CN112708192B - Polypropylene/thermoplastic elastomer blend and preparation method and application thereof - Google Patents
Polypropylene/thermoplastic elastomer blend and preparation method and application thereof Download PDFInfo
- Publication number
- CN112708192B CN112708192B CN201911025334.3A CN201911025334A CN112708192B CN 112708192 B CN112708192 B CN 112708192B CN 201911025334 A CN201911025334 A CN 201911025334A CN 112708192 B CN112708192 B CN 112708192B
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- polypropylene
- parts
- antioxidant
- thermoplastic elastomer
- elastomer blend
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 99
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 98
- -1 Polypropylene Polymers 0.000 title claims abstract description 91
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 49
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical class C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004005 microsphere Substances 0.000 claims abstract description 21
- 229920001577 copolymer Polymers 0.000 claims abstract description 13
- 238000004806 packaging method and process Methods 0.000 claims abstract description 5
- 229940127554 medical product Drugs 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 21
- 230000003078 antioxidant effect Effects 0.000 claims description 21
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 18
- 229920001971 elastomer Polymers 0.000 claims description 18
- 239000002667 nucleating agent Substances 0.000 claims description 18
- 229910052709 silver Inorganic materials 0.000 claims description 18
- 239000004332 silver Substances 0.000 claims description 18
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- 239000011701 zinc Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 9
- 239000003242 anti bacterial agent Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- OHOPPQTXVSRTMW-UHFFFAOYSA-N 3-methyl-4-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C)=C1C=CC1=CC=CC=C1 OHOPPQTXVSRTMW-UHFFFAOYSA-N 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 239000005060 rubber Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 5
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 5
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 4
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 claims description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 235000011010 calcium phosphates Nutrition 0.000 claims description 4
- XXHCQZDUJDEPSX-KNCHESJLSA-L calcium;(1s,2r)-cyclohexane-1,2-dicarboxylate Chemical compound [Ca+2].[O-]C(=O)[C@H]1CCCC[C@H]1C([O-])=O XXHCQZDUJDEPSX-KNCHESJLSA-L 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 239000010436 fluorite Substances 0.000 claims description 4
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 4
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- YHKRPJOUGGFYNB-UHFFFAOYSA-K sodium;zirconium(4+);phosphate Chemical compound [Na+].[Zr+4].[O-]P([O-])([O-])=O YHKRPJOUGGFYNB-UHFFFAOYSA-K 0.000 claims description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
- 239000004599 antimicrobial Substances 0.000 claims description 3
- 238000010146 3D printing Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 11
- 230000003287 optical effect Effects 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 6
- 229920003023 plastic Polymers 0.000 abstract description 6
- 238000001746 injection moulding Methods 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 239000013538 functional additive Substances 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- 239000000806 elastomer Substances 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 238000012648 alternating copolymerization Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical class CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 2
- 238000011925 1,2-addition Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Chemical class CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical class CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical group CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical class C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical group N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920006465 Styrenic thermoplastic elastomer Polymers 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229920005603 alternating copolymer Polymers 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a polypropylene/thermoplastic elastomer blend, a preparation method and application thereof, belonging to the field of plastic processing. The polypropylene/thermoplastic elastomer blend comprises the following components in parts by weight: the polypropylene is 60-99 parts by mass, the hydrogenated styrene-butadiene-styrene block copolymer (SEBS) is 1-40 parts by mass, and the alpha-methylstyrene-maleic anhydride copolymer microspheres are 0.1-1 part by mass based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer. The technical scheme mainly uses polypropylene as a matrix, is blended with hydrogenated styrene-butadiene-styrene block copolymer (SEBS), is mixed with other functional additives to improve the performance, is tested after injection molding to obtain the transparent tough material with excellent optical performance and mechanical performance, has good antibacterial capability, and is suitable for application of high polymer materials in the field of packaging of medical instruments and medical products.
Description
Technical Field
The invention relates to the field of plastic processing, in particular to a polypropylene/thermoplastic elastomer blend and a preparation method and application thereof.
