CN112646141A - Flame-retardant aromatic liquid crystal copolyester and preparation method thereof - Google Patents

Flame-retardant aromatic liquid crystal copolyester and preparation method thereof Download PDF

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CN112646141A
CN112646141A CN202011502413.1A CN202011502413A CN112646141A CN 112646141 A CN112646141 A CN 112646141A CN 202011502413 A CN202011502413 A CN 202011502413A CN 112646141 A CN112646141 A CN 112646141A
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flame
aromatic liquid
liquid crystal
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刘萍
陈导
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Shanghai Sitao New Material Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C08G63/605Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds the hydroxy and carboxylic groups being bound to aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91Polymers modified by chemical after-treatment
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91Polymers modified by chemical after-treatment
    • C08G63/914Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916Dicarboxylic acids and dihydroxy compounds
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
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    • C09K19/3804Polymers with mesogenic groups in the main chain
    • C09K19/3809Polyesters; Polyester derivatives, e.g. polyamides

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Abstract

The invention discloses a flame-retardant aromatic liquid crystal copolyester which comprises a main chain, a main chain and a side chain, wherein the main chain is formed by copolymerizing rigid mesomorphic elements and polyester granules, and end-sealing groups are phenylacetylene or norbornene acetylene groups; the mesogen element is composed of a full aromatic diphenol monomer, a full aromatic diacid monomer and an AB type full aromatic monomer containing a terminal carboxyl group A and a terminal hydroxyl group B; the wholly aromatic diphenol monomer is hydroquinone; the wholly aromatic diacid monomers are 1, 4-terephthalic acid and 2, 6-naphthalene dicarboxylic acid; meanwhile, the AB type wholly aromatic monomer containing the terminal carboxyl A and the terminal hydroxyl B is 6-hydroxy-2-naphthoic acid. The flame-retardant aromatic liquid crystal copolyester has lower melting processing temperature and flame-retardant anti-dripping performance, can effectively reduce life and property losses caused by fire, has wide application prospect in the fields of civil textiles and high-temperature protective materials, has controllable molecular weight in the polymerization process, is simpler, more efficient and environment-friendly in preparation process, and does not generate harmful gas during combustion.

