CN112646283A - Dual-ion composite anti-dust-deposition antibacterial material for cross-flow fan of indoor unit of air conditioner, and application and preparation method thereof - Google Patents
Dual-ion composite anti-dust-deposition antibacterial material for cross-flow fan of indoor unit of air conditioner, and application and preparation method thereof Download PDFInfo
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- CN112646283A CN112646283A CN202011433051.5A CN202011433051A CN112646283A CN 112646283 A CN112646283 A CN 112646283A CN 202011433051 A CN202011433051 A CN 202011433051A CN 112646283 A CN112646283 A CN 112646283A
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 129
- 239000000463 material Substances 0.000 title claims abstract description 116
- 239000002131 composite material Substances 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 68
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002216 antistatic agent Substances 0.000 claims abstract description 33
- 239000002270 dispersing agent Substances 0.000 claims abstract description 24
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 23
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 239000011256 inorganic filler Substances 0.000 claims abstract description 20
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 20
- 239000004033 plastic Substances 0.000 claims abstract description 20
- 229920003023 plastic Polymers 0.000 claims abstract description 20
- 239000000428 dust Substances 0.000 claims description 44
- 229910052709 silver Inorganic materials 0.000 claims description 30
- 239000004332 silver Substances 0.000 claims description 30
- -1 silver ions Chemical class 0.000 claims description 29
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
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- 238000002156 mixing Methods 0.000 claims description 14
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- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 7
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
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- 150000002500 ions Chemical class 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 claims description 3
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940123208 Biguanide Drugs 0.000 claims description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 239000001506 calcium phosphate Substances 0.000 claims description 3
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- 235000011010 calcium phosphates Nutrition 0.000 claims description 3
- 238000011068 loading method Methods 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000011248 coating agent Substances 0.000 abstract description 16
- 238000000576 coating method Methods 0.000 abstract description 15
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
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- 241000894006 Bacteria Species 0.000 description 4
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
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- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
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- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000883990 Flabellum Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
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- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
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- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
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- 239000002105 nanoparticle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
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- 238000004088 simulation Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a dual-ion composite antibacterial anti-dust-deposition material for a cross-flow fan of an indoor unit of an air conditioner, and an application and a preparation method thereof, wherein the dual-ion composite antibacterial anti-dust-deposition material comprises the following components: 60-90 parts by weight of a plastic base material; 0.1-3 parts by weight of a silver-zinc composite antibacterial agent; 0.4-0.8 weight parts of organic antibacterial agent; 1-35 parts by weight of a long-acting antistatic agent; 1-6 parts by weight of a dispersant; 10-35 parts by weight of an inorganic filler; and 0.1-1 part by weight of an antioxidant. Therefore, the dual-ion composite antibacterial and dust-deposition-preventing material has good mechanical performance, ideal antibacterial and mildew-proof performance and dust-deposition-preventing performance, can be directly used for preparing the fan blade of the cross-flow fan of the indoor unit of the air conditioner, further eliminates the use defect of the existing antibacterial coating, obviously improves the production efficiency of the fan blade, reduces the production cost and improves the antibacterial durability.
Description
Technical Field
The invention belongs to the field of materials, and particularly relates to a diionic composite antibacterial and dust-deposition-preventing material, and an application and a preparation method thereof.
Background
For products such as air conditioning fans, consumers are more concerned about the cleanliness and health of indoor air during the use of air conditioners. Meanwhile, with the rise of living standard, young people gradually become the dominant force of air conditioner consumption, and higher requirements are provided for air quality and air health in the using process of the air conditioner.
Indoor unit cross-flow fan is AS the air conditioner indoor air conditioning air supply source, mainly adds glass reinforcing for the AS material at present and makes, produces the dust easily and piles up in long-term use, and then the phenomenon that breed and go mildy of bacterium appear at the fan blade, leads to the air conditioner to blow out the wind to have the peculiar smell, seriously influences the cleanness and the health of indoor air, uses probably to cause respiratory disease to take place for a long time. And the cross-flow fan is positioned in the air conditioner, so that a user is not easy to disassemble and clean, and the traditional self-cleaning method only can be carried out on the heat exchanger and cannot clean the fan. Therefore, the application of the anti-bacterial technology to the cross-flow fan reduces the bacterial growth and the mildew of the fan and improves the air health in the use of the air conditioner.
The Ag + antibacterial agent mainly used in the current antibacterial product can be directly Ag + release type, and can be Ag + loaded to carriers such as molecular sieve, phosphate and the like, slow release type, AgO type, nano silver and the like. However, silver ions are aged under the conditions of illumination and the like, so that the color of the product becomes dark, the antibacterial performance is reduced, and the antibacterial weather resistance and the antibacterial long-acting performance are limited to a certain extent. In addition, the existing antibacterial fan is mainly added in a coating form, and has the following problems: 1. because the limited color of the coating agent is relatively single, the individual selection cannot be carried out; 2. special equipment and tooling are required for supporting, so that the cost is relatively high; 3. the antibacterial coating only stays on the surface of the fan material, the antibacterial effect of the uncovered area of the coating is poor, and the antibacterial durability is limited.
