CN1127175A - Pouring protective slag for electric slag centrifugal casting - Google Patents

Pouring protective slag for electric slag centrifugal casting Download PDF

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Publication number
CN1127175A
CN1127175A CN 95110010 CN95110010A CN1127175A CN 1127175 A CN1127175 A CN 1127175A CN 95110010 CN95110010 CN 95110010 CN 95110010 A CN95110010 A CN 95110010A CN 1127175 A CN1127175 A CN 1127175A
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China
Prior art keywords
slag
blast furnace
centrifugal casting
electric
pouring
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Granted
Application number
CN 95110010
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Chinese (zh)
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CN1059364C (en
Inventor
姜周华
肖玉光
姜兴渭
张颖
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Northeastern University China
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Northeastern University China
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Priority to CN95110010A priority Critical patent/CN1059364C/en
Publication of CN1127175A publication Critical patent/CN1127175A/en
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Publication of CN1059364C publication Critical patent/CN1059364C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Manufacture Of Iron (AREA)

Abstract

The invented casting powder is composed of blast furnace grain slag 65-70 wt%, fluorite 15-20wt% and industrial soda ash 15-20 wt%, where the blast furnace grain slag is composed of CaO 34-37 wt%, SiO2 38-47 wt%, MgO 8-10 wt% and Al2O3 8-12 wt%. Advantages are low melting temp., small heat-conducting coefficient and low oxidisability. It can be extensively used in the electroslag metallurgy of steel works.

Description

Pouring protective slag for electric slag centrifugal casting
The present invention relates to the electroslag metallurgy technical field, particularly a kind of pouring protective slag for electric slag centrifugal casting.
Centrifugal electroslag casting is the new technology of the eighties by the electric welding institute invention of Ukraine's crust.It is applicable to the various black and the non-ferrous casting of production lopps, cover class, tubing band hollow.Be the molten steel that will have the refining of lining electroslag furnace to go out, the band slag is poured into coagulation forming in the centrifugal casting machine.Because whole foundry goods is that dynamic solidification forms under the protection of slag.Therefore, the strand of acquisition not only surface quality is good, and dense internal organization, and its performance reaches with steel grade forging level, and production process is simplified, and cost reduces.Studies show that slag plays a crucial role to the casting solidification quality.Yet cast at present is to utilize the slag that the molten refining of lining electroslag is arranged with slag, because the effect of slag is heating and refining during melting, and its effect is moulding, insulation etc. when pouring into a mould.Therefore, obviously different to the slag performance requriements between the two, in existing technology,, bring up to the slag temperature more than 1800 ℃, though this method has satisfied the needs of slag crust moulding when pouring into a mould in order to make slag when pouring into a mould, good flowability be arranged, but slag Wen Taigao has not only aggravated the etch of slag to furnace lining, increase power consumption, and made molten steel temperature raise, increased the air-breathing of molten steel, also strengthened simultaneously thermal shocking, and too high liquid steel temperature has increased the tendency of cast(ing) surface crackle to mould.Because the smelting slag fusing point is very high, make that cast back cast outer surface slag crust is too thick in addition, influenced surface quality and heat transfer, foundry goods internal surface slag premature solidification has influenced the discharge of foundry goods obnoxious flavour and the removal of non-metallic inclusion simultaneously.Therefore, utilizing smelting slag is irrational as pouring protective slag for electric slag centrifugal casting.
In view of the deficiency that the covering slag prior art exists, it is low to the purpose of this invention is to provide a kind of oxidisability, and thermal conductivity is little, and viscosity number is little, the pouring protective slag for electric slag centrifugal casting that temperature of fusion is low.
For achieving the above object, the present invention is achieved by the following technical solutions.
Covering slag is made up of blast furnace granulated slag, fluorite and calcined soda for industry.Its content proportioning is by weight percentage: 65-70%: 15-20%: 15-20%.
The blast furnace granulated slag main component is: CaO, SiO 2, MgO, Al 2O 3, compositions in weight percentage:
CaO,38—4%∶SiO 2,34—37%∶MgO,8—10%∶Al 2O 3,8—12%。
Blast furnace granulated slag is the refuse of blast furnace ironmaking, is mainly used in cement raw material at present, and price is very cheap, and quantity is many, is characterized in that basicity is low, thereby slag character is tending towards long slag, and also low about 1320 ℃ of temperature of fusion, good heat insulating.Ferric oxide is low in the slag, and the impurity element phosphorus content is low, thereby is applicable to the base-material of making covering slag.Adding fluorite and calcined soda for industry has been the flux effect, can reduce the temperature of fusion and the viscosity of covering slag.
Its preparation method is: 1, solid slag, with above-mentioned several raw materials mixing of weighing in proportion, in plumbago crucible, to give moltenly with electroslag furnace, and cooling back fragmentation is ground to below 100 orders, and adds 100 gram ferrosilicon powders (75%Si) and mix in the per kilogram slag charge.The protection quantity of slag is 3-5% of a molten steel weight when using, and earlier slag charge is placed in the mould, and the molten steel that reinjects carries out centrifugal casting.
2, liquid slag will be the slag of molten steel weight 5-8%, be melted to 1550 ℃ in plumbago crucible, water earlier to water molten steel behind the slag and carry out centrifugal casting.
The present invention compared with prior art has following advantage:
1, be generally 1000-1200 ℃ because oxidisability is low, temperature of fusion is low, interfacial tension is big between slag and the metal, and thermal conductivity is little, therefore, significantly improve the foundry goods internal soundness, dense internal organization, no slag inclusion, pore, macroscopic defectss such as shrinkage cavity, mechanical property can reach with steel grade forging level.Form even slag crust in cast outer surface, the bright and clean esr level that reaches of this cast(ing) surface.
2,, therefore can not produce any detrimentally affect, thereby lining life is long to the furnace lining that the lining electroslag furnace is arranged because the cast covering slag is formulated separately outside stove.
The embodiment of the invention below is provided.
Embodiment one:
Covering slag is by blast furnace granulated slag, and fluorite and calcined soda for industry are formed.Its proportioning is by weight percentage: 65: 20: 15, the blast furnace granulated slag main component was: CaO, SiO 2, MgO, Al 2O 3, its compositions in weight percentage is:
34∶44∶10∶12。
Embodiment two:
The covering slag component is with embodiment one, and the basigamy ratio is for by weight percentage:
70∶15∶15:
The blast furnace granulated slag main component is: CaO, SiO 2, MgO, Al 2O 3, its compositions in weight percentage is 37: 47: 8: 8.
Embodiment three:
The covering slag component is with embodiment one, and its proportioning is by weight percentage
58∶15∶17。
The blast furnace granulated slag main component is: CaO, SiO 2, MgO, Al 2O 3, its compositions in weight percentage is: 35: 45: 8: 12.