Description

Flame-retardant aromatic liquid crystal copolyester and preparation method thereof
Technical Field
The invention relates to the field of high polymer materials, in particular to flame-retardant aromatic liquid crystal copolyester and a preparation method thereof.
Background
The semi-aromatic polyester is used as a high polymer material with wide application, and has wide application in civil and industrial aspects due to the characteristics of high strength, high modulus and low water absorption. Polyester fiber, also known as terylene, occupies most of the share of chemical fiber industry. The class of polyesters that are marketed includes PET, PBT, PTT, and the like. As the polymer can be oxidized and degraded at high temperature, once the polymer is burnt, fire is easily formed, and the life and property safety of people can be seriously influenced. Therefore, the flame retardant property of the polyester material is improved, and the flame retardant property has great significance.
The patent CN107938014A discloses a preparation method of a flame-retardant thermotropic polyarylate liquid crystal fiber, wherein a thermotropic liquid crystal polyarylate slice is obtained by introducing a phosphorus-containing aromatic unit into a main chain, the slice is spun into filaments by melt extrusion, and finally the flame-retardant thermotropic polyarylate liquid crystal fiber is prepared by post-treatment. The process flow is simple, the fiber has good flame retardant effect, but white smoke and molten drops can be generated during combustion due to the phosphorus flame retardant. Therefore, in order to reduce the dripping of the flame-retardant polyester fiber and the harm to human body, research on a novel phosphorus-free flame-retardant polyester material is urgently needed. On the other hand, if the main chain of the liquid crystalline polyarylate is a rigid linear structure, it needs to be melted at a high temperature (300 ℃ or higher) to be molded, and the liquid crystalline polyarylate monomer is relatively expensive, which further increases the production cost.
Disclosure of Invention
The present invention has been made to solve the above problems, and an object of the present invention is to provide a flame retardant aromatic liquid crystal copolyester having low melting point, anti-dripping property, and no harmful gas generation during combustion, and a method for preparing the same.
The purpose of the invention is realized as follows:
the flame-retardant aromatic liquid crystal copolyester comprises a main chain, a main chain and a side chain, wherein the main chain is formed by copolymerizing rigid mesomorphic elements and polyester granules, and end-sealing groups are phenylacetylene or norbornene acetylene groups; the mesogen element is composed of a full aromatic diphenol monomer, a full aromatic diacid monomer and an AB type full aromatic monomer containing a terminal carboxyl group A and a terminal hydroxyl group B;
the wholly aromatic diphenol monomer is hydroquinone; the wholly aromatic diacid monomers are 1, 4-terephthalic acid and 2, 6-naphthalene dicarboxylic acid; meanwhile, the AB type wholly aromatic monomer containing the terminal carboxyl A and the terminal hydroxyl B is 6-hydroxy-2-naphthoic acid.
The polyester particles in the flame-retardant aromatic liquid crystal copolyester are one or more of polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.
The phenylacetylene or norbornene acetylene group in the flame-retardant aromatic liquid crystal copolyester is one or more of the following compounds:
Figure BDA0002843834200000021
wherein Y is amino or imino; z is hydroxyl, carboxyl, ester group or carbonyl.
The polyester particles in the flame-retardant aromatic liquid crystal copolyester are polybutylene terephthalate;
the end capping group is
Figure BDA0002843834200000022
Wherein Y is amino and Z is carboxyl.
The structural formula of the flame-retardant aromatic liquid crystal copolyester in the flame-retardant aromatic liquid crystal copolyester is as follows:
Figure BDA0002843834200000023
wherein m is 90-100, and n is 2-20.
The molecular weight of the flame-retardant aromatic liquid crystal copolyester in the flame-retardant aromatic liquid crystal copolyester is 1000-10000 g/mol.
The invention provides a preparation method of flame-retardant aromatic liquid crystal copolyester, which comprises the following steps:
(1) adding a hydroquinone monomer, terephthalic acid, 2, 7-naphthalenedicarboxylic acid, 6-hydroxy-2-naphthoic acid, polyester particles, a compound containing phenylacetylene or norbornene acetylene groups, acetic anhydride and a catalyst in a molar ratio of 10-40: 80-20: 100-500: 2-8 into a reactor; performing acetylation reaction for 30-60 min under the protection of inert gas at the temperature of 120-150 ℃;
(2) heating to 300-340 ℃ at a heating rate of 0.5-1.5 ℃/min, and carrying out ester exchange reaction for 1-3 h;