Therefore, the antibacterial materials used for products such as cross-flow fans of indoor units of air conditioners are required to be further improved.
Disclosure of Invention
The present invention is directed to solving, at least to some extent, one of the technical problems in the related art. Therefore, one purpose of the invention is to provide a dual-ion composite antibacterial and anti-dust material, and an application and a preparation method thereof, wherein the dual-ion composite antibacterial and anti-dust material has good mechanical properties, ideal antibacterial and mildew-proof properties and an anti-dust advantage, can be directly used for preparing blades of a cross-flow fan of an indoor unit of an air conditioner, further eliminates the use defects of the existing antibacterial coating, remarkably improves the production efficiency of the blades, reduces the production cost and improves the antibacterial durability.
According to one aspect of the invention, the invention provides a dual-ion composite antibacterial and anti-dust-deposition material for a cross-flow fan of an indoor unit of an air conditioner, which comprises the following components in part by weight: 60-90 parts by weight of a plastic base material; 0.1-3 parts by weight of a silver-zinc composite antibacterial agent; 0.4-0.8 weight parts of organic antibacterial agent; 1-35 parts by weight of a long-acting antistatic agent; 1-6 parts by weight of a dispersant; 10 to 35 parts by weight of an inorganic filler and 0.1 to 1 part by weight of an antioxidant.
Therefore, the double-ion composite antibacterial and anti-dust-deposition material adopts the silver-zinc double ions as effective antibacterial active ingredients, so that the aim of better synergistic antibacterial effect is achieved on one hand, and on the other hand, the stability of the antibacterial effect of the silver ions can be effectively improved by adding the zinc ions, and the problems of darkening of the color of a product and reduction of the antibacterial effect caused by reduction and oxidation of the silver ions in the using process are solved. In addition, the long-acting antistatic agent can effectively reduce the dust accumulation on the surface of the fan blade caused by static electricity, so that the cleanliness of the fan blade is improved, and the bacterial breeding can be avoided.
More importantly, the final material has good mechanical property and antibacterial, antiseptic and antistatic properties by optimizing the proportion of the components. The dual-ion composite antibacterial and dust-deposition-preventing material can be directly used for preparing the fan blades of the cross-flow fan of the indoor unit of the air conditioner, so that an antibacterial coating is completely replaced, the use defect of the antibacterial coating is thoroughly eliminated, the production efficiency of the fan blades is obviously improved, and the production cost is reduced; and the integral fan blade is made of antibacterial and antistatic materials, so that the antibacterial durability can be obviously improved, and the service life can be prolonged.
In addition, the dual-ion composite antibacterial and anti-dust-deposition material according to the above embodiment of the present invention may further have the following additional technical features:
according to some embodiments of the invention, the plastic substrate is AS.
According to some embodiments of the present invention, the silver-zinc composite antibacterial agent is an antibacterial agent formed after silver ions and zinc ions are supported on zeolite, water-soluble glass, or calcium phosphate.
According to some embodiments of the present invention, the mass ratio of silver ions to zinc ions in the silver-zinc composite antibacterial agent is 1: (0.1-100).
According to some embodiments of the present invention, the organic antibacterial agent is at least one selected from the group consisting of SLM-04, quaternary ammonium salt type antibacterial mildewcide, and biguanide type antibacterial mildewcide.
According to some embodiments of the invention, the long-acting antistatic agent is at least one selected from the group consisting of antistatic agents TM, octadecyl diethanolamine, PEG, methyl acrylate, polyethylene oxide, and polyether ester amide.
According to some embodiments of the invention, the dispersant is at least one selected from the group consisting of CH-10S, ST-278, polyethylene wax, and stearic acid.
According to some embodiments of the invention, the inorganic filler is long glass fibers, which have been previously treated with a silane coupling agent.
According to some embodiments of the invention, the antioxidant is at least one selected from the group consisting of antioxidant 1010, antioxidant 168, and antioxidant 618.
According to another aspect of the invention, the invention further provides a fan, and according to an embodiment of the invention, fan blades of the fan are prepared from the dual-ion composite antibacterial and dust-deposition-preventing material described in the previous embodiment.
According to a further aspect of the present invention, there is also provided an air conditioner having the fan according to the previous embodiment, according to an embodiment of the present invention.
According to a further aspect of the present invention, the present invention also provides a method for preparing the diionic composite antibacterial and anti-dust material according to the previous embodiment, the method according to an embodiment of the present invention comprises:
(1) adding a plastic substrate, a silver-zinc composite antibacterial agent, an organic antibacterial agent, a dispersing agent, an inorganic filler, an antioxidant and a long-acting antistatic agent into a single-screw or double-screw extruder according to a predetermined proportion, and heating and mixing to obtain a mixed material;
(2) and cooling the mixed material to room temperature by water, drying and granulating so as to obtain the diionic composite antibacterial anti-dust material.