Background
Polypropylene (PP) is a versatile plastic with extremely wide applications, due to its abundant sources, low price, low density, good rigidity and good flowability: easy processing, and better comprehensive performance compared with other plastics, so the development of polypropylene is very rapid, and the demand for polypropylene is more and more increased particularly along with the rapid development of industries such as automobiles, household appliances, information, machinery, chemical engineering and the like. However, polypropylene itself has many disadvantages, mainly poor impact resistance, poor transparency in the aspects of packaging, daily necessities and medical appliances, which leads to aesthetic lack of appearance of products, and the disadvantages severely restrict the application of the polypropylene, therefore, in industrial production, the polypropylene is often subjected to permeability-increasing or toughening modification, which can effectively solve the contradictions. The transparency of polypropylene is generally improved by adding transparent nucleating agent, or the transparent polypropylene is directly synthesized and produced by adopting a special polymerization method. Blending with thermoplastic elastomers is another commonly used method to improve both the transparency and toughness of materials. On one hand, the toughness of the elastomer is higher than that of the matrix polypropylene, when the elastomer is distributed in a PP continuous phase as a dispersed phase to form a 'sea-island' structure, when the blend is acted by an external force, elastomer particles are used as stress concentration points and preferentially deform under impact, if the interface of two phases is well bonded, a large amount of silver grains and shear zones are generated in the region where the particles are located, so that energy is consumed, and meanwhile, the elastomer particles can retard, turn and stop the development of small cracks, so that the toughness of the system is increased; on the other hand, the addition of the elastomer destroys the PP crystals, so that the spherulites of the PP are refined, and the elastomer plays a role in heterogeneous nucleation and thus plays a toughening role.
Styrenic thermoplastic elastomers can be classified into styrene and butadiene block copolymers (SBS), styrene and isoprene block copolymers (SIS), hydrogenated styrene-butadiene-styrene block copolymers (SEBS), and the like. SBS and SEBS are commonly used for PP modification. SEBS has excellent stability, heat resistance, oxidation resistance and other properties compared with SBS, SEBS has good fluidity and can be used as a compatibilizer of PP and a reinforcing material, and an SEBS/PP blending system can easily obtain good properties.
Chinese patent with publication number CN101955609A (application number CN201010293952.9) reports a medical irradiation-resistant polypropylene alloy material, which comprises one or more of polypropylene powder, SIS or SEPS (hydrogenated SIS), Ethylene Propylene Diene Monomer (EPDM) or ethylene propylene elastomer (VISTAMAXX), and the nucleating agent is sorbitol nucleating agent. The publication No. CN102311584A (application No. CN201110210602.6) reports a medical polypropylene material, which adopts homopolymerized polypropylene, sorbitol nucleating agent, POE as toughening agent, antistatic agent, etc. Chinese patent publication No. CN109320842A discloses a medical polypropylene thermoplastic elastomer and a preparation method thereof, wherein the elastomer material is prepared from atactic polypropylene, rubber (ethylene propylene diene monomer), an antioxidant 626, a light stabilizer 770, calcium stearate and a nucleating agent (3988) by extruding and granulating through a twin-screw extruder. The product meets the requirements of medical polypropylene materials, and can be applied to the production of disposable medical instruments such as disposable drug infusion bags and the like.
In the middle of the packaging films or the middle of the processing equipment, the friction coefficient of the polyolefin during film processing is high, and the adhesion phenomenon is easy to occur. The opening agent, also called slipping agent, anti-blocking agent and anti-caking agent, is commonly used in the production and preparation process of plastic film material products, and can effectively improve the opening performance of the film. The slip agent improves the surface properties of the polyolefin film and reduces film-to-film friction (on a roll) and film-to-other contacting surface layers. Effectively prevent the adhesion between films and the agglomeration between granules, increase the surface smoothness of the films, prevent the dust from attaching on the surface of the products and produce very smooth plastic products. The earliest opening agents were inorganic talc, diatomaceous earth, etc.; the medium-term development is to organic oleamide, erucamide, EBS derivatives and the like; common such adjuvants are generally small molecule inorganic or organic compounds. Erucamide has a lower melting point, is easy to migrate and separate out, is easy to turn yellow for a long time, and reduces the performance of the material. At present, the synthetic silicon dioxide is widely applied to films as an opening agent. The synthetic silica opening agent has better optical degree, is amorphous, can be directly used in food after being approved by FDA, meets European standards, and is a more effective opening agent. The disadvantage is high price (price 10000-70000 yuan/ton).