(3) reacting for 10-30 min at 300-320 ℃ and under the condition that the vacuum degree is 1-3 mbar;
(4) and (3) cooling to room temperature in an inert gas atmosphere, grinding the product obtained in the step (3) into powder, and performing post-polycondensation reaction for 18-36 h under the conditions that the temperature is 200-260 ℃ and the vacuum degree is 1-3 mbar.
In the preparation method of the flame-retardant aromatic liquid crystal copolyester, the catalyst is one or more of sodium acetate, potassium acetate, zinc acetate, antimony trioxide, tetrabutyl titanate and germanium dioxide.
In the preparation method of the flame-retardant aromatic liquid crystal copolyester, the mass of the catalyst is 0.1-0.5% of the total mass of all raw materials;
in the preparation method of the flame-retardant aromatic liquid crystal copolyester, the molar weight of acetic anhydride is more than the total molar weight of hydroxyl in a full aromatic diphenol monomer, a full aromatic diacid monomer, an AB type full aromatic monomer containing a terminal carboxyl group A and a terminal hydroxyl group B, polyester particles and a compound containing phenylacetylene or norbornene acetylene groups.
The preparation method of the flame-retardant aromatic liquid crystal copolyester comprises the following steps:
(1) adding hydroquinone, terephthalic acid, 2, 7-naphthalenedicarboxylic acid, 6-hydroxy-2-naphthoic acid, PBT particles, 3-ethynylaniline, 2- (3-ethynylphenyl) -1, 3-dioxoisoindole-5-carboxylic acid and 160 ml of acetic anhydride and 0.3 wt% of zinc acetate as a catalyst in a molar ratio of 20:16:4:60:500:2:2, and acetylating the reaction mixture in a fluid sand bath at 150 ℃ for 60min by introducing a moderate nitrogen flow through a sealed glass paddle stirrer equipped in a flask;
(2) heating to 320 ℃ at the heating rate of 1.5 ℃/min to perform ester exchange reaction for 3 h;
(3) slowly vacuumizing the reaction system, and keeping the vacuum degree at 3mbar and the temperature at 320 ℃ for 30 min;
(4) and (4) cooling the opaque melt obtained in the step (3) to room temperature, removing the product from the flask, grinding the product into fine powder, and carrying out solid-state polycondensation reaction for 18 hours at the temperature of 200 ℃ and the vacuum degree of 1 mbar.
Naphthalene monomers are introduced into a molecular chain of the flame-retardant aromatic liquid crystal copolyester material copolymer to destroy the linearity of the main chain, the molecular chain is in a semi-aromatic structure and has a lower melting processing temperature compared with a straight-chain fully aromatic liquid crystal material, on the other hand, two ends of the molecular chain are blocked by active groups which can be thermally cured, such as phenylacetylene or norbornene acetylene, and the like, and can undergo cycloaddition reaction to form a solidified cross-linked network structure under a high-temperature environment (350-plus-500 ℃) during combustion, and the cross-linked network structure has certain coating capability during the formation process and can effectively reduce the molten drop phenomenon during combustion.
Compared with the prior art, the invention has the following technical effects:
(1) the macromolecular chain of the flame-retardant aromatic liquid crystal copolyester material is in a semi-aromatic structure and has lower melting processing temperature, and a cross-linked network structure formed after the active end group is introduced for thermosetting reaction has excellent flame-retardant and anti-dripping performance, so that the life and property loss caused by fire can be effectively reduced, and the flame-retardant aromatic liquid crystal copolyester material has wide application prospect in the fields of civil textiles and high-temperature protective materials.
(2) The flame-retardant aromatic liquid crystal copolyester has controllable molecular weight in the polymerization process, and can be obtained into materials with different molecular weights according to requirements.
(3) The flame-retardant aromatic liquid crystal copolyester prepared by the invention does not contain any solvent, no small molecules are generated in the curing process, thermotropic liquid crystal polyarylate plates and fibers can be prepared by hot pressing or melt spinning, and the solvent is not required to be removed in the process, so that the preparation process is simpler, more efficient and more environment-friendly;
(4) the flame-retardant aromatic liquid crystal copolyester prepared by the invention does not contain a phosphorus flame retardant, so that harmful gas is not generated during combustion.
Drawings
FIG. 1 is a DSC chart of example 1 and comparative examples 1-2.
Detailed Description
The invention will be further explained with reference to the drawings.
The starting materials used in example 1 and comparative examples 1-2 below were purchased from Shanghai Bailingwei chemical technology, Inc., 100 g/bottle, and had a purity of > 98%.