Claims (2)

1, a kind of pouring protective slag for electric slag centrifugal casting is characterized in that: covering slag is made up of blast furnace granulated slag, fluorite and calcined soda for industry, and its proportioning is by weight percentage: 65-70%: 15-20%: 15-20%.
2, covering slag according to claim 1 is characterized in that: the blast furnace granulated slag main component is CaO, SiO 2, MgO, Al 2O 3, its components based on weight percentage is: 34-37%: 38-47%: 8-10%: 8-12%.
CN95110010A 1995-01-17 1995-01-17 Pouring protective slag for electric slag centrifugal casting Expired - Fee Related CN1059364C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN95110010A CN1059364C (en) 1995-01-17 1995-01-17 Pouring protective slag for electric slag centrifugal casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN95110010A CN1059364C (en) 1995-01-17 1995-01-17 Pouring protective slag for electric slag centrifugal casting

Publications (2)

Publication Number Publication Date
CN1127175A true CN1127175A (en) 1996-07-24
CN1059364C CN1059364C (en) 2000-12-13

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CN95110010A Expired - Fee Related CN1059364C (en) 1995-01-17 1995-01-17 Pouring protective slag for electric slag centrifugal casting

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965519A (en) * 2012-11-22 2013-03-13 河南省西保冶材集团有限公司 Carburizing bearing steel electroslag remelting casting powder
CN104439194A (en) * 2014-11-19 2015-03-25 北京天力创玻璃科技开发有限公司 Anti-oxidation protective agent for composite roll
CN110964976A (en) * 2019-11-13 2020-04-07 中煤张家口煤矿机械有限责任公司 Steel for chain wheel and preparation method and application thereof
CN114126783A (en) * 2020-01-14 2022-03-01 泰安特夫德新材料科技有限公司 Method for centrifugally casting composite steel pipe by utilizing slag

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1037246C (en) * 1991-08-12 1998-02-04 北京科技大学 Special hollow casting made by inductive electroslag with centrifugal method
CN1023861C (en) * 1992-07-14 1994-02-23 冶金工业部钢铁研究总院 Centrifugal casting molten-slag
CN1038566C (en) * 1994-12-23 1998-06-03 冶金工业部钢铁研究总院 Centrifugal casting scoria

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965519A (en) * 2012-11-22 2013-03-13 河南省西保冶材集团有限公司 Carburizing bearing steel electroslag remelting casting powder
CN104439194A (en) * 2014-11-19 2015-03-25 北京天力创玻璃科技开发有限公司 Anti-oxidation protective agent for composite roll
CN104439194B (en) * 2014-11-19 2017-02-01 北京天力创玻璃科技开发有限公司 Anti-oxidation protective agent for composite roll
CN110964976A (en) * 2019-11-13 2020-04-07 中煤张家口煤矿机械有限责任公司 Steel for chain wheel and preparation method and application thereof
CN114126783A (en) * 2020-01-14 2022-03-01 泰安特夫德新材料科技有限公司 Method for centrifugally casting composite steel pipe by utilizing slag
CN114126783B (en) * 2020-01-14 2023-11-03 泰安特夫德新材料科技有限公司 Method for centrifugally casting composite steel pipe by utilizing slag

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