Detailed Description
The following detailed description of embodiments of the invention is intended to be illustrative, and is not to be construed as limiting the invention.
According to one aspect of the invention, the invention provides a dual-ion composite antibacterial and anti-dust-deposition material for a cross-flow fan of an indoor unit of an air conditioner, which comprises the following components in part by weight: 60-90 parts by weight of a plastic base material; 0.1-3 parts by weight of a silver-zinc composite antibacterial agent; 0.4-0.8 weight parts of organic antibacterial agent; 1-6 parts by weight of a dispersant; 10-35 parts by weight of an inorganic filler; 0.1 to 1 part by weight of an antioxidant; and 1-35 parts by weight of a long-acting antistatic agent.
Therefore, the double-ion composite antibacterial and anti-dust-deposition material adopts the silver-zinc double ions as effective antibacterial active ingredients, so that the aim of better synergistic antibacterial effect is achieved on one hand, and on the other hand, the stability of the antibacterial effect of the silver ions can be effectively improved by adding the zinc ions, and the problems of darkening of the color of a product and reduction of the antibacterial effect caused by reduction and oxidation of the silver ions in the using process are solved. In addition, the long-acting antistatic agent can effectively reduce the dust accumulation on the surface of the fan blade caused by static electricity, so that the cleanliness of the fan blade is improved, and the bacterial breeding can be avoided.
More importantly, the final material has good mechanical property and antibacterial, antiseptic and antistatic properties by optimizing the proportion of the components. The dual-ion composite antibacterial and dust-deposition-preventing material can be directly used for preparing the fan blades of the cross-flow fan of the indoor unit of the air conditioner, so that an antibacterial coating is completely replaced, the use defect of the antibacterial coating is thoroughly eliminated, the production efficiency of the fan blades is obviously improved, and the production cost is reduced; and the integral fan blade is made of antibacterial and antistatic materials, so that the antibacterial durability can be obviously improved, and the service life can be prolonged.
The following describes the dual-ion composite antibacterial anti-dust material according to the embodiment of the present invention.
According to the above-mentioned embodiments of the present invention, the plastic substrate can be an AS (acrylonitrile-styrene resin). And the plastic base material is used as the base material, and the dosage of the plastic base material can be 60-90 parts by weight, so that the basic mechanical properties of the material, such as rigidity, hardness, toughness and the like, can be ensured. According to the specific embodiment of the invention, the usage amount of the plastic base material is preferably 60-80 parts by weight, so that the material can better meet the mechanical performance requirements of the cross-flow fan blade of the indoor unit of the air conditioner by matching with other components.
According to a specific embodiment of the present invention, the silver-zinc composite antibacterial agent is an antibacterial agent formed by loading silver ions and zinc ions on zeolite, water-soluble glass or calcium phosphate. Therefore, the antibacterial effect can be further improved by using the silver ions and the zinc ions together, the stability of the antibacterial effect of the silver ions can be effectively improved by using the zinc ions, and the situations that the color of a product is darkened and the antibacterial effect is reduced due to reduction and oxidation in the use process of the silver ions are reduced.
According to a specific embodiment of the present invention, the silver-zinc composite antibacterial agent is an antibacterial agent formed by loading silver ions and zinc ions on water-soluble glass. The silver-zinc composite antibacterial agent prepared by using the water-soluble glass as the carrier has high transparency and stable and long-acting ion release rate, so that the stability of the antibacterial effect can be further improved. Meanwhile, the method has the characteristic of low addition ratio, and is favorable for reducing the reduction of mechanical property of the fan material caused by the addition of the antibacterial agent.
According to the specific embodiment of the invention, the mass ratio of the silver ions to the zinc ions in the silver-zinc composite antibacterial agent is 1: (0.1-100). The inventor finds that the mechanical and thermal properties of the fan material can be better maintained while the better antibacterial effect is ensured by adopting the preferable proportion. The inventors have also found that if the amount of zinc ions is too large relative to the amount of silver ions, the antibacterial effect of the fan material is greatly reduced. On the contrary, if the amount of zinc ions is too small relative to silver ions, the synergistic effect of zinc ions and silver ions is reduced, silver ions are easily reduced and re-oxidized, the fan product is easily darkened, and the discoloration resistance and durability are somewhat reduced. Therefore, according to a specific example of the present invention, the mass ratio of silver ions to zinc ions is preferably 1: (2 to 30) may be, for example, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1:22, 1:23, 1:24, 1:25, 1:26, 1:27, 1:28, 1:29, or 1: 30.
