 2014-01-15 北京金隅加气混凝土有限责任公司 Method for preparing steel bar antirust paint for autoclaved aerated concrete slabs
CN104231857A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Composite epoxy anticorrosive paint and preparation method thereof
CN104530902A (en) * 2014-12-11 2015-04-22 青岛佰众化工技术有限公司 Water-based anticorrosive paint and preparation method thereof
CN106833250A (en) * 2017-02-23 2017-06-13 广州梵竹水性涂料有限公司 A kind of waterborne metal anti-corrosive paint and preparation method thereof
CN108003708A (en) * 2017-12-26 2018-05-08 陕西凝远新材料科技股份有限公司 A kind of antirust agent and preparation method for steam pressure sand aerated concrete plate reinforcing bar
CN108585739A (en) * 2018-08-02 2018-09-28 遵义市旭辉新型节能建材有限公司 A kind of New Type Aerated Concrete mortar and preparation method thereof
CN109626932A (en) * 2019-01-14 2019-04-16 青岛天利兴达新型建材有限公司 A kind of steam-aerated concrete plate and preparation method thereof
CN111533501A (en) * 2020-05-20 2020-08-14 江苏中昌绝热技术工程有限公司 Composite novel building anticorrosive material and preparation method thereof

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Application publication date: 20210430