Disclosure of Invention
In order to solve the above problems in the prior art, the present invention proposes a polypropylene/thermoplastic elastomer blend. In particular to a polypropylene/thermoplastic elastomer blend and a preparation method and application thereof. The technical scheme mainly uses polypropylene as a matrix, is blended with hydrogenated styrene-butadiene-styrene block copolymer (SEBS), is mixed with other functional additives to improve the performance, is tested after injection molding to obtain a transparent tough material with excellent optical performance and mechanical performance, has good antibacterial capability, and is suitable for application of high polymer materials in the field of packaging of medical instruments and medical products.
One object of the present invention is to provide a polypropylene/thermoplastic elastomer blend, which may comprise the following components in parts by weight:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
60-99 parts of polypropylene, preferably 65-99 parts; more preferably 70-95 parts; further preferably 75 to 90 parts;
1-40 parts of hydrogenated styrene-butadiene-styrene block copolymer (SEBS), preferably 1-35 parts; more preferably 5 to 30 parts; further preferably 10 to 25 parts;
0.1-1 part of alpha-methylstyrene-maleic anhydride copolymerized microsphere, preferably 0.2-0.7 part.
Preferably, the first and second electrodes are formed of a metal,
the polypropylene/thermoplastic elastomer blend may further comprise a nucleating agent;
the nucleating agent is used in an amount of 0.02 to 0.5 part, preferably 0.03 to 0.3 part, and preferably 0.03 to 0.15 part, based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer.
And/or the presence of a gas in the atmosphere,
the polypropylene/thermoplastic elastomer blend may further comprise an antimicrobial agent;
the amount of the antibacterial agent is 0.1-1 part, preferably 0.3-0.8 part, based on 100 parts of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer.
And/or the presence of a gas in the gas,
the polypropylene/thermoplastic elastomer blend may also contain an antioxidant,
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the using amount of the antioxidant is 0.1-3 parts, preferably 0.1-1.5 parts;
the antioxidant is selected from at least one of an antioxidant 1010, an antioxidant 168, an antioxidant 1076, an antioxidant 2246, an antioxidant CA, an antioxidant 626 and an antioxidant 636, and preferably one or two of the above.
Wherein,
the polypropylene is used as a matrix to provide mechanical strength; the hydrogenated styrene-butadiene-styrene block copolymer thermoplastic elastomer is toughened and the haze is reduced; the nucleating agent improves the mechanical property and the optical property; the alpha-methyl styrene-maleic anhydride copolymer microsphere improves the opening performance; the antimicrobial agent provides antimicrobial properties.
The melt index of the polypropylene can be 2-6 g/10min, and the polypropylene can be at least one selected from homo-polypropylene, random copolymerization polypropylene or impact copolymerization polypropylene.
The hydrogenated styrene-butadiene-styrene block copolymer may have a linear structure. Specifically, the hydrogenated styrene-butadiene-styrene block copolymer can also be selected from commercially available products commonly used in the field, preferably medical grade SEBS, such as medium petrochemical baring SEBS YH-506, medium petrochemical baring SEBS YH-688, G-1651H manufactured by Kobusta corporation, and preferably medium petrochemical baring SEBS YH-506. Preferably, the preparation method of the hydrogenated styrene-butadiene-styrene block copolymer can refer to the preparation method of the SEBS elastomer disclosed in chinese patent with publication number CN107759948A (application number CN201610687014.4) and chinese patent with publication number CN109206568A (application number CN 201710516400.1). Herein, methods for preparing SEBS elastomers disclosed in chinese patent publication No. CN107759948A (application No. CN201610687014.4) and chinese patent publication No. CN109206568A (application No. CN201710516400.1) are introduced.