According to the specific embodiment of the invention, a certain content of organic antibacterial agent is added into the dual-ion composite antibacterial and dust-deposition-preventing material, so that the dual-ion composite antibacterial and dust-deposition-preventing material can achieve a synergistic antibacterial and mildew-preventing effect with the silver-zinc composite antibacterial agent, further the antibacterial effect is more durable, and the limitation of poor antibacterial durability of the existing antibacterial coating is effectively overcome. Specifically, the organic antibacterial agent may be at least one selected from SLM-04, quaternary ammonium salt antibacterial mildewcide, and biguanide antibacterial mildewcide. Thus, the mildew-proof performance can be further improved, and the inventor finds that the mechanical performance influence of the organic antibacterial agent on the material can be minimized. According to the specific embodiment of the invention, the amount of the organic antibacterial agent is 0.4-0.8 part by weight, so that the diionic composite antibacterial and dust-deposition-preventing material has a certain antibacterial effect and a certain mildew-proof effect by adding a proper amount of the organic antibacterial agent, and the antibacterial durability of the diionic composite antibacterial and dust-deposition-preventing material can be further remarkably improved. According to specific embodiments of the present invention, the organic antimicrobial agent may be preferably used in an amount of 0.5 to 0.7 parts by weight, for example, 0.5 parts by weight, 0.6 parts by weight, or 0.7 parts by weight.
According to some embodiments of the present invention, a certain amount of a long-acting antistatic agent is added to the above-mentioned dual-ion composite antibacterial and anti-dust-deposition material. And further, the dust accumulation on the surface of the fan blade caused by static electricity can be effectively reduced, so that the bacterial breeding is avoided. According to a specific embodiment of the present invention, the long-acting antistatic agent may specifically be at least one selected from the group consisting of antistatic agents TM, octadecyl diethanolamine, PEG, methyl acrylate, polyethylene oxide, and polyether ester amide. According to an embodiment of the present invention, the long-acting antistatic agent may be added in an amount of 1 to 35 parts by weight. The preferable addition amount can be 10-20 parts by weight, and by adopting the preferable addition amount, both the antistatic performance and the mechanical property of the modified material can be achieved. For example, the inventors have found that when the addition amount of the long-acting antistatic agent is too low, the material has poor anti-dust performance, whereas when the addition amount of the long-acting antistatic agent is too high, the mechanical properties of the material are easily reduced, and the material is easily subjected to fracture deformation. Therefore, the amount of the long-acting antistatic agent used is very important as an important component for modification and additional functions.
According to an embodiment of the present invention, the dispersant in the above formulation may be at least one selected from the group consisting of CH-10S, ST-278, polyethylene wax and stearic acid. This can further improve the dispersibility of the respective components, so that the respective components can be sufficiently mixed in the preparation process. Specifically, the dispersant may be used in an amount of 1 to 6 parts by weight. The amount of the dispersing agent is not too small or too much, if the amount is too small, the dispersing effect is not good, the antibacterial powder is in an aggregation state, and if the amount is too large, the aggregation phenomenon occurs again. The concentration of the dispersant used should comply with a dynamic equilibrium according to the actual situation. When the external conditions are changed, the equilibrium is broken and the nanoparticles agglomerate. When H in the dispersant and SiO in the antibacterial agent carrier2When the-OH of (A) is re-reacted to form a new surface chemical film, a new balance is reached so as to realize good dispersion. According to an embodiment of the present invention, the dispersant may be preferably used in an amount of 1 to 2%, for example, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, or 2.0%.
According to a specific embodiment of the present invention, the inorganic filler contained in the above formulation may be long glass fibers, which have been previously treated with a silane coupling agent. Thereby further improving the impact toughness, strength and hardness of the material. According to the specific embodiment of the invention, the usage amount of the long glass fiber can be 10-35 parts by weight, and since the antibacterial agent contained in the dual-ion composite antibacterial and dust-deposition-preventing material disclosed by the invention has influence on the mechanical property of the material, the influence can be effectively avoided by optimizing the usage amount of the long glass fiber, so that the dual-ion composite antibacterial and dust-deposition-preventing material has good mechanical property and also has better antibacterial and mildew-proof properties and dust-deposition-preventing properties. According to a specific example of the present invention, the long glass fiber may be preferably used in an amount of 15 to 30 parts by weight, for example, 15 parts by weight, 16 parts by weight, 174 parts by weight, 18 parts by weight, 19 parts by weight, 20 parts by weight, 21 parts by weight, 22 parts by weight, 23 parts by weight, 24 parts by weight, 25 parts by weight, 26 parts by weight, 27 parts by weight, 28 parts by weight, 29 parts by weight, or 30 parts by weight.
According to a specific embodiment of the invention, the dual-ion composite antibacterial and dust-deposition-preventing material further comprises 0.1-1 part by weight of an antioxidant, and the antioxidant is added to mainly prevent the material from being oxidized and degraded due to high temperature in the preparation process. Specifically, the antioxidant may be at least one selected from the group consisting of antioxidant 1010, antioxidant 168, and antioxidant 618. Thereby preventing the improvement of the antioxidant effect of the material during the preparation process.
