CN112703289A

CN112703289A - Press jacket, use thereof and press roll, shoe press and use of polyurethane for producing press jacket

Info

Publication number: CN112703289A
Application number: CN201980060271.7A
Authority: CN
Inventors: D.德尔马斯; H.雷彻特; M.沃库雷克; J.邹
Original assignee: Voith Patent GmbH
Current assignee: Voith Patent GmbH
Priority date: 2018-09-18
Filing date: 2019-07-11
Publication date: 2021-04-23
Also published as: WO2020057798A1; DE102018122782A1; JP2022501529A; JP7295245B2; EP3853412A1

Abstract

The invention relates to a press jacket comprising a plurality of polymer layers made of or comprising polyurethane, wherein the polyurethane is obtained by reacting isocyanate with polyol and a crosslinking agent, wherein a radially outermost polymer layer is provided with a view to the longitudinal axis of the press jacket and a radially inner polymer layer is provided with a view to the longitudinal axis of the press jacket, wherein the polyurethane of the radially outermost polymer layer comprises 1, 4-or 1, 3-bis (isocyanatomethyl) cyclohexane (H6XDI) as isocyanate, and the polyurethane of the radially inner polymer layer comprises 4,4' -diphenylmethane diisocyanate (MDI) as isocyanate, toluene 2, 4-diisocyanate (TDI) or mixtures thereof, polytetramethylene ether glycol (PTMEG) as polyol and 4 as crosslinking agent, 4' -methylenebis (3-chloro-2, 6-diethylaniline) (MCDEA), dimethylthiotoluenediamine (DMTDA), or mixtures thereof. Furthermore, the invention relates to a press roll, a shoe press and the use of a press jacket therein.

Description

Press jacket, use thereof and press roll, shoe press and use of polyurethane for producing press jacket

The invention is based on a press jacket for a press apparatus, in particular for treating a fibrous web, for example for calendering or dewatering thereof, in particular according to the independent claim. The invention also relates to a press roll, a shoe press and the use of a press jacket in such a press roll, in particular according to the accompanying independent claims.

Press equipment, such as shoe presses, have long been an integral part of modern paper machines. The press apparatus mainly comprises a fixedly arranged shoe (also called press shoe) extending in the cross-machine direction and a press jacket surrounding the fixed shoe. The latter is deformable and in operation substantially tubular. The shoe is shaped so that it forms a press nip with a mating roll. The press nip is defined by the contact surfaces of the mating rolls in the shoe. The shoe is designed to be movable and can be moved onto the mating roll.

The press sleeves are subject to great demands with regard to their stability, i.e. with regard to surface hardness, pressure resistance, temperature resistance and hydrolysis resistance. The press sleeves are also subjected to strong alternating bending loads during operation. When entering at the edge of the shoe (in front of the press nip seen in the direction of rotation of the press jacket), bending occurs initially over a relatively small radius. This bending immediately changes to a bending in the opposite direction when passing through the press nip. When exiting at the other shoe edge, i.e. after the press nip seen in the direction of rotation of the press jacket, a bending in the opposite direction occurs again. Such deformations of the press jacket on entry and exit are also referred to as alternating press zones. It is clear that the press jacket is easily broken, in particular at this location, due to the high mechanical stresses. Accordingly, a number of measures are known from the prior art which should increase the stability of the press jacket.

The press jacket must therefore be flexible enough to be guided around the shoe, rigid enough so that it does not deform or compress too severely in the nip under the press load, and wear resistant enough. The press jacket therefore consists of a single-layer or multi-layer polymer layer, preferably made of polyurethane, in which reinforcing threads in the form of a scrim or fabric can be embedded.

The invention relates to a solution of the type mentioned at the beginning.

The multi-layer press sleeves known in the prior art are prone to premature failure during normal operation due to the, usually only local, peeling of one of the polymer layers. In practice, this results in unplanned downtime of the press equipment, resulting in more costly downtime. In the operation of such press nips, local overloads can also occur in the press nip. This occurs in the case of foreign bodies passing through the nip in the so-called wet-stock covering process (batzenendurchgan). This overload also leads to this type of flaking.

The object of the invention is to provide a press jacket which avoids the disadvantages of the prior art. In particular, the peeling off of the individual polymer layers should be avoided, the service life of such press jackets should be increased and the downtime of press plants equipped with such press jackets should be reduced. The technical problem is also solved by a press roll, a shoe press and the use of a press jacket in such a press.