Specifically, the hydrogenated styrene-butadiene-styrene block copolymer may be hydrogenated from an SBS elastomer. The SBS elastomer has the following molecular configuration: s- [ (1,2 addition unit) a- (1,4 addition unit) c- (1,2 addition unit) b- (1,4 addition unit) d]n-S, wherein: s is a polystyrene unit; a. b, c and d are all larger than 1, and have small values and basically present random distribution, (a + b)/(c + d) ═ 38-42)/(62-58); preferably, the SBS has a number average molecular weight Mn of 10 × 10 4 ～25×10 4 . Preferably, the SBS has an S/B block ratio of (25-35)/(75-65).
The nucleating agent can be selected from
3988、
NX TM 8000. At least one of Hyperform HPN-20E, VP101B, VP101T and VP 101E.
3988 is produced by Milliken, USA, and is dimethyl-substituted dibenzylidene sorbitol ("DMDBS"), 1, 3:2, 4-bis (3, 4-dimethylbenzylidene) sorbitol;
NX TM 8000 for American Milliken company, sorbitol transparent nucleating agent; hyperform HPN-20E is a nucleating agent from Milliken company, USA, is a calcium dicarboxylate metal salt, and can be used for improving transparency, physical properties, barrier and sealing properties. VP101B, VP101T and VP101E (Beijing Yanshan Xin Tianze chemical Co., Ltd.) are superfine fully vulcanized powdered rubber composite nucleating agents, wherein VP101B is formed by compounding superfine fully vulcanized powdered rubber and sodium benzoate and the like, VP101T is formed by compounding superfine fully vulcanized powdered rubber and substituted aromatic derivatives, and VP101E is formed by compounding superfine fully vulcanized powdered rubber and Hyperform HPN-20E.
The antibacterial agent can be selected from at least one of silver-loaded zirconium phosphate, zinc-loaded zirconium phosphate, silver-loaded sodium zirconium phosphate, zinc-loaded sodium zirconium phosphate, silver-loaded fluorspar, zinc-loaded fluorspar, silver-loaded activated carbon, zinc-loaded activated carbon, silver-loaded copper phosphate, zinc-loaded copper phosphate, silver-loaded calcium phosphate, zinc-loaded calcium phosphate, silver-loaded silica gel, zinc-loaded silica gel, silver-loaded hydroxyapatite and zinc-loaded hydroxyapatite, or can be selected from at least one of fully vulcanized powdered rubber compound antibacterial agents.
The alpha-methylstyrene-maleic anhydride copolymer microspheres can be alpha-methylstyrene-maleic anhydride copolymer microspheres with uniform particle size and monodispersity.
The alpha-methylstyrene-maleic anhydride alternating copolymerization microsphere is prepared according to a preparation method disclosed in Chinese patent with the publication number of CN101580565A (with the application number of CN200910087181.5), and the molar ratio of maleic anhydride monomer to alpha-methylstyrene monomer is 4: 1-1: 4; the mass concentration of the total mass of the monomers in a dispersion polymerization reaction system is 1 to 50 percent. In the polymer microsphere dispersion system, the monodisperse microspheres have clean surfaces and controllable particle sizes. When the alpha-methyl styrene-maleic anhydride alternating copolymerization microspheres are used in the polypropylene/thermoplastic elastomer blend, the friction between the surfaces of polypropylene composition products and equipment can be effectively reduced, the adhesion and agglomeration among granules can be effectively prevented, the surface smoothness of the products can be improved, the deposition of dust on the surfaces of the products can be prevented, and the smooth plastic finished products can be produced; thereby improving the opening performance very remarkably. And compared with small molecular lubricants and opening agents, the lubricant has high melting temperature and is difficult to precipitate.