According to the specific embodiment of the invention, the diionic composite antibacterial and dust-deposition-preventing material with the components and the proportion of the embodiment of the invention not only has good mechanical property, but also has better antibacterial and mildew-proof properties and dust-deposition-preventing properties. The dual-ion composite antibacterial dust-deposition-preventing material is tested under the conditions of a 2.75J pendulum and an A-type milling notch according to the requirements of GB/T1843, and the impact strength of the notch of the cantilever beam is measured to be more than 5.5kJ/m2(ii) a According to GB/T1040The test is carried out under the test condition of 50mm/min, the tensile strength is more than 105Mpa, and the elongation at break is more than 4.0%; the method is carried out according to the requirement of GB/T1634, and the heat distortion temperature is more than 95 ℃ when the test pressure is 1.80 MPa. In addition, the mildew-proof grade of the dual-ion composite antibacterial dust-deposition-preventing material can reach 0-1 grade, and the sterilization rate is not lower than 99 percent; the dust deposition prevention effect is reduced by more than 30 percent compared with the dust deposition amount of the common fan. Therefore, the composite antibacterial material can meet the requirement on the mechanical strength of the fan blade, and can be used for preparing the fan blade of the cross-flow fan of the indoor unit of the air conditioner, so that the fan blade has the advantages of antibiosis, mildew resistance and dust accumulation resistance. Therefore, the antibacterial coating is more convenient to use than the antibacterial coating, special equipment for the coating is not required for supporting, and the cost can be obviously saved compared with the antibacterial coating. In addition, the fan blade integrally has antibacterial mildew resistance and dust deposition resistance, the defect of incomplete coverage of an antibacterial coating can be overcome, the integral antibacterial mildew resistance is more durable, and the service life of the fan blade can be obviously prolonged.
According to another aspect of the invention, the invention further provides a fan, and according to an embodiment of the invention, fan blades of the fan are prepared from the dual-ion composite antibacterial and dust-deposition-preventing material described in the previous embodiment. From this, the fan flabellum that adopts the compound antibiotic deposition prevention material of dual ion to directly prepare not only has good mechanical properties, still has good antibiotic mould proof nature and deposition prevention advantage, and then can avoid piling up the phenomenon that breeds and go mildy of appearance bacterium because of the dust, and then effectively improve the clean health of air in the fan use, effectively avoid the fan to blow off the peculiar smell wind, seriously influence the indoor air quality, but also can avoid long-term use to arouse respiratory disease's possibility.
According to another aspect of the present invention, the present invention further provides an air conditioner, according to a specific embodiment of the present invention, an indoor unit cross flow fan of the air conditioner is prepared from the dual-ion composite antibacterial and anti-dust-deposition material described in the previous embodiment or directly adopts the fan of the previous embodiment. From this, this interior unit cross-flow fan has lasting antibiotic mould proof nature and prevents the deposition advantage, can avoid piling up the phenomenon that breeds and go mildy of appearance bacterium because of the dust, and then effectively improve the clean health of air in the air conditioner use, effectively avoid the air conditioner to blow off the peculiar smell wind, seriously influence the indoor air quality, but also can avoid long-term use to arouse respiratory disease's possibility. Therefore, the quality and the use health of the air conditioner can be remarkably improved by adopting the diion composite antibacterial dust-deposition-preventing material to prepare the internal machine cross-flow fan of the air conditioner, so that the requirements of vast consumers on health are met.
According to a further aspect of the present invention, the present invention also provides a method for preparing the diionic composite antibacterial and anti-dust material according to the previous embodiment, the method according to an embodiment of the present invention comprises: (1) adding a plastic substrate, a silver-zinc composite antibacterial agent, an organic antibacterial agent, a long-acting antistatic agent, a dispersing agent, an inorganic filler and an antioxidant into a single-screw or double-screw extruder according to a predetermined proportion, and heating and mixing to obtain a mixed material; (2) and cooling the mixed material to room temperature by water, drying and granulating so as to obtain the diionic composite antibacterial anti-dust material. Therefore, the dual-ion composite antibacterial and dust-deposition-preventing material can be effectively prepared by the method, and the method is simple in process, easy to implement and low in equipment requirement.
According to the specific embodiment of the present invention, in the step (1), the temperature for heating and mixing in the single-screw or twin-screw extruder is 190 to 240 ℃, preferably 210 to 220 ℃. The product performance is poor due to insufficient mixing of the product caused by too low temperature and too low material mixing speed; when the temperature is too high, the plastic base material and the organic antibacterial agent are degraded, the mechanical and thermal properties of the material are influenced, and meanwhile, the mildew resistance is reduced due to the decomposition of the organic antibacterial agent.