This object is achieved by the features of the independent claims. Particularly preferred and advantageous embodiments of the invention are given in the dependent claims.

The inventors have realized that when the individual polymer layers of the press jacket are combined according to the invention, flaking of the individual polymer layers can be avoided.

Since it has been shown that not only is it easier to produce, in particular, a multi-layer press jacket, by means of the polyurethanes according to the invention, but also improved properties are obtained, which also overcome the flaking off of the individual polymer layers. The two polymer layers lying one above the other are purposefully torn apart from one another in a peel test which shows a significantly greater resistance to peeling than previously known press sleeves. Surprisingly, tests have shown that the press jacket according to the invention simultaneously has an increased impact resistance. Thereby, damage caused by the wet material covering process can be reduced.

A press jacket according to the invention is understood to be a belt, a hose or a jacket which, as shown, is guided together with the fibrous web through the press nip of a shoe press. In order to dewater the fibrous web, the radially outermost surface (polymer layer) of the press jacket can be in contact with a press felt during normal operation, by means of which the fibrous web to be dewatered is directly supported. Depending on the embodiment of the press device, the press jacket can also be in direct contact with the fibrous web during normal operation, for example to calender the fibrous web. The press jacket is embodied here as a continuous, closed jacket (hose) in the circumferential direction about its longitudinal axis. The press jacket is open at its axial ends, viewed in the width direction (along the longitudinal axis). The press jacket can thus be fixed at said axial ends by two lateral chucks to form a shoe press roll. As in the case of open shoe presses, the press jacket can be guided over the press shoe and a plurality of guide rollers without having to be guided over two lateral chucks. The press shoe (or guide roll) will be in (temporary) contact with a portion of the radially innermost surface of the press jacket, whether or not the press jacket is guided by a chuck or guide roll. The radially outermost surface of such a press sleeve, i.e. for example the radially outermost polymer layer of the press sleeve, may be provided with grooves and/or blind holes.

The longitudinal direction is the direction extending parallel to the longitudinal axis of the press jacket. The longitudinal axis also corresponds to the axis of symmetry or rotation of the finished press jacket or roll. The circumferential direction of the press jacket extends around the longitudinal axis, viewed from the radial boundary of the press jacket. The term "parallel" also includes angular deviations of +/-5 deg. between two reinforcing wires located in different planes.

The press jacket or at least one of the polymer layers can be made partially or completely of a polymer. As polymers, use may be made here of pourable, curable, preferably elastomeric polymers, such as polyurethanes. Thus, the polymer may be provided as a cast elastomer.

By polymer layer is meant a layer comprising or entirely made of such a pourable, curable, preferably elastomeric, polymer. The polymer layer may be a cured layer that is preferably manufactured in one piece by a forming process. In other words, the polymer layer is integrally formed, i.e. for example produced by casting. The term "one-piece" also includes the case where this layer is in turn made of a plurality of layers of the same material when the polymer is cast. However, the extent to which these layers are substantially no longer visible after curing is limited, but rather a single, preferably uniform layer is formed. The same applies to the press jacket produced.

When a plurality of polymer layers are provided, these can be arranged one above the other, at least partially over the width of the press jacket, as seen in the radial direction. "at least partially over the width of the press jacket" means: the press jacket is, for example, only single-layered at its axial ends along the longitudinal axis of the press jacket, while it is constructed in two or more layers between the axial ends. However, it is also possible for a plurality of polymer layers to extend over the entire width of the press jacket. The thickness of the press jacket, and thus of the individual polymer layers, can also vary locally along the longitudinal axis in a cross section through its longitudinal axis. For example, the radially outermost polymer layer may be smaller in the widthwise edge regions of the press sleeve than in the center of the press sleeve. In other words, the thickness of the radially outermost polymer layer in the region of the width edge may be less than the thickness of the radially inner or radially innermost polymer layer. Preferably exactly one, two or three polymer layers are provided. The polymer layers may be identical in their polymers or the hardness of the polymer layers or the stoichiometry of the prepolymers may vary. The press sleeve produced may have a total thickness, measured in the radial direction in a section through the longitudinal axis, of 5 to 10mm, preferably 5 to 7mm, particularly preferably 5 to 6 mm. According to the invention, when only one layer is provided, the press sleeve can be made of only one casting, i.e. integrally, so that the only layer has the above-mentioned thickness.