The alpha-methylstyrene-maleic anhydride alternating copolymerization microsphere can be prepared by a method comprising the following steps: under the protection of nitrogen, adding a monomer and an initiator into a medium for dissolving, reacting for 1/4-12 h at 60-90 ℃ to obtain a dispersion system of the alpha-methylstyrene and maleic anhydride polymer microspheres, and then performing centrifugal separation to obtain a white solid of the alternating copolymer of the alpha-methylstyrene and the maleic anhydride. The monomer is maleic anhydride and alpha-methyl styrene, the molar ratio of the maleic anhydride to the alpha-methyl styrene is 4: 1-1: 4, and the mass concentration of the monomer in a reaction system is 1-50%. The initiator is organic peroxide or azo compound, and the mass concentration of the initiator in the reaction system is 0.01-1%; the medium is a mixed solution of organic acid alkyl ester or ketone and alkane, wherein the volume fraction of the ketone in the mixed solution of the ketone and the alkane is 20-62.5%. The technical proposal of the method for copolymerization of alpha-methyl styrene and maleic anhydride disclosed in Chinese patent with publication number CN101580565A (application number CN200910087181.5) is introduced here.
The polypropylene/thermoplastic elastomer blend can also comprise an antioxidant, and the amount of the antioxidant can be 0.1-3 parts by weight based on 100 parts by weight of the polypropylene; the antioxidant can be at least one, preferably one or two, selected from antioxidant 1010, antioxidant 1076, antioxidant 2246, antioxidant CA, antioxidant 626 and antioxidant 636.
Another object of the present invention is to provide a process for preparing the polypropylene/thermoplastic elastomer blend, which comprises the steps of:
the polypropylene/maleic anhydride composite material is prepared by uniformly mixing the components including polypropylene, hydrogenated styrene-butadiene-styrene block copolymer, nucleating agent, antibacterial agent, antioxidant and alpha oxymethylstyrene-maleic anhydride copolymer microspheres according to the dosage, and melting and blending. The melt blend may be processed by granulation, drying, etc. as is common in the art.
Specifically, the preparation method may include the steps of:
mixing components including polypropylene, hydrogenated styrene-butadiene-styrene block copolymer, nucleating agent, antibacterial agent and alpha-methylstyrene-maleic anhydride copolymer microspheres in a high-speed stirrer for 0.5-5 minutes, setting the rotating speed of a motor to be 500-3000 rpm, mixing for 0.5-5 minutes at room temperature to obtain a uniform mixture, melting and blending through a double-screw extruder, and drawing, granulating and drying a melt through a die cutter to obtain the polypropylene/butadiene-styrene composite material. The melting temperature of the double-screw extruder can be set to be 210-230 ℃.
The reactor or the reaction equipment in the preparation method of the invention is the reactor or the reaction equipment which is common in the prior art.
The invention also aims to provide application of the polypropylene/thermoplastic elastomer blend in the fields of medical appliances, medical products, 3D printing and packaging.
The polypropylene/thermoplastic elastomer blend material has proper rigidity and flexibility, good transparency, smooth and clean surface, no adhesion and good antibacterial effect, and is particularly suitable for being applied to the fields of medical instruments and related packages.
Detailed Description
The present invention will be further described with reference to the following examples. However, the present invention is not limited to these examples.
[ Experimental Material sources ]
Polypropylene, B4908, manufactured by yanshan petrochemical company;
SEBS produced by Korotkam, USA;
silver-loaded zirconium phosphate, produced by Mianzhu chemical company;
oleamide, Crodamida VRX, manufactured by british procter;
silica, zheng zhou long and chemical limited;
antioxidant 1010, manufactured by basf corporation;
antioxidant 168, manufactured by basf corporation;
the preparation method of the alpha-methylstyrene-maleic anhydride copolymerized microsphere comprises the following steps: the molar ratio of maleic anhydride to alpha-methyl styrene is 1:1, wherein 0.6139g of maleic anhydride and 0.7387g of alpha-methyl styrene are contained; the initiator is AIBN, 0.0329 g; the medium is isoamyl acetate (40 mL), and the mixture is heated by a water bath and reacts for 6 hours at the temperature of 70 ℃ to obtain the alpha-methylstyrene-maleic anhydride copolymer microspheres.