Example 1
The flame-retardant aromatic liquid crystal copolyester of the embodiment has the following chemical structural formula:
Figure BDA0002843834200000041
wherein n is 2-20, and m is 90-100;
in a 250 ml three-necked round bottom flask, hydroquinone, terephthalic acid, 2, 7-naphthalenedicarboxylic acid, 6-hydroxy-2-naphthoic acid, PBT pellets, 3-ethynylaniline, 2- (3-ethynylphenyl) -1, 3-dioxoisoindole-5-carboxylic acid, 160 ml of acetic anhydride and 0.3 wt% of zinc acetate as catalyst were added in a molar ratio of 20:16:4:60:500:2: 2. The flask was fitted with a sealed glass paddle stirrer, a nitrogen inlet and an insulated distillation head. The reaction mixture was acetylated at 150 ℃ for 60min in a fluid sand bath with a moderate nitrogen flow and then raised to 320 ℃ at a heating rate of 1.5 ℃/min for 3h transesterification. At this time, the reaction system was slowly evacuated to a vacuum of 3mbar and a temperature of 320 ℃ for 30 min. The opaque melt was cooled to room temperature and the product was removed from the flask and ground to a fine powder. The sample of the present example was obtained by solid state polycondensation at 200 ℃ and a vacuum of 1mbar for 18 hours.
Comparative example 1
4, 4' -dihydroxybiphenyl, terephthalic acid, 2, 6-naphthalenedicarboxylic acid, p-hydroxybenzoic acid, N- (3-carboxyphenyl) -4-phenylethynylphthalimide, N- (3-hydroxyphenyl) -4-phenylethynylphthalimide, as well as 150 ml of acetic anhydride and 0.1 wt% potassium acetate were added in a 250 ml three-necked round bottom flask in a molar ratio of 10:8:2:80:8: 8. The flask was fitted with a sealed glass paddle stirrer, a nitrogen inlet and an insulated distillation head. The reaction mixture was acetylated at 140 ℃ for 40min in a fluid sand bath with a moderate nitrogen flow and then raised to 300 ℃ at a heating rate of 0.5 ℃/min for 2h transesterification. At this time, the reaction system was slowly evacuated to a vacuum of 2mbar and a temperature of 310 ℃ for 20 min. The opaque melt was cooled to room temperature and the product was removed from the flask and ground to a fine powder. Performing solid state polycondensation reaction for 24 hours at 230 ℃ and under the vacuum degree of 2mbar to obtain a target product with the chemical formula as follows:
Figure BDA0002843834200000051
comparative example 2
4, 4' -dihydroxybiphenyl, bis (p-carboxyphenyl) phenylphosphinate, 2, 6-naphthalenedicarboxylic acid, p-hydroxybenzoic acid, 150 ml acetic anhydride and 0.1% by weight potassium acetate were added in a 250 ml three-necked round bottom flask in a molar ratio of 10:8:2: 80. The flask was fitted with a sealed glass paddle stirrer, a nitrogen inlet and an insulated distillation head. The reaction mixture was acetylated at 140 ℃ for 40min in a fluid sand bath with a moderate nitrogen flow and then raised to 300 ℃ at a heating rate of 0.5 ℃/min for 2h transesterification. At this time, the reaction system was slowly evacuated to a vacuum of 2mbar and a temperature of 310 ℃ for 20 min. The opaque melt was cooled to room temperature and the product was removed from the flask and ground to a fine powder. Performing solid state polycondensation reaction for 24 hours at 230 ℃ and under the vacuum degree of 2mbar to obtain a target product with the chemical formula as follows:
Figure BDA0002843834200000061
performance testing
The thermal properties of the product were tested by Differential Scanning Calorimetry (DSC) and thermogravimetric analysis (TGA), and its flame retardant properties were determined by testing the vertical burning of the product while the intrinsic viscosity, thermal properties and flame retardant properties and the results of the intrinsic viscosity tests are shown in tables 1 and 2, respectively:
TABLE 1 results of the differential scanning calorimetry
Figure BDA0002843834200000062
TABLE 2 thermogravimetric analysis test results
Figure BDA0002843834200000063
The DSC curves of comparative examples 1-2 and example 1 are shown in FIG. 1.
As can be seen from fig. 1 and table 1, the melting point of the pure thermotropic liquid crystal high polymer of comparative example 1 is 267 ℃, the melting point of the pure thermotropic liquid crystal high polymer of comparative example 2 is 270 ℃, and the melting point of the copolymer of example 1 is lower than that of comparative examples 1-2 and PET (Tm is 250-260 ℃), which can reduce the molding production cost of the copolyester material to some extent; meanwhile, the thermal decomposition temperature Td 5% of the liquid crystal copolyester is above 370 ℃, and the liquid crystal copolyester has high thermal stability.
The above embodiments are provided only for illustrating the present invention and not for limiting the present invention, and those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention, and therefore all equivalent technical solutions should also fall within the scope of the present invention, and should be defined by the claims.