A press jacket produced according to the invention is a press jacket in which at least one polymer layer is cured and possibly finally treated, i.e. for the purposes mentioned at the outset, for example in a shoe press. Similarly, the resulting polymer layer is referred to as the cured layer.

A reinforcing thread according to the invention is understood to be a flexible textile thread structure which has a predominant extent and homogeneity in its longitudinal direction.

According to the invention, the term "reinforcing structure" refers to a reinforcement of at least one layer comprising or consisting of a polymer (i.e. a polymer layer). The reinforcing structure can be completely embedded in the polymer layer, so that the reinforcing structure does not extend beyond the boundary of the polymer layer. In other words, the polymer layer functions as a matrix which surrounds the reinforcing structure and is bonded to the matrix due to adhesion or cohesion. Such reinforcing structures may comprise a textile thread structure, such as yarns or twisted threads, and/or a flat textile, such as a fabric, a knitted fabric, a weft-knitted fabric, a knit or a scrim, and may be produced from a corresponding raw material, for example by winding. In other words, the individual reinforcing threads according to the invention are themselves considered to be textile thread structures. A plurality of such reinforcing threads can be designed, for example, as longitudinal threads and/or circumferential threads, so that together they form a flat fabric. The at least one reinforcing thread embedded in the at least one polymer layer is then a reinforcing structure of the press jacket or of the polymer layer thereof.

The starting material is understood to be a material or a semi-finished product from which the reinforcing structure of the press jacket according to the invention can be produced. Thus, the reinforcing wire is the raw material of the reinforcing structure.

The definition that at least the longitudinal threads are produced as reinforcement threads according to the invention means that only the longitudinal threads are designed in this way or additionally the longitudinal threads and at least one further circumferential thread are produced in this way. If a scrim is present, preferably consisting of circumferential and longitudinal threads, for example, this means that at least the longitudinal threads are designed according to the invention.

According to the invention, a press device is, for example, a shoe press, for example for dewatering or treating, for example calendering, a fibrous web. The shoe press comprises a shoe press roll and a mating roll which together form or define a press nip. The shoe press roll also comprises a circulating press jacket and a stationary press element, the so-called press shoe. The latter is supported, for example by means of hydraulic press elements, on a likewise fixed carrier yoke and is pressed against the revolving press jacket. The press jacket runs around relative to the stationary press shoe and the yoke and is thus pressed against the mating roll in the nip. The press shoe and the yoke are radially arranged within the press jacket. The term "fixed" is understood to mean that the press element does not run around relative to the shoe press roll or the mating roll, but can move in a translatory manner towards and away from the mating roll, preferably in the radial direction thereof and thus relative to the mating roll. In addition to the fibrous web and the press jacket, one or more press felts running continuously around in the circumferential direction and/or other press belts running continuously around may also be guided through the press nip of the shoe press. Such a shoe press may of course comprise more than one press nip.

The fibrous web according to the invention is to be understood as meaning a scrim or entanglement of fibers, for example wood fibers, plastic fibers, glass fibers, carbon fibers, auxiliaries, additives or the like. For example, the fibrous web can be designed as a paper, cardboard or tissue web. It may comprise mainly wood fibres, wherein small amounts of other fibres or auxiliaries and additives may also be present. Depending on the use case, this will depend on the decisions of the skilled person.

If according to the invention it is made of a substance, for example, it means that it is made partly or completely of such a substance.

The invention also relates to a press roll, such as a shoe press roll, for a shoe press for dewatering a fibrous web, the press roll having at least one press jacket according to the invention.

The invention also relates to a shoe press for dewatering a fibrous web, preferably a paper, cardboard, tissue or cellulose web, comprising a press roll and a counter roll which together form or define a nip, said press roll comprising a rotating press jacket designed according to the invention.

The invention also relates to the use of a press jacket according to the invention for dewatering a fibrous web, preferably a paper, board, tissue or cellulose web, in a press, for example a shoe press.

Finally, the invention relates to the use of the composition according to the invention for press sleeves that can be produced therefrom.