[ examples 1 to 4 ] and comparative examples 1 to 3 ]
Preparation examples of Polypropylene/thermoplastic elastomer blends
Mixing polypropylene and an auxiliary agent in a high-speed stirrer according to a certain proportion, adding the mixture into a double-screw extruder, wherein the melting temperature is 210-250 ℃, and drawing the filaments through an oral die, cooling and granulating the filaments through a water tank.
The formulation is shown in table 1.
TABLE 1
[ test of physical Properties ]
After the pellets obtained in examples 1 to 4 and comparative examples 1 to 3 were fed to an injection molding machine to perform injection molding (the temperature of each stage of the injection molding machine was 180 ℃, 190 ℃, 210 ℃, 210 ℃, 200 ℃, 50MPa, 60s, and 10s), injection molded samples were prepared and tested for their properties.
Adding the modified polypropylene slices into a feed inlet of a multilayer extrusion casting machine, quenching the modified polypropylene slices on a cooling roll at 235 ℃, and carrying out traction forming to obtain a casting film with the thickness of 50 mu m, wherein the temperature of the cooling roll is set to be 30 ℃.
The physical property test of the sample is carried out according to the national standard: the flexural modulus was tested according to GB/T9341-; the impact strength of the notch of the simply supported beam is tested according to GB/T1043 + 1993; the optical properties were tested according to GB/T2410-80. The test results are shown in tables 2 and 3.
TABLE 2
| Flexural modulus (GPa) | Tensile Strength (MPa) | Impact Strength (kJ/m) 2 ) | |
| Comparative example 1 | 0.64 | 21.2 | 37.4 |
| Example 1 | 0.67 | 21.3 | 47.9 |
| Example 2 | 0.71 | 21.2 | 49.4 |
| Example 3 | 0.43 | 20.6 | 60.8 |
| Example 4 | 0.50 | 21.3 | 62.8 |
| Comparative example 2 | 0.68 | 22.1 | 42.3 |
| Comparative example 3 | 0.56 | 22.6 | 40.8 |
TABLE 3
| Haze (%) | Light transmittance (%) | Coefficient of dynamic friction | |
| Comparative example 1 | 5.6 | 92.4 | 0.26 |
| Example 1 | 3.2 | 92.6 | 0.24 |
| Example 2 | 3.1 | 93.5 | 0.11 |
| Example 3 | 2.1 | 92.5 | 0.16 |
| Example 4 | 2.2 | 92.6 | 0.14 |
| Comparative example 2 | 3.3 | 92.9 | 0.23 |
| Comparative example 3 | 3.2 | 93.5 | 0.17 |
Compared with the comparative example 1, the toughness of the material is increased, the optical performance is obviously improved, and the haze of the casting film is reduced after the maleic anhydride copolymer is added. The cast film friction coefficient was reduced compared to other opening agents (oleamide, silica), indicating improved opening performance. When the SEBS content reaches 40 parts, the modulus is greatly reduced, the opening performance is poorer and poorer, the use value is reduced, and a phase separation structure of polypropylene and SEBS possibly occurs due to the change of the phase structure.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the technical principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (15)
1. A polypropylene/thermoplastic elastomer blend comprising the following components in parts by weight:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
60-99 parts by mass of polypropylene; 1-40 parts by mass of hydrogenated styrene-butadiene-styrene block copolymer (SEBS);
0.1-1 parts by mass of alpha-methylstyrene-maleic anhydride copolymerized microspheres;
the alpha-methylstyrene-maleic anhydride copolymer microspheres are alpha-methylstyrene-maleic anhydride copolymer microspheres with uniform particle size and monodispersity;
the monomer molar ratio of the maleic anhydride to the alpha-methylstyrene in the alpha-methylstyrene-maleic anhydride copolymerized microsphere is 4: 1-1: 4.
2. The polypropylene/thermoplastic elastomer blend according to claim 1, characterized in that:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
65-99 parts by mass of polypropylene; 1-35 parts by mass of a hydrogenated styrene-butadiene-styrene block copolymer (SEBS); 0.2-0.7 parts of alpha-methylstyrene-maleic anhydride copolymer microspheres.