Claims (10)

1. The flame-retardant aromatic liquid crystal copolyester is characterized by comprising a main chain which is formed by copolymerizing rigid mesomorphic elements and polyester granules, wherein end-sealing groups are phenylacetylene groups or norbornene acetylene groups; the mesogen element is composed of a full aromatic diphenol monomer, a full aromatic diacid monomer and an AB type full aromatic monomer containing a terminal carboxyl A and a terminal hydroxyl B;
the wholly aromatic diphenol monomer is hydroquinone; the wholly aromatic diacid monomers are 1, 4-terephthalic acid and 2, 6-naphthalene dicarboxylic acid; the AB type wholly aromatic monomer containing both the terminal carboxyl group A and the terminal hydroxyl group B is 6-hydroxy-2-naphthoic acid.
2. The flame retardant aromatic liquid crystalline copolyester of claim 1, wherein the polyester particles are one or more of polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.
3. The flame retardant aromatic liquid crystalline copolyester of claim 1 or 2, wherein the phenylacetylene or norbornenyl acetylene group is one or more of the following compounds:
Figure FDA0002843834190000011
wherein Y is amino or imino; z is hydroxyl, carboxyl, ester group or carbonyl.
4. The flame retardant aromatic liquid crystalline copolyester of claim 1, wherein the polyester particles are polybutylene terephthalate;
the end capping group is
Figure FDA0002843834190000012
Wherein Y is amino and Z is carboxyl.
5. The flame retardant aromatic liquid crystalline copolyester of claim 4, wherein the structural formula of the flame retardant aromatic liquid crystalline copolyester is as follows:
Figure FDA0002843834190000021
wherein m is 90-100, and n is 2-20.
6. The flame retardant aromatic liquid crystalline copolyester of any one of claims 1 to 5, wherein the molecular weight of the flame retardant aromatic liquid crystalline copolyester is 1000 to 10000 g/mol.
7. The method for preparing flame retardant aromatic liquid crystal copolyester according to claim 1, comprising the steps of:
(1) adding a hydroquinone monomer, terephthalic acid, 2, 7-naphthalenedicarboxylic acid, 6-hydroxy-2-naphthoic acid, polyester particles, a compound containing phenylacetylene or norbornene acetylene groups, acetic anhydride and a catalyst in a molar ratio of 10-40: 80-20: 100-500: 2-8 into a reactor; performing acetylation reaction for 30-60 min under the protection of inert gas at the temperature of 120-150 ℃;
(2) heating to 300-340 ℃ at a heating rate of 0.5-1.5 ℃/min, and carrying out ester exchange reaction for 1-3 h;
(3) reacting for 10-30 min at 300-320 ℃ and under the condition that the vacuum degree is 1-3 mbar;
(4) and (3) cooling to room temperature in an inert gas atmosphere, grinding the product obtained in the step (3) into powder, and performing post-polycondensation reaction for 18-36 h under the conditions that the temperature is 200-260 ℃ and the vacuum degree is 1-3 mbar.
8. The preparation method of the flame-retardant aromatic liquid crystal copolyester as claimed in claim 7, wherein the catalyst is one or more of sodium acetate, potassium acetate, zinc acetate, antimony trioxide, tetrabutyl titanate and germanium dioxide, and/or the mass of the catalyst is 0.1-0.5% of the total mass of all raw materials;
9. the method of claim 7, wherein the molar amount of acetic anhydride is greater than the total molar amount of hydroxyl groups in the wholly aromatic diphenol monomer, the wholly aromatic diacid monomer, the AB-type wholly aromatic monomer containing both terminal carboxyl groups A and terminal hydroxyl groups B, the polyester particles, the compound containing phenylacetylene or norbornene acetylene groups.
10. The method for preparing flame retardant aromatic liquid crystal copolyester according to claim 7, comprising the steps of:
(1) adding hydroquinone, terephthalic acid, 2, 7-naphthalenedicarboxylic acid, 6-hydroxy-2-naphthoic acid, PBT particles, 3-ethynylaniline, 2- (3-ethynylphenyl) -1, 3-dioxoisoindole-5-carboxylic acid and 160 ml of acetic anhydride and 0.3 wt% of zinc acetate as a catalyst in a molar ratio of 20:16:4:60:500:2:2, and acetylating the reaction mixture in a fluid sand bath at 150 ℃ for 60min by introducing a moderate nitrogen flow through a sealed glass paddle stirrer equipped in a flask;
(2) heating to 320 ℃ at the heating rate of 1.5 ℃/min to perform ester exchange reaction for 3 h;
(3) slowly vacuumizing the reaction system, and keeping the vacuum degree at 3mbar and the temperature at 320 ℃ for 30 min;
(4) and (4) cooling the opaque melt obtained in the step (3) to room temperature, removing the product from the flask, grinding the product into fine powder, and carrying out solid-state polycondensation reaction for 18 hours at the temperature of 200 ℃ and the vacuum degree of 1 mbar.
CN202011502413.1A 2020-12-17 2020-12-17 Flame-retardant aromatic liquid crystal copolyester and preparation method thereof Pending CN112646141A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI823776B (en) * 2023-02-15 2023-11-21 長春人造樹脂廠股份有限公司 Liquid crystal polymer resin and formed material comprising the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04225021A (en) * 1990-12-27 1992-08-14 Toray Ind Inc Production of liquid crystal polyester
CN102153738A (en) * 2010-12-29 2011-08-17 浙江超维新材料有限公司 Preparation method of polyester liquid crystal polymer and product thereby
CN107793585A (en) * 2017-10-30 2018-03-13 苏州大学 A kind of liquid crystal flame-retardant foam material and preparation method thereof
CN112250848A (en) * 2020-09-28 2021-01-22 浙江恒澜科技有限公司 Thermotropic flame-retardant anti-dripping aromatic liquid crystal copolyester material and preparation method thereof
CN112574402A (en) * 2020-12-17 2021-03-30 上海思涛新材料科技有限公司 Thermotropic anti-droplet aromatic liquid crystal copolyester and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04225021A (en) * 1990-12-27 1992-08-14 Toray Ind Inc Production of liquid crystal polyester
CN102153738A (en) * 2010-12-29 2011-08-17 浙江超维新材料有限公司 Preparation method of polyester liquid crystal polymer and product thereby
CN107793585A (en) * 2017-10-30 2018-03-13 苏州大学 A kind of liquid crystal flame-retardant foam material and preparation method thereof
CN112250848A (en) * 2020-09-28 2021-01-22 浙江恒澜科技有限公司 Thermotropic flame-retardant anti-dripping aromatic liquid crystal copolyester material and preparation method thereof
CN112574402A (en) * 2020-12-17 2021-03-30 上海思涛新材料科技有限公司 Thermotropic anti-droplet aromatic liquid crystal copolyester and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI823776B (en) * 2023-02-15 2023-11-21 長春人造樹脂廠股份有限公司 Liquid crystal polymer resin and formed material comprising the same

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