The invention is explained in more detail below with reference to the drawings without limiting the generality. In the drawings:

fig. 1 shows a shoe press with a press jacket according to an embodiment of the invention in a schematic side view, partly in section;

fig. 2a and 2b each show an embodiment of the press jacket in a section through the longitudinal axis of the press jacket;

fig. 3 shows a very simplified schematic representation of a device for producing a press jacket in a side view.

Fig. 1 shows in a schematic side view, partly in section, a shoe press 10, which in the present case comprises press rolls according to the invention, such as a shoe press roll 12 and a mating roll 14. The shoe press roll 12 and the mating roll 14 are arranged with their longitudinal axes parallel to each other. Which together form a nip 22 or define the boundaries of such a nip.

The mating roll 14 consists here of a cylindrically designed roll rotating about its longitudinal axis, while the shoe press roll 12 consists of a press shoe 16, a stationary yoke 18 carrying the press shoe 16 and a press jacket 20. The press shoe 16 and the yoke 18 are arranged in a fixed manner with respect to the mating roll 14 or the press jacket 20, respectively. This means that the shoe and the yoke do not rotate. In this case, the press shoe 16 is supported by a yoke 18 and is pressed by a not shown hydraulic press element against the radially innermost surface of a press jacket 20 running round with respect to the press element. The press jacket 20, which surrounds the press shoe 16 and the yoke 18 in the circumferential direction, rotates about its longitudinal axis in the opposite rotational direction to the counter roll 14. A relatively long nip 22 is obtained due to the concave design of the press shoe 16 on its side facing the mating roll 14.

The shoe press 10 is particularly suitable for dewatering a fibrous web 24. When the shoe press is in operation, fibrous web 24 having one or two press felts 26, 26' is directed through press nip 22. In the present case, exactly two press felts 26, 26' sandwich the fibrous web 24 between them. When passing through nip 22, pressure is indirectly applied to fibrous web 24 in nip 22 by press felts 26, 26'. This occurs in such a manner that the radially outermost surface of mating roll 14 and the radially outermost surface of press jacket 20 are in direct contact with the respective press felts 26, 26'. Liquid drained from fibrous web 24 is absorbed instantaneously by one or both of the press felts 26, 26' and possibly depressions (not shown) provided in the press jacket surface. After leaving the press nip 22, the liquid absorbed in the depressions of the press jacket 20 is thrown away, whereafter the press jacket 20 re-enters the press nip 22. Additionally, water absorbed by the press felts 26, 26' may also be removed by the absorbent member after exiting the press nip 22.

In another embodiment of the invention, not shown in the figures, the press felts 26, 26' may be omitted. In this case, the fibrous web 24 is in direct contact with the press jacket 20 on one side and the mating roll 14 on the other side, which together form a press nip. The latter can then be designed as a heated drying cylinder.

As shown in the following figures, the press jacket shown in fig. 1 can be designed according to the invention.

Fig. 2a and 2b show different embodiments of the invention in a partial cross-section, not to scale, through the longitudinal axis 20' of the finished press jacket 20. The distance between the longitudinal axis 20' and the radially innermost surface of the respective polymer layer of the press sleeve 20 is also not shown to scale.

According to fig. 2a, exactly two polymer layers are provided, namely a first polymer layer 20.1 and a second polymer layer 20.2. In the present case, the first polymer layer 20.1 is also the radially outermost polymer layer of the press jacket 20. In contrast, the second polymer layer 20.2 is also the radially innermost polymer layer of the press jacket 20. The two polymer layers 20.1, 20.2, seen in the radial direction, directly adjoin one another, i.e. without an intermediate layer between them.

As shown, a reinforcing structure 20 "may be provided in the second polymer layer 20.2. In the present case, the reinforcing structure 20 "is completely embedded in the polymer layer 20.2. This is indicated by the shaded circles, which may be a flat fabric or a thread structure, such as a fiber. This means that the reinforcing structure 20 "does not extend beyond the boundary of the polymer layer 20.2.

The reinforcing structure 20 "here comprises a plurality of reinforcing threads 21 serving as longitudinal threads 21.1. These reinforcing threads are arranged spaced apart from one another in the longitudinal direction of the press jacket 20 over its circumference and extend parallel to one another. In addition, at least one further reinforcing thread 21 is provided as a circumferential thread 21.2, which preferably extends helically in the circumferential direction of the press jacket within the same polymer layer 20.1, 20.2, 20.3, in which polymer layer 20.1, 20.2, 20.3 a longitudinal thread 21.1 is also arranged. The longitudinal threads 21.1 and the circumferential threads 21.2 form a scrim with each other in such a way that the longitudinal threads 21.1 are arranged radially inside at least one circumferential thread 21.2, seen with reference to the longitudinal axis 20' of the press jacket 20.