3. The polypropylene/thermoplastic elastomer blend according to claim 1, characterized in that:
the polypropylene/thermoplastic elastomer blend comprises a nucleating agent;
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the nucleating agent is used in an amount of 0.02-0.5 parts by mass.
4. The polypropylene/thermoplastic elastomer blend according to claim 3, characterized in that:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the nucleating agent is used in an amount of 0.03-0.3 parts by mass.
5. The polypropylene/thermoplastic elastomer blend according to claim 3, characterized in that:
the nucleating agent is selected from
3988、
NX TM 8000. At least one of Hyperform HPN-20E, VP101B, VP101T and VP 101E.
6. The polypropylene/thermoplastic elastomer blend according to claim 1, characterized in that:
the polypropylene/thermoplastic elastomer blend comprises an antimicrobial agent;
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the dosage of the antibacterial agent is 0.1-1 parts by mass.
7. The polypropylene/thermoplastic elastomer blend according to claim 6, characterized in that:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the dosage of the antibacterial agent is 0.3-0.8 parts by mass.
8. The polypropylene/thermoplastic elastomer blend according to claim 6, characterized in that:
the antibacterial agent is selected from at least one of silver-loaded zirconium phosphate, zinc-loaded zirconium phosphate, silver-loaded sodium zirconium phosphate, zinc-loaded sodium zirconium phosphate, silver-loaded fluorite, zinc-loaded fluorite, silver-loaded activated carbon, zinc-loaded activated carbon, silver-loaded copper phosphate, zinc-loaded copper phosphate, silver-loaded calcium phosphate, zinc-loaded calcium phosphate, silver-loaded silica gel, zinc-loaded silica gel, silver-loaded hydroxyapatite and zinc-loaded hydroxyapatite, or at least one of fully vulcanized powdered rubber compound antibacterial agents.
9. The polypropylene/thermoplastic elastomer blend according to claim 1, characterized in that:
the polypropylene/thermoplastic elastomer blend comprises an antioxidant,
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the using amount of the antioxidant is 0.1-3 parts by mass.
10. The polypropylene/thermoplastic elastomer blend according to claim 9, characterized in that:
based on 100 parts by weight of the total weight of the polypropylene and the hydrogenated styrene-butadiene-styrene block copolymer,
the using amount of the antioxidant is 0.1-1.5 parts by mass.
11. The polypropylene/thermoplastic elastomer blend according to claim 9, characterized in that:
the antioxidant is at least one selected from antioxidant 1010, antioxidant 168, antioxidant 1076, antioxidant 2246, antioxidant CA, antioxidant 626 and antioxidant 636.
12. The polypropylene/thermoplastic elastomer blend according to claim 11, characterized in that:
the antioxidant is one or two selected from antioxidant 1010, antioxidant 168, antioxidant 1076, antioxidant 2246, antioxidant CA, antioxidant 626 and antioxidant 636.
13. The polypropylene/thermoplastic elastomer blend according to any one of claims 1 to 12, wherein:
the melt index of the polypropylene is 2-6 g/10 min; and/or the presence of a gas in the gas,
the polypropylene is selected from at least one of homo-polypropylene, random co-polypropylene or impact co-polypropylene; and/or the presence of a gas in the gas,
the hydrogenated styrene-butadiene-styrene block copolymer has a linear structure.
14. The process for preparing a polypropylene/thermoplastic elastomer blend according to any one of claims 1 to 13, characterized in that it comprises:
the polypropylene/maleic anhydride copolymer composite material is prepared by uniformly mixing the components including polypropylene, hydrogenated styrene-butadiene-styrene block copolymer and alpha-methylstyrene-maleic anhydride copolymer microspheres according to the dosage, and carrying out melt blending.
15. Use of the polypropylene/thermoplastic elastomer blend according to any one of claims 1 to 13 or the blend prepared by the preparation method according to claim 14 in the fields of medical devices, medical products, 3D printing, packaging.
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