The cross-flow fan of the air conditioner indoor unit, which is made of the dual-ion composite antibacterial and dust-deposition-preventing material in the embodiment of the invention, has excellent antibacterial and mildew-proof performance, and simultaneously keeps the advantages of good mechanical property and static dust deposition prevention:
1. the mildew-proof grade is 0-1 grade, the degerming rate (escherichia coli and staphylococcus aureus) reaches 99% or more, and the detection is carried out according to the method specified in the standard GB 21551.2-2010.
2. The tensile strength is more than 105Mpa, the elongation at break is more than 4 percent, and the detection is carried out according to the method specified by GB/T1040 and the test condition of 50 mm/min.
The notch impact strength of the 3 cantilever beam is more than 5.5kJ/m2, and the test condition is 2.75J pendulum bob and A-type milling notch detection is carried out according to the requirement of GB/T1843.
4. The heat distortion temperature is higher than 95 ℃, the detection is carried out according to the GB/T1634 requirement, and the test pressure is 1.80 MPa.
5. Through the dust deposition prevention effect test, the dust deposition of the fan product prepared by the formula is reduced by more than or equal to 30 percent compared with that of an untreated product.
Example 1
The formula of the dual-ion composite antibacterial anti-dust material comprises the following components: the weight percentage is as follows: 64.6 percent of AS plastic base material, 1.5 percent of silver-zinc composite antibacterial agent, 0.4 percent of organic antibacterial agent, 1.1 percent of dispersing agent, 30 percent of inorganic filler, 0.4 percent of antioxidant and 2 percent of long-acting antistatic agent.
Wherein the silver-zinc antibacterial agent is a silver-zinc antibacterial agent taking zeolite as a carrier, the weight ratio of silver to zinc ions is 0.4:3.8, and the silver ions are added in sequence after the zinc ions are added;
the organic antibacterial agent is SLM-04, produced by Dongguan triple chemical Co., Ltd, Guangdong province;
the dispersant is CH-10S;
the inorganic filler is long glass fiber treated by silane coupling agent KH-550;
the antioxidant is antioxidant 618, produced by the Gilg group Fine Chemicals Co., Ltd;
the antistatic agent is an antistatic agent TM, and is produced by Shanghai Jinshan Longitude and Longitude chemical Co.
And adding the proportioned materials into a double-screw extruder, heating, stirring and mixing, fully stirring and mixing by a screw, cooling and granulating to obtain the antibacterial and mildewproof fan material granules. The granules can be used for producing the same injection molding equipment, mold and tool of a common fan, and are subjected to injection molding to prepare the anti-bacterial and dust-deposition-preventing cross-flow fan product of the air conditioner indoor unit.
Example 2
The formula of the dual-ion composite antibacterial anti-dust material comprises the following components: the weight percentage is as follows: 61.7 percent of AS plastic base material, 2 percent of silver-zinc antibacterial agent, 0.5 percent of organic antibacterial agent, 1.3 percent of dispersing agent, 20 percent of inorganic filler, 0.5 percent of antioxidant and 15 percent of long-acting antistatic agent.
Wherein the silver-zinc antibacterial agent is a silver-zinc antibacterial agent taking water-soluble glass as a carrier, the weight ratio of silver to zinc ions is 0.7:2.3, and the silver ions are added in sequence after the zinc ions are added;
the organic antibacterial agent is SLM-04, produced by Dongguan triple chemical Co., Ltd, Guangdong province;
the dispersant is CH-10S;
the inorganic filler is long glass fiber treated by silane coupling agent KH-550;
the antioxidant is antioxidant 1010, produced by Cheng Guang Chemicals Co., Ltd, Tianjin;
the long-acting antistatic agent is polyethylene oxide, produced by DuPont corporation, usa.
And adding the proportioned materials into a double-screw extruder, heating, stirring and mixing, fully stirring and mixing by a screw, cooling and granulating to obtain the antibacterial and mildewproof fan material granules. The granules can be used for producing the same injection molding equipment, mold and tool of a common fan, and are subjected to injection molding to prepare the anti-bacterial and dust-deposition-preventing cross-flow fan product of the air conditioner indoor unit.
Example 3
The formula of the dual-ion composite antibacterial anti-dust material comprises the following components: the weight percentage is as follows: 67.5% of AS plastic base material, 3% of silver-zinc antibacterial agent, 0.8% of organic antibacterial agent, 1.7% of dispersion, 15% of inorganic filler, 2% of antioxidant and 10% of long-acting antistatic agent.
Wherein the silver-zinc antibacterial agent is a silver-zinc antibacterial agent taking zeolite as a carrier, and the weight ratio of silver ions to zinc ions is 0.5: 5.6, adding silver first and then zinc;
the organic antibacterial agent is SLM-04, produced by Dongguan triple chemical Co., Ltd, Guangdong province;
the dispersant is ST-278;
the inorganic filler is long glass fiber treated by silane coupling agent KH-550;
the antioxidant is antioxidant 1010, produced by Cheng Guang Chemicals Co., Ltd, Tianjin;
the long-acting antistatic agent is PEG, and is produced by Arkema France.