In the present case, the first and second polymer layers 20.1, 20.2 are made of polyurethane. This can be obtained, for example, from a prepolymer and a crosslinking agent. Each prepolymer may be obtained by reacting an isocyanate with a polyol.

Figure 2b shows a three-layer press jacket different from that of figure 2 a. This comprises a first polymer layer 20.1, here the radially outermost layer, a third polymer layer 20.3, which is the radially innermost layer, and a second polymer layer 20.2 arranged in between. As shown in the illustration in fig. 2a, the arrangement relates to the press jacket 20, viewed from its longitudinal axis 20' in the radial direction. In the present case, a (single) reinforcing structure 20 ″ is provided only in the second polymer layer 20.2. Of course, this can also be different, so that alternatively or additionally such a reinforcing structure 20 "can also be arranged in the first polymer layer 20.1 and/or the third polymer layer 20.3.

It has been shown that the preferred embodiments according to the invention can be realized particularly well: in one aspect, the polyurethane of the radially outermost polymer layer 20.1 has 1, 4-or 1, 3-bis (isocyanatomethyl) cyclohexane (H6XDI) as isocyanate. On the other hand, the polyurethane of the radially inner (or innermost) polymer layer 20.2 contains 4,4 '-diphenylmethane diisocyanate (MDI), toluene-2, 4-diisocyanate (TDI) or a mixture thereof as an isocyanate, and polytetramethylene ether glycol (PTMEG) as a polyol and 4,4' -methylenebis (3-chloro-2, 6-diethyldiethylamine) (MCDEA), dimethylthiotoluenediamine (DMTDA) or a mixture thereof as a crosslinking agent.

Fig. 3 shows a device for producing a press jacket 20 according to the invention in a very schematic side view. In the present case, the device has exactly one cylindrical winding mandrel 4, wherein, for example, a starting material 20' ″ is applied helically to the radially outermost circumferential surface of the winding mandrel. After embedding in the polymer, the raw material 20 "' forms the reinforcing structure 20" of the press jacket 20 made according to the invention.

The figure shows an initial stage of the manufacturing method. For this purpose, in the present case, this one end of the raw material 20 "' is fixed on the polymer arranged on the outer circumference of the winding mandrel 4. In addition to the schematic illustration shown, the one end of the starting material 20 "'can also be placed or applied directly, i.e. next to, on the winding mandrel 4 without the polymer initially being arranged between the starting material 20"' and the winding mandrel 4. The raw material 20 "' may here be a flat fabric or a thread structure.

The winding mandrel 4 is mounted rotatably about its longitudinal axis 20', which longitudinal axis 20' corresponds to the longitudinal axis of the press jacket to be produced. The longitudinal axis 20' extends perpendicular to the drawing plane. A casting material, for example a pourable, curable, elastomeric polymer, for example polyurethane, is applied from above via a line 5 through a casting nozzle 6 onto the radially outermost circumferential surface of the winding mandrel 4 or onto the starting material 20' ″. Such a casting material can be selected, for example, in terms of its pot life and viscosity, such that it does not drip off the winding mandrel 4 during casting. At the same time, the winding mandrel 4 rotates about its longitudinal axis in the direction of the arrow. At the same time as this rotation, the pouring nozzle 6 is guided by suitable guide means, not shown in any further detail in fig. 3, parallel to the longitudinal axis 20' of the winding mandrel, relative to the winding mandrel 4. At the same time as the casting material is poured, the raw material 20 "' is unwound and wound onto the rotating winding mandrel 4 to form a winding. Here, the casting compound can pass through the starting material 20' ″ to the winding mandrel 4. In this example, after the curing step, the polymer forms the radially innermost and preferably elastomeric polymer layer, which corresponds to the polymer layer 20.2 of the press jacket of fig. 2a, only a part of which is shown in fig. 3.

