CN112694537A - Preparation method of oxidized nanocellulose - Google Patents
Preparation method of oxidized nanocellulose Download PDFInfo
- Publication number
- CN112694537A CN112694537A CN202011525354.XA CN202011525354A CN112694537A CN 112694537 A CN112694537 A CN 112694537A CN 202011525354 A CN202011525354 A CN 202011525354A CN 112694537 A CN112694537 A CN 112694537A
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- CN
- China
- Prior art keywords
- cellulose
- mass
- oxidized
- pulp
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229920001046 Nanocellulose Polymers 0.000 title claims description 28
- 239000001913 cellulose Substances 0.000 claims abstract description 167
- 229920002678 cellulose Polymers 0.000 claims abstract description 147
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000006243 chemical reaction Methods 0.000 claims abstract description 46
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 117
- 239000000243 solution Substances 0.000 claims description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 239000007864 aqueous solution Substances 0.000 claims description 29
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 28
- 239000012634 fragment Substances 0.000 claims description 25
- 239000002994 raw material Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 24
- 239000000725 suspension Substances 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 23
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- 239000008367 deionised water Substances 0.000 claims description 17
- 229910021641 deionized water Inorganic materials 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 230000007935 neutral effect Effects 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 15
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 238000000967 suction filtration Methods 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- 238000012544 monitoring process Methods 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 239000005708 Sodium hypochlorite Substances 0.000 abstract description 3
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000007086 side reaction Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 235000010980 cellulose Nutrition 0.000 description 81
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 32
- 229920001131 Pulp (paper) Polymers 0.000 description 9
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 7
- 235000017491 Bambusa tulda Nutrition 0.000 description 7
- 241001330002 Bambuseae Species 0.000 description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 7
- 239000011425 bamboo Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000706 filtrate Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000005070 sampling Methods 0.000 description 5
- 239000010902 straw Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202011525354.XA CN112694537B (en) | 2020-12-22 | 2020-12-22 | Preparation method of oxidized nanocellulose |
Applications Claiming Priority (1)
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CN202011525354.XA CN112694537B (en) | 2020-12-22 | 2020-12-22 | Preparation method of oxidized nanocellulose |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112694537A true CN112694537A (en) | 2021-04-23 |
CN112694537B CN112694537B (en) | 2022-11-22 |
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Family Applications (1)
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CN202011525354.XA Active CN112694537B (en) | 2020-12-22 | 2020-12-22 | Preparation method of oxidized nanocellulose |
Country Status (1)
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CN (1) | CN112694537B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113908078A (en) * | 2021-11-29 | 2022-01-11 | 水木山海科技(佛山)有限责任公司 | Toothpaste gel and preparation method thereof |
CN113999322A (en) * | 2021-12-03 | 2022-02-01 | 青岛大学 | Low-energy-consumption preparation method of tempo oxidized cellulose with high carboxyl content |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103255663A (en) * | 2013-05-27 | 2013-08-21 | 江南大学 | Method for improving efficiency of catalytically oxidizing cellulose by tetramethyl piperidine through pre-treatment |
WO2015137888A1 (en) * | 2014-03-12 | 2015-09-17 | Kemijski Institut | Method for the production of nanocrystalline cellulose |
CN108659135A (en) * | 2018-05-29 | 2018-10-16 | 南京林业大学 | A kind of cellulose nano-fibrous or chitin nanofiber dispersion liquid preparation method |
CN109053906A (en) * | 2018-09-10 | 2018-12-21 | 北京理工大学 | A kind of preparation method of nano-cellulose fiber dry powder |
-
2020
- 2020-12-22 CN CN202011525354.XA patent/CN112694537B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103255663A (en) * | 2013-05-27 | 2013-08-21 | 江南大学 | Method for improving efficiency of catalytically oxidizing cellulose by tetramethyl piperidine through pre-treatment |
WO2015137888A1 (en) * | 2014-03-12 | 2015-09-17 | Kemijski Institut | Method for the production of nanocrystalline cellulose |
CN108659135A (en) * | 2018-05-29 | 2018-10-16 | 南京林业大学 | A kind of cellulose nano-fibrous or chitin nanofiber dispersion liquid preparation method |
CN109053906A (en) * | 2018-09-10 | 2018-12-21 | 北京理工大学 | A kind of preparation method of nano-cellulose fiber dry powder |
Non-Patent Citations (2)
Title |
---|
ARUN SAINI等: ""Mixed-Acid-Assisted Hydrothermal Process for Simultaneous Preparation and Carboxylation of Needle-Shaped Cellulose Nanocrystals"", 《ACS APPL. POLYM. MATER.》 * |
BIN LI等: ""Cellulose nanocrystals prepared via formic acid hydrolysis followed by TEMPO-mediated oxidation"", 《CARBOHYDRATE POLYMERS》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113908078A (en) * | 2021-11-29 | 2022-01-11 | 水木山海科技(佛山)有限责任公司 | Toothpaste gel and preparation method thereof |
CN113999322A (en) * | 2021-12-03 | 2022-02-01 | 青岛大学 | Low-energy-consumption preparation method of tempo oxidized cellulose with high carboxyl content |
Also Published As
Publication number | Publication date |
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CN112694537B (en) | 2022-11-22 |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230505 Address after: Room 208, 2nd Floor, Building A, No. 92 Suiyan West Road, Dali Town, Nanhai District, Foshan City, Guangdong Province, 528200 Patentee after: Guangdong Qingfo Industry Investment and Development Co.,Ltd. Patentee after: Luo Yidong Address before: 1101, 14th floor, No. 8, area a, Hantian science and Technology City, No. 17, Shenhai Road, Guicheng Street, Nanhai District, Foshan City, Guangdong Province, 528200 Patentee before: Foshan (South China) New Material Research Institute |
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Effective date of registration: 20230629 Address after: 528200 309, 311 and 313, third floor, block B, No. 92, Hexi section, Suiyan Road, Yanbu Town, Dali Town, Nanhai District, Foshan City, Guangdong Province (residence declaration) Patentee after: Shuimu Shanhai Technology (Foshan) Co.,Ltd. Address before: Room 208, 2nd Floor, Building A, No. 92 Suiyan West Road, Dali Town, Nanhai District, Foshan City, Guangdong Province, 528200 Patentee before: Guangdong Qingfo Industry Investment and Development Co.,Ltd. Patentee before: Luo Yidong |
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TR01 | Transfer of patent right |
Effective date of registration: 20240504 Address after: Room 405, Building 12, No. 3 Shengxi Road, Kunshan Development Zone, Suzhou City, Jiangsu Province, 215300 Patentee after: Kunshan Shuimu Yuankun Technology Co.,Ltd. Country or region after: China Address before: 528200 309, 311 and 313, third floor, block B, No. 92, Hexi section, Suiyan Road, Yanbu Town, Dali Town, Nanhai District, Foshan City, Guangdong Province (residence declaration) Patentee before: Shuimu Shanhai Technology (Foshan) Co.,Ltd. Country or region before: China |