And adding the proportioned materials into a double-screw extruder, heating, stirring and mixing, fully stirring and mixing by a screw, cooling and granulating to obtain the antibacterial and mildewproof fan material granules. The granules can be used for producing the same injection molding equipment, mold and tool of a common fan, and are subjected to injection molding to prepare the anti-bacterial and dust-deposition-preventing cross-flow fan product of the air conditioner indoor unit.
Comparative example 1
The formula of the dual-ion composite antibacterial anti-dust material comprises the following components: the weight percentage is as follows: 72.7 percent of AS plastic base material, 4 percent of silver-zinc composite antibacterial agent, 0.8 percent of organic antibacterial agent (SLM-04), 1.5 percent of dispersing agent (CH-10S), 20 percent of inorganic filler (long glass fiber), 0.5 percent of antioxidant (antioxidant 618) and 0.5 percent of antistatic agent (antistatic agent TM).
The silver-zinc composite antibacterial agent is a silver-zinc antibacterial agent taking zeolite as a carrier, wherein the weight ratio of silver ions to zinc ions is 1:120, and the silver-zinc composite antibacterial agent is prepared by adding silver first and zinc later in sequence; the organic antibacterial agent is SLM-04, produced by Dongguan triple chemical Co., Ltd, Guangdong province; the dispersant is CH-10S; the inorganic filler is long glass fiber treated by a silane coupling agent KH-550; the antioxidant is antioxidant 618, produced by the Gilg group Fine Chemicals Co., Ltd.
The preparation method comprises the following steps: adding the raw materials into a double-screw extruder, heating to 210 ℃, and stirring and mixing to obtain a mixed material; and (4) cooling with water, drying with a blower, and granulating to obtain the diionic composite antibacterial material.
The product of the cross-flow fan of the indoor unit of the air conditioner is prepared by injection molding by using the same injection molding equipment, mold and tool for producing common fans by using the dual-ion composite antibacterial material.
Comparative example 2
The formula of the dual-ion composite antibacterial anti-dust material comprises the following components: the weight percentage is as follows: 47.5% of AS plastic base material, 15% of silver-zinc composite antibacterial agent, 3% of organic antibacterial agent (SLM-04), 4.5% of dispersing agent (CH-10S), 18% of inorganic filler (long glass fiber), 2% of antioxidant (antioxidant 1010) and 10% of long-acting antistatic agent (PEG).
The silver-zinc composite antibacterial agent is a silver-zinc antibacterial agent taking zeolite as a carrier, wherein the weight ratio of silver ions to zinc ions is 2:1, and the silver-zinc composite antibacterial agent is prepared by adding silver first and zinc later in sequence; the organic antibacterial agent is SLM-04, produced by Dongguan triple chemical Co., Ltd, Guangdong province; the dispersant is CH-10S; the inorganic filler is long glass fiber treated by a silane coupling agent KH-550; the antioxidant is antioxidant 1010, produced by Cheng photochemistry Co., Ltd, Tianjin.
The preparation method comprises the following steps: adding the raw materials into a double-screw extruder, heating to 210 ℃, and stirring and mixing to obtain a mixed material; and (4) cooling with water, drying with a blower, and granulating to obtain the diionic composite antibacterial material.
The product of the cross-flow fan of the indoor unit of the air conditioner is prepared by injection molding by using the same injection molding equipment, mold and tool for producing common fans by using the dual-ion composite antibacterial material.
Evaluation: the anti-bacterial property, anti-mildew property and mechanical property of the cross flow fan products of the air conditioner internal unit prepared in the examples 1-3 and the comparative examples 1-2 are respectively tested. Wherein the sterilization rate and the mildew-proof grade are detected according to the specified method of GB 21551.2-2010; the impact strength is detected according to a specified method of GB/T1843 under the test condition of a 2.75J pendulum and an A-type milling notch; the tensile strength and the elongation at break were measured under the test conditions of 50mm/min by the method specified in GB/T1040. The heat distortion temperature is carried out according to the GB/T1634 requirement, and the testing pressure is 1.80 MPa. The anti-dust effect is measured by the following method: the fan is placed in a tool clamp in a 1m x 1m x 1m sealed dust box, and the fan rotates at the speed of 1300-1400 r/min to simulate the actual operation condition of the conventional fan. And adding 10g of kaolin, wall ash and other dust into the dust adding pipe every 1h, and blowing the dust at the speed of 1-4 m/s to perform accelerated experiment simulation of fan dust environment operation. The experiment was performed for one week. And after the experiment is finished, collecting the dust deposition weight of the fan blade, comparing the dust deposition weight with the dust deposition weight of the fan without the anti-static treatment, and calculating the reduction percentage of the treated dust deposition amount. The results are shown in Table 1.