The casting material discharged from the casting nozzle 6 is in this case a mixture of prepolymer and crosslinking agent, the former being supplied from a prepolymer container, not shown, in which the prepolymer is stored or stirred. The prepolymer is the reaction product of an isocyanate and a polyol according to the present invention. In the prepolymer vessel, it may be present, for example, in the form of a prepolymer made from the above-mentioned materials.

The crosslinking agent may be provided in a crosslinking agent container.

The prepolymer container and the crosslinking agent container are associated with an apparatus for manufacturing the press jacket 20. They are fluidically connected via lines, also not shown, to a mixing chamber (not shown) upstream of the pouring nozzle 6 in the flow direction. The prepolymer-crosslinker mixture is thus produced upstream of the pouring nozzle 6 and outside, i.e. mixed in a mixing chamber. Regardless of how the mixture is made, the mixture is then applied to the surface of the winding mandrel 4 to form at least one polymer layer of the press jacket 20.

In principle, it is conceivable to provide two or more pouring nozzles 6. They can be connected to separate prepolymer and crosslinker containers by means of corresponding lines, in order to also feed polymers which differ from one another independently of one another into a plurality of pouring nozzles 6. The casting nozzles 6 can then be arranged at a distance from one another along the longitudinal axis of the press jacket 20 in order to produce a plurality of polymer layers 20.1, 20.2, 20.3 simultaneously in one casting by simultaneously discharging the polymer from the casting nozzles 6.

By means of this continuous casting process, known as spin casting, a continuous, cylindrical tubular press jacket 20 closed about the longitudinal axis 20' of the winding mandrel is produced gradually over the width of the winding mandrel 4, the inner circumference of which press jacket corresponds essentially to the outer circumference of the winding mandrel 4.

In principle, it is conceivable to wind the starting material 20' ″ around more than one winding mandrel 4 as shown in fig. 3. For example, two winding mandrels can be provided, which can be arranged with their longitudinal axes parallel at a distance from one another. Alternatively, it is also conceivable to apply the polymer to the radially inner circumferential surface of the winding mandrel 4, for example in a cast manner. Regardless of the embodiment mentioned, the finished press jacket 20 is finally removed from the at least one winding mandrel 4.

As shown in fig. 3, a press jacket 20 is designed according to the present invention.

Although not shown in the figures, the reinforcing structure 20 "of at least one polymer layer 20.1, 20.2 may also consist of a plurality of raw materials 20'" stacked in the radial direction extending in the direction of the longitudinal axis and in the circumferential direction of the press jacket 20, respectively.

Claims

1. Press jacket comprising a plurality of polymer layers (20.1, 20.2, 20.3), the plurality of polymer layers (20.1, 20.2, 20.3) being made of polyurethane or comprising such polyurethane, wherein the polyurethane is obtained by reaction of isocyanate with polyol and a crosslinking agent, wherein there is provided a radially outermost polymer layer (20.1) seen with reference to the longitudinal axis (20') of the press jacket (20) and a radially inner polymer layer (20.2) seen with reference to the longitudinal axis (20') of the press jacket (20), wherein the polyurethane of the radially outermost polymer layer (20.1) comprises 1, 4-or 1, 3-bis (isocyanatomethyl) cyclohexane (H6XDI) as isocyanate and the polyurethane of the radially inner polymer layer (20.2) comprises 4,4' -diphenylmethane diisocyanate (MDI) as isocyanate, Toluene 2, 4-diisocyanate (TDI) or mixtures thereof, polytetramethylene ether glycol (PTMEG) as a polyol and 4,4' -methylenebis (3-chloro-2, 6-diethylaniline) (MCDEA), dimethylthiotoluenediamine (DMTDA) or mixtures thereof as a crosslinker.

2. Press sleeve according to claim 1, characterised in that the polyurethane of the radially inner polymer layer (20.2) comprises 4,4' -diphenylmethane diisocyanate (MDI) as isocyanate, polytetramethylene ether glycol (PTMEG) as polyol and 4,4' -methylenebis (3-chloro-2, 6-diethylaniline) (MCDEA), dimethylthiotoluenediamine (DMTDA) as cross-linking agent, or that the polyurethane of the radially inner polymer layer (20.2) comprises toluene-2, 4-diisocyanate (TDI) as isocyanate, polytetramethylene ether glycol (PTMEG) as polyol and 4,4' -dimethylthiotoluenediamine (DMTDA) as cross-linking agent.

3. Press jacket according to claim 1 or 2, characterised in that the isocyanate and the polyol are reacted with a prepolymer.

4. Press jacket according to one of the claims 1 to 3, a reinforcing structure (20 ") being embedded in at least one polymer layer, wherein the reinforcing structure (20") comprises at least one reinforcing thread (21).

5. Press jacket according to claim 4, characterized in that the at least one reinforcing thread (21) is designed as a longitudinal thread (21.1) extending in the longitudinal direction of the press jacket (20).

6. Press jacket according to claim 5, characterized in that a plurality of reinforcement threads (21) are designed as longitudinal threads (21.1), which longitudinal threads (21.1) are arranged to run mutually spaced and parallel on the circumference of the press jacket in the longitudinal direction of the press jacket (20).

7. Press jacket according to one of the claims 4 to 6, characterized in that at least one further reinforcing thread (21) is designed as a circumferential thread (21.2), which circumferential thread (21.2) preferably extends helically inside the polymer layer (20.1, 20.2, 20.3) in the circumferential direction of the press jacket.

8. Press jacket according to claims 6 and 7, characterized in that the reinforcing threads (21) implemented as longitudinal threads (21.1) and the at least one further reinforcing thread (21) implemented as circumferential threads (21.2) form a scrim with each other, preferably such that the longitudinal threads (21.1) are arranged radially inside the at least one circumferential thread (21.2) seen with reference to the longitudinal axis (20') of the press jacket.

9. Press jacket according to claim 8, characterised in that the longitudinal threads (21.1) are spaced apart from the at least one circumferential thread (21.2) in the radial direction at an intersection point, seen in the radial direction of the press jacket (20).

10. Press jacket according to one of the preceding claims, characterised in that a plurality of polymer layers are provided, and that at least one polymer layer (20.1, 20.2, 20.3) is the radially outermost polymer layer (20.1) seen with reference to the longitudinal axis (20') of the press jacket (20), and that a further polymer layer (20.2) is additionally provided which is radially inner seen with reference to the longitudinal axis (20') of the press jacket (20).

11. Press sleeve according to claim 10, characterised in that exactly two polymer layers (20.1, 20.2) are provided and that the radially inner polymer layer (20.2) is simultaneously the radially innermost polymer layer of the press sleeve (20).

12. A press roll, such as a shoe press roll (12) of a shoe press (10) for treating a fibrous web (24), characterized in that the press roll has at least one press jacket (20) according to one of the preceding claims.

13. Shoe press (10) for treating a fibrous web (24), preferably a paper, cardboard, tissue or cellulose web, comprising a press roll and a mating roll (14), which together form or define a press nip (22), wherein the press roll comprises a surrounding press jacket, characterized in that the press jacket (20) is designed according to one of claims 1 to 11.

14. Use of a press jacket (20) according to one of claims 1 to 11 for a press, such as a shoe press (10), for treating a fibrous web (24), preferably a paper, cardboard, tissue or cellulose web.

15. Use of polyurethane for producing a press jacket, preferably according to one of claims 1 to 11, wherein the press jacket comprises a plurality of polymer layers (20.1, 20.2, 20.3), wherein the plurality of polymer layers (20.1, 20.2, 20.3) are made of polyurethane or comprise such polyurethane, wherein the polyurethane is obtained by reaction of isocyanate with polyol and a crosslinking agent, wherein a radially outermost polymer layer (20.1) is provided, viewed with reference to the longitudinal axis (20') of the press jacket (20), and a radially inner polymer layer (20.2) is provided, viewed with reference to the longitudinal axis (20') of the press jacket (20), wherein the polyurethane of the radially outermost polymer layer (20.1) comprises 1, 4-or 1, 3-bis (isocyanatomethyl) cyclohexane (H6XDI) as isocyanate, and the polyurethane of the radially inner polymer layer (20.2) comprises 4 as isocyanate, 4 '-diphenylmethane diisocyanate (MDI), toluene 2, 4-diisocyanate (TDI) or mixtures thereof, polytetramethylene ether glycol (PTMEG) as polyol and 4,4' -methylenebis (3-chloro-2, 6-diethylaniline) (MCDEA), dimethylthiotoluenediamine (DMTDA) or mixtures thereof as crosslinker.