TABLE 1
| Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | |
| Percent bacteria removal (%) | 99％ | 99％ | 99％ | 98％ | 99％ |
| Mildew resistance rating | 1 | 1 | 1 | 1 | 1 |
| Impact strength (kJ/m2) | 6.76 | 6.07 | 5.63 | 5.26 | 4.13 |
| Tensile strength (Mpa) | 124.33 | 113.87 | 111.69 | 100.26 | 90.34 |
| Elongation at Break (%) | 7.12 | 6.54 | 6.40 | 5.33 | 4.98 |
| Heat distortion temperature | 100.55 | 100.21 | 99.65 | 97.45 | 92.55 |
| Dust deposition reduction rate | 31.2％ | 38.6％ | 36.5％ | 15％ | 33.0％ |
And (4) conclusion: as can be seen from the above test results, the fan prepared in comparative example 1 has a lower sterilization rate, mechanical properties, heat distortion temperature and dust deposition preventing effect than those of examples 1 to 3. Analysis shows that in the formula of the comparative example 1, the antibacterial effect of the fan is not ideal because the silver-zinc ratio is too small and the silver ion content is too small; meanwhile, the long-acting antistatic agent is too little in dosage, so that the anti-dust effect is poor; in addition, the small decrease in mechanical properties and heat distortion temperature of comparative example 1 compared with those of examples 1-2 is due to the fact that the content of the inorganic antibacterial agent exceeds the required range, and the small decrease has little influence on the mechanical and thermal properties of the material.
The fan prepared in comparative example 2 mainly has the defect of poor mechanical performance, and analysis is mainly that the mechanical performance of the fan product is poor due to the fact that the proportion of the material is too small because the plastic base material is used too little and the antibacterial, mildewproof and oxidation-resistant materials are used too much.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.
Claims (12)
1. The utility model provides a two ion composite antibiotic anti-dust material for cross flow fan of air conditioner indoor unit which characterized in that includes:
60-90 parts by weight of a plastic base material;
0.1-3 parts by weight of a silver-zinc composite antibacterial agent;
0.4-0.8 weight parts of organic antibacterial agent;
1-35 parts by weight of a long-acting antistatic agent;
1-6 parts by weight of a dispersant;
10-35 parts by weight of an inorganic filler; and
0.1 to 1 part by weight of an antioxidant.
2. The diionic composite antibacterial and dust-deposition-preventing material AS claimed in claim 1, wherein said plastic substrate is AS.
3. The diionic composite antibacterial and dust-deposition preventing material as claimed in claim 1, wherein said silver-zinc composite antibacterial agent is an antibacterial agent formed by loading silver ions and zinc ions on zeolite, water-soluble glass or calcium phosphate.
4. The diionic composite antibacterial and dust-deposition-preventing material as claimed in claim 3, wherein the mass ratio of silver ions to zinc ions in the silver-zinc composite antibacterial agent is 1: (0.1-100).
5. The diionic composite antibacterial and dust-deposition-preventing material as claimed in claim 1, wherein said organic antibacterial agent is at least one selected from the group consisting of SLM-04, quaternary ammonium salt antibacterial and mildewproof agents and biguanide antibacterial and mildewproof agents.
6. The diionic composite antibacterial and anti-dust material as claimed in claim 1, wherein said long-acting antistatic agent is at least one selected from the group consisting of antistatic agents TM, octadecyl diethanolamine, PEG, methyl acrylate, polyethylene oxide and polyether ester amide.
7. The diionic composite antibacterial and dust-deposition preventing material as claimed in claim 1, wherein said dispersant is at least one selected from the group consisting of CH-10S, ST-278, polyethylene wax and stearic acid.
8. The diionic composite antibacterial and dust-deposition-preventing material as claimed in claim 1, wherein said inorganic filler is a long glass fiber, and said long glass fiber is previously treated with a silane coupling agent.
9. The diionic composite antibacterial dust-deposition preventing material as claimed in claim 1, wherein said antioxidant is at least one selected from the group consisting of antioxidant 1010, antioxidant 168 and antioxidant 618.
10. A fan, wherein the fan blades are made of the diion composite antibacterial and dust-deposition-preventing material as claimed in claims 1-9.
11. An air conditioner characterized in that it comprises the fan of claim 10.
12. A method for preparing the diionic composite antibacterial and anti-dust material as defined in any one of claims 1 to 9, which comprises:
(1) adding a plastic substrate, a silver-zinc composite antibacterial agent, an organic antibacterial agent, a long-acting antistatic agent, a dispersing agent, an inorganic filler and an antioxidant into a single-screw or double-screw extruder according to a predetermined proportion, and heating and mixing to obtain a mixed material;
(2) and cooling the mixed material to room temperature by water, drying and granulating so as to obtain the diionic composite antibacterial anti-dust material.
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Application publication date: